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Source-linked reports with geographic coverage including Pennsylvania.

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Water resources and the hydrologic effects of coal mining in Washington County, Pennsylvania

Washington County occupies an area of 864 square miles in southwestern Pennsylvania and lies within the Pittsburgh Plateaus Section of the Appalachian Plateaus physiographic province. About 69 percent of the county population is served by public water-supply systems, and the Monongahela River is the source for 78 percent of the public-supply systems. The remaining 31 percent of the population depends on wells, springs, and cisterns for its domestic water supply. The sedimentary rocks of Pennsylvanian and Permian age that underlie the county include sandstone, siltstone, limestone, shale, and coal. The mean reported yield of bedrock wells ranges from 8.8 gallons per minute in the Pittsburgh .Formation to 46 gallons per minute in the Casselman Formation. Annual water-level fluctuations usually range from less than 3 ft (feet) beneath a valley to about 16 ft beneath a hilltop. Average hydraulic conductivity ranges from 0.01 to 18 ft per day. Water-level fluctuations and aquifer-test results suggest that most ground water circulates within 150 ft of land surface. A three-dimensional computer flow-model analysis indicates 96 percent of the total ground-water recharge remains in the upper 80 to 110 ft of bedrock (shallow aquifer system). The regional flow system (more than 250ft deep in the main valley) receives less than 0.1 percent of the total ground-water recharge from the Brush Run basin. The predominance of the shallow aquifer system is substantiated by driller's reports, which show almost all water bearing zones are less than 150ft below land surface. The modeling of an unmined basin showed that the hydrologic factors that govern regional groundwater flow can differ widely spatially but have little effect on the shallow aquifers that supply water to most domestic wells. However, the shallow aquifers are sensitive to hydrologic factors within this shallow aquifer system (such as ground-water recharge, hydraulic conductivity of the streamaquifer interface, and hydraulic conductivity of the aquifer). A vertical fracture zone would probably increase ground-water availability within the zone and would probably result in a lower head in the shallow aquifers in an upland draw area and an increased head in a valley. l Streams in the northern and western parts of the county drain to the Ohio River and streams in the eastern and southern parts of the county drain to the Monongahela River. The computed 7-day, 10-year low-flow frequencies for the surface-water sites ranged from 0.0 to 55 x 10-3 cubic feet per second per square mile. The lowest low-flow discharges per square mile were in the south-central and southwestern parts of the county. The highest low-flow discharges per square mile were in the eastern and northern parts of the county. The annual water loss at five gaged streams ranged from 52 to 75 percent of the total precipitation. The loss resulted from evaporation, transpiration, diversion, mines, ground-water outflow from the system, and plant and animal consumption. The major ground-water-quality problems are elevated concentrations of iron, manganese, and dissolved solids, and very hard water. Minor groundwater-quality problems include elevated concentrations of fluoride, chloride, and sulfate. Downgradient along the ground-water flow path, principal ions change from mostly calcium, magnesium, sulfate, and bicarbonate to sodium and chloride. Dissolyed-solids concentrations generally increase with residence time .. Elevated concentrations of sulfate and total dissolved solids were common at the surface-water sites in the northern and eastern parts of the county where most of the active and abandohed coal mines are located and where acid mine drainage is most prevalent. However, measured alkalinity at most of the surface-water sites ranged from 86 to 345 milligrams per liter, indicating that these streams would have a neutralizing effect on most inflows of acid mine drainage. The model of the hypothetically mined Brush Run basin shows that the vertical hydraulic conductivity (either existing or induced by mine subsidence) between the shallow ground-water system and the mine, and the depth to the mine are critical controls on the amount of ground water entering the mine. When the vertical hydraulic conductivity was increased by a factor of four for a mine about 250 ft deep in the main valley, inflow to the mine increased almost by the same factor. The model also shows that increasing the depth to a mine by 200 ft (mine about 450 ft deep in main valley) would cause mine inflow to decrease one order of magnitude. Comparisons between stream discharges during low base-flow conditions in a mined basin (Daniels Run) and an unrnined basin (Brush Run) indicated that the deep mining did not substantially lower streamflow. Although streamflow decreased and, at times, completely disappeared in the middle and lower parts of Daniels Run basin, it reappeared again downstream as ground-water discharge and was part of the flow at the mouth of Daniels Run. Comparison of the water-quality characteristics of the two basins showed that concentrations of dissolved solids, sulfate, sodium, chloride, fluoride, and manganese were greater in the mined basin than in the unmined basin. The pH and iron concentrations were similar in both basins.

