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Research about Minnesota

Source-linked reports with geographic coverage including Minnesota.

At least 559 records · Page 31Linked to original sources

Characterization of ground-water discharge from bedrock aquifers to the Mississippi and Minnesota Rivers at three areas, Minneapolis-St. Paul area, Minnesota

The hydrogeology at three areas along the Mississippi and Minnesota Rivers in the Minneapolis-St. Paul area were studied to characterize ground-water discharge from bedrock aquifers to the two rivers. Along the Mississippi River between Fridley and Brooklyn Center, a buried valley underlying the Mississippi River cuts through the overlying terrace deposits and glacial-drift deposits into two underlying bedrock hydro- geologic units: the St Peter aquifer, and a rubble zone between the St. Peter and Prairie du Chien-Jordan aquifers. Shallow ground-water flow in the near-surface gray and upper red tills and sand and gravel outwash aquifer discharges to springs along the edge of the river. Ground water flowing through the rubble zone and upper part of the Prairie du Chien-Jordan aquifer probably discharges through alluvial deposits to the river. In study area 2, along the Minnesota River between Eagan and Bloomington, almost 200 feet of post-glacial alluvium, glaciofluvial sand and gravel, Pleistocene lake deposits, and peat fill a bedrock valley under the present-day Minnesota River. As much as 40 feet of post-glacial peat, silty clay, clay, and muck lie near the river-valley walls. Confining units beneath the river channel impede the discharge of ground water from the underlying Prairie du Chien-Jordan aquifer to the river. Ground water discharges to wetlands, lakes, and springs along both the north and south side of the river. Along the Mississippi River at Minneapolis about 5 miles upstream of the confluence of the Minnesota and Mississippi Rivers, the Mississippi River lies in a post-glacial valley cut through thin glacial drift into the St. Peter aquifer. Beneath the river, ground water flows from the St. Peter aquifer through the overlying post-glacial ailuvium to the Mississippi River. No confining unit separates the St. Peter aquifer and the river.

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Elk Lake in perspective

Elk Lake is located in the forested region of north-central Minnesota at the headwaters of the Mississippi River and occupies one of countless basins left behind as the last great Pleistocene ice sheet retreated northward into Canada. In this respect it resembles many other moderately deep, dimictic, hard-water lakes in the north-central United States, the sediments of which contain a history of postglacial and Holocene climatic and environmental change. Elk Lake is different, however, because the Holocene sediments in the deeper part of the lake form an uninterrupted sequence of annual laminations or varves. The varves are a chronometer for timing precisely the biologic, geochemical, and sedimentological responses in the lake to cyclic and progressive changes in climate. The varves also, through profound changes in their composition, divide the history of Elk Lake into three, sharply defined episodes; a postglacial lake, a prairie lake, and a modern, mesic-forest lake. We use these episodes and the character of the varves as a framework to guide the reader to the chapters and discussions found in this volume.

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Geochemistry of surface sediments of Minnesota lakes

Analyses of 36 trace, minor, and major elements were used to classify the sediments of 46 Minnesota lakes. Q-mode factor analyses grouped Minnesota lake sediments according to clastic-, carbonate-, organic-, and redox-related elements. Carbonate lakes occur in west-central Minnesota; their sediments have relatively high concentrations of CaCO 3 , Ba, and Sr. Lakes with sediments containing more than 30% organic matter occur in east-central and northeastern Minnesota; these sediments have high concentrations of organic C, N, and H, and slightly elevated concentrations of Pb. Only three lakes have sediments included in the “redox” group, with relatively high concentrations of Fe, Mn, Mo, La, and Zn. High concentrations of redox-sensitive elements appear to be associated with oxidized iron and manganese minerals, but in Elk Lake, one of the three lakes in this group, a significant amount of iron and manganese is contained in iron phosphate, iron sulfide, and manganese carbonate. Clastic lake sediments are not diluted by large amounts of organic matter, carbonate minerals, or iron-manganese minerals, and are of two types: a western group derived largely from Cretaceous shales in the prairie regions, and a northeastern group derived from Precambrian crystalline rocks in the forested arrowhead region. Western clastic lake sediments have higher concentrations of Al, Na, K, B, Ba, V, Mg, and Sr. Most northeastern clastic lake sediments contain higher concentrations of Cu, Y, Be, and Ni, but several are chemically more similar to those of western prairie lakes.

