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Water-quality assessment of the Trinity River Basin, Texas - Nutrients in streams draining an agricultural and an urban area, 1993-95

Water samples collected from streams draining an agricultural area in the west-central part of the Trinity River Basin upstream from the Richland-Chambers Reservoir and from streams draining an urban area in the Dallas-Fort Worth metropolitan area during March 1993 - September 1995 were analyzed for nutrients (nitrogen and phosphorus compounds). A comparison of the data for agricultural and urban streams shows the maximum concentration of total nitrogen is from an urban stream and the maximum concentration of total phosphorus is from an agricultural stream. One-half of the samples have total nitrogen concentrations equal to or less than 1.1 and 1.0 milligrams per liter in the agricultural and urban streams, respectively; and one-half of the samples have total phosphorous concentrations equal to or less than 0.04 and 0.05 milligram per liter in the agricultural and urban streams, respectively. The highest concentrations of total nitrogen in both types of streams are in the spring. The minimum concentrations of total nitrogen are during the summer in the agricultural streams and during the winter in the urban streams. Concentrations of total phosphorus in agricultural streams show negligible seasonal variability. The highest concentrations of total phosphorus are in spring and possibly late summer in the urban streams. In the midrange of streamflow in the urban streams and throughout the range of streamflow in the agricultural streams, concentrations of total nitrogen increase. Concentrations of total phosphorus increase with streamflow in the middle and upper ranges of streamflow in both agricultural and urban streams.

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Index of stations: Surface-water data-collection network of Texas, September 1995

As of September 30, 1995, the surface-water data-collection network of Texas (table 1) included 305 continuous-recording streamflow stations (D), 28 gageheight record only stations (G), 23 crest-stage partialrecord stations (C), 42 flood-hydrograph partial-record stations (H), 33 low-flow partial-record stations (L), 19 continuous-recording temperature and conductivity stations (M2), 5 continuous-recording temperature, conductivity, and dissolved oxygen stations (M3), 17 continuous-recording temperature, conductivity, dissolved oxygen, and pH stations (M4), 6 daily chemicalquality stations (Q), 143 periodic chemical-quality stations (Qp), 20 reservoir/lake surveys for water quality (Qs), and 64 continuous or daily reservoir-content stations (R). Plate 1 identifies the major river basins in Texas and shows the location of the stations listed in table 1. Table 1 shows the station number and name, latitude and longitude, type of station, and the office responsible for the collection of the data and the record. An 8-digit permanent numerical designation for all gaging stations has been adopted on a nationwide basis; stations are numbered and listed in downstream order. In the downstream direction along the main stem, all stations on a tributary entering between two main-stem stations are listed between them. A similar order is followed in listing stations by first rank, second rank, and other ranks of tributaries. The rank of any tributary with respect to the stream to which it is an immediate tributary is indicated by an indention in the table. Each indention represents one rank. This downstream order and system of indention shows which gaging stations are on tributaries between any two stations on a main stem and the rank of the tributary on which each gaging station is situated.

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Hydrogeologic framework of the Edwards-Trinity aquifer system, west-central Texas

The Edwards-Trinity aquifer system underlies about 42,000 square miles of west-central Texas, where mostly gently dipping Lower Cretaceous strata comprise three regional aquifers and two regional confining units. The aquifers are the Edwards Aquifer of the Balcones fault zone, the Trinity Aquifer of the Balcones fault zone and Hill County, and the Edwards-Trinity Aquifer of the Edwards Plateau and Trans-Pecos. The Navarro-Del Rio confining unit confines the downdip part of the Edwards Aquifer, and the Hammett confining unit confines the updip, basal part of the Trinity Aquifer and a small southeastern fringe of the Edwards-Trinity Aquifer. Transmissivity averages less than 10,000 feet squared per day throughout more than 90 percent of the study area as the result of widespread cementation and secondary mineral growth. However, in fractured and leached rocks in the Balcones fault zone, transmissivity averages about 750,000 feet squared per day in the Edwards aquifer, which occupies less than 10 percent of the area.

