USGS ScienceSearch

USGS · 70025518

Elevation effects in volcano applications of the COSPEC

Abstract

Volcano applications commonly involve sizeable departures from the reference pressure and temperature of COSPEC calibration cells. Analysis shows that COSPEC SO2 column abundances and derived mass emission rates are independent of pressure and temperature, and thus unaffected by elevation effects related to deviations from calibration cell reference state. However, path-length concentrations are pressure and temperature dependent. Since COSPEC path-length concentration data assume the reference pressure and temperature of calibration cells, they can lead to large errors when used to calculate SO2 mixing ratios of volcanic plumes. Correction factors for COSPEC path-length concentrations become significant (c.10%) at elevations of about 1 km (e.g. Kilauea volcano) and rise rapidly to c.80% at 6 km (e.g. Cotopaxi volcano). Calculating SO2 mixing ratios for volcanic plumes directly from COSPEC path-length concentrations always gives low results. Corrections can substantially increase mixing ratios; for example, corrections increase SO2 ppm concentrations reported for the Mount St Helens, Colima, and Erebus plumes by 25-50%. Several arguments suggest it would be advantageous to calibrate COSPEC measurements in column abundance units rather than path-length concentration units.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

T.M. Gerlach. 2003. Elevation effects in volcano applications of the COSPEC. https://pubs.usgs.gov/publication/70025518

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related USGS reports

Slope failure and mass transport processes along the Queen Charlotte Fault, southeastern Alaska

The Queen Charlotte Fault defines the Pacific–North America transform plate boundary in western Canada and southeastern Alaska for c. 900 km. The entire length of the fault is submerged along a continental margin dominated by Quaternary glacial processes, yet the geomorphology along the margin has never been systematically examined due to the absence of high-resolution seafloor mapping data. Hence the geological processes that influence the distribution, character and timing of mass transport events and their associated hazards remain poorly understood. Here we develop a classification of the first-order shape of the continental shelf, slope and rise to examine potential relationships between form and process dominance. We found that the margin can be split into six geomorphic groups that vary smoothly from north to south between two basic end-members. The northernmost group (west of Chichagof Island, Alaska) is characterized by concave-upwards slope profiles, gentle slope gradients (<6°) and relatively low along-strike variance, all features characteristic of sediment-dominated siliciclastic margins. Dendritic submarine canyon/channel networks and retrogressive failure complexes along relatively gentle slope gradients are observed throughout the region, suggesting that high rates of Quaternary sediment delivery and accumulation played a fundamental part in mass transport processes. Individual failures range in area from 0.02 to 70 km2 and display scarp heights between 10 and 250 m. Transpression along the Queen Charlotte Fault increases southwards and the slope physiography is thus progressively more influenced by regional-scale tectonic deformation. The southernmost group (west of Haida Gwaii, British Columbia) defines the tectonically dominated end-member: the continental slope is characterized by steep gradients (>20°) along the flanks of broad, margin-parallel ridges and valleys. Mass transport features in the tectonically dominated areas are mostly observed along steep escarpments and the larger slides (up to 10 km2) appear to be failures of consolidated material along the flanks of tectonic features. Overall, these observations highlight the role of first-order margin physiography on the distribution and type of submarine landslides expected to occur in particular morphological settings. The sediment-dominated end-member allows for the accumulation of under-consolidated Quaternary sediments and shows larger, more frequent slides; the rugged physiography of the tectonically dominated end-member leads to sediment bypass and the collapse of uplifted tectonic features. The maximum and average dimensions of slides are an order of magnitude smaller than those of slides observed along other (passive) glaciated margins. We propose that the general patterns observed in slide distribution are caused by the interplay between tectonic activity (long- and short-term) and sediment delivery. The recurrence (<100 years) of M > 7 earthquakes along the Queen Charlotte Fault may generate small, but frequent, failures of under-consolidated Quaternary sediments within the sediment-dominated regions. By contrast, the tectonically dominated regions are characterized by the bypass of Quaternary sediments to the continental rise and the less frequent collapse of steep, uplifted and consolidated sediments.

Alaska

Advances in carbonate exploration and reservoir analysis

The development of innovative techniques and concepts, and the emergence of new plays in carbonate rocks are creating a resurgence of oil and gas discoveries worldwide. The maturity of a basin and the application of exploration concepts have a fundamental influence on exploration strategies. Exploration success often occurs in underexplored basins by applying existing established geological concepts. This approach is commonly undertaken when new basins &lsquo;open up&rsquo; owing to previous political upheavals. The strategy of using new techniques in a proven mature area is particularly appropriate when dealing with unconventional resources (heavy oil, bitumen, stranded gas), while the application of new play concepts (such as lacustrine carbonates) to new areas (i.e. ultra-deep South Atlantic basins) epitomizes frontier exploration. Many low-matrix-porosity hydrocarbon reservoirs are productive because permeability is controlled by fractures and faults. Understanding basic fracture properties is critical in reducing geological risk and therefore reducing well costs and increasing well recovery. The advent of resource plays in carbonate rocks, and the long-standing recognition of naturally fractured carbonate reservoirs means that new fracture and fault analysis and prediction techniques and concepts are essential.

Geological Society Special Publication

The indication of Martian gully formation processes by slope-area analysis

The formation process of recent gullies on Mars is currently under debate. This study aims to discriminate between the proposed formation processes - pure water flow, debris flow and dry mass wasting - through the application of geomorphological indices commonly used in terrestrial geomorphology. High-resolution digital elevation models (DEMs) of Earth and Mars were used to evaluate the drainage characteristics of small slope sections. Data from Earth were used to validate the hillslope, debris-flow and alluvial process domains previously found for large fluvial catchments on Earth, and these domains were applied to gullied and ungullied slopes on Mars. In accordance with other studies, our results indicate that debris flow is one of the main processes forming the Martian gullies that were being examined. The source of the water is predominantly distributed surface melting, not an underground aquifer. Evidence is also presented indicating that other processes may have shaped Martian crater slopes, such as ice-assisted creep and solifluction, in agreement with the proposed recent Martian glacial and periglacial climate. Our results suggest that, within impact craters, different processes are acting on differently oriented slopes, but further work is needed to investigate the potential link between these observations and changes in Martian climate.

Geological Society Special Publication