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Physical properties, mineralogy, and geochemistry of Holocene varved sediments from Elk Lake, Minnesota

Elk Lake in northwestern Minnesota is situated close to a climatically sensitive ecotone, the forest-prairie border, that migrated back and forth over the drainage basin of the lake during the Holocene. The entire postglacial (Holocene) sediment record in the deepest part of Elk Lake is composed of annual layers (varves) that record the seasonal pulses of many sediment components, and, most important, provide high-resolution (seasonal) time calibration of rates and timing of environmental change. These varved sediments contain many allochthonous and autochthonous components that are sensitive to changing environmental conditions in the drainage basin and the lake. The mineral components of Elk Lake sediments consist mainly of authigenic calcium, magnesium, and manganese carbonate minerals (low-Mg calcite, high-Mg calcite, dolomite, and rhodochrosite), opaline silica (from diatoms), X-ray amorphous iron and manganese oxyhydroxides, and an iron phosphate mineral tentatively identified as rock-bridgeite [(Fe, Mn)Fe 4 (PO 4 ) 3 (OH) 5 ], plus minor contributions from fine-grained detrital quartz, feldspar, illite, and kaolinite. The most notable characteristic of the sediments in Elk Lake is that most of the components were formed in the lake. Q-mode factor analysis of sediment geochemistry reduced 23 observed compositional variables, expressed as percent or parts per million of elements, to three composite variables (factor loadings) whose “concentrations” are expressed on a scale of −1.0 to 1.0. Factor 1 expresses the composition of the inorganic clastic fraction based on concentrations of Mg, Na, Al, Cr, V, Y, Sc, Ni, Sr, Co, and Cu. Factor 2 expresses the similarities in variations of Fe, Mn, P, organic carbon, and Mo. Factor 3 loadings are a synthesis of concentrations of Mn, S, Ca, La, and Ba. Geochemical characteristics define three distinct chemical stages in the development of Elk lake: (1) a carbonate-, manganese-, iron-, sulfur-rich early-lake stage that lasted from 10,400 to 8200 varve yr; (2) a clastic- and diatom-rich mid-Holocene prairie-lake stage that lasted from 8200 to 4000 varve yr; and (3) a final iron-, manganese-, phosphate-, and organic-rich modern-lake stage that developed over the past 4000 yr. The chemical characteristics of the sediments deposited during these three lake phases can be represented by the average compositions of three groups of samples: (1) the average composition of sediments deposited over the past 2000 yr, representing the modern-lake stage; (2) the composition of a 50 varve sample centered on 5700 varve yr that represents the maximum clastic influx into the lake during the prairie period; and (3) the average composition of sediments deposited over the initial 2000 yr of the lake’s existence (10,400 to 8400 varve yr). The amplitudes of climatic oscillations, as reflected by changes in concentration of many climatically sensitive elements, were greatest during the prairie period, pronounced cycles having periodicities of several hundred years. The extremes of these oscillations occurred within several centuries or less, which suggests that significant changes in climate may occur abruptly and rapidly. Most notably, the end of the mid-Holocene prairie period, marked by a sudden decrease in the influx of detrital clastic material, occurred within a few decades.

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Climatic and limnologic setting of Elk Lake

Elk Lake is located on the Itasca moraine near the source of the Mississippi River in northwestern Minnesota. The basin is in calcareous glacial drift, and the lake water is a dilute solution of calcium and magnesium bicarbonate. Low-magnesian calcite formed by precipitation from the lake water has been a major component of the sediment throughout the lake’s history. The sediment also is laminated with alternating light and dark, millimeter-thick layers containing diatoms, organic matter, Fe(OH) 3 , and CaCO 3 . The sediment microstratigraphy has been preserved because the lake is unusually deep (maximum depth is 30 m) for its size (surface area is 1.01 km 2 ). Oxygen is present in low concentrations or absent in the deepest water during summer and winter. Water movements in the deepest part of the lake are insufficient some years for the complete aeration of the deepst water during spring and autumn circulation periods. Phytoplankton photosynthesis, which occurs mostly in the surficial 6 m of water, typically removes 0.5 g C m −2 day −1 from the epilimnion, which becomes strongly oversaturated with calcite during late spring and summer as the pH increases above the equilibrium pH (7.73) for calcite saturation. Most of the CaCO 3 that makes up the light-colored layers of sediments probably is formed during the late summer, when concentrations of calcium in the epilimnion decrease most rapidly. The silica and organic matter that form the darker sediment laminae are deposited earlier in the year, during a period extending from April to late June, when silica decreases fastest in the epilimnion.

