USGS Science⌕ Search
Home/Archive/USGS

USGS · 70023346

Radiocarbon studies of plant leaves and rings from mammoth mountain, CA: A long-term record of magmatic CO2 release

A.C. Cook·L.J. Hainsworth·M.L. Sorey·William C. Evans·J. R. Southon
View original source ↗Export metadata ↓

Abstract

Evaluation of 14C in tree rings provides a measure of the flux of magmatic CO2 from Mammoth Mountain both before and after 1994 when copious diffuse emissions were first discovered and linked to tree kill. We analyzed the annual rings of trees with two main purposes: (1) to track changes in the magnitude of magmatic CO2 emission over time, and (2) to determine the onset of magmatic CO2 emission at numerous sites on Mammoth Mountain. The onset of CO2 emission at different areas of tree kill was determined to be in 1990, closely following the seismic events of 1989. At Horseshoe Lake (HSL), CO2 emission was found to have peaked in 1991 and to have subsequently declined by a factor of two through 1998. The tree-ring data also show that emissions of magmatic carbon from cold springs below the tree-kill areas occurred well before 1989. Trees located on the margins of the kill areas or otherwise away from zones of maximum gas discharge were found to be better integrators of magmatic CO2 emission than those located in the center of tree kills. Although quantitative extrapolations from our data to a flux history will require that a relationship be established between 14C depletion in tree rings and average annual magmatic CO2 flux, the pattern of 14C depletion in tree rings is likely to be the most reliable indicator of the long-term changes in the magnitude of CO2 release from Mammoth Mountain. ?? 2001 Elsevier Science B.V. All rights reserved.

Explore related subjects

Chemical GeologyArticle

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

A.C. Cook, L.J. Hainsworth, M.L. Sorey, William C. Evans, J. R. Southon. 2001. Radiocarbon studies of plant leaves and rings from mammoth mountain, CA: A long-term record of magmatic CO2 release. https://doi.org/10.1016/s0009-2541(00)00386-7

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related USGS reports

USGS2026

Trace element heterogeneity and crystallization history of the Plesovice zircon: Implications for its use as a U–Pb LA-ICP-MS reference material

Zircon crystals from Plešovice hyperpotassic granulite (HPG) have been widely used as a reference material for LA-ICP-MS dating. Detailed cathodoluminescence (CL) imaging and trace element analysis reveal a complex internal structure of Plešovice zircon linked to extreme chemical heterogeneity, which allows us to distinguish different zircon domains formed during its crystallization: (i) rare low-CL cores enriched in U, Nb, HREE and Y; (ii) dominant sector-zoned to oscillatory-zoned domains, and (iii) CL-bright rims poor in trace elements. Relic fine oscillatory zoned areas are chemically homogeneous, whereas coarsened and blurred areas, and CL-dark replacement domains, are heterogeneous. Based on these data we suggest a complex and protracted zircon evolution: (i) crystallization of metamorphic zircon in anatectic calc-alkaline granulite; (ii) magmatic zircon crystallization at high temperature and pressure in a dry ultrapotassic melt at presence of peritectic garnet; (iii) coupled zircon dissolution-precipitation processes triggered by percolating hydrous residual melt; and (iv) coarsening and replacement of the pre-existing zircon due to prolonged exposure to a reactive fluid/hydrous melt. New CA-ID-TIMS U Pb dates between 337.167 ± 0.080 and 337.840 ± 0.080 Ma confirm crystallization age for HPG zircon at around 337.4 Ma and suggest that previously published dates of 336.37 Ma were biased by non-mitigated lead loss. We thus confirm the U/Pb homogeneity of Plešovice reference zircon despite its chemical heterogeneity. We further discuss the implications of using the chemically extremely heterogeneous Plešovice reference zircon as primary or secondary standard for in-situ LA-ICP-MS geochronology, in particular for quantification of the chemical matrix-dependence of the relative sensitivity factor ( β ) of laser ablation.

Plešovice quarry↗
USGS2026

Re-Os dating of paleozoic organic-rich black shales by LA-ICP-MS/MS

We present a new in-situ method for Re- Os geochronology of black shales using LA-ICP-MS/MS that is rapid, cost-effective, and sufficiently accurate and precise to address many geological questions. The method is tested on Paleozoic organic-rich black shales with independently constrained stratigraphic or radiometric ages. Results demonstrate that LA-ICP-MS/MS analysis yields Re- Os dates and initial Os isotopic compositions generally within uncertainty of published values using a laser spot size of 100 to 120 μ m in diameter. Despite low Os abundances in many samples, high-density microscale sampling compensates through large numbers of analyses, enabling robust inverse isochron regressions. The approach also allows contemporaneous acquisition of trace- element data (V, Ni, Mo and Re), providing insight into metal distribution in a sample, degree of metal enrichments, and serve as a proxy for open-system behavior for Re- Os. As a result, LA-ICP-MS/MS Re- Os analysis can serve both as a stand-alone geochronological tool and as an efficient screening method prior to conventional ID-N-TIMS, helping to identify optimal intervals and exclude isotopically disturbed material. Together, our study demonstrates that in-situ Re- Os geochronology of organic-rich shales is technically viable, geologically informative, and broadly applicable, opening new opportunities to investigate basin evolution, metallogenesis, hydrocarbon systems, and Earth-system processes across deep time.

Chemical Geology↗
USGS2026

Osmium isotope constraints on Mauna Loa–Kilauea magmatic connectivity, Island of Hawai‘i

The Hawaiian volcanic chain exhibits a long-recognized double track of volcanism defined by the Loa and Kea trends, which erupt chemically and isotopically distinct lavas. Mauna Loa and Kīlauea, the two most frequently active volcanoes of the Loa and Kea trends, produce distinct endmember compositions. However, historical periods of compositional convergence have prompted debate regarding a potential magmatic connection between the two adjacent volcanoes. Proposed links include a shallow edifice-level plumbing system, a common magma source at ∼40 km depth, or a deeper asthenospheric source. In the latter scenario, based on correlated Sr–Nd–Pb isotopes and trace-element systematics, a “shared” mantle source supplies melt alternately to both volcanoes on multi-decadal timescales. Here, we use Os isotopes to evaluate the proposed connections. We measured Os isotopes in eight historical Mauna Loa tholeiites along with three Kīlauea tholeiites (1832 summit eruption; Uēkahuna Bluff; 2000 Pu‘u‘ō‘ō eruption) previously identified as isotopically intermediate between Mauna Loa and Kīlauea endmembers. We found that the acidic bromide leachates of all samples yield more radiogenic 187 Os/ 188 Os than corresponding bulk residues, with the labile Os-bearing phase comprising ∼0.4–27% of bulk Os. Mauna Loa tholeiites display nearly constant 187 Os/ 188 Os over the past ∼200 years (0.134–0.136; mean = 0.1357 ± 0.0013, n = 8, 2SD), despite large variations in total [Os] ranging from ∼30 pg/g (2022 tholeiite) to ∼966 pg/g (1868 picrite). The Kīlauea 1832 sample has 187 Os/ 188 Os = 0.1302 ± 0.0008, slightly higher than the Kīlauea endmember (0.1285 ± 0.0008), whereas the Uēkahuna Bluff and Pu‘u‘ō‘ō samples exhibit more elevated ratios (0.1314 ± 0.0008 and 0.1327 ± 0.0008, respectively). We conclude that the “shared” mantle source exerts negligible control on Mauna Loa Os isotope systematics. In contrast, the Kīlauea mantle source is more heterogeneous, with contributions from small-scale recycled domains with variable time-integrated Re/Os ratios.

Hawaii↗