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Research about New Jersey

Source-linked reports with geographic coverage including New Jersey.

At least 199 records · Page 11Linked to original sources
USGS2006

Overview of investigations into mercury in ground water, soils, and septage, New Jersey coastal plain

Since the early 1980s, investigations by health departments of eight counties in southern New Jersey, by the NJ Department of Environmental Protection (NJDEP), and subsequently by the US Geological Survey (USGS), have shown that Hg concentrations in water tapped by about 600 domestic wells exceed the maximum contaminant level (MCL) of 2 μg/L. The wells are finished in the areally extensive unconfined Kirkwood-Cohansey aquifer system of New Jersey's Coastal Plain; background concentrations of Hg in water from this system are < 0.01 μg/L. Evidence of contributions from point sources of Hg, such as landfills or commercial and industrial hazardous-waste sites, is lacking. During 1996–2003, the USGS collected water samples from 203 domestic, irrigation, observation, and production wells using ultraclean techniques; septage, leach-field effluent, soils, and aquifer sediments also were sampled. Elevated concentrations of NH 4 , B, Cl, NO 3 , and Na and presence of surfactants in domestic-well water indicate that septic-system effluent can affect water quality in unsewered residential areas, but neither septage nor effluent appears to be a major Hg source. Detections of hydrogen sulfide in ground water at a residential area indicate localized reducing conditions; undetectable SO 4 concentrations in water from other residential areas indicate that reducing conditions, which could be conducive to Hg methylation, may be common locally. Volatile organic compounds (VOCs), mostly chlorinated solvents, also are found in ground water at the affected areas, but statistically significant associations between presence of Hg and VOCs were absent for most areas evaluated. Hg concentrations are lower in some filtered water samples than in paired unfiltered samples, likely indicating that some Hg is associated with particles or colloids. The source of colloids may be soils, which, when undisturbed, contain higher concentrations of Hg than do disturbed soils and aquifer sediments. Soil disturbance during residential development and inputs from septic systems are hypothesized to mobilize Hg from soils to ground water.

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USGS2006

Tracing the continuity of pleistocene aquifers in northern New Jersey by seismic methods

Seismic refraction measurements were used to draw a new bedrock contour map in Morris County, New Jersey , where the major ground‐water supplies are found in Quaternary sand and gravel deposits filling pre‐ Pleistocene channels. Aquifer performance tests aided in tracing the continuity of the Quaternary aquifers in these channels. In one case, the lack of continuity between two wells substantiated the seismic prediction that two separate channels were involved. The success of the seismic exploration emphasizes the value of using such methods , so that test drilling can be devoted to exploring the more favorable areas for production wells.

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USGS2006

Mercury in ground water, septage, leach-field effluent, and soils in residential areas, New Jersey coastal plain

Water samples were collected from domestic wells at an unsewered residential area in Gloucester County, New Jersey where mercury (Hg) concentrations in well water were known to exceed the USEPA maximum contaminant level (MCL) of 2000 ng/L. This residential area (the CSL site) is representative of more than 70 such areas in southern New Jersey where about 600 domestic wells, sampled previously by State and county agencies, yielded water containing Hg at concentrations that exceed the MCL. Recent studies indicate that background concentrations of Hg in water from this unconfined sand and gravel aquifer system are < 10 ng/L. Additional sampling was conducted at the CSL site in order to better understand sources of Hg and potential Hg transport mechanisms in the areas with Hg-contaminated ground water. At the CSL site, concentrations of Hg were substantially lower (although still exceeding the MCL in some cases) in filtered water samples than in the unfiltered water samples collected previously from the same wells. Surfactants and elevated concentrations of sodium, chloride, nitrate, ammonium, and phosphate in water from domestic and observation wells indicated septic-system effects on water quality; detections of sulfide indicated localized reducing conditions. Hg concentrations in septage and leach-field effluent sampled at several other households in the region were low relative to the contaminant-level Hg concentrations in water from domestic wells. Relations of Hg concentrations in leach-field effluent to iron concentrations indicate that reductive dissolution of iron hydroxides in soils may release Hg to the percolating effluent.

