USGS Science⌕ Search
Home/Archive/USGS

USGS · 70028307

Multiple injected and natural conservative tracers quantify mixing in a stream confluence affected by acid mine drainage near Silverton, Colorado

L. E. Schemel·M.H. Cox·R.L. Runkel·B. A. Kimball
View original source ↗Export metadata ↓

Abstract

The acidic discharge from Cement Creek, containing elevated concentrations of dissolved metals and sulphate, mixed with the circumneutral-pH Animas River over a several hundred metre reach (mixing zone) near Silverton, CO, during this study. Differences in concentrations of Ca, Mg, Si, Sr, and SO42- between the creek and the river were sufficiently large for these analytes to be used as natural tracers in the mixing zone. In addition, a sodium chloride (NaCl) tracer was injected into Cement Creek, which provided a Cl- 'reference' tracer in the mixing zone. Conservative transport of the dissolved metals and sulphate through the mixing zone was verified by mass balances and by linear mixing plots relative to the injected reference tracer. At each of seven sites in the mixing zone, five samples were collected at evenly spaced increments of the observed across-channel gradients, as determined by specific conductance. This created sets of samples that adequately covered the ranges of mixtures (mixing ratios, in terms of the fraction of Animas River water, %AR). Concentrations measured in each mixing zone sample and in the upstream Animas River and Cement Creek were used to compute %AR for the reference and natural tracers. Values of %AR from natural tracers generally showed good agreement with values from the reference tracer, but variability in discharge and end-member concentrations and analytical errors contributed to unexpected outlier values for both injected and natural tracers. The median value (MV) %AR (calculated from all of the tracers) reduced scatter in the mixing plots for the dissolved metals, indicating that the MV estimate reduced the effects of various potential errors that could affect any tracer.

Explore related subjects

Hydrological ProcessesArticle

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

L. E. Schemel, M.H. Cox, R.L. Runkel, B. A. Kimball. 2006-04-03. Multiple injected and natural conservative tracers quantify mixing in a stream confluence affected by acid mine drainage near Silverton, Colorado. https://doi.org/10.1002/hyp.6081

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related USGS reports

USGS2026

Potential warming-induced changes in stream water sources between proglacial and non-glacial streams, south-central Alaska

Snow and ice-melt are essential for global water resources. Rising air temperatures are causing vegetation encroachment and shrubification of previously snow- and ice-covered landscapes, and precipitation regimes are changing. Collectively, these changes will likely affect the hydrology of mountain environments, although the exact ways in which the hydrology will change are poorly understood. Changing source waters (i.e., the proportion of ice-melt, snowmelt, rain and groundwater) affect the timing and magnitude of streamflow and affect stream temperature, sediment, solute and nutrient fluxes. We investigate spatial and seasonal source water contributions across sub-watersheds of the Nellie Juan River watershed on Alaska's Kenai Peninsula, which differ in glacier cover, elevation and land cover, using a space-for-time approach. To do so, we use a three-endmember mixing model to quantify the contribution of rain, snow/ice-melt and deep groundwater. We show that snow/ice-melt peak later in proglacial streams compared to non-glacial streams. Endmember contributions in non-glacial streams generally vary with elevation and season. We also found that groundwater is a major contributor to streamflow across the study area, contributing between 12% and 47% seasonally, and may become increasingly important as snowpack and ice-melt decrease. This research characterises the shift from a glacierised to a deglaciating landscape through the lens of source water contribution. Broadly, these findings could help improve understanding of how water resources in glacierised watersheds are affected by warming air temperatures.

Alaska↗
USGS2026

Streamflow and surface-water presence data availability across the conterminous United States: A review for headwater systems

Water is essential for life on Earth, supporting ecosystems, human health, and economic activities. Hydrology relies on observational data, and this paper discusses regional and national datasets for the conterminous United States (CONUS) publicly available as of 2023, focusing on headwaters, defined as first- and second-order streams at 1:24000 scale. It identifies 72 primary and secondary datasets and 11 repositories and argues how better integration and accessibility of hydrological data can improve research. The paper distinguishes between datasets where streamflow was the primary data collection objective and those where it was secondary. This distinction highlights opportunities to consider data from efforts peripheral to hydrology but is still useful for understanding hydrologic conditions. The analysis reveals that out of about 118 000 active and inactive stream observation sites, about 6.6% and 25% are located on first- and second-order streams, respectively. This indicates a substantial data gap for headwater systems, which account for over 77% of stream length in CONUS. Federal agencies manage 72% of hydrologic monitoring sites across all stream orders, but only 34% of these are in headwater systems. Academic institutions operate about 2% of sites, with almost half (48%) in headwater systems, focusing on ecosystem research. State agencies also operate about 2% of sites, primarily on larger systems, with 19% on headwaters. Additionally, 23% of sites are managed by multiple agencies. Spatial patterns further reveal pronounced disparities among physiographic regions. Eastern and coastal provinces show relatively dense monitoring, while central and western regions show sparse coverage. These gaps reflect historical priorities, logistical constraints, funding limitations, and the high cost of continuous instrumentation. To address biases in monitoring networks, data collection could be enhanced with low-cost monitoring, community science, and remote sensing technologies. This study also notes the benefits of long-term monitoring and prioritizing retention of streamgages with longer records.

conterminous United States↗
USGS2026

A novel drive-point multilevel system to investigate PFAS and other contaminants of global concern in the hyporheic zone of a wastewater effluent dominated stream

Contaminants found in treated wastewater discharged to streams, including pharmaceuticals and per- and polyfluoroalkyl substances (PFAS), are of global concern due to their deleterious effects on aquatic ecosystems and potential impacts to human health. Hyporheic zones have strong potential for contaminant attenuation. Assessing this potential requires collection of physical and biogeochemical data within the hyporheic zone. This study tested the applicability of a novel drive-point multilevel system (DP-MLS) for quantifying head profiles and characterizing contaminant concentrations in the hyporheic zone of a temperate region effluent dominated stream (EDS). DP-MLS, each with 4 ports, were installed in the stream bed at two sites, DS-1 and DS-2, 0.2 and 4.7 km downstream of the effluent outfall, respectively. Head profiles were measured and groundwater collected for analysis of pharmaceuticals and PFAS temporally over two years. The DP-MLS withstood rapid changes in stage, ice formation, and floating debris. Vertical hydraulic gradients (VHG) were generally upward but varied in magnitude indicating heterogeneity in hydraulic conductivity and variability in flow conditions. Upward VHG were also about 2X larger at DS-1 than at DS-2. Contaminant concentration profiles consistently showed penetration of pharmaceuticals and PFAS to 1 m below the bed at DS-2 while there was less penetration, lower groundwater concentrations, and more temporal variability in concentrations at DS-1. Integration of the physical and chemical data suggests weaker upwelling conditions at DS-2 are more easily reversed during periods of high stream stage, which could facilitate migration of wastewater contaminants into the bed. However, further studies incorporating other transport processes and reach scale dynamics are required to fully characterize these exchanges. Overall, this study demonstrates the efficacy of these novel DP-MLSs for characterization of the hyporheic zone and provides new insights into the occurrence, composition, and persistence of wastewater derived contaminants in the hyporheic zone of a well-studied EDS.

Iowa↗