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Holocene climatic and limnologic history of the north-central United States as recorded in the varved sediments of Elk Lake, Minnesota: A synthesis

Integration of the results and interpretations of geochemical, paleoecological, and sedimentological analyses of a varved sediment record provides a detailed chronicle of limnological and climatic changes for the past 10 ka at Elk Lake, west-central Minnesota. The early Holocene record at Elk Lake was controlled by circumstances of glacial history (e.g., basin morphometry and surrounding till lithology) in combination with global warming at the end of the Pleistocene. Later, the interplay of climate change and a disintegrating ice sheet determined the character of local environments that were affected by reduction of precipitation and increased windiness during the middle Holocene. Elk Lake became more productive and clastic sediment increased to dominate the record as the forests thinned and prairie vegetation characterized the region. During this prairie period, winters may have been cold because disintegrating northern ice sheets ceased to block winter outbreaks of Arctic air. Correlations of wind-deposited materials throughout much of the eastern two-thirds of the United States suggest that drought conditions and strong winds were widespread between 8 and 4 ka. The mid-Holocene was climatically variable, however, with strong fluctuations in varve thickness at decadal, centennial, and millennial scales testifying to rapid climatic changes. Although the cause of such climatic cycles is not yet clear, correlations between 14 C anomalies and varve thickness suggest that variations in solar flux and resulting magnetic storms and zonal winds may have induced strong climatic changes. A particularly strong 600 yr fluctuation to cool and wet climates that may document neoglacial conditions around 5 ka interrupted the prairie period. After 4 ka, the climate at Elk Lake was dominated by a tropical airstream during the summer, and dry arctic and Pacific airstreams during the winter. Large-scale variations ceased, although decadal and multi-decadal variations in varve thickness chronicle changes similar, but not clearly correlative, to historically documented climatic episodes such as the Medieval Warm Period and the Little Ice Age.

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Modern sedimentation in Elk Lake, Clearwater County, Minnesota

The varved sediments of Elk Lake, Clearwater County, Minnesota, contain a 10,000 year record of climatic and limnologic events. Sediment traps deployed in the lake’s water column from 1979 to 1981 and from 1983 to 1984 collected samples that permitted us to identify materials, to see the timing of sedimentation events, and to deduce processes that form the microlaminae within varves. Fall and spring microlaminae consist mainly of sequential accumulations of biogenic silica and resuspended calcific and siliceous materials. Precipitates of iron, manganese, and organic detritus dominate the thin winter microlaminae. Calcific microlaminae are deposited in summer. Concentrated iron and manganese precipitates form when the onset of seasonal circulation (especially in autumn) oxygenates the lower water column, but precipitation of these metals also continues throughout periods of seasonal stratification, when these dissolved elements migrate upward and are converted to particles that rain back to the bottom. Mineraloids dominate the sediment; minerals compose only a minor part and include quartz, calcite, rhodochrosite, and rockbridgeite (iron phosphate). The bulk of the bottom accumulation occurs during the longer, calmer summer and winter periods, but important contributions are also made during spring and autumn overturn events. Sediment resuspended from the shallows accumulates together with newly formed endogenic sediment, and can even briefly dominate the seston in autumn and spring. Vigor and duration of seasonal circulations in the upper water column dictate the amount of resuspended sediment contributed annually to a varve. When abrupt warming within days after ice-out stratifies the lake, sedimentation in that year is diminished by resultant suppression of plankton blooms and lack of vernal resuspension that would normally move sediment from the littoral areas into the deep parts of Elk Lake. Thin sections of varves confirm that resuspension during autumn and spring is a varve-forming process that has probably varied in importance as a function of climate and changing morphometry due to infilling. Through an entire year, sediment traps catch a greater proportion of material from spring and autumn overturns than accumulates on the bottom. Lake morphometry is the most important factor governing sediment resuspension and associated annual accumulation rates in traps.

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Environment of deposition of CaCO3 in Elk Lake, Minnesota