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USGS2006

Delineating a shallow fault zone and dipping bed rock strata using multichannal analysis of surface waves with a land streamer

The multichannel analysis of surface waves (MASW) seismic method was used to delineate a fault zone and gently dipping sedimentary bedrock at a site overlain by several meters of regolith. Seismic data were collected rapidly and inexpensively using a towed 30-channel land streamer and a rubberband-accelerated weight-drop seismic source. Data processed using the MASW method imaged the subsurface to a depth of about 20 m "> 20 m 20m and allowed detection of the overburden, gross bedding features, and fault zone. The fault zone was characterized by a lower shear-wave velocity ( V s ) "> ( V s ) (Vs) than the competent bedrock, consistent with a large-scale fault, secondary fractures, and in-situ weathering. The MASW 2D V s "> V s Vs section was further interpreted to identify dipping beds consistent with local geologic mapping. Mapping of shallow-fault zones and dipping sedimentary rock substantially extends the applications of the MASW method.

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USGS2006

Hydraulic and solute-transport properties and simulated advective transport of contaminated ground water in a fractured-rock aquifer at the Naval Air Warfare Center, West Trenton, New Jersey, 2003

Volatile organic compounds, predominantly trichloroethylene and its degradation products, have been detected in ground water at the Naval Air Warfare Center (NAWC), West Trenton, New Jersey. An air-stripping pump-and-treat system has been in operation at the NAWC since 1998. An existing ground-water-flow model was used to evaluate the effect of a change in the configuration of the network of recovery wells in the pump-and-treat system on flow paths of contaminated ground water. The NAWC is underlain by a fractured-rock aquifer composed of dipping layers of sedimentary rocks of the Lockatong and Stockton Formations. Hydraulic and solute-transport properties of the part of the aquifer composed of the Lockatong Formation were measured using aquifer tests and tracer tests. The heterogeneity of the rocks causes a wide range of values of each parameter measured. Transmissivity ranges from 95 to 1,300 feet squared per day; the storage coefficient ranges from 9 x 10-5 to 5 x 10-3; and the effective porosity ranges from 0.0003 to 0.002. The average linear velocity of contaminated ground water was determined for ambient conditions (when no wells at the site are pumped) using an existing ground-water-flow model, particle-tracking techniques, and the porosity values determined in this study. The average linear velocity of flow paths beginning at each contaminated well and ending at the streams where the flow paths terminate ranges from 0.08 to 130 feet per day. As a result of a change in the pump-and-treat system (adding a 165-foot-deep well pumped at 5 gallons per minute and reducing the pumping rate at a nearby 41-foot-deep well by the same amount), water in the vicinity of three 100- to 165-foot-deep wells flows to the deep well rather than the shallower well.

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USGS2006

Occurrence of diatoms in lakeside wells in northern New Jersey as an indicator of the effect of surface water on ground-water quality

In a novel approach for detecting ground-water/surface-water interaction, diatoms were used as an indicator that surface water affects ground-water quality in lakeside communities in northern New Jersey. The presence of diatoms, which are abundant in lakes, in adjacent domestic wells demonstrated that ground water in these lakeside communities was under the direct influence of surface water. Entire diatom frustules were present in 17 of 18 water samples collected in August 1999 from domestic wells in communities surrounding Cranberry Lake and Lake Lackawanna. Diatoms in water from the wells were of the same genus as those found in the lakes. The presence of diatoms in the wells, together with the fact that most static and stressed water levels in wells were below the elevation of the lake surfaces, indicates that ground-water/surface-water interaction is likely. Ground-water/surface-water interaction also probably accounts for the previously documented near-ubiquitous presence of methyl tertiary-butyl ether in the ground-water samples. Recreational use of lakes for motor boating and swimming, the application of herbicides for aquatic weed control, runoff from septic systems and roadways, and the presence of waterfowl all introduce contaminants to the lake. Samples from 4 of the 18 wells contained Navicula spp., a documented significant predictor of Giardia and Cryptosporidium. Because private well owners in New Jersey generally are not required to regularly monitor their wells, and tests conducted by public-water suppliers may not be sensitive to indicators of ground-water/surface-water interaction, these contaminants may remain undetected. The presence of diatoms in wells in similar settings can warn of lake/well interactions in the absence of other indicators.

