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Research about New Jersey

Source-linked reports with geographic coverage including New Jersey.

At least 289 records · Page 16Linked to original sources

Sr-isotopic evidence for leakage of pore water from clay-silt confining units to the Atlantic City 800-foot sand, Atlantic City, New Jersey

The evolution of water quality in confined aquifers in the New Jersey Coastal Plain may be affected by leakage of pore water from the adjacent confining units. We investigated the distribution and sources of solutes, particularly Sr, in pore water mechanically extracted from clay-silt core samples collected from depths of 552–840 ft (168–256 m) in the lower Miocene Kirkwood Formation at Atlantic City, New Jersey (Ocean Drilling Program Leg 150X). The sampled sediments consist of thin clay-silt stringers in the upper part of the Atlantic City 800-ft sand, a major aquifer, and the massive clay-silt units above and below it. The distribution of Sr and the ratio of 87 Sr to 86 Sr in the pore water and adjacent shell material were used to identify the possible sources of, and physical processes that may affect the distribution of, Sr in the pore water. Concentrations of Sr in 14 pore-water samples from the clay-silt unit above the aquifer and the clay-silt interbeds in the upper part of the aquifer ranged from 2.74 to 28.19 µM/L; those in the four pore-water samples from the clay-silt unit below the aquifer ranged from 0.52 to 7.30 µM/L. Concentrations of Sr in the samples varied with depth but correlated strongly with pore-water concentrations of Ca, Mg, Na, and SO4. Cation-exchange processes may be responsible, in part, for the lower concentrations of Sr, Ca, and Mg in pore water from the clay-silt unit below the aquifer than in that above the aquifer. 87 Sr/ 86 Sr values in 11 samples of aragonitic mollusk shells (bearing no visible evidence of recrystallization) collected from depths in the clay-silt unit similar to those from which the pore-water samples were collected ranged from 0.708468 to 0.708713 , and decreased (Sr in the shells was less radiogenic) with depth. This trend is consistent with the decrease in the 87 Sr/ 86 Sr value in seawater through time during the early Miocene. The 87 Sr/ 86 Sr values in 12 pore-water samples from the studied stratigraphic interval ranged from 0.708257 to 0.708527 and also decreased with depth. The Sr-isotope ratios in the pore water were lower than those in the shell material from nearby or adjacent sediments for all samples but one. Because the only known source of Sr with an isotope ratio this low is shell material from sediments deeper than the strata from which the pore-water samples were collected (including pre-Miocene stratigraphic units), the isotope ratio in the pore-water samples from the lower Miocene claysilt units may result from upward movement of pore water into lower Miocene strata through geologic time, which could create the observed difference in Sr isotope ratios between the pore water and shells.

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Upper Eocene sequence stratigraphy and the Absecon Inlet Formation, New Jersey Coastal Plain

We evaluate the age, benthic biofacies, and sequence stratigraphy of thick and well-recovered upper Eocene sediments from the New Jersey Coastal Plain. These strata are herein defined as a lithostratigraphic unit and named the Absecon Inlet Formation. The formation is divided into upper and lower portions. At its type locality in the Atlantic City borehole, the lower portion of the Absecon Inlet Formation consists of 171 ft (52 m) of glauconitic silts and silty clays and is assigned to calcareous nannoplankton Zone NP 19/20 (late Eocene). At the ACGS#4 borehole, the type locality for its upper portion, the formation consists of slightly sandy clays and is assigned to Zone NP 21 (late Eocene to earliest Oligocene). The continuous stratigraphic occurrence of Hantkenina spp. in these sediments is evidence of an Eocene age for the upper portion of the Absecon Inlet Formation. Benthic foraminiferal analysis reveals five biofacies in the Absecon Inlet Formation, three of which can be related to paleowater depth: a Siphonina biofacies inhabited water depths of 75 ± 25 m; a Cibicidoides biofacies inhabited water depths of 100 ± 30 m; and a Globobulimina biofacies inhabited water depths of 125 ± 30 m. In addition, a Gyroidinoides biofacies occurs only within transgressive systems tracts. A Bulimina jacksonensis biofacies is believed to be related to a circum-Atlantic paleoceanographic event unrelated to depth changes on the shelf. Gamma-log, lithologic, and faunal/floral data are used to interpret the sequence stratigraphic architecture of the Absecon Inlet Formation. We conclude that the timing of unconformities (sequence boundaries) and maximum flooding surfaces within the Absecon Inlet Formation is consistent with the eustatic record of Exxon and the global δ 18 O record.

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Presence and distribution of trace elements in streambed sediments, New Jersey

The National Water Quality Assessment (NAWQA) Program, developed by the U.S. Geological Survey (USGS), was implemented in 1991 to (1) provide a nationally consistent description of the status of surface- and ground-water quality in systems that represent a large part of the Nation's water resources, (2) determine water-quality trends, and (3) determine relations between past and present water quality and land- and waste-management practices. Information collected and interpreted as part of NAWQA will add to the scientific basis for water-management decisions and policy formulation (Leahy and others, 1990).

