Ground water age and nitrate distribution within a glacial aquifer beneath a thick unsaturated zone

Abstract

The impact on ground water quality from increasing fertilizer application rates over the past 40 years is evaluated within a glacial aquifer system beneath a thick unsaturated zone. Ground water ages within the aquifer could not be accurately determined from the measured distribution of 3 H and as a result, chlorofluorocarbon (CFC) and 3 H/ 3 He dating techniques were applied. Beneath a 25 m thick unsaturated zone, ground water ages based on CFC‐11 concentrations were greater than 3 H/ 3 He ground water ages by 6 to 10 years, due to the time lag associated with the diffusion of CFCs through the unsaturated zone. Using the corrected CFC‐11 and 3 H/ 3 He ground water ages and the estimated travel time of 3H within the unsaturated zone, the approximate position of ground water recharged since the mid‐1960s was determined. Nitrate concentrations within post mid‐1960s recharge were generally elevated and near or above the drinking water limit of 10 mg‐N/L. In comparison, pre mid‐1960s recharge had nitrate concentrations <2.5 mg‐N/L. The elevated NO 3 − concentrations in post mid‐1960s recharge are attributed mainly to increasing fertilizer application rates between 1970 and the mid‐ to late 1980s. Anaerobic conditions suitable for denitrifkation are present within pre mid‐1960s recharge indicating that removal of DO is a slow process taking tens of years. Over the next 10 to 20 years, nitrate concentrations at municipal well fields that are currently capturing aerobic ground water recharged near the mid‐1960s are expected to increase because of the higher fertilizer application rates beginning in the 1970s and 1980s.