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USGS2006

Methodology to evaluate the effect of sorption in the unsaturated zone on the storage of nitrate and other ions and their transport across the water table, southern New Jersey

A new field-based approach for determining sorption in the unsaturated zone and its effect on the storage of ions and their transport in recharge to ground water has been demonstrated for a small agricultural watershed in the Coastal Plain of southern New Jersey. Moisture-content and chemical-concentration data obtained from unsaturated-zone-core and shallow-ground-water samples were used to estimate the mass flux of chemical constituents across the water table, as well as sorption coefficients (Kd). The selectivity order of the Kd values for cations is consistent with the expected selectivity order: for example, Na+ > Mg++ > Ca++ for sands. Although calculated sorption coefficients, as expected, were greater for cations than for anions, sorption had a substantial effect on the transport of anions through the unsaturated zone; in particular, average Kd values for NO3- were 0.22 liters per milligram for sands and 0.62 liters per milligram for finer grained sediments. The unsaturated zone in the study area is a large reservoir for nitrogen. Models that do not account for sorption are likely to result in unrealistic predictions of contaminant transport rate and provide overly optimistic expectations for natural cleansing in this watershed and those in other similar hydrogeologic settings.

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USGS2006

Simulation of proposed increases in ground-water withdrawals on the Atlantic City 800-foot sand, New Jersey Coastal Plain

The confined Atlantic City 800-foot sand and the unconfined Kirkwood-Cohansey aquifer system (surficial aquifer) are major sources of water for southeastern New Jersey. Because of recent concerns about streamflow depletion resulting from ground-water withdrawals and the potential ecological effects on stream habitat in the area, the focus on future withdrawals has been shifted away from the surficial aquifer to the confined Atlantic City 800-foot sand until the effects of increased withdrawals from the surficial aquifer can be investigated. A study was conducted to evaluate the effects of seven proposed increases in ground-water withdrawals from the Atlantic City 800-foot sand and the Kirkwood-Cohansey aquifer system on the Atlantic City 800-foot sand. The proposed withdrawals are increases above the 2004 allocated rates (full allocation). The effects of full-allocation ground-water withdrawals and the cumulative effect of withdrawals for each of seven proposed increases in withdrawals were simulated using three previously published ground-water flow models: the New Jersey Coastal Plain Regional Aquifer System Analysis model, the Coastal Plain Optimization model, and a model of the Atlantic City 800-foot sand in Atlantic County, New Jersey. These models were used to simulate changes in water levels, the source supplying the increased ground-water flow, and the effects on saltwater movement towards production wells in Cape May County as a result of the proposed increased withdrawals at proposed or existing wells. The results of the simulations represent the effects of the proposed increase from full-allocation withdrawals to an additional 1,825 Mgal/yr (million gallons per year) from the Atlantic City 800-foot sand and an additional 1,045 Mgal/yr from the deep part of the Kirkwood-Cohansey aquifer system near the updip limit of the Atlantic City 800-foot sand. Most of the simulated decline in water levels in Atlantic County occurred as the result of the proposed increased withdrawals simulated for the New Jersey American Water Company wells. Simulated declines in water levels in Cape May were caused mainly by the simulated increased withdrawals for the Cape May City Desalination Plant wells. The additional water to supply the proposed increases in the scenarios was primarily horizontal flow from the unconfined updip part of the Kirkwood-Cohansey aquifer system, which accounted for 63 percent of the inflow, and flow from the overlying Kirkwood-Cohansey aquifer system into the Atlantic City 800-foot sand, which supplied 27 percent of the additional water. Because the withdrawals were made from the confined aquifer and the deeper part of the unconfined aquifer, the effect on streamflow was substantially less than would have occurred had the withdrawals been made directly from the shallower parts of the unconfined aquifer. The travel times from the 250-mg/L isochlor to production wells in Stone Harbor were longer as a result of all the additional withdrawals. For some scenarios, withdrawals in Atlantic County caused the saltwater to move slightly faster towards the production wells. These effects were offset by the increase in travel time caused by the potential increased withdrawals simulated for the Cape May City desalination wells, which either diverted water towards the desalination wells or increased the travel time towards production wells.