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Relation of hydrogeologic characteristics to distribution of radioactivity in ground water, Newark Basin, New Jersey

The distribution of radioactivity in ground water in the Newark Basin is controlled by the lithology of the aquifer and the degree of contact between the water that flows through the fractured strata and the radioactive lithologic units. The primary water-bearing lithologic units of the Newark Basin that contain elevated levels of radioactivity are the arkosic sandstones of the Stockton Formation and the black mudstones of the lower part of the Passaic Formation. Lithologic and hydrogeologic characteristics of these rock aquifers that affect the spatial distribution of radionuclides in the water include the concentration of radioactive minerals in the strata; the continuity of radioactive strata; the orientation, depth, interconnectedness, and continuity of regional and local fracture patterns; and the geochemical environment, which affects radionuclide solubility. The stratigraphic zones of uranium enrichment and the continuity of the radioactive strata differ between the Stockton Formation and the lower part of the Passaic Formation. Uranium enrichment in both formations, however, is identified in permeable sections of strata that have sharp contacts with, or that are enclosed by, less permeable zones. In the Stockton Formation, basal conglomerates overlying fine-grained mudstones are the most radioactive lithology. In interbedded red and black mudstones of the lower part of the Passaic Formation, the uranium-rich zones are the black and white carbonate-rich siltstone and mudstone laminae overlying massive fine-grained mudstones. Most samples of the arkosic sandstones of the Stockton Formation tended to be slightly enriched in uranium relative to thorium, whereas all samples of the black mudstones of the lower part of the Passaic Formation were heavily enriched in uranium with respect to thorium, with a maximum concentration of uranium of 6,200 parts per million (ppm). Spatial orientation of radioactive zones is controlled by the depositional environment of the host lithology. Radioactive strata in the arkosic sandstones of the Stockton Formation, which is deltaic or fluvial/deltaic in origin, arc stratigraphically discontinuous and nonplanar. In contrast, the radioactive lacustrine black mudstones of the lower part of the Passaic Formation are laterally continuous and planar. Geophysical logs of boreholes indicate that the number and depths of probable waterbearing fractures are greater in the arkoses of the Stockton Formation and red mudstones of the lower part of the Passaic Formation than in the interbedded red and black mudstones of the lower part of the Passaic Formation, despite the fact that fracture-density counts in cores indicate that black mudstones are more highly fractured than the other rock types. The total number of fractures is greater and bedding-plane fractures are generally more common in the lower part of the Passaic Formation than in the Stockton Formation. Fractures in the Stockton Formation form a well-connected network consisting of both bedding-plane and several sets of high-angle fractures present on a regional scale. The large-scale continuity of interconnected bedding-plane fractures and high-angle regional fractures may be partly responsible for the higher yields observed for wells in the Stockton Formation than for wells in the Passaic Formation and may facilitate migration of dissolved radionuclides far from their source. The well-connected fracture network may increase the likelihood that circulating water comes in contact with radioactive strata. Water in the black mudstones of the lower part of the Passaic Formation may also contain high levels of radioactivity, primarily as a result of the high frequency of radioactive strata and of fracturing, rather than the presence of a well-connected regional fracture system. Ground-water chemistry is dominated by the calcium cation and the bicarbonate anion, both derived from abundant secondary calcite in the fractures. The concentrations of uranium and radium in water that comes into contact with radioactive rock are controlled by the water chemistry. Uranium is the dominant alpha emitter in the oxidizing waters in the red mudstones of the Passaic Formation, whereas radium-226 (226Ra) is the dominant alpha emitter in the suboxic (reducing) water in the black mudstones of the lower part of the Passaic Formation. Because the lithology of the Stockton Formation and, in places, the lower part of the Passaic Formation varies greatly, wells can intercept multiple fracture zones that can contain oxic or suboxic waters, thereby resulting in the presence of both uranium and radium in detectable quantities in the same water sample.