Elk Lake is near the present forest-prairie border in northwestern Minnesota, and is also located on the boundary between hard-water lakes that are typical of once-glaciated parts of the north-central United States and more saline prairie lakes of western Minnesota and the Dakotas. The sediments of the prairie lakes just west of Elk Lake are unusual in that they commonly contain high-Mg calcite and dolomite in addition to low-Mg calcite, which is the dominant carbonate mineral in most marl lakes. During the mid-Holocene dry period, prairie conditions expanded eastward into the forested regions of Minnesota. Variations in types and abundances of carbonate minerals in the Holocene sediments of Elk Lake recorded this climatic change. Studies of primary productivity, carbonate saturation, water chemistry, and sediment-trap samples show that low-Mg calcite precipitates during the summer, triggered by algal photosynthesis. The epilimnion of Elk Lake is always oversaturated with calcite, and the degree of oversaturation increases progressively during the summer. The pH of the epilimnion increases from <8.0 after spring overturn to almost 9.0 in late summer in response to photosynthetic removal of CO 2 during the summer months. The rate of calcium depletion from the epilimnion is proportional to the increase in pH and the rate of photosynthetic carbon fixation. Today the only carbonate minerals that are accumulating in the sediments of Elk Lake are low-Mg calcite and manganese carbonate (rhodochrosite). Rhodochrosite, and probably manganese oxyhydroxide, precipitates when manganese-rich anoxic bottom waters come in contact with carbonate-rich oxic surface waters. During the arid mid-Holocene prairie period, however, low-Mg calcite, dolomite, aragonite, and rhodochrosite all accumulated in the sediments of Elk Lake. Dolomite formed in Elk Lake during this period in response to a higher Mg:Ca ratio in the water, just as it is forming today in lakes of the prairie regions of western Minnesota. The coincident occurrence of aragonite and biological indicators of high salinity suggests that the salinity of Elk Lake and the Mg:Ca ratio were higher than in any of the present prairie lakes of western Minnesota.

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Crude oil in a shallow sand and gravel aquifer—I. Hydrogeology and inorganic geochemistry

Changes in the distribution of inorganic solutes in a shallow ground water contaminated by crude oil document a series of geochemical reactions initiated by biodegradation of the oil. Upgradient of an oil body floating on the water table, oxidation of oil to carbonic acid dissolves carbonate minerals in the aquifer matrix. In this oxidized zone pH is depressed &sim;1 pH unit, and the concentrations of Ca, Mg and HCO 3 &minus; increase to more than twice that of the native ground water. In the anoxic zone beneath the oil body concentrations of dissolved SiO 2 , Sr, K, Fe and Mn increase significantly. Here, Fe is mobilized by microbial reduction, pH is buffered by the carbonate system, and silicates weather via hydrolysis and organic-acid-enhanced dissolution. Farther down-gradient the ground water is reoxygenated and Fe precipitates from solution, possibly as iron hydroxide or iron carbonates, while SiO 2 precipitates as amorphous silica. Other solutes, such as Mg, are transported more conservatively down-gradient where contaminated and native ground water mix. The observed changes in inorganic aqueous chemistry document changes in water-mineral interactions caused by the presence of an organic contaminant. These organic-initiated interactions are likely present in many contaminated aquifers and may be analogous to interactions occurring in other organic-rich natural waters.

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Crude oil in a shallow sand and gravel aquifer-III. Biogeochemical reactions and mass balance modeling in anoxic groundwater

Crude oil floating on the water table in a sand and gravel aquifer provides a constant source of hydrocarbons to the groundwater at a site near Bemidji, Minnesota. The degradation of hydrocarbons affects the concentrations of oxidized and reduced aqueous species in the anoxic part of the contaminant plume that developed downgradient from the oil body. The concentrations of Fe 2+ , Mn 2+ and CH 4 , Eh measurements, and the δ 13 C ratios of the total inorganic C indicate that the plume became more reducing ver a 5-a period. However, the size of the contaminant plume remained stable during this time. Field data coupled with laboratory microcosm experiments indicate that benzene and the alkylbenzenes are degraded in an anoxic environment. In anaerobic microcosm experiments conducted under field conditions, almost complete degradation (98%) was observed for benzene in 125 d and for toluene in 45 d. Concentrations of aqueous Fe 2+ and Mn 2+ increased in these experiments, indicating that the primary reactions were hydrocarbon degradation coupled with Fe and Mn reduction. Mass transfer calculations on a 40-m flowpath in the anoxic zone, downgradient from the oil body, indicated that the primary reactions in the anoxic zone are oxidation of organic compounds, precipitation of siderite and a ferroan calcite, dissolution of iron oxide and outgassing of CH 4 and CO 2 . The major difference in the two models presented is the ratio of CO 2 and CH 4 that outgasses. Both models indicate quantitatively that large amounts of Fe are dissolved and reprecipitated as ferrous iron in the anoxic zone of the contaminant plume.

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Selected basin characteristics and water-quality data of the Minnesota River basin

Selected basin characteristics and water-quality dam for the Minnesota River Basin are presented in this report as 71 maps, 22 graphs, and 8 tables. The data were compiled as part of a four-year study to identify non-point sources of pollution and the effect of this pollution on water quality. The maps were prepared from geographic information system data bases. Federal, State, and local agencies, and colleges and universities collected and assembled these data as part of the Minnesota River Assessment Project.