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USGS2005

Change in field turbidity and trace element concentrations during well purging

Various physical and chemical properties were monitored sequentially in the field during well purging as indicators of stabilization of the composition of the water in the well. Turbidity was monitored on site during purging of oxic water from three wells with screened intervals open to an unconfined aquifer system in the Coastal Plain of southern New Jersey to determine if stabilization of turbidity is a reliable indicator of the optimum purge time required to collect unbiased trace element samples. Concurrent split (one filtered, one unfiltered) samples collected during purging of the wells were analyzed for concentrations of trace elements so that the relationships between trace element concentrations and turbidity could be compared. Turbidity correlated with the whole water recoverable (WWR) concentration of trace element species, such as iron (Fe), aluminum (Al), and manganese (Mn) in the oxic ground water. Turbidity appeared to be independent of other field-measured characteristics of water such as conductivity, pH, temperature, and dissolved oxygen. The WWR concentration of lead and copper, considered to be hydrophobic, correlated significantly with the sum of the WWR concentration of Fe, Al, and Mn. High values of field-measured turbidity were a key indicator of an overestimate of ambient hydrophobic trace element WWR concentrations. Stabilization of turbidity was a better indicator of stable, unfiltered trace element concentrations than were the other commonly measured field characteristics. At one well, turbidity was a better indicator of stable, filtered trace element concentrations than the other commonly measured field characteristics. As analytical methods for trace elements improve resulting in smaller MRLs (method reporting levels) and better precision, turbidity of ground water at values of less than 10 NTU (nepheiometric turbidity units) will become important in interpreting the significance of both unfiltered and filtered sample results.

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USGS2005

Comparison of a novel passive sampler to standard water-column sampling for organic contaminants associated with wastewater effluents entering a New Jersey stream

Four water samples collected using standard depth and width water-column sampling methodology were compared to an innovative passive, in situ, sampler (the polar organic chemical integrative sampler or POCIS) for the detection of 96 organic wastewater-related contaminants (OWCs) in a stream that receives agricultural, municipal, and industrial wastewaters. Thirty-two OWCs were identified in POCIS extracts whereas 9-24 were identified in individual water-column samples demonstrating the utility of POCIS for identifying contaminants whose occurrence are transient or whose concentrations are below routine analytical detection limits. Overall, 10 OWCs were identified exclusively in the POCIS extracts and only six solely identified in the water-column samples, however, repetitive water samples taken using the standard method during the POCIS deployment period required multiple trips to the sampling site and an increased number of samples to store, process, and analyze. Due to the greater number of OWCs detected in the POCIS extracts as compared to individual water-column samples, the ease of performing a single deployment as compared to collecting and processing multiple water samples, the greater mass of chemical residues sequestered, and the ability to detect chemicals which dissipate quickly, the passive sampling technique offers an efficient and effective alternative for detecting OWCs in our waterways for wastewater contaminants.

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USGS2005

Mercury concentrations in water from an unconfined aquifer system, New Jersey coastal plain

Concentrations of total mercury (Hg) from 2 μg/L (the USEPA maximum contaminant level) to 72 μg/L in water from about 600 domestic wells in residential parts of eight counties in southern New Jersey have been reported by State and county agencies. The wells draw water from the areally extensive (7770 km 2 ) unconfined Kirkwood–Cohansey aquifer system, in which background concentrations of Hg are about 0.01 μg/L or less. Hg is present in most aquifer materials at concentrations <50 μg/kg, but is at 100–150 μg/kg in undisturbed surficial soils. No point sources of contamination to the affected areas have been conclusively identified. To determine whether high levels of Hg in ground water are related to a particular land use and (or) water chemistry, water samples from 105 wells that tap the aquifer system were collected by the United States Geological Survey. These included randomly selected domestic wells, domestic and observation wells in selected land uses, and sets of clustered observation wells—including two sets that are downgradient from residential areas with Hg-contaminated ground water. Hg concentrations in filtered samples (Hg f ) were at or near background levels in water from most wells, but ranged from 0.1 to 3.8 μg/L in water from nearly 20% of wells. Hg f concentrations from 0.0001 to 0.1 μg/L correlated significantly and positively with concentrations of other constituents associated with anthropogenic inputs (Ca, Cl, Na, and NO 3 ) and with dissolved organic carbon. Hg f concentrations >0.1 μg/L did not correlate significantly with concentrations of the inorganic constituents. Hg f concentrations near or exceeding 2 μg/L were found only in water from wells in areas with residential land use, but concentrations were at background levels in most water samples from undeveloped land. The spatial distribution of Hg-contaminated ground water appears to be locally and regionally heterogeneous; no extensive plumes of Hg contamination have yet been identified.

