Automatic photometric titrations of calcium and magnesium in carbonate rocks

Leonard Shapiro; W. W. Brannock

doi:10.1021/ac60101a008

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USGS · 70010671

Automatic photometric titrations of calcium and magnesium in carbonate rocks

Leonard Shapiro·W. W. Brannock

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Abstract

Rapid nonsubjective methods have been developed for the determination of calcium and magnesium in carbonate rocks. From a single solution of the sample, calcium is titrated directly, and magnesium is titrated after a rapid removal of R2O3 and precipitation of calcium as the tungstate. A concentrated and a dilute solution of disodium ethylenediamine tetraacetate are used as titrants. The concentrated solution is added almost to the end point, then the weak solution is added in an automatic titrator to determine the end point precisely.

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Leonard Shapiro, W. W. Brannock. 2002-05-01. Automatic photometric titrations of calcium and magnesium in carbonate rocks. https://doi.org/10.1021/ac60101a008

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