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Geohydrologic site characterization of the municipal solid waste landfill facility, U.S. Army Air Defense Artillery Center and Fort Bliss, El Paso County, Texas

Geohydrologic conditions of the Municipal Solid Waste Landfill Facility (MSWLF) on the U.S. Army Air Defense Artillery Center and Fort Bliss, El Paso County, Texas, were evaluated by the U.S. Geological Survey in cooperation with the U.S. Army. The 106.03-acre MSWLF has been in operation since January 1974. The landfill contains household refuse, Post solid wastes, bulky items, grass and tree trimmings from family housing, refuse from litter cans, construction debris, classified waste (dry), dead animals, asbestos, and empty oil cans. The MSWLF, located about 1,200 feet east of the nearest occupied structure, is estimated to receive an average of approximately 56 tons of municipal solid waste per day and, at a fill rate of 1-4 acres per year, is expected to reach its capacity by the year 2004. The MSWLF is located in the Hueco Bolson, 4 miles east of the Franklin Mountains. Elevations at the MSWLF range from 3,907 to 3,937 feet above sea level. The climate at the MSWLF and vicinity is arid continental, characterized by an abundance of sunny days, high summer temperatures, relatively cool winters typical of arid areas, scanty rainfall, and very low humidity throughout the year. Average annual temperature near the MSWLF and vicinity is 63.3 degrees Fahrenheit and annual precipitation is 7.8 inches. Potential evaporation in the El Paso area was estimated to be 65 inches per year. Soils at and adjacent to the MSWLF are nearly level to gently sloping, have a fine sandy loam subsoil, and are moderately deep over caliche. The MSWLF is underlain by Hueco Bolson deposits of Tertiary age and typically are composed of unconsolidated to slightly consolidated interbedded sands, clay, silt, gravel, and caliche. Individual beds are not well defined and range in thickness from a fraction of an inch to about 100 feet. The primary source of ground water in the MSWLF area is in the deposits of the Hueco Bolson. A relatively thick vadose zone of approximately 300 feet overlies the aquifer of the Hueco Bolson deposits in the vicinity of the MSWLF. A deep water table prevails for all of the study area. Whether any perched water zones exist below the MSWLF is unknown. Under current conditions, extensive ground-water development by the City of El Paso encompasses the MSWLF. Hydraulic characteristics of the Hueco Bolson vary significantly as a result of the nonuniform nature of the individual beds. Wells in the vicinity of the MSWLF range in depth from about 600 feet to greater than 1,200 feet. Recharge resulting from direct infiltration of precipitation is minor due to the high evaporation and low precipitation rates. The hydraulic gradient in the vicinity of the MSWLF is generally to the south but may vary due to pumpage of a well located on the northeast corner of the perimeter boundary. Ground-water monitoring data for the MSWLF vicinity show a water-level decline of 55.65 feet from November 1958 to December 1987. Depth to water at the northeast corner of the MSWLF as of July 26, 1994, was 325.8 feet below land surface. The city-operated Shearman Well Field, located north of the MSWLF, is a primary source of ground water for the City of El Paso. The test-pumping rate of well JL-49-05-914 (the well nearest to the MSWLF having test-pumping data) was 1,972 gallons per minute on July 20, 1992; the static water level prior to pumping was 317.54 feet below land surface. El Paso Water Utilities reports that the pumping level after 8 hours of pumping was 367.80 feet below land surface, resulting in a drawdown of 50.26 feet, transmissivity of 22,200 feet squared per day (166,000 gallons per day per foot), and specific capacity of 39.2 gallons per minute per foot of drawdown. After the well was shut off, the well recovered to a static water level of 317.46 feet below land surface on July 21, 1992. Ground water in the El Paso area is chemically suitable for most uses. El Paso Water Utilities reports that concentrations of dissolved solids in the vicinity of the MSWLF generally range from 297 to 625 milligrams per liter (wells JL-49-05-904 and JL-49-05-915, respectively).