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USGS2005

A novel approach to fitting the von Bertalanffy relationship to a mixed stock of Atlantic sturgeon harvested off the New Jersey Coast

We examined the growth characteristics of 303 Atlantic sturgeon, Acipenser oxyrinchus , caught in the commercial fishery off the New Jersey coast from 1992 to 1994 (fork length range: 93&ndash;219 cm). Sections taken from the leading pectoral fin ray were used to age each sturgeon. Ages ranged from 5&ndash;26 years. Von Bertalanffy growth models for males and females fit well, but test statistics (t-test, maximum likelihood) failed to reject the null hypothesis that growth was not significantly different between sexes. Consequently, all data were pooled and the combined data gave L &infin; and K estimates of 174.2 cm and 0.144, respectively. Our growth data do not fit the pattern of slower growth and increased size in more northernly latitudes for Atlantic sturgeon observed in other work. Lack of uniformity of our growth data may be due to (1) the sturgeon fishery harvesting multiple stocks having different growth rates, and (2) size limits for the commercial fishery having created a bias in estimating growth parameters.

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USGS2005

Evidence of cold climate slope processes from the New Jersey Coastal Plain: Debris flow stratigraphy at Haines Corner, Camden County, New Jersey

Excavations through surficial deposits across the New Jersey Coastal Plain commonly reveal homogenized surficial sediments, deformed sedimentary structures, chaotically rearranged bed-forms, and wedge-shaped cracks filled with sand from the top-most layers of extant soil profiles. As a whole, these abundant, broadly distributed phenomena are best explained as artifacts of an era of frozen ground during the last Pleistocene glacial maximum. Vigorous freeze-thaw processes and abundant seasonal rainfall created a landscape of low relief covered by highly mobile surficial deposits. The surficial deposits are at grade into broad, flat bottomed valleys now drained by small, tightly meandering, under-fit streams. Modern fluvial, aeolian, and slope processes are ineffectual in either creating or modifying these landscapes. One particularly brief exposure of complex slope deposits was documented at Haines Corner, Camden County, during the field work (1986) for the Surficial Geologic Map of southern and central New Jersey. The exposure, now presented and interpreted here, provides previously unavailable details of a system of freeze-thaw driven processes that unfolded upon a frozen, impermeable substrate 80 miles south of the southern margin of the Wisconsinan glacial advance to Long Island, N.Y. At the time of these extreme processes, the presently sub-aerial New Jersey Coastal Plain was not proximal to moderating effects of the Atlantic Ocean, being about 100 miles inland and 300 feet above the lowered sea level. Current studies of analogous deposits across the mid-Atlantic Coastal Plain now benefit from dating techniques that were not available during the geologic mapping field work (1985-'92). During the mapping in New Jersey, hundreds of exposures failed to produce datable carbon remains within the stratigraphy of the surficial deposits. Recently reported TL dates from wind-blown sand filling frost wedges, exposed elsewhere in New Jersey, indicate that the widely distributed surficial deposits of the New Jersey Coastal Plain were active during the maximum cold period of the late Pleistocene (around 18,000 years ago).

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USGS2005

Vulnerability of production wells in the Potomac-Raritan-Magothy aquifer system to saltwater intrusion from the Delaware River in Camden, Gloucester, and Salem Counties, New Jersey

The Potomac-Raritan-Magothy aquifer system is hydraulically connected to the Delaware River in parts of Camden and Gloucester Counties, New Jersey, and has more limited contact with the river in Salem County, New Jersey. The aquifer system is used widely for water supply, and 122 production wells that are permitted by the New Jersey Department of Environmental Protection to pump more than 100,000 gallons per year in the three counties are within 2 miles of the river. During drought, saltwater may encroach upstream from the Atlantic Ocean and Delaware Bay to areas where the aquifer system is recharged by induced infiltration through the Delaware River streambed. During the drought of the mid-1960's, water with a chloride concentration in excess of potability standards (250 mg/L (milligrams per liter)) encroached into the reach of the river that recharges the aquifer system. The vulnerability of the major production wells in the area to similar saltwater encroachment in the future is a concern to water managers. This vulnerability was evaluated by investigating two scenarios: (1) a one-time recurrence of the conditions approximating those that occurred in the1960's, and (2) the recurrence of those same conditions on an annual basis. Results of ground-water-flow simulation in conjunction with particle tracking and one-dimensional transport analysis indicate that the wells that are most vulnerable to saltwater intrusion are those in the Morris and Delair well fields in Camden County. A single 30-day event during which the concentration of dissolved chloride or sodium exceeds 2,098 mg/L or 407 mg/L, respectively, in the Delaware River would threaten the potability of water from these wells, given New Jersey drinking-water standards of 250 mg/L for dissolved chloride and 50 mg/L for dissolved sodium. This chloride concentration is about six times that observed in the river during the 1960's drought. An annually occurring 1-month event during which the concentrations of dissolved chloride or sodium in the river exceeds 1,818 mg/L or 358 mg/L, respectively, would threaten the potability of water from these wells. Wells outside the Morris and Delair well fields are substantially less vulnerable to the intermittent saltwater intrusion that was simulated.