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Occurrence of nitrate, pesticides, and volatile organic compounds in the Kirkwood-Cohansey aquifer system, southern New Jersey

Water samples were collected from a network of 72 shallow monitoring wells to assess the chemical quality of recently recharged ground water in the surficial Kirkwood- Cohansey aquifer system of southern New Jersey. The wells are randomly distributed among agricultural, urban, and undeveloped areas to provide data representative of chemical conditions of ground water underlying each of these land-use settings. Samples were analyzed for nutrients, pesticides, and volatile organic compounds (VOC's). Concentrations of nitrate were highest in agricultural areas, where the U.S. Environmental Protection Agency (USEPA) Maximum Contaminant Level (MCL) of 10 mg/L (milligrams per liter) as nitrogen was exceeded in 60 percent of the samples. Concentrations of nitrate were intermediate in urban areas, where the 10-mg/L concentration was exceeded in only 1 of 44 samples. All concentrations in samples from undeveloped areas were less than 1.0 mg/L. Pesticides and VOC's were frequently detected; however, concentrations were low and rarely exceeded established or proposed USEPA or N.J. Department of Environmental Protection (NJDEP) drinking-water regulations. With the exception of the agricultural pesticide dinoseb, established regulations are at least 2.9 times the maximum concentration for pesticides and at least 5 times the maximum concentration for VOC's reported in the samples from the 72-well network. Investigations by the U.S. Geological Survey (USGS) are ongoing in southern New Jersey to evaluate the (1) presence and concentration of pesticide-degradation byproducts in shallow ground water; (2) presence and movement of nitrate, pesticides, and VOC's in the atmosphere, streams, unsaturated zone, and aquifers; (3) transport and fate of these compounds as they migrate deeper into the aquifer system; and (4) implications of these findings for the integrity of the regional water supply.

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Cometabolic biodegradation of trichloroethylene in microcosms

Laboratory microcosms were used to determine the concentrations of oxygen (O 2 ) and methane (CH 4 ) that optimize trichloroethylene (TCE) biodegradation in sediment and ground-water samples from a TCE-contaminated aquifer at Picatinny Arsenal, Morris County, New Jersey. The mechanism for degradation is the cometabolic activity of methanotrophic bacteria. The laboratory data will be used to support a field study designed to demonstrate the effectiveness of combining air sparging with cometabolic degradation of TCE for the purpose of aquifer remediation. Microcosms were constructed in autoclaved 250-mL (milliliter) amber glass bottles with valves for repeated headspace sampling. Equal volumes (25 mL) of sediment and ground water, collected from a depth of 40 feet, were added. TCE was added to attain initial aqueous concentrations equal to the field level of 1,400 mu g/L (micrograms per liter). Nine microcosms were constructed with initial headspace O 2 concentrations of 5%, 10%, or 14% and CH 4 concentrations of 0.5%, 3%, or 5%, with nitrogen making up the balance. Sterile controls, controls without CH 4 , and controls without sediment were also constructed. A 4-mL gas sample was removed periodically and TCE, O 2 , CH 4 , and carbon dioxide (CO 2 ) concentrations were measured by using gas chromatography. As biodegradation proceeded, the decrease in O 2 , CH 4 , and TCE concentrations and the production of CO 2 were monitored. An initial acclimation period of at least 100 days was observed in those microcosms in which significant microbial activity occurred, as determined from decreases in O 2 and CH 4 concentrations and an increase in CO 2 content. Degradation of TCE occurred with O 2 concentrations of 2.7 to 8.7% and CH 4 concentrations of 0.5 to 3.5%. Microcosms that initially contained 10% O 2 and 3% CH 4 showed the greatest microbial activity and the greatest amount of TCE degradation. The greatest rates of TCE degradation occurred when O 2 and CH 4 headspace concentrations reached levels of 7.7 to 8.7% and 1.7 to 2.7%, respectively, which correspond to aqueous concentrations of 2.9 to 3.5 mg/L and 0.4 to 0.6 mg/L, respectively. Over these ranges, TCE degradation rates ranged from 15 to 20 mu g of TCE per kilogram of sediment per day. Analysis of the control microcosms indicated that these TCE degradation rates are much greater than those attributable to experimental variation. The results indicate that the microbial community of the sediment is capable of TCE degradation and that significant rates of degradation can be achieved with obtainable O 2 and CH 4 concentrations.

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Age dating of shallow groundwater with chlorofluorocarbons, tritium/helium: 3, and flow path analysis, southern New Jersey coastal plain