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Effects of low-flow diversions from the South Wichita River on downstream salinity of the South Wichita River, Lake Kemp, and the Wichita River, North Texas, October 1982-September 1992

In parts of the upper reaches of the Red River Basin in Texas, streamflow is characterized by levels of salinity that limit its usefulness for most purposes. Large dissolved solids and dissolved chloride concentrations are caused primarily by flow from natural salt springs in tributaries to the Red River. To reduce downstream salinity in the Wichita River, a dam in the South Wichita River downstream of an area of salt springs (designated salinity source area VIII) diverts low flows (which are the most saline) to a manmade brine lake for evaporation. Statistical tests on salinity data for the South Wichita River, Lake Kemp, and the Wichita River for the period October 1982–September 1992 were done to determine the effects on downstream salinity of low-flow diversions from the South Wichita River that began in May 1987. Salinity in the South Wichita River downstream of the low-flow diversion structure was (statistically) significantly less during the 65-month period of record after diversion than during the 55- month period of record before diversion. Wilcoxon rank-sum tests yielded strong evidence that discharge-weighted dissolved solids and dischargeweighted dissolved chloride concentrations, as well as discharge-weighted specific conductance, were significantly less after diversion. Whether salinity in Lake Kemp had a significant downward trend during the period of record August 1989–August 1992 could not be determined conclusively from observed salinity data. Mann-Kendall trend tests yielded weak evidence that volume-weighted dissolved solids and dissolved chloride concentrations in Lake Kemp tended to decrease with time. However, serial correlation in the time series of salinity data could have adversely affected the test results. The significant effects of low-flow diversions on salinity in the South Wichita River are not discernible in the Wichita River downstream from Lake Kemp. Although salinity was significantly less downstream from Lake Kemp after diversion, the decrease probably is mostly a result of dilution of Lake Kemp by large inflows of (assumed) low-salinity water that occurred in the spring of 1989 rather than an effect of diversion.

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Floods in Central Texas, December 1991

Record-breaking peak discharges were recorded at eight U.S. Geological Survey (USGS) streamflow-gaging stations in central Texas during December 1991 (fig. 1), and substantial peak discharges also occurred at numerous other stations. Large peak discharges during December are unusual in central Texas. The rainfall causing the flooding began on December 18, with 6-day totals exceeding 10 inches (in.) in the area of heaviest rainfall. This report documents peak discharges and runoff volumes during December 1991. Recurrence intervals were determined for the peak discharges and runoff volumes for 1-, 3-, and 7-day periods. A recurrence interval references the approximate number of years during which a given peak discharge or runoff volumes is expected to be equaled or exceeded only once. A flood of a given recurrence interval is defined on the basis of peak discharge – for example, a 100-year flood is defined as the peak discharge that has a 1-percent chance of being equaled or exceeded in any given year.

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Estimated depth to the water table and estimated rate of recharge in outcrops of the Chicot and Evangeline aquifers near Houston, Texas

In 1989, the U.S. Geological Survey, in cooperation with the Harris-Galveston Coastal Subsidence District, began a field study to determine the depth to the water table and to estimate the rate of recharge in outcrops of the Chicot and Evangeline aquifers near Houston, Texas. The study area comprises about 2,000 square miles of outcrops of the Chicot and Evangeline aquifers in northwest Harris County, Montgomery County, and southern Walker County. Because of the scarcity of measurable water-table wells, depth to the water table below land surface was estimated using a surface geophysical technique, seismic refraction. The water table in the study area generally ranges from about 10 to 30 foot below land surface and typically is deeper in areas of relatively high land-surface altitude than in areas of relatively low land- surface altitude. The water table has demonstrated no long-term trends since ground-water development began, with the probable exception of the water table in the Katy area: There the water table is more than 75 feet deep, probably due to ground-water pumpage from deeper zones. An estimated rate of recharge in the aquifer outcrops was computed using the interface method in which environmental tritium is a ground-water tracer. The estimated average total recharge rate in the study area is 6 inches per year. This rate is an upper bound on the average recharge rate during the 37 years 1953-90 because it is based on the deepest penetration (about 80 feet) of postnuclear-testing tritium concentrations. The rate, which represents one of several components of a complex regional hydrologic budget, is considered reasonable but is not definitive because of uncertainty regarding the assumptions and parameters used in its computation.