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Water resources data, Pennsylvania, water year 1992. Volume 2. Susquehanna and Potomac River basins

Water resources data for the 1992 water year for Pennsylvania consist of records of discharge and water quality of streams; contents and elevations of lakes and reservoirs; and water levels and water quality of ground-water wells. This report, Volume 2, includes records from the Susquehanna and Potomac River basins. Specifically, it contains (1) discharge records for 85 continuous-record streamflow-gaging stations and 38 partial-record stations; (2) elevation and contents records for 13 lakes and reservoirs; (3) water-quality records for 12 streamflow-gaging stations and 48 ungaged streamsites; and (4) water-level records for 25 observation wells. The location of these sites is shown in the figures. Additional water data collected at various sites not involved in the systematic data-collection program are also presented. These data together with the data in Volumes 1 and 3, represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating State, local, and Federal agencies in Pennsylvania.

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Water resources data, Pennsylvania, water year 1992. Volume 3: Ohio and St. Lawrence River basins

Water resources data for the 1992 water year for Pennsylvania consists of records of discharge and water quality of streams; contents and elevations of lakes and reservoirs; and water levels of ground-water wells. This report, Volume 3, includes records from the Ohio and St. Lawrence River basins. Specifically, it contains: (1) discharge records for 69 continuous record streamflow-gaging stations and 12 partial-record stations; (2) elevation and contents records for 3 lakes and reservoirs; (3) water-quality records for 3 streamflow-gaging stations and 36 partial-record stations; and (4) water-level records for 20 network observation wells. Locations of these sites are shown on figures 4-5. Additional water data were collected at various sites not involved in the systematic data-collection program and are published as miscellaneous measurements and analyses. These data, together with the data in Volume 1 and 2, represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating State, Local, and Federal agencies in Pennsylvania.

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Evaluation of nutrient quality-assurance data for Alexanders and Mount Rock Spring basins, Cumberland County, Pennsylvania

A total of 304 nutrient samples were collected from May 1990 through September 1991 to determine concentrations and loads of nutrients in water discharged from two spring basins in Cumberland County, Pa. Fifty-four percent of these nutrient samples were for the evaluation of (1) laboratory consistency, (2) container and preservative cleanliness, (3) maintenance of analyte representativeness as affected by three different preservation methods, and (4) comparison of analyte results with the "Most Probable Value" for Standard Reference Water Samples. Results of 37 duplicate analyses indicate that the Pennsylvania Department of Environmental Resources, Bureau of Laboratories (principal laboratory) remained within its ±10 percent goal for all but one analyte. Results of the blank analysis show that the sampling containers did not compromise the water quality. However, mercuric-chloride-preservation blanks apparently contained measurable ammonium in four of five samples and ammonium plus organic nitrogen in two of five samples. Interlaboratory results indicate substantial differences in the determination of nitrate and ammonium plus organic nitrogen between the principal laboratory and the U.S. Geological Survey National Water-Quality Laboratory. In comparison with the U.S. Environmental Protection Agency Quality-Control Samples, the principal laboratory was sufficiently accurate in its determination of nutrient anafytes. Analysis of replicate samples indicated that sulfuric-acid preservative best maintained the representativeness of the anafytes nitrate and ammonium plus organic nitrogen, whereas, mercuric chloride best maintained the representativeness of orthophosphate. Comparison of nutrient analyte determinations with the Most Probable Value for each preservation method shows that two of five analytes with no chemical preservative compare well, three of five with mercuric-chloride preservative compare well, and three of five with sulfuricacid preservative compare well.

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Fold patterns, lateral ramps and seismicity in central Pennsylvania

The Susquehanna lateral ramp crosses the entire length of Pennsylvania in a NNE direction and extends into southern New York State. Its presence was first suspected because of a dramatic change in fold wavelength across the Susquehanna River, seen on both side-looking airborne radar (SLAR *) data and the geologic map of Pennsylvania. Seismic reflection profiles confirm the presence of a ramp and show the detailed nature of structures associated with it. These structures include antiformal stacks, juxtaposed anticlines and synclines, and folds beheaded by thrust faults. The change in the fold pattern, which led to recognizing the lateral ramp, occurs above a rapid dropoff in depth to the basement suggesting that the ramp and the basement configuration may somehow be related. In plain view, eleven earthquakes are spatially related to the Susquehanna lateral ramp, although they are in the basement rocks rather than in the cover rocks which contain the lateral ramp itself. The earthquakes are, therefore, not likely directly associated with the ramp, though they may be affiliated with strike-slip faulting in the basement which, itself, appears to be partly responsible for the formation of the ramp. The initial age of the faulting along, and in the vicinity of, the Susquehanna lateral ramp is presumably Early to Middle Paleozoic. However, the presence of a surficially-exposed Mesozoic dike along the ramp and modern seismicity suggest that the Susquehanna lateral ramp may be a zone of protracted, and perhaps repeated, tectonism which is currently being reactivated. A preliminary evaluation of the distribution of modern earthquakes in the Valley and Ridge, Blue Ridge and Appalachian Plateau shows that nearly half of the earthquakes are located under lateral ramps. If this observation is true, the presence of ramps may be a useful geological indicator of areas susceptible to seismicity.

