USGS Science⌕ Search
Home/Archive/USGS

USGS · 70023474

Radiocarbon dating of dissolved inorganic carbon in groundwater from confined parts of the Upper Floridan aquifer, Florida, USA

Niel Plummer·C.L. Sprinkle
View original source ↗Export metadata ↓

Abstract

Geochemical reaction models were evaluated to improve radiocarbon dating of dissolved inorganic carbon (DIC) in groundwater from confined parts of the Upper Floridan aquifer in central and northeastern Florida, USA. The predominant geochemical reactions affecting the 14 C activity of DIC include (1) dissolution of dolomite and anhydrite with calcite precipitation (dedolomitization), (2) sulfate reduction accompanying microbial degradation of organic carbon, (3) recrystallization of calcite (isotopic exchange), and (4) mixing of fresh water with as much as 7% saline water in some coastal areas. The calculated cumulative net mineral transfers are negligibly small in upgradient parts of the aquifer and increase significantly in downgradient parts of the aquifer, reflecting, at least in part, upward leakage from the Lower Floridan aquifer and circulation that contacted middle confining units in the Floridan aquifer system. The adjusted radiocarbon ages are independent of flow path and represent travel times of water from the recharge area to the sample point in the aquifer. Downgradient from Polk City (adjusted age 1.7 ka) and Keystone Heights (adjusted age 0.4 ka), 14 of the 22 waters have adjusted 14 C ages of 20–30 ka, indicating that most of the fresh-water resource in the Upper Floridan aquifer today was recharged during the last glacial period. All of the paleowaters are enriched in 18 O and 2 H relative to modern infiltration, with maximum enrichment in δ 18 O of approximately 2.0‰.

Explore related subjects

Hydrogeology JournalArticle

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Niel Plummer, C.L. Sprinkle. 2001. Radiocarbon dating of dissolved inorganic carbon in groundwater from confined parts of the Upper Floridan aquifer, Florida, USA. https://doi.org/10.1007/s100400000121

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related USGS reports

USGS2025

Review: The hydrogeology of critical mineral resources relevant to the energy transition

Attaining the goals of the international treaty on climate change (the Paris Agreement) will greatly increase the demand for the critical minerals required to implement clean-energy technologies. This poses both challenges and opportunities to the hydrogeologic community from several perspectives. Here, important insights that the hydrogeological sciences have to offer for mineral exploration, mineral production, and addressing environmental issues related to mining and mine decommissioning are summarized. This study focuses on copper, cobalt, lithium, and rare earths to represent the broad spectrum of critical minerals and illustrate their relevance by referring to projected demands and production rates. The current understanding of the hydrogeologic processes that form major deposits of these minerals are then summarized. Ore is defined as the naturally occurring material from which minerals of economic value can be extracted, where most ore deposits are the products of complex hydrogeologic couplings between fluid flow, heat transport, solute transport, chemical reactions, and mechanical deformation. Exploration models for the discovery of deeper, hidden deposits are potentially informed by hydrogeologic theory and hydrogeochemical processes. Hydrogeologic understanding and methods are also essential to production and recovery. Longstanding challenges are mine dewatering and (conversely) mine water supply, as well as mineral-extraction practices such as spoil heap leaching and in situ mining. New challenges arise from element extraction from subsurface brines. Finally, the quantity of water use and potential environmental impacts of mining on water quality are at the core of ‘social license’: the approval and acceptance of society to mining activities.

Hydrogeology Journal↗
USGS2025

Controls on water quality below a reclaimed surface coal mine, southeastern Montana

Coal mining and reclamation can have a profound influence on hydrogeologic systems, with clear consequences for groundwater quality, yet their long-term influence on downgradient water quality over time following reclamation is less well documented. Geochemical trends were evaluated in water quality downgradient of a fully reclaimed landscape at the former Big Sky Mine in the Rosebud Creek watershed (southeastern Montana, USA), over a 3-year period (2020–2022), including bond release in 2022. Within 6 km downgradient from the reclaimed area, sulfate concentrations decreased from approximately 3500 to 1800 mg l −1 within the Miller Coulee alluvial aquifer. Major ions, δ 34 S SO4 values, and residence time tracers suggest that the observed decreases in sulfate concentration result from a combination of dilution by mixed-age inflows and incomplete transit of the high salinity plume from the mine boundary. Both bedrock and alluvial aquifers of the Rosebud Creek corridor contained contributions of millennia-old regional groundwater, which may serve to mitigate mine-derived high salinity waters. Rosebud Creek, which traverses the outflow zone of Miller Coulee in the study area, exhibited high sulfate concentrations during low flows and consistent downgradient increases in sulfate concentration. The possibility of plume dynamics in Miller Coulee suggests that the greatest water quality impacts may not yet have reached Rosebud Creek.

Montana↗
USGS2023

Arizona Groundwater Explorer: Interactive maps for evaluating the historical and current groundwater conditions in wells in Arizona, USA

Groundwater is an important water source in Arizona, accounting for about 41% of water use in this mostly arid-to-semiarid state in the southwestern United States, and the availability of groundwater resources in the state is a concern. To provide accessible information from depth-to-groundwater data, a series of web-based interactive maps were developed, called the Arizona Groundwater Explorer (AGEx). Scripts were written to harmonize and synthesize groundwater datasets from the two largest publicly available sources, subset these data to address different groundwater availability questions, and display the results in online, interactive maps. The combined dataset contained 1,820,122 depth-to-groundwater measurements from 1891 through 2022 from 41,918 wells in Arizona. Data views are provided for 20 topics, including recent (2020 or later) depth to groundwater (4,569 wells), historical (pre-1950) depth to groundwater (4,287 wells), wells with long-term (≥50 years) records (1,183 wells), wells with recent groundwater level decline (277 wells), wells with recent groundwater level rise (120 wells), and linear trends in groundwater levels over ten 10-year periods (number of wells ranging from 341 in 1978–1987 to 1,208 in 2003–2012), among others. With ongoing drought in the region resulting in declining surface-water supplies in Arizona, groundwater may play an even larger role in satisfying water needs in the state. The AGEx series of maps provides a nonspecialist audience with an improved understanding of historical, current, and changes in groundwater levels in Arizona.

Arizona↗