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Geohydrologic units and water-level conditions in the Terrace alluvial aquifer and Paluxy Aquifer, May 1993 and February 1994, near Air Force Plant 4, Fort Worth area, Texas

The terrace alluvial aquifer underlying Air Force Plant 4 and the adjacent Naval Air Station (formerly Carswell Air Force Base) in the Fort Worth area, Texas, is contaminated locally with organic and metal compounds. Residents south and west of Air Force Plant 4 and the Naval Air Station are concerned that contaminants might enter the underlying Paluxy aquifer, which provides water to the city of White Settlement, south of Air Force Plant 4, and to residents west of Air Force Plant 4. The U.S. Environmental Protection Agency has qualified Air Force Plant 4 for Superfund cleanup. The pertinent geologic units include -A~rom oldest to youngest the Glen Rose, Paluxy, and Walnut Formations, Goodland Limestone, and terrace alluvial deposits. Except for the Glen Rose Formation, all units crop out at or near Air Force Plant 4 and the Naval Air Station. The terrace alluvial deposits, which nearly everywhere form the land surface, range from 0 to about 60 feet thick. These deposits comprise a mostly unconsolidated mixture of gravel, sand, silt, and clay. Mudstone and sandstone of the Paluxy Formation crop out north, west, and southwest of Lake Worth and total between about 130 and about 175 feet thick. The terrace alluvial deposits and the Paluxy Formation comprise the terrace alluvial aquifer and the Paluxy aquifer, respectively. These aquifers are separated by the Goodland-Walnut confining unit, composed of the Goodland Limestone and (or) Walnut Formation. Below the Paluxy aquifer, the Glen Rose Formation forms the Glen Rose confining unit. Water-level measurements during May 1993 and February 1994 from wells in the terrace alluvial aquifer indicate that, regionally, ground water flows toward the east-southeast beneath Air Force Plant 4 and the Naval Air Station. Locally, water appears to flow outward from ground-water mounds maintained by the localized infiltration of precipitation and reportedly by leaking water pipes and sanitary and (or) storm sewer lines beneath the assembly building at Air Force Plant 4. North of Farmers Branch, the terrace alluvial aquifer discharges into Lake Worth, Meandering Road Creek, Farmers Branch, and the West Fork Trinity River. South of Farmers Branch, ground water appears to flow mostly north-northeastward. Greater precipitation prior to the May 1993 measurements caused water levels to average approximately 5 ft higher in May 1993 than in February 1994. Regional ground-water gradients indicate west to east-southeastward flow in the Paluxy aquifer, with a dominant southeastward component beneath Air Force Plant 4. Water-level maps for the Paluxy "upper sand" reveal an elongated groundwater mound beneath southeastern parts of Air Force Plant 4, which indicates a localized, vertical conduit through which contaminated water from the terrace alluvial aquifer might enter upper parts of the Paluxy aquifer. The Paluxy "upper sand" apparently is mostly unsaturated and hydraulically separated from the deeper, regionally extensive parts of the Paluxy aquifer, most of which are fully saturated. While water levels in the "upper sand" were as much as 10 ft higher in May 1993 than in February 1994, water levels in most deeper parts of the Paluxy aquifer were slightly higher in February 1994 than they were in May 1993.

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Hydrogeology and ground-water quality of the chromic acid pit site, U.S. Army Air Defense Artillery Center and Fort Bliss, El Paso, Texas

