Preliminary geologic and structure map of the northeast part of the Burdock quadrangle, Fall River and Custer counties, South Dakota
Prepared in cooperation with the U.S. Atomic Energy Commission
Geology topics
Source-linked reports with geographic coverage including South Dakota.
Prepared in cooperation with the U.S. Atomic Energy Commission
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Several uranium deposits are present in the Fall River sandstone of Early Cretaceous age on the northeast flank of the Black Hills, Butte County, South Dakota. The deposits are within a fine-grained, well-sorted, persistent basal sandstone unit that ranges in thickness from 2 to 18 feet and dips about 4° NE. Detailed mapping of about 2 square miles surrounding the deposits have shown that all the uranium occurrences and most of the areas of high radioactivity are where the color changes in the basal sandstone from reddish on the up-dip side of the the occurrences to yellowish-gray or buff down-dip. Radioactivity measurements show that uranium is distributed almost continuously along the sinuous red-buff contact for more than 5 miles. Laboratory work indicates that the red color is caused by the hematite resulting from the alteration of ferrous iron minerals and hydrous ferric oxides. The close association of the red-buff contact and the uranium deposits suggest that the two were formed by the same solutions. The uranium was probably deposited originally from ground water which moved down-dip and gradually changed from an oxidizing solution near the surface to a mildly reducing solution at depth. Concentrations of uranium have resulted from the localization of reducing conditions cause perhaps by structures superimposed on the regional dip, local thinning or decrease in permeability of the sandstone, or concentrations of pyritiferous carbonaceous material. The red alteration is probably the result of pre-Oligocene weathering that has extended downward in the more permeable beds about 200 feet below the ancient erosion surface. Oxidation of the primary uranium during the present weathering cycle has resulted in the formation of carnotite and possibly other secondary uranium minerals.
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Detailed studies have been carried out on a uraniferous lignite from the Mendenhall strip mine, Harding County, S. Dak. By means of heavy-liquid separations, a mineral-free concentrate of the lignite was obtained that contained 13.8 percent ash and 0.31 percent uranium in the ash. The minerals (gypsum 69 percent, jarosite 10 percent, quartz 2 percent, kaolinite and clay minerals 19 percent, and calcite trace) contain only 7 percent of the uranium in the original coal, indicating an association of the uranium with the organic components of the lignite.Batch extractions show that 88.5 percent of the uranium can be extracted from the lignite by two consecutive treatments with boiling 1 N hydrochloric acid. Continuous extraction with hot 6 N hydrochloric acid removes 98.6 percent of the uranium.Columns of coal were treated with water, 1 N hydrochloric acid, 6 N hydrochloric acid, and a solution of lanthanum nitrate. The experiment with lanthanum nitrate indicated that only 1.2 percent of the uranium in the coal is held by ion exchange. The elutriation experiments showed that the uranium is held in the coal as an organo-uranium compound or complex that is soluble at a pH of less than 2.18.A geochemical mechanism by which the uranium may have been introduced into and retained by the lignite is discussed.
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The Triangle A pegmatite is 4 miles southeast of Custer in the SW 1/4, sec. 34, T. 3 S., R. 5 E., Custer County, S. Dak. It may be reached from Custer by a gravel road 2.4 miles long that leaves U.S. Highway 16A at a point 3.2 miles east of Custer.