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Research about Minnesota

Source-linked reports with geographic coverage including Minnesota.

At least 523 records · Page 29Linked to original sources
USGS1996

Laboratory and quality assurance protocols for the analysis of herbicides in ground water from the Management Systems Evaluation Area, Princeton, Minnesota

Laboratory and quality assurance procedures for the analysis of ground-water samples for herbicides at the Management Systems Evaluation Area near Princeton, Minnesota are described. The target herbicides include atrazine, de-ethylatrazine, de-isopropylatrazine, metribuzin, alachlor, 2,6-diethylaniline, and metolachlor. The analytical techniques used are solid-phase extraction, and analysis by gas chromatography with mass-selective detection. Descriptions of cleaning procedures, preparation of standard solutions, isolation of analytes from water, sample transfer methods, instrumental analysis, and data analysis are included.

Minnesota↗
USGS1996

Availability and quality of water from drift aquifers in Marshall, Pennington, Polk, and Red Lake counties, northwestern Minnesota

Sand and gravel aquifers present within glacial deposits are important sources of water in Marshall, Pennington, Polk, and Red Lake Counties in northwestern Minnesota. Saturated thicknesses of the unconfined aquifers range from 0 to 30 feet. Estimated horizontal hydraulic conductivities range from 2.5 to 600 feet per day. Transmissivity of the unconfined aquifers ranges from 33 to greater than 3,910 feet squared per day. Theoretical maximum well yields for 6 wells with specific-capacity data range from 12 to 123 gallons per minute. Saturated thicknesses of shallow confined aquifers (depth to top of the aquifer less than 100 feet below land surface) range from 0 to 150 feet. Thicknesses of intermediate, deep, and basal confined aquifers (depths to top of the aquifer from 100 to 199 feet, from 200 to 299 feet, and 300 feet or more below land surface, respectively) range from 0 to more than 126 feet. Transmissivity of the confined aquifers ranges from 2 to greater than 210,000 feet squared per day. Theoretical maximum well yields range from 3 to about 2,000 gallons per minute. Recharge to ground water is predominantly from precipitation that percolates downward to the saturated zone. Recharge to unconfined aquifers in the study area ranged from 4.5 to 12.0 inches per year during 1991 and 1992, based on hydrograph analysis. Model simulations done for this study indicate that recharge rates from 8 to 9 inches per year to unconfined aquifers produce the best matches between model-simulated and measured water levels in wells. Discharge from ground water occurs by seepage to streams, lakes and wetlands, ground-water evapotranspiration, and withdrawals through wells. In 1990, total ground-water withdrawals in the study area were 6.0 million gallons per day. All of the withdrawals were from drift aquifers. Numerical models of ground-water flow were constructed to represent two beach-ridge aquifer systems under steady-state conditions. Beach-ridge aquifer systems were simulated in Pennington, Polk, and Red Lake County. Simulated recharge from the infiltration of precipitation accounts for most of the sources of water to the beach-ridge aquifer systems and simulated evapotranspiration accounts for all of the discharge other than ground-water withdrawals. The numerical-model simulations indicate that upward movement of water from underlying confined aquifers to overlying unconfined aquifers is an important component of ground-water flow within the beach-ridge aquifer systems. Simulated long-term, steady-state yields from the unconfined aquifers are generally less than 50 gallons per minute, due to the generally low saturated thickness of the aquifers and the relatively low hydraulic conductivity of the aquifer material. Water from all the drift aquifers in the study area is very hard (more than 180 milligrams per liter of calcium carbonate). The predominant ions in water from the unconfined and shallow confined aquifers were generally calcium and bicarbonate. Water from the intermediate confined aquifers includes a variety of water types, including calcium bicarbonate, calcium sulfate, mixed calcium-sodium bicarbonate, and sodium chloride type waters. Waters from the deep confined aquifers are predominantly calcium bicarbonate, mixed calcium-sodium bicarbonate, and sodium chloride type waters. Mean concentrations of calcium and magnesium generally decreased with depth below land surface. Mean concentrations of sodium and sulfate generally increased with depth. Mean chloride concentrations were greatest for the shallow and deep confined aquifers and least for the unconfined and intermediate confined aquifers. The concentration and percentage (as percent of total cations) of sodium, and concentration of dissolved solids tend to increase from east to west along regional flow paths. Concentrations and percentages (as percent of total anions) of chloride tend to be greater in the western part of the study area than in the eastern part. These trends are probably due to longer residence time of the water in the flow system, and upward leakage of water from the underlying Cretaceous and Paleozoic strata. Waters from the drift aquifers underlying most of the study area generally are suitable for domestic consumption, crop irrigation, and most other uses. Water from 20 wells screened in unconfined and confined aquifers exceeded U.S. Environmental Protection Agency recommended limits for dissolved solids concentrations. Chemical analyses of waters from the unconfined and confined aquifers generally indicated a potentially low sodium hazard and a medium to high salinity hazard for irrigation. Water samples analyzed for nitrate had nitrate concentrations below the reporting limit (0.05 milligrams per liter) in 10 out of 23 wells. Two samples had nitrate concentrations greater than 10 milligrams per liter. Pesticide concentrations in water samples from 17 wells screened in unconfined and shallow confined aquifers were below or only slightly above laboratory reporting limits.