The Chromic Acid Pit site is an inactive waste disposal site that is regulated by the Resource Conservation and Recovery Act of 1976. The 2.2-cubic-yard cement-lined pit was operated from 1980 to 1983 by a contractor to the U.S. Army Air Defense Artillery Center and Fort Bliss. The pit, located on the Fort Bliss military reservation, in El Paso, Texas, was used for disposal and evaporation of chromic acid waste generated from chrome plating operations. The site was certified closed in 1989 and the Texas Natural Resources Conservation Commission issued Permit Number HW-50296 (U.S. Environmental Protection Agency Permit Number TX4213720101), which approved and implemented post-closure care for the Chromic Acid Pit site. In accordance with an approved post-closure plan, the U.S. Geological Survey is cooperating with the U.S. Army in evaluating hydrogeologic conditions and ground- water quality at the site. One upgradient and two downgradient ground-water monitoring wells were installed adjacent to the chromic acid pit by a private contractor. Quarterly ground-water sampling of these wells by the U.S. Geological Survey began in December 1993. The Chromic Acid Pit site is situated in the Hueco Bolson intermontane valley. The Hueco Bolson is a primary source of ground water in the El Paso area. City of El Paso and U.S. Army water-supply wells are located on all sides of the study area and are completed 600 to more than 1,200 feet below land surface. The ground-water level in the area of the Chromic Acid Pit site has declined about 25 feet from 1982 to 1993. Depth to water at the Chromic Acid Pit site in September 1994 was about 284 feet below land surface; ground-water flow is to the southeast. Ground-water samples collected from monitoring wells at the Chromic Acid Pit site contained dissolved-solids concentrations of 442 to 564 milligrams per liter. Nitrate as nitrogen concentrations ranged from 2.1 to 2.7 milligrams per liter; nitrite plus nitrate as nitrogen concentrations ranged from 2.3 to 3.0 milligrams per liter. Nitrate concentrations are abnormally high in the Old Mesa well field located about 5,000 feet southwest of the Chromic Acid Pit site. Volatile and semivolatile organic compounds in water samples were analyzed for the first sampling round; no confirmed volatile or semivolatile organic compounds were detected above the laboratory reporting limits. Total chromium concentrations ranged from 0.0099 to 0.092 milligram per liter; dissolved chromium concentrations ranged from 0.0068 to 0.0094 milligram per liter. Overall, water-quality characteristics in water from the chromic acid pit ground-water monitoring wells are similar to those in the surrounding area. Detected chemical concentrations in water from the chromic acid pit monitoring wells during the four sampling periods were below U.S. Environmental Protection Agency-established maximum contaminant levels for public drinking water supplies. Statistical analyses were performed on 39 of the chemical constituents analyzed for in ground water from the chromic acid pit monitoring wells. Concentrations of chloride and fluoride were significantly less in water from the downgradient wells than in water from the upgradient well, whereas concentrations of nitrate as nitrogen, nitrite plus nitrate as nitrogen, and dissolved solids were significantly greater in water from the downgradient wells than in water from the upgradient well. Concentrations of nitrate as nitrogen were significantly different in water from the two downgradient wells. Differences detected through statistical analysis of chemical constituents of water in the chromic acid pit monitoring wells did not appear to indicate a release of hazardous chemicals from the chromic acid pit. There was no indication of ground-water contamination in either downgradient well.

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Hydrogeologic factors that affect the flowpath of water in selected zones of the Edwards Aquifer, San Antonio region, Texas

The Edwards aquifer in the San Antonio region supplies drinking water for more than 1 million people. Proper development and protection of the aquifer is a high priority for local and State authorities. To better understand the flow of water in two major flowpaths in the Edwards aquifer, stratigraphic, structural, hydrologic, and geochemical data were analyzed. The western Medina flowpath is in parts of Uvalde, Medina, and Bexar Counties, and the eastern flowpath is in northern Bexar and central Comal Counties. A major hydrogeologic factor that affects the pattern of flow in the Edwards aquifer is the spatial and temporal distribution of recharge. Other hydrogeologic factors that affect flowpaths include internal boundaries and the location and rate of spring discharge. The relative displacement of faults and the high permeability layers have substantial control on the discharge at springs and on the flowpaths in the Edwards aquifer. Analysis of the estimated recharge to the Edwards aquifer during 1982 89 indicated that during years of substantial precipitation, a large part of the net recharge probably is diffuse infiltration of precipitation over large parts of the recharge area. During years with below-normal precipitation, most recharge is leakage from rivers and streams that drain the catchment subbasins. In the western Medina flowpath, concentrations of major ions indicate saturation of calcite and undersaturation of dolomite the two minerals that constitute most of the Edwards aquifer matrix. Concentrations of dissolved calcium, alkalinity, and dissolved chloride in the eastern flowpath are greater than those in the western Medina flowpath. These upward trends in concentrations might result in part from: (1) increased development in the recharge area, (2) mineralized effluent from developed areas, or (3) increased dissolution of aquifer material. Tritium data from wells sampled in and near the western Medina flowpath indicate no vertical stratification of flow. Tritium concentrations in the recharge area of the western Medina flowpath are smaller than would be expected from previous studies and for the amount of recharge the area presumably received since 1952. Stable-isotopic data indicate that the water in the Edwards aquifer is meteoric and, except in one known area, has not been subjected to substantial evaporation or other isotope-fractionating processes. Evaporation of water from Medina Lake results in a heavier stable-isotopic ratio in lake water, which subsequently recharges the Edwards aquifer. The stable-isotopic data indicate that lake water does not enter either of the two flowpaths.