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Water-resources data for North Fork Bens Creek, Somerset County, Pennsylvania, August 1983 through September 1988

Basin and climatological characteristics, quality-assurance data and results, and water-resources data for North Fork Bens Creek, in Somerset County, Pennsylvania are available from August 1983 through September 1988. The lowest temperature (-30. 0 C) was recorded during January 1985, and the highest temperature (36.7 C) was recorded during July 1988. Snowfall accumulates mostly during January and February and averages about 69 in annually. Solar radiation is most intense from late May to early June. Pan evaporation averages 0.17 in/day during the growing season and 0.02 in/day during the nongrowing season. Sulfur dioxide and sulfate contaminants in the air have declined since 1977; nitrogen dioxide and nitrates have remained constant. Average volume-weighted pH for precipitation in western Pennsylvania is about 4.0. Quality assurance analyses show that chemical data collected from August 1983 through February 1986 were satisfactory. Precision of data quality for March 1986 through September 1988 are marginal to satisfactory. Monthly base flow water-quality data are available from August 1983 through September 1988. Continuous precipitation data are available from October 1983 through September 1988. Precipitation was typically higher than normal for the 1984, 1985, and 1986 water years. Continuous streamflow data are available for water years 1985 and 1988. The maximum recorded discharge of 92 cu ft/sec was observed on March 31, 1985. (USGS)

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Tributary-stream infiltration in Marsh Creek Valley, north-central Pennsylvania

The geohydrology of infiltration from five tributary streams along a 3.6-mile reach of Marsh Creek valley in north-central Pennsylvania was investigated during 1983-85. Marsh Creek valley is underlain by up to 100 feet of stratified drift that overlies Devonian bedrock. The stratified drift is overlain by up to 30 feet of alluvial-fan deposits near the tributary streams. Four of the five tributary streams lose large amounts of water to the stratified-drift aquifer in Marsh Creek valley. Along reaches away from the valley wall, infiltration losses from the streams averaged about 2 cubic feet per second per 1,000 feet of wetted channel length. Estimated hydraulic conductivity of the deposits near these streams ranges from 31 to 100 feet per day and averages 61 feet per day. Silty beds of lower permeability near the streams may significantly affect infiltration. The low permeability of the sediments near the fifth stream, which probably consist largely of fine-grained alluvium and swamp deposits, may account for the lack of infiltration losses along this stream. Tributary-stream infiltration accounted for more than 70 percent of the estimated recharge to the stratified-drift aquifer along the reach investigated during water year 1985, in which annual precipitation was below average. The sources of recharge and their estimated rates were: (1) direct infiltration of precipitation on the valley, 1.7 cubic feet per second; (2) unchanneled runoff and ground-water inflow from the uplands, 2.7 cubic feet per second; and (3) tributary-stream infiltration from Asaph Run, 3.7 cubic feet per second, Straight Run, 3.7 cubic feet per second, Dantz Run, 1.2 cubic feet per second, and Canada Run, 1.9 cubic feet per second. The temporal variation in recharge from tributary-stream infiltration greatly affects drawdowns caused by pumping from the wellfield at the National Fisheries Research and Development Laboratory near Straight Run.