Minnesota↗
USGS1995

Ostracode δ18O and δ13C evidence of Holocene environmental changes in the sediments of two Minnesota lakes

Stable oxygen and carbon isotope geochemistry of ostracode valves, abundance and assemblages of ostracode species, and sedimentological parameters from cores taken in Williams and Shingobee Lakes in north-central Minnesota show changes in climatic and hydrologic history during the Holocene. Isotopic records are consistent with the following scenario: Before 9800 yr B.P. the two lakes were connected. Increasing evaporation through the jack/red pine period (9800-7700 yr B.P.) led to lower lake levels, leaving small separated basins. The prairie period (7700-4000 yr B.P.) reflects high aridity, and lake levels reached low stands shortly before 6500 yr B.P. Low lake levels are associated with groundwater discharge between 6500 and 6000 yr B.P. The hardwood period (4000-3200 yr B.P.) corresponds to long cold winters and warm to cool summers with lower evaporation rates and slower sedimentation. During the white pine period (<3200 yr B.P.) evaporation increased and/or precipitation shifted to the summer months. These changes can be related to shifting atmospheric circulation patterns. Zonal flow was probably dominant during the early Holocene until the end of the prairie period ( c. 4000 yr B.P.). During the hardwood period a combination of zonal and meridional flow patterns caused long and cold winters and wetter summers. During the white pine period wintners were shorter and the meridional flow pattern more significant. Today meridional flow dominates the circulation pattern.

Minnesota↗
USGS1995

Methane production and consumption monitored by stable H and C isotope ratios at a crude oil spill site, Bemidji, Minnesota

Stable isotopic ratios of C and H in dissolved CH 4 and C in dissolved inorganic C in the ground water of a crude-oil spill near Bemidji, Minnesota, support the concept of CH 4 production by acetate fermentation with a contemporaneous increase in HCO 3 − concentration. Methane concentrations in the saturated zone decrease from 20.6 mg L −1 to less than 0.001 mg L −1 along the investigated flow path. Dissolved N 2 and Ar concentrations in the ground water below the oil plume are 25 times lower than background; this suggests that gas exsolution is removing dissolved CH 4 (along with other dissolved gases) from the ground water. Oxidation of dissolved CH 4 along the flow path seems to be minimal because no measurable change in isotopic composition of CH 4 occurs with distance from the oil body. However, CH 4 is partly oxidized to CO 2 as it diffuses upward from the ground water through a 5- to 7-m thick unsaturated zone; the δ 13 C of the remaining CH 4 increases, the δ 13 C of the CO 2 decreases, and the partial pressure of CO 2 increases. Calculations of C fluxes in the saturated and unsaturated zones originating from the degradation of the oil plume lead to a minimum estimated life expectancy of 110 years. This is a minimum estimate because the degradation of the oil body should slow down with time as its more volatile and reactive components are leached out and preferentially oxidized. The calculated life expectancy is an order of magnitude estimate because of the uncertainty in the average linear ground-water velocities and because of the factor of 2 uncertainty in the calculation of the effective CO 2 diffusion coefficient.

