USGS ScienceSearch

USGS · 70018336

Nature of migrabitumen and their relation to regional thermal maturity, Ouachita Mountains, Oklahoma

Abstract

Two grahamite and three impsonite localities are within an 82-km-long segment of the Ouachita Mountains of southeastern Oklahoma. Grab samples were collected to study the petrographic and geochemical characteristics of the migrabitumen at the grahamite-impsonite transition and the relation of the migrabitumen to the regional thermal maturity pattern. Maximum and random bitumen reflectance values increased from 0·75 to 1·80% from west to east, consistent with the regional thermal maturation trend. Mean bireflectance values increased from 0·04 to 0·38%. The two grahamite samples are classified at the grahamite-impsonite boundary with conflicting petrographic (bitumen reflectance) and bulk chemical (volatile matter) maturity indicators. The regional maturation trend, based on vitrinite reflectance and bitumen reflectance values, was confirmed by a detailed geochemical investigation of bitumen extracts. Although biomarker analyses were influenced by extensive biodegradation effects, molecular parameters based on the phenanthrenes, dibenzothiophenes, and tricyclic terpanes were identified as useful maturity indicators.

Explore related subjects

90° N90° S · 180° W ← longitude → 180° E
Source-reported bounding extent: 33.65536790182706° to 34.97935792446523° latitude; -95.39359789520772° to -94.46276382083498° longitude. This indicates report coverage, not an exact sampling location. View area on OpenStreetMap.

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Brian J. Cardott, Tim E. Ruble, Neil H. Suneson. 1993. Nature of migrabitumen and their relation to regional thermal maturity, Ouachita Mountains, Oklahoma. https://doi.org/10.1080/00908319308909026

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related USGS reports

Producing ammonium sulfate from flue gas desulfurization by-products

Emission control technologies using flue gas desulfurization (FGD) have been widely adopted by utilities burning high-sulfur fuels. However, these technologies require additional equipment, greater operating expenses, and increased costs for landfill disposal of the solid by-products produced. The financial burdens would be reduced if successful high-volume commercial applications of the FGD solid by-products were developed. In this study, the technical feasibility of producing ammonium sulfate from FGD residues by allowing it to react with ammonium carbonate in an aqueous solution was preliminarily assessed. Reaction temperatures of 60, 70, and 80??C and residence times of 4 and 6 hours were tested to determine the optimal conversion condition and final product evaluations. High yields (up to 83%) of ammonium sulfate with up to 99% purity were achieved under relatively mild conditions. The optimal conversion condition was observed at 60??C and a 4-hour residence time. The results of this study indicate the technical feasibility of producing ammonium sulfate fertilizer from an FGD by-product. Copyright ?? Taylor & Francis Inc.

Energy Sources

Chemical and engineering properties of fired bricks containing 50 weight percent of class F fly ash

The generation of fly ash during coal combustion represents a considerable solid waste disposal problem in the state of Illinois and nationwide. In fact, the majority of the three million tons of fly ash produced from burning Illinois bituminous coals is disposed of in landfills. The purpose of this study was to obtain a preliminary assessment of the technical feasibility of mitigating this solid waste problem by making fired bricks with the large volume of fly ash generated from burning Illinois coals. Test bricks were produced by the extrusion method with increasing amounts (20-50% by weight) of fly ash as a replacement for conventional raw materials. The chemical characteristics and engineering properties of the test bricks produced with and without 50 wt% of fly ash substitutions were analyzed and compared. The properties of the test bricks containing fly ash were at least comparable to, if not better than, those of standard test bricks made without fly ash and met the commercial specifications for fired bricks. The positive results of this study suggest that further study on test bricks with fly ash substitutions of greater than 50wt% is warranted. Successful results could have an important impact in reducing the waste disposal problem related to class F fly ash while providing the brick industry with a new low cost raw material.

Energy Sources

Characterization of fly ash from low-sulfur and high-sulfur coal sources: Partitioning of carbon and trace elements with particle size

Fly ash samples were collected in November and December of 1994, from generating units at a Kentucky power station using high- and low-sulfur feed coals. The samples are part of a two-year study of the coal and coal combustion byproducts from the power station. The ashes were wet screened at 100, 200, 325, and 500 mesh (150, 75, 42, and 25 mu m, respectively). The size fractions were then dried, weighed, split for petrographic and chemical analysis, and analyzed for ash yield and carbon content. The low-sulfur ''heavy side'' and ''light side'' ashes each have a similar size distribution in the November samples. In contrast, the December fly ashes showed the trend observed in later months, the light-side ash being finer (over 20 % more ash in the 500 mesh [25 mu m] fraction) than the heavy-side ash. Carbon tended to be concentrated in the coarse fractions in the December samples. The dominance of the 325 mesh (42 mum) fractions in the overall size analysis implies, though, that carbon in the fine sizes may be an important consideration in the utilization of the fly ash. Element partitioning follows several patterns. Volatile elements, such as Zn and As, are enriched in the finer sizes, particularly in fly ashes collected at cooler, light-side electrostatic precipitator (ESP) temperatures. The latter trend is a function of precipitation at the cooler-ESP temperatures and of increasing concentration with the increased surface area of the finest fraction. Mercury concentrations are higher in high-carbon fly ashes, suggesting Hg adsorption on the fly ash carbon. Ni and Cr are associated, in part, with the spinel minerals in the fly ash.

Energy Sources