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Peak-flow frequency and extreme flood potential for streams in the vicinity of the Highland Lakes, central Texas

The Highland Lakes on the Colorado River are in an area periodically threatened by large storms and floods. Many storms exceeding 10 inches (in.) in depth have been documented in the area, including some with depths approaching 40 in. These storms typically produce large peak discharges that often threaten lives and property. The storms sometimes occur with little warning. Steep stream slopes and thin soils characteristic of the area often cause large peak discharges and rapid movement of floods through watersheds. A procedure to predict the discharge associated with large floods is needed for the area so that appropriate peak discharges can be used in the design of flood plains, bridges, and other structures. The U.S. Geological Survey (USGS), in cooperation with the Lower Colorado River Authority (LCRA), studied flood peaks for streams in the vicinity of the Highland Lakes of central Texas. The Highland Lakes are a series of reservoirs constructed on the Colorado River. The chain of lakes (and year each was completed) comprises Lake Buchanan (1937), Inks Lake (1938), Lake Lyndon B. Johnson (1950), Lake Marble Falls (1951), Lake Travis (1942), and lake Austin (1890). The study area (fig. 1), which includes all or parts of 21 counties in the vicinity of the Highland Lakes, was selected because most streams in the area have flood characteristics similar to streams entering the Highland Lakes. The entire study area is in a region subject to large storms. The purpose of this report is to present (1) peak-flow frequency data for stations and equations to estimate peak-flow frequency for large streams with natural drainage basins in the vicinity of the Highland Lakes, and (2) a technique to estimate the extreme flood peak discharges for the large streams in the vicinity of the Highland Lakes. Peak-flow frequency in this report refers to the peak discharges for recurrence intervals of 2,5, 10,25,50, and 100 years. A large stream is defined as having a contributing drainage area of at least0.5 square mile (mi’); and a natural drainage basin has less than 10 percent impervious cover and less than 10 percent of its drainage area controlled by reservoirs. The mean annual precipitation in the study area for 1951–80 ranges from about 20 in, in western Kimble County to about 34 in. at the eastern edge of Williamson County (Riggio and others, 1987, p. 23). Many large storms and catastrophic floods have occurred along or in the adjacent area west of the Balcones escarpment (fig. 1) (Dalrymple and others, 1939, Breeding and Dalrymple, 1944; Breeding and Montgomery, 1954; Schroeder and others, 1979; Caran and Baker, 1986; Slade, 1986; and Hejl and others, 1996). About a dozen storms with precipitation depths exceeding 15 in. in a few days or less have been documented in this area during the past 60 years. Some of these storms have produced world-record precipitation depths for durations less than 48 hours. The documentation for these and for other large storms indicates that they are not uniformly distributed temporally or spatially; therefore, the recurrence intervals for such storms cannot be verified (Slade, 1986, p. 17). These large storms can cause flood peaks that would exceed those that can be predicted accurately by analyses of available precipitation or flood data. The peak-flow frequency was estimated for each of 55 qualified stations in the study area (table 1) following guidelines established by the Interagency Advisory Committee on Water Data (1982). Qualified streamflow-gaging stations for the study area are those with at least 8 years of data from natural drainage basins (sites 1–55, fig. 1). Equations to estimate peak-flow frequency for large streams with natural drainage basins in the vicinity of the Highland Lakes were developed. These equations were developed from selected stations on the basis of the relation between peak-flow frequency and basin characteristics for each station. The entire period of systematic record (through 1993) was used in the frequency analyses for each qualified station except for stations at which streamflow was regulated during part of the record. These stations are Leon River near Belton (site 1): Lampasas River near Youngsport (site 5); North Fork San Gabriel River near Georgetown (site 6); San Gabriel River at Laneport (site 12); Brady Creek at Brady (site 16); San Saba River at San Saba (site 18); Rebecca Creek near Spring Branch (site 51); and Cibolo Creek near Boerne (site 54). One or more reservoirs were completed in the basin of each of these stations during the period of systematic record. These reservoirs caused the annual peak discharges to become regulated. The annual peak discharges for 1994 and 1995 at Sandy Creek near Kingsland (site 28) were used to include data associated with extreme flooding that occurred in 1995. The extreme flood potential in the study area was investigated using an "envelope" or "extreme flood potential" curve. This curve is based on the relation between the contributing drainage area and (1) the maximum peak discharge of record for each qualified station (table 1); (2) substantial peak discharges documented for 84 sites without stations (sites 56–139, fig. 1, table 2); and (3) 100-year peak discharges from peak-flow frequency for stations (table 1). Peak discharges estimated from this curve represent the extreme flood potential for the study area.