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Effects of focused recharge on the transport of agricultural chemicals at the Princeton, Minnesota Management Systems Evaluation Area, 1991-92

Rates of water movement through the unsaturated zone greatly affect the amount and concentrations of agricultural chemicals that may reach the water table. For example, recharge can flush chemicals to the water table which have accumulated in the unsaturated zone during dry periods. A better understanding of how topography influences recharge and the movement of agricultural chemicals is needed. In 1991, the U.S. Geological Survey (USGS), with funding from the USGS Toxic Substances Hydrology Program, began studying the movement of water and agricultural chemicals to the water table at the Management Systems Evaluation Area (MSEA) near Princeton, Minnesota. The primary objective of this four-year research study is to evaluate the effects of transient recharge, topography, and subsurface heterogeneities on the flux of water and agricultural chemicals to ground water. To achieve this objective the approach was to (1) install instruments to sample and measure the movement of water through the unsaturated zone beneath topographically high and low areas of a corn field; (2) conduct recharge and tracer tests in the field to evaluate the movement of water and agricultural chemicals at both topographic settings; and (3) simulate the field recharge and tracer tests in the laboratory. The primary research hypothesis was that the vertical flux of water and agricultural chemicals is greater in topographically low areas than in topographically high areas.

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Ground-water quality at the Management Systems Evaluation Area (MSEA) near Princeton, Minnesota, 1991

The northern cornbelt sand-plains Management Systems Evaluation Area (MSEA) program is a multiagency, multistate initiative to evaluate the effects of modified and prevailing fanning systems on water quality in a sand-plain area in Minnesota and at satellite areas in North and South Dakota, and Wisconsin (Delin and others, 1992). The primary objective of the northern cornbelt sand-plains MSEA is to evaluate the effects of ridge-tillage practices in a corn and soybean farming system on ground-water quality. The Minnesota MSEA program is a cooperative study primarily between the U.S. Department of Agriculture-Agricultural Research Service, the University of Minnesota Soil Science Department, and the U.S. Geological Survey. The Minnesota Pollution Control Agency and the Department of Geology and Geophysics at the University of Minnesota are also cooperating in the evaluation of ground-water quality at the MSEA.

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Hydrogeologic data collected from a crude-oil spill site near Bemidji, Minnesota, 1983-91

The U.S. Geological Survey began a research project at the site of a crude oil spill near Bemidji, Minnesota in 1983. The project is part of the U.S. Geological Survey's Toxic Substances Hydrology Program. The objectives of research at this site are to obtain an understanding of the mobilization, transport, and fate of petroleum derivatives in the shallow subsurface and to use this understanding to develop predictive models of contaminant behavior. This report presents location and altitude data for selected features at the research site, water and oil level records from observation wells collected from 1983 through 1991, geologic logs from 45 observation wells and test holes, particle-size distribution data from 45 observation wells and test holes, and precipitation records from 1948 through 1991.

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Effects of recharge on the transport of agricultural chemicals at the Princeton, Minn. Management Systems Evaluation Area (MSEA), 1991-92

Rates of water movement through the unsaturated zone greatly affect the amount and concentrations of agricultural chemicals that may reach the water table. For example, recharge can flush to the water table chemicals that have accumulated In the unsaturated zone during dry periods. A better understanding of how topography influences recharge and the movement of agricultural chemicals is needed. In 1991, the U.S. Geological Survey (USGS), with funding from the USGS Toxic Substances Hydrology Program, began studying the movement of water and agricultural chemicals to the water table at the Management Systems Evaluation Area (MSEA) near Princeton, Minnesota. Instruments were installed to measure the movement of moisture through the soil beneath a corn field. Samples of the recharge water were analyzed for concentrations of agricultural chemicals and tracers. Field recharge and tracer tests were simulated In the laboratory.

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Ground-water quality at the Management Systems Evaluation Area near Princeton, Minnesota, 1991-92

The northern cornbelt sand-plains Management Systems Evaluation Area (MSEA) program is a multiagency, multistate initiative to evaluate the effects of modified and prevailing farming systems on water quality in a sand-plain area in Minnesota and at satellite areas in North and South Dakota, and Wisconsin. The primary objective of Minnesota MSEA is to evaluate the effects of ridge-tillage practices in a corn and soybean farming system on ground-water quality. The Minnesota MSEA program is a cooperative study primarily between the U.S. Department of Agriculture Agricultural Research Service, the University of Minnesota Soil Science Department, and the U.S. Geological Survey. The Minnesota Pollution Control Agency and the Department of Geology and Geophysics at the University of Minnesota are also cooperating in the evaluation of groundwater quality at the MSEA.

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