Minnesota↗
USGS1995

Winter range arrival and departure of white-tailed deer in northeastern Minnesota

I analyzed 364 spring and 239 fall migrations by 194 white-tailed deer (Odocoileus virginianus) from 1975 to 1993 in northeastern Minnesota to determine the proximate cause of arrivals on and departures from winter ranges. The first autumn temperatures below -7?C initiated fall migrations for 14% (95% confidence interval (CI) = 0-30) of female deer prior to snowfall in three autumns, but only 2% remained on winter ranges. During 14 autumns, the first temperatures below -7?C coincidental with snowfalls elicited migration in 45% (95% CI = 34-57) of females, and 91 % remained on winter ranges. Arrival dates failed to correlate with independent variables of temperature and snow depth, precluding predictive modeling of arrival on winter ranges. During 13 years, a mean of 80% of females permanently arrived on winter ranges by 31 December. Mean departure dates from winter ranges varied annually (19 March - 4 May) and between winter ranges (14 days) and according to snow depth (15-cm differences). Only 15 - 41 % of deer departed when snow depths were> 30 cm but 80% had done so by the time of lO-cm depths. Mean weekly snow depths in March (18-85 cm) and mean temperature in April (0.3 -8.1 ?c) explained most of the variation in mean departure dates from two winter ranges (Ely, R2 = 0.87, P < 0.0005, n = 19 springs; Isabella, R2 = 0.85, P = 0.0001, n = 12 springs). Mean differences between observed mean departure dates and mean departure dates predicted from equations ranged from 3 days (predictions within the study area) to 8 days (predictions for winter ranges 100-440 km distant).

Minnesota↗
USGS1995

Responses of bluegills and black crappies to dissolved oxygen, temperature, and current in backwater lakes of the upper Mississippi River during winter

We conducted a radiotelemetry study to examine the effects of dissolved oxygen (DO), water temperature, and current velocity on winter habitat selection by bluegills Lepomis macrochirus and black crappies Pomoxis nigromaculatus in the Finger Lakes backwater complex, Pool 5, on the upper Mississippi River. When DO was above 2 mg/L, both species selected areas with water temperature greater than 1°C and undetectable current. As dissolved oxygen concentrations fell below 2 mg/L, fish moved to areas with higher DO, despite water temperatures of 1°C and lower and current velocities of 1 cm/s. Areas with water temperature less than 1°C and current velocity greater than 1 cm/s were avoided. To incorporate the winter habitat requirements of bluegills and black crappies into habitat restoration projects, we recommend designs that allow the inflow of oxygenated water to maintain adequate DO without substantially decreasing temperature and increasing current velocity.

Minnesota↗
USGS1995

Effects of canine parvovirus on gray wolves in Minnesota

Long-term effects of disease on wild animal population demography is not well documented. We studied a gray wolf (Canis lupus) population in a 2,060-km 2 area of Minnesota for 15 years to determine its response to canine parvovirus (CPV). The CPV had little effect ( P > 0.05) on wolf population size while epizootic during 1979-83. However, after CPV became enzootic, percentage of pups captured during summer-fall 1984-93 and changes in subsequent winter wolf numbers were each inversely related to the serological prevalence of CPV in wolves captured during July-November ( r 2 = 0.39 and 0.72, P = 0.05 and < 0.01, respectively). The CPV antibody prevalence in adult wolves increased to 87% in 1993 (r2 = 0.28, P = 0.05). However, because population level remained stable, CPV-induced mortality appeared to compensate for other mortality factors such as starvation. We -predict that the winter wolf population will decline when CPV prevalence in adults consistently exceeds 76%. The CPV may become important in limiting wolf populations.

Minnesota↗
USGS1995

Withdrawal and delivery of water by municipal supplies in Minnesota, 1993

Total withdrawal Statewide by municipal suppliers serving over 1,000 people was 108 billion gallons in 1993. Most of Minnesota's municipal deliveries were for residential purposes. About 87 percent of suppliers withdraw from ground-water and 13 percent withdraw from surface-water sources. Water withdrawn for public supply has steadily risen since 1955 and the increase has mainly come from ground water. Declines in per capita use since 1990 may be related to heavy rainfall, conservation measures, and the installation of more efficient water-using machines.