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Hydrogeology at Air Force Plant 4 and vicinity and water quality of the Paluxy Aquifer, Fort Worth, Texas

Ground water in the surficial terrace alluvial aquifer is contaminated at Air Force Plant 4, Fort Worth, Texas, and at the adjacent Naval Air Station. Some of the contaminated water has leaked from the terrace alluvial aquifer to an uppermost interval of the Paluxy Formation (the Paluxy "upper sand") beneath the east parking lot, east of the assembly building, and to the upper and middle zones of the Paluxy aquifer near Bomber Road, west of the assembly building. Citizens are concerned that contaminants from the plant, principally trichloroethylene and chromium might enter nearby municipal and domestic wells that pump water from the middle and lower zones of the Paluxy aquifer. Geologic formations that crop out in the study area, from oldest to youngest, are the Paluxy Formation (aquifer), Walnut Formation (confining unit), and Goodland Limestone (confining unit). Beneath the Paluxy Formation is the Glen Rose Formation (confining unit) and Twin Mountains Formation (aquifer). The terrace alluvial deposits overlie these Cretaceous rocks. The terrace alluvial aquifer, which is not used for municipal water supply, is separated from the Paluxy aquifer by the Goodland-Walnut confining unit. The confining unit restricts the flow of ground water between these aquifers in most places; however, downward leakage to the Paluxy aquifer might occur through the "window," where the confining unit is thin or absent. The Paluxy aquifer is divided into upper, middle, and lower zones. The Paluxy "upper sand" underlying the "window" is an apparently isolated, mostly unsaturated, sandy lens within the uppermost part of the upper zone. The Paluxy aquifer is recharged by leakage from Lake Worth and by precipitation on the outcrop area. Discharge from the aquifer primarily occurs as pumpage from municipal and domestic wells. The Paluxy aquifer is separated from the underlying Twin Mountains aquifer by the Glen Rose confining unit. Water-level maps indicate that (1) ground water in the terrace alluvial aquifer appears to flow outward, away from Air Force Plant 4; (2) a ground-water mound, possibly caused by downward leakage from the terrace alluvial aquifer, is present in the Paluxy "upper sand" beneath the "window;" and (3) lateral ground-water flow in regionally extensive parts of the Paluxy aquifer is from west to east-southeast. Trichloroethylene concentrations at Air Force Plant 4 have ranged from about 10,000 to about 100,000 micrograms per liter in the terrace alluvial aquifer, from 8,000 to 11,000 micrograms per liter in the Paluxy "upper sand," and from 2 to 50 micrograms per liter in the upper and middle zones of the Paluxy aquifer. Chromium concentrations at Air Force Plant 4 have ranged from 0 to 629 micrograms per liter in the terrace alluvial aquifer. The seven municipal wells mostly west and south of Air Force Plant 4 are not along a flowpath for leakage of contaminants from the plant because ground-water flow in the Paluxy aquifer is toward the east-southeast. Furthermore, trichloroethylene was not detected in any of these wells in 1993 when all were sampled for water quality. The results of water-quality sampling at 10 domestic wells northwest of the Air Force Plant 4 during April 1993 and April 1995 indicated that neither trichloroethylene nor chromium had migrated off-site to these wells.

