USGS ScienceSearch

USGS · 70020787

Recommended nomenclature for zeolite minerals: Report of the subcommittee on zeolites of the International Mineralogical Association, Commission of New Minerals and Mineral Names

Abstract

This report embodies recommendations on zeolite nomenclature approved by the International Mineralogical Association Commission of New Minerals and Mineral Names. In a working definition of a zeolite mineral used for review, interrupted tetrahedral framework structures are accepted where other zeolitic properties prevail, and complete substitution by elements other than Si and Al is allowed. Separate species are recognized in topologically distinctive compositional series in which different extra-framework cations are the most abundance in atomic proportions. To name these, the appropriate chemical symbol is attached by a hyphen to the series name as a suffix except for the names harmotome, pollucite and wairakite in the phillipsite and analcime series. Differences in space-group symmetry and in order-disorder relationships in zeolites having the same topologically distinctive framework do not in general provide adequate grounds for recognition of separate species. Zeolite species are not to be distinguished solely on Si:Al ratio except for heulandite (Si:Al < 4.0) and clinoptilolite ( Si : Al ⩾ 4.0 ). Dehydration, partial hydration, and over-hydration are not sufficient grounds for the recognition of separate species of zeolites. Use of the term 'ideal formula' should be avoided in referring to a simplified or averaged formula of a zeolite. Newly recognized species in compositional series are as follows: brewsterite-Sr.-Ba: chabazite-Ca.-Na.-K; clinoptilolite-K, -Na, -Ca: dachiardite-Ca, -Na; erionite-K, -Ca: faujasite-Na, -Ca, -Na: paulingite-K. -Ca; phillipsite-Na, -Ca, -Ka; stilbite-Ca, -Na. Key references, type locality, origin of name, chemical data. IZA structure-type symbols, space-group symmetry; unit-cell dimensions, and comments on structure are listed for 13 compositional series, 82 accepted zeolite mineral species, and three of doubtful status. Herschelite, leonhardite, svetlozarite, and wellsite are discredited as mineral species names. Obsolete and discredited names are listed.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

D.S. Coombs, A. Alberti, T. Armbruster, G. Artioli, C. Colella, E. Galli, Joel D. Grice, F. Liebau, J.A. Mandarino, H. Minato, E.H. Nickel, E. Passaglia, D.R. Peacor, S. Quartieri, R. Rinaldi, M. Ross, R.A. Sheppard, E. Tillmanns, G. Vezzalini. 2018-07-05. Recommended nomenclature for zeolite minerals: Report of the subcommittee on zeolites of the International Mineralogical Association, Commission of New Minerals and Mineral Names. https://doi.org/10.1180/002646198547800

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related USGS reports

Evaluation for internal consistency in the thermodynamic network involving fluorite, cryolite and villiaumite solubilities and aqueous species at 25°C and 1 bar

Thermodynamic data are constrained by the interrelated thermodynamic equations in addition to the observational measurements and their uncertainties. The consequence is a network of thermodynamic properties that can be evaluated for their internal consistency. In this study, three fluoride minerals that can cause high fluoride concentrations in groundwaters are evaluated for their solubilities and their internal thermodynamic consistency with calorimetric, isopiestic and electrochemical measurements: fluorite, CaF 2 , cryolite, Na 3 AlF 6 , and villiaumite, NaF. This evaluation involves the three solids and 13 aqueous species, the free ions of Ca 2+ , Na + , Al 3+ and F – , and the hydroxido and fluorido complexes of Al 3+ , and the CaF + ion pair. For the fluorite–cryolite–villiaumite–aqueous species network, the number of components is minimal, and the solubility studies are mostly of high quality. Re-evaluations of original data using PHREEQC helps to broaden the quantitative evaluation of thermodynamic properties and to resolve apparent discrepancies. A check on this thermodynamic network shows that through a careful appraisal of the literature, a highly consistent set of values can be derived. The resultant infinite-dilution solubility-product constants at 25°C and 1 bar are: for fluorite solubility, log K sp = –10.57 ± 0.08; for cryolite solubility, log K sp = –33.9 ± 0.2; and for villiaumite solubility, log K sp = –0.4981 ± 0.003.

Mineralogical Magazine

Compositional variation in minerals of the chevkinite group

The composition of chevkinite and perrierite, the most common members of the chevkinite group, is closely expressed by the formula A4BC2D2Si4O22, where A = (La,Ce,Ca,Sr,Th), B = Fe2+, C = (Fe2+,Fe3+,Ti,Al,Zr,Nb) and D = Ti. The A site is dominated by a strong negative correlation between (Ca+Sr) and the REE. Chondrite-normalized REE patterns are very variable, e.g. in LREE/HREE and Eu/Eu*. The C site is dominated by Ti, Al and Fe2+, in very variable proportions. Most chevkinites and perrierites are close to stoichiometric, with cation sums between 12.9 and 13.5, compared to the theoretical 13. There is no single, generally applicable charge balancing substitution scheme in the group; however, the general relationship (Ca+Sr)A + TiC + REEA + M3C+2+ defines a linear array with r2 = 0.91. Chevkinite and perrierite are shown to be compositionally distinct on the basis of CaO, FeO* Al2O3 and Ce2O3 abundances. Chevkinite forms mainly in chemically evolved parageneses, such as syenites, rhyolites and fenites associated with carbonatite complexes. Perrierite is more commonly recorded from igneous rocks of mafic to intermediate composition. The compositional characteristics and possible structural formulae of other members of the chevkinite group are reviewed briefly.

Mineralogical Magazine

Origin of placer laurite from Borneo: Se and As contents, and S isotopic compositions

We examined grains of the platinum-group mineral, laurite (RuS2), from the type locality, Pontyn River, Tanah Laut, Borneo, and from the Tambanio River, southeast Borneo. The grains show a variety of morphologies, including euhedral grains with conchoidal fractures and pits, and spherical grains with no crystal faces, probably because of abrasion. Inclusions are rare, but one grain contains Ca-Al amphilbole inclusions, and another contains an inclusion of chalcopyrite+bornite+pentlandite+heazlewoodite (Ni3S2) that is considered to have formed by a two-stage process of exsolution and crystallization from a once homogeneous Fe-Cu-Ni sulphide melt. All grains examined are solid solutions of Ru and Os with Ir (2.71-11.76 wt.%) and Pd (0.31-0.66 wt%). Their compositions are similar to laurite from ophiolitic rocks. The compositions show broad negative correlations between Os and Ir, between As and Ir, and between As (0.4-0.74 wt.%) and Se (140 to 240 ppm). Laurite with higher Os contains more Se and less Ir and As. The negative correlations between Se and As may be attributed to their occupancy of the S site, but the compositional variations of Os. Ir and As probably reflect the compositional variation of rocks where the crystals grew. Ratios of S/Se in laurite show a narrow spread from 1380 to 2300, which are similar to ratios for sulphides from the refractory sub-are mantle. Sulphur isotopic compositions of laurite are independent of chemical compositions and morphologies and are similar to the chondritic value of 0???. The data suggest that S in laurite has not undergone redox changes and originated from the refractory mantle. The data support the formation of laurite in the residual mantle or in a magnia generated from such a refractory mantle, followed by erosion after the obduction of the host ultramafic rocks. ?? 2004 The Mineralogical Society.

Mineralogical Magazine