Minnesota↗
USGS1995

Ground-water baseflow to the upper Mississippi River upstream of the Minneapolis-St. Paul area, Minnesota during July 1988

Ground-water baseflow to six subreaches of the Upper Mississippi River were estimated for July 1988, a period of drought. Ground-water baseflow to each subreach was estimated on the basis of streamflow gains determined from records of daily discharge at gaging stations. Streamflow gains were adjusted for estimated inflow from tributaries, municipal and industrial discharges, withdrawals, and evaporation. Low-flow frequency characteristics were computed for the Mississippi River near Anoka, Minnesota and the Mississippi River at St. Paul, Minnesota.

Minnesota↗
USGS1995

Presence and distribution of nitrate and selected pesticides in surficial-sand aquifers and selected lakes, 1993-94, East Otter Tail County, Minnesota

This report presents selected data collected during the first year (December 1993 to September 1994) of a three year water-quality study of surficial-sand aquifers and selected lakes in east Otter Tail County, Minnesota. The objectives of the study are (1) to determine the presence and distribution of nitrate-nitrogen and selected pesticides in ground water from the surficial-sand aquifers; and (2) to characterize the water quality of selected lakes and the Otter Tail River. Ground water was sampled from 73 wells. The concentration of nitrate nitrogen in ground water was above 10 mg/L (milligrams per liter) in 30 of the sampled wells (38 percent). The concentration of triazine herbicide compounds, as determined by immunoassay, was above the detection limit 0.10 ug/l (micrograms per liter) in water from 17 of the sampled wells (24 percent). The nitrate- nitrogen concentration in water from 14 wells, compared to data collected during a previous study in 1979-81, increased in water from 4 wells and decreased in water from 4 wells. Lake water was sampled from 11 sites on Little Pine, Big Pine, Rush, and Otter Tail Lakes. Nitrate-nitrogen concentrations were all below the detection limit (0.05 mg/L). The concentration of triazine herbicide compounds, as determined by immunoassay, was at or below the detection limit (0.10 ug/L) at all 11 sites. Dissolved oxygen concentrations at the sites ranged from 7.3 to 10.1 mg/L at the water surface, and from 5.3 to 9.7 mg/L at depth. Secchi disk transparency readings ranged from 4.0 to 7.4 feet. Total phosphorus concentrations were generally near or below the detection limit (0.01 mg/L) except at one site where the water had a total phosphorus concentration of 0.06 mg/L.

Minnesota↗
USGS1995

Physical characteristics of stream subbasins in the Cottonwood River basin, southwestern Minnesota

Data that describe the physical characteristics of stream subbasins upstream from selected points on streams in the Cottonwood River Basin, located in southwestern Minnesota, are presented in this report. The physical characteristics are the drainage area of the subbasin, the percentage area of the subbasin covered only by lakes, the percentage area of the subbasin covered by both lakes and wetlands, the main-channel length, and the main-channel slope. The points on the stream include outlets of subbasins of at least 5 square miles, outlets of sewage treatment plants, and locations of U.S. Geological Survey low-flow, high-flow, and continuous-record gaging stations.

Minnesota↗
USGS1995

Relation of fracture orientation to linear terrain features, anisotropic transmissivity, and seepage to streams in the karst Prairie du Chien Group, southeastern Minnesota