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Simulation of storm peaks and storm volumes for selected subbasins in the West Fork Trinity River Basin, Texas, water years 1993-94

A model parameter set for use with the Hydrologic Simulation Program FORTRAN watershed model was developed to simulate storm peaks and storm volumes for the 28 subbasins of the West Fork Trinity River Basin upstream from Lake Worth, northwest of Fort Worth, Texas, from the calibration and testing of 5 gaged subbasins. These parameters can be transferred to the 23 ungaged subbasins. The model simulates storm runoff for a channel-routing model that can be used to improve reservoir operation during floods in the basin. Rainfall and runoff data were collected from October 1, 1992, to September 30, 1994. A total of 55 storms were recorded at the 5 streamgage stations during the 24 months. Twelve different pervious land segments were defined based on types of soil, land cover, and watershed slope. A total of 20 process-related parameters were defined for each land segment, and 6 basin-related parameters were defined for each stream reach. The mean absolute errors for the 5 subbasins for simulation of storm peaks range from 48.0 to 470 percent and for simulation of storm volumes range from 34.4 to 416 percent. A sensitivity analysis was done to determine what a change in a parameter value has on the largest storm peak and on the total storm volume. The model then was recalibrated and tested on the basis of the analysis of the sensitivity of parameters and on the analysis of the errors from the initial model calibration and testing. The mean absolute errors for the 5 subbasins using the recalibrated parameters for simulation of storm peaks range from 47.1 to 297 percent, and for simulation of storm volumes range from 27.6 to 193 percent. The model produced better results for simulation of the larger storm peaks and storm volumes than for simulation of the smaller storm peaks and storm volumes, especially after an extended period of no runoff. The same range in errors can be expected when transferring the parameters to the 23 ungaged subbasins. Additional data collection and model refinement could decrease the range of expected model errors. More storm data and improved discharge rating curves could result in model parameters that account for the wide seasonal variations in runoff in the study area.

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Water-quality assessment of the Trinity River Basin, Texas — Pesticides in streams draining an urban and an agricultural area, 1993-95

Water and bed-sediment samples from streams draining an urban and an agricultural area in the Trinity River Basin, Texas, were analyzed. The samples were collected during March 1993?September 1995 by the Trinity River Basin study-unit team of the National Water-Quality Assessment Program. A comparison of pesticide data for water samples from seven streams in the Dallas-Fort Worth urban area with five streams in an agricultural area in the west-central part of the Trinity River Basin showed detections of 24 herbicides in urban-area streams and 19 herbicides in agricultural-area streams and 10 insecticides in each area. Atrazine, a herbicide, was detected in all samples from both areas. Diazinon, an insecticide, was detected in all samples collected in urban-area streams and in about 60 percent of the samples collected in agricultural-area streams. Concentrations of alachlor, atrazine, fluometuron, metolachlor, and pendimethalin (herbicides) were always greater in agricultural-area streams, and prometon and simazine concentrations were always greater in urban-area streams. Atrazine was the only herbicide with concentrations greater than a health advisory limit of 3 micrograms per liter. Concentrations were greater in about 20 percent of the samples; all were in the agricultural area and occurred during spring and during higher streamflow. Diazinon was the only insecticide with concentrations greater than the health advisory of 0.6 microgram per liter. Concentrations were greater in about 15 percent of the samples from the urban area. All exceedances were during spring through early fall and during all ranges of streamflow. In the agricultural area, atrazine and metolachlor concentrations peaked during spring and early summer and increased with increasing streamflow; in the urban area, carbaryl, chlorpyrifos, and diazinon peaked in April and remained relatively high during the summer and increased with increasing streamflow. A comparison of pesticide data for bed-sediment samples from five urban streams and five agricultural streams showed detections of 11 organochlorine insecticides in the urban area and 1 in the agricultural area. All compounds were either DDT-related or one of the components of chlordane except for mirex and dieldrin.

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