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USGS2005

Occurrence of radium-224, radium-226, and radium-228 in water of the unconfined Kirkwood-Cohansey aquifer system, southern New Jersey

Water in the unconfined Kirkwood-Cohansey aquifer system in the New Jersey Coastal Plain contains elevated concentrations (above 3 pCi/L (picocuries per liter)) of the alpha-particle-emitting radionuclide radium-224. Previously, water from the aquifer system had been found to contain radium-226 and radium-228. This observation is of concern because the previously undetected presence of radium-224 may pose an additional, quantifiable health risk that currently is not accounted for by the Maximum Contaminant Level (MCL) of 5 pCi/L for combined radium (the sum of radium-226 plus radium-228 is termed 'combined radium') in drinking water. Water samples were collected from a regional network of 88 wells for determination of concentrations of radium-224, radium-226, and radium-228; gross alpha-particle activity; and concentrations of major ions and selected trace elements. Both gamma and alpha spectroscopic techniques were used to determine concentrations of radium-224, which ranged from <0.5 to 16.8 pCi/L (median 2.1 pCi/L, interquartile range 1.2-3.7 pCi/L). Concentrations of radium-226 and radium-228 in the same samples ranged from <0.5 to 17.4 pCi/L (median 1.7 pCi/L, interquartile range 0.9-2.9 pCi/L) and <0.5 to 12.8 pCi/L (median 1.6 pCi/L, interquartile range, 0.9-2.6 pCi/L), respectively. Concentrations of radium-224 typically were greater than those of the other two radium radionuclides, as evidenced by the highest median, third quartile, and maximum concentrations, as well as the highest concentration among the three radium radioisotopes in 52 (59 percent) of the 88 samples. Concentrations of 5.0 to 5.5 pCi/L of radium-224 result in a gross alpha-particle activity of about 15 pCi/L (the MCL) 36 to 48 hours, respectively, after sample collection when ingrowth of radium-224 progeny radionuclides is considered, even with the unlikely assumption that no other alpha-particle-emitting radionuclide is present in the water. Concentrations of 3.4 to 3.7 pCi/L radium-224 result in a gross alpha-particle activity of 10 pCi/L 36 to 48 hours, respectively, after sample collection when ingrowth of Ra-224 progeny radionuclides is considered. In this latter case, it is possible that the summed alpha-particle activity from radium-226 present at a concentration less than or equal to 5 pCi/L (the MCL for combined radium) and from radium-224 present at a concentration about 3.4 pCi/L or greater may exceed the 15-pCi/L MCL for gross alpha-particle activity. In this study, gross alpha-particle activities were measured within 48 hours after sample collection and were found to exceed the MCL of 15 pCi/L in nearly half (43) of the 88 samples collected. The concentration of radium-224 exceeded that of radium-226 in 55 (62.5 percent) of the 88 samples. Concentrations of radium-224 correlate strongly with those of both radium-226 and radium-228 (Spearman correlation coefficients r=0.74 and 0.91, respectively). Concentrations of radium-224, radium-226, and radium-228 were greatest in the most acidic ground water. Concentrations of radium-224 and combined radium-226 and radium-228 in samples of ground water with pH less than 4.7 exceeded 5 pCi/L in 33 and 67 percent of the samples, respectively. Concentrations of radium-224, radium-226, and radium-228 (measured separately) were greatest in water from the southern part of the aquifer outcrop area. In water from the northern part of the aquifer system outcrop area, radium-224 concentrations were as high as 3.6 pCi/L, and concentrations of combined radium and gross alpha-particle activity in some samples exceeded their respective MCLs. The presence of gross alpha-particle activities greater than 15 pCi/L and combined radium-226 and radium-228 concentrations greater than 5 pCi/L in the southwestern part of the aquifer system outcrop area is common and had been documented before 1997. Results of this study confirm these earlier findings.