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Hydrology and the hypothetical effects of reducing nutrient applications on water quality in the Bald Eagle Creek Headwaters, southeastern Pennsylvania prior to implementation of agricultural best-management practices

The report characterizes a 0.43-square-mile agricultural watershed in York County, underlain by albite-chlorite and oligoclase-mica schist in the Lower Susquehanna River basin, that is being studied as part of the U.S. Environmental Protection Agency's Chesapeake Bay Program. The water quality of Bald Eagle Creek was studied from October 1985 through September 1987 prior to the implementation of Best-Management Practices to reduce nutrient and sediment discharge into Muddy Creek, a tributary to the Chesapeake Bay. About 88 percent of the watershed is cropland and pasture, and nearly 33 percent of the cropland is used for corn. The animal population is entirely dairy cattle. About 85,640 pounds of nitrogen (460 pounds per acre) and 21,800 pounds of phosphorus (117 pounds per acre) were applied to fields; 52 percent of the nitrogen and 69 percent of the phosphorus was from commercial fertilizer. Prior to fertilization, nitrate nitrogen in the soil ranged from 36 to 136 pounds per acre and phosphorus ranged from 0.89 to 5.7 pounds per acre in the top 4 feet of soil. Precipitation was about 18 percent below normal and streamflow about 35 percent below normal during the 2-year study. Eighty-four percent of the 20.44 inches of runoff was base flow. Median concentrations of total nitrogen and dissolved phosphorous in base flow were 0.05 and 0.04 milligrams per liter as phosphorus, respectively. Concentrations of dissolved nitrate in base flow increased following wet periods after crops were harvested and manure was applied. During the growing season, concentrations decreased similarly to those observed in carbonate-rock areas as nutrient uptake and evapotranspiration by corn increased. About 4,550 pounds of suspended sediment, 5,250 pounds of nitrogen, and 66.6 pounds of phosphorus discharged in base flow during the 2-year period. The suspended sediment load was about 232,000 pounds in stormflow from 26 storms that contributed 51 percent of the total stormflow. The nitrogen load was about 651 pounds and the phosphorus load was about 74 pounds in stormflow from 16 storms that contributed 28 percent of the total stormflow. It is estimated that concentrations of total nitrogen and phosphorus in base flow need to be reduced by 12 and 48 percent, respectively, to detect changes during the nutrient-management phase. Likewise, loads to total nitrogen and phosphorus in base flow need to be reduced by 62 and 57 percent.

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Geochemical evolution of acidic ground water at a reclaimed surface coal mine in western Pennsylvania

Concentrations of dissolved sulfate and acidity in ground water increase downflow in mine spoil and underlying bedrock at a reclaimed surface coal mine in the bituminous field of western Pennsylvania. Elevated dissolved sulfate and negligible oxygen in ground water from bedrock about 100 feet below the water table suggest that pyritic sulfur is oxidized below the water table, in a system closed to oxygen. Geochemical models for the oxidation of pyrite (FeS 2 ) and production of sulfate (SO 4 2- ) and acid (H + ) are presented to explain the potential role of oxygen (O 2 ) and ferric iron (Fe 3+ ) as oxidants. Oxidation of pyrite by O 2 and Fe 3+ can occur under oxic conditions above the water table, whereas oxidation by Fe 3+ also can occur under anoxic conditions below the water table. The hydrated ferric-sulfate minerals roemerite [Fe 2+ Fe 4 3+ (SO 4 ) 4 ·14H 2 O], copiapite [Fe 2+ Fe 4 3+ (SO 4 ) 6 (OH) 2 ·20H 2 0], and coquimbite [Fe 2 (SO 4 ) 3 · 9H 2 O] were identified with FeS 2 in coal samples, and form on the oxidizing surface of pyrite in an oxic system above the water table. These soluble ferric-sulfate 11 salts11 can dissolve with recharge waters or a rising water table releasing Fe 3+ , SO 4 2- . and H + , which can be transported along closed-system ground-water flow paths to pyrite reaction sites where O 2 may be absent. The Fe 3+ transported to these sites can oxidize pyritic sulfur. The computer programs WATEQ4F and NEWBAL were used to compute chemical speciation and mass transfer, respectively, considering mineral dissolution and precipitation reactions plus mixing of waters from different upflow zones. Alternative mass-balance models indicate that (a) extremely large quantities of O 2 , over 100 times its aqueous solubility, can generate the observed concentrations of dissolved SO 4 2- from FeS 2 , or (b) under anoxic conditions, Fe 3+ from dissolved ferric-sulfate minerals can oxidize FeS 2 along closed-system ground-water flow paths. In a system open to O 2 , such as in the unsaturated zone, the aqueous solubility of O 2 is not limiting, and oxidation of pyrite by O 2 and Fe 3+ accounts for most SO 4 2- and Fe 2+ observed in acidic ground water. However, in a system closed to O 2 , such as in the saturated zone, O 2 solubility is limiting; hence, ferric oxidation of pyrite is a reasonable explanation for the observed elevated SO 4 2- with increasing depth below the water table.

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