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Quadratic elongation: A quantitative measure of distortion in coordination polyhedra

Kelly F. Robinson·G.V. Gibbs·P.H. Ribbe
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Abstract

Quadratic elongation and the variance of bond angles are linearly correlated for distorted octahedral and tetrahedral coordination complexes, both of which show variations in bond length and bond angle. The quadratic elonga tion is dimensionless, giving a quantitative measure of polyhedral distortion which is independent of the effective size of the polyhedron.

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Kelly F. Robinson, G.V. Gibbs, P.H. Ribbe. 1971. Quadratic elongation: A quantitative measure of distortion in coordination polyhedra. https://doi.org/10.1126/science.172.3983.567

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