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USGS2005

Radiochemical sampling and analysis of shallow ground water and sediment at the BOMARC Missile Facility, east-central New Jersey, 1999-2000

A field sampling experiment was designed using low-flow purging with a portable pump and sample-collection equipment for the collection of water and sediment samples from observation wells screened in the Kirkwood-Cohansey aquifer system to determine radionuclide or trace-element concentrations for various size fractions. Selected chemical and physical characteristics were determined for water samples from observation wells that had not been purged for years. The sampling was designed to define any particulate, colloidal, and solution-phase associations of radionuclides or trace elements in ground water by means of filtration and ultrafiltration techniques. Turbidity was monitored and allowed to stabilize before samples were collected by means of the low-flow purging technique rather than by the traditional method of purging a fixed volume of water at high-flow rates from the observation well. A minimum of four water samples was collected from each observation well. The samples of water from each well were collected in the following sequence. (1) A raw unfiltered sample was collected within the first minutes of pumping. (2) A raw unfiltered sample was collected after at least three casing volumes of water were removed and turbidity stabilized. (3) A sample was collected after the water was filtered with a 0.45-micron filter. (4) A sample was collected after the water passed through a 0.45-micron filter and a 0.003-micron tangential-flow ultrafilter in sequence. In some cases, a fifth sample was collected after the water passed through a 0.45-micron filter and a 0.05-micron filter in sequence to test for colloids of 0.003 microns to 0.05 microns in size. The samples were analyzed for the concentration of manmade radionuclides plutonium-238 and -239 plus -240, and americium-241. The samples also were analyzed for concentrations of uranium-234, -235, and -238 to determine whether uranium-234 isotope enrichment (resulting from industrial processing) is present. A subset of samples was analyzed for concentrations of thorium-232, -230, and -228 to determine if thorium-228 isotope enrichment, also likely to result from industrial processing, is present. Concentrations of plutonium isotopes and americium-241 in the water samples were less than 0.1 picocurie per liter, the laboratory reporting level for these manmade radionuclides, with the exception of one americium-241 concentration from a filtered sample. A sequential split sample from the same well did not contain a detectable concentration of americium-241, however. Other filtered and unfiltered samples of water from the same well did not contain quantities of americium-241 nearly as high as 0.1 pCi/L. Therefore, the presence of americium-241 in a quantifiable concentration in water samples from this well could not be confirmed. Neither plutonium nor americium was detected in samples of settled sediment collected from the bottom of the wells. Concentrations of uranium isotopes (maximum of 0.05 and 0.08 picocuries per liter of uranium-238 and uranium-234, respectively) were measurable in unfiltered samples of turbid water from one well and in the settled bottom sediment from 6 wells (maximum concentrations of 0.25 and 0.20 picocuries per gram of uranium-238 and uranium-234, respectively). The uranium-234/uranium-238 isotopic ratio was near 1:1, which indicates natural uranium. The analytical results, therefore, indicate that no manmade radionuclide contamination is present in any of the well-bottom sediments, or unfiltered or filtered water samples from any of the sampled wells. No evidence of manmade radionuclide contamination was observed in the aquifer as settled or suspended particulates, colloids, or in the dissolved phase.

New Jersey↗
USGS2003

Seasonal and daily variations in concentrations of methyl-tertiary-butyl ether (MTBE) at Cranberry Lake, New Jersey

Methyl-tertiary-butyl ether (MTBE), an additive used to oxygenate gasoline, has been detected in lakes in northwestern New Jersey. This occurrence has been attributed to the use of gasoline-powered watercraft. This paper documents and explains both seasonal and daily variations in MTBE concentrations at Cranberry Lake. During a recent boating season (late April to September 1999), concentrations of MTBE typically exceeded 20 μg/L. MTBE concentrations varied daily from 12 to 24 μg/L over a 2-week period that included the Labor Day holiday. Concentrations were highest on weekends when there is more boat traffic, which had an immediate effect on MTBE mass throughout the lake. MTBE concentrations decreased to about 2 μg/L shortly after the end of the summer recreational season. The loss of MTBE can be accounted for by volatilization, with a half-life on the order of 10 days. The volatilization rate was modeled with the daily decrease in MTBE then the modeled rate was validated using the data from the seasonal decline.

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