Groundwater age dating through the combination of transient tracer methods (chlorofluorocarbons (CFCs) and tritium/helium 3 ( 3 H/ 3 He)) and groundwater flow path analysis is useful for investigating groundwater travel times, flow patterns, and recharge rates, as demonstrated by this study of the homogeneous shallow, unconfined Kirkwood-Cohansey aquifer system in the southern New Jersey coastal plain. Water samples for age dating were collected from three sets of nested observation wells (10 wells) with 1.5-m-long screens located near groundwater divides. Three steady state finite difference groundwater flow models were calibrated by adjusting horizontal and vertical hydraulic conductivities to match measured heads and head differences (range, 0.002–0.23 m) among the nested wells, with a uniform recharge rate of 0.46 m per year and porosities of 0.35 (sand) and 0.45 (silt) that were assumed constant for all model simulations and travel time calculations. The simulated groundwater travel times increase with depth in the aquifer, ranging from about 1.5 to 6.5 years for the shallow wells (screen bottoms 3–4 m below the water table), from about 10 to 25 years for the medium-depth wells (screen bottoms 8–19 m below the water table), and from about 30 to more than 40 years for the deep wells (screen bottoms 24–26 m below the water table). Apparent groundwater ages based on CFC- and 3 H/ 3 He-dating techniques and model-based travel times could not be statistically differentiated, and all were strongly correlated with depth. Confinement of 3He was high because of the rapid vertical flow velocity (of the order of 1 m/yr), resulting in clear delineation of groundwater travel times based on the 3 H/ 3 He-dating technique. The correspondence between the 3 H/ 3 He and CFC ages indicates that dispersion has had a minimal effect on the tracer-based ages of water in this aquifer. Differences between the tracer-based apparent ages for seven of the 10 samples were smaller than the error values. A slight bias toward older apparent ages, found not to be statistically significant, was noted for the 3 H/ 3 He-dating technique relative to the CFC-dating technique. This result may be caused by enrichment of local air in CFC-Il and CFC-12 from urban and industrial sources in the northeastern United States and minor contamination from sampling equipment. The demonstrated validity of the combined tracer-dating techniques to determine the age of water in the Kirkwood-Cohansey aquifer system indicates that groundwater flow models can be refined when apparent ages based on 3 H/ 3 He- and CFC- dating are used as calibration targets.

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Vulnerability of public drinking water supplies in New Jersey to pesticides

Beginning in 1993, Safe Drinking Water Act (SDWA) regulations required the 626 large community water systems in New Jersey to monitor their 2,600 wells and 45 surface-water intakes quarterly for 23 pesticides. Monitoring costs would increase consumers’ water bills by $6.4 million each year. The New Jersey Department of Environmental Protection (NJDEP) can waive monitoring requirements for wells or intakes that are not vulnerable to pesticide contamination. The U.S. Geological Survey (USGS), in cooperation with NJDEP, determined the vulnerability of wells and surface-water intakes to pesticide contamination on the basis of hydrogeology and pesticide use. The NJDEP estimated that because many wells and intakes are not vulnerable to contamination by pesticides, monitoring waivers will save taxpayers at least $5.1 million annually for a one-time study cost of $1 million.

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Managing drought risk with a computer model of the Raritan River Basin water-supply system in central New Jersey

The reservoirs and pumping stations that comprise the Raritan River Basin water-supply system and its interconnections to the Delaware-Raritan Canal water-supply system, operated by the New Jersey Water Supply Authority (NJWSA), provide potable water to central New Jersey communities. The water reserve of this combined system can easily be depleted by an extended period of below-normal precipitation. Efficient operation of the combined system is vital to meeting the water-supply needs of central New Jersey. In an effort to improve the efficiency of the system operation, the U.S. Geological Survey (USGS), in cooperation with the NJWSA, has developed a computer model that provides a technical basis for evaluating the effects of alternative patterns of operation of the Raritan River Basin water-supply system. This fact sheet describes the model, its technical basis, and its operation.

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Reconnaissance of volatile organic compounds in the subsurface at Rutgers University, Busch Campus, Piscataway Township, New Jersey

During 1991-92, the U.S. Geological Survey conducted a hydrogeologic reconnaissance at a site near the Rutgers University, Busch Campus, Chemical Engineering building, C-Wing. Results of analyses of the soil-gas samples, which were collected at 43 locations, indicated the presence of volatile organic compounds, primarily carbon tetrachloride, near the C-Wing building and about 550 feet downgradient from and southwest of the C-Wing building. Concentrations of the compound in soil-gas samples were highest (2.1 ug/L (micrograms per liter)) along the southwestern wall of the C-Wing building. Ground-water samples were collected at depths as great as 55 feet from five wells and piezometers near the C-Wing building. Samples collected along the southwestern wall of the building also contained the highest concentrations of volatile organic compounds. Concentrations of carbon tetrachloride in the ground-water samples ranged from < 0.35 ug/L to 3,400 ug/L, and concentrations of tetrachloro- ethylene ranged from < 0.28 ug/L to 85 ug/L. Ground-water samples collected at depths of 55 feet or more from two wells located on the Rutgers University Golf Course about 2,400 feet down- gradient from the C-Wing building contained concentrations of tetrachloroethylene as great as 17.7 ug/L. Water levels measured in six wells and six piezometers indicated that the general flow direction in the shallow part of the aquifer is to the southwest of the C-Wing building. An electrical-resistivity survey was conducted by azimuthal resistivity techniques. The results of the survey were consistent with field measurements, and the dominant vertical fractures near the Busch Campus trend northeast. An electromagnetic survey was ineffective as a result of cultural interferences and could not be used to determine the hydrogeologic characteristics of the site.

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