Ground-water flow in the karst-terrane aquifers of southeastern Minnesota is not well defined. Variable fracture patterns in the bedrock affect permeability. Techniques to predict the effects of fracture patterns on ground-water flow in the karst-terrane aquifers of southeastern Minnesota are unavailable. The use of such techniques may be useful to officials responsible for the management and protection of ground water in these aquifers, which have a high susceptibility to contamination. The U.S. Geological Survey, in cooperation with the Minnesota Department of Natural Resources and the Legislative Commission on Minnesota Resources, investigated fracture patterns, anisotropic transmissivity, and seepage to streams from the Prairie du Chien Group, which is the karst portion of the St. Peter-Prairie du Chien-Jordan aquifer, to improve the understanding of ground-water flow through karst-terrane aquifers in southeastern Minnesota. This report presents the results of testing hypotheses that (1) the major axes of linear terrain features correlate with the major axes of subsurface fractures in the Prairie du Chien Group, and that (2) the major axes of subsurface fractures in the Prairie du Chien Group correlate with seepage from the Prairie du Chien Group. The first hypothesis was tested by comparison of linear terrain features to fracture orientation measurements. Fracture orientations in 10 exposures of the Prairie du Chien Group at quarries, road cuts, and natural outcrops showed statistically significant directional trends at 8 of 10 sites. Directional trends of linear terrain features identified from 1:80,000 aerial photographs were significant in four of the ten 60-square mile areas that surround these sites. The fracture orientation measurements correlate with the local linear terrain features in 2 of the 10 sites. The second hypothesis was tested by analyzing the correlation between seepage rates into streams hydraulically connected to the Prairie du Chien Group and surrounding linear terrain features that were mapped in approximately 300 square mile areas. Data from Riceford Creek support this hypothesis; data from Crow Creek and Middle Fork of the Whitewater River and from Duschee Creek are inconclusive. This hypothesis could not be tested by the data from the Middle Fork of the Zumbro River, the South Branch of the Root River, and the South Branch of the Middle Fork of the Zumbro River because the surrounding linear terrain features lack directional trends. The transmissivity of the karst portion of the St. Peter-Prairie du Chien-Jordan aquifer is anisotropic at an aquifertest site in the study area. Results of the aquifer test indicate that the major axis of transmissivity is along a line N95&deg;E. The aquifer-test results indicate that the principal axis of joint fractures at the test site is slightly clockwise from an east-west line because this axis is assumed to correlate with the major axis of horizontal transmissivity.

Minnesota↗
USGS1995

Water resources of the Grand Portage Indian Reservation, northeastern Minnesota

The Grand Portage Indian Reservation Tribal Council needs information about the availability and quality of the ground water in the Reservation to develop, protect, and manage this resource for future use. The U.S. Geological Survey, in cooperation with the Grand Portage Indian Reservation Tribal Council, did a three-year study of the ground water in the Reservation to provide this needed information. This report presents the results of that study. Presently, ground water from bedrock is the principal source of supply for municipal, commercial, and residential water use. The bedrock aquifers are the (1) North Shore Volcanic Group basalt, (2) Keweenawan Volcanic and intrusive rocks, which are gabbro and diabase, and (3) Rove Formation argillite, slate, and graywacke. Sand and gravel aquifers are a small source of ground water. The storage coefficient of the bedrock aquifers was estimated to be 1 x 10 -4 , which is a small value typical of confined, fractured rock aquifers. The median estimate of transmissivity determined from data for 17 wells completed in bedrock was 20 feet squared per day; the range was from 3 to 500 feet squared per day. Reported yield of 19 wells completed in bedrock had a range of 1 to 100 gallons per minute and a median of 7 gallons per minute. The median yield of 11 wells completed in the North Shore Volcanic Group was 16 gallons per minute; the median yield of 8 wells completed in the Keweenawan Volcanic and intrusive rocks and Rove Formation was 4 gallons per minute. Geophysical logs and televiewer images of two wells completed in bedrock indicated the boreholes penetrated many fractures. Hydrofracturing of the two wells increased their yield from about 0.05 and 0.25 gallons per minute to about 1.5 and 1.2 gallons per minute, respectively. Although the estimated yield from the two wells was increased by 30 and by nearly 5 times after hydrofracturing, the well yield after hydrofracturing was still small. Water types determined from analyses of water from nine wells completed in bedrock were sodium-chloride, calcium-chloride, sodium-bicarbonate, and calcium-bicarbonate. Water from three wells had concentrations of dissolved solids (800 to 3,110 milligrams per liter) and dissolved chloride (410 to 1,600 milligrams per liter) that were higher than their respective Secondary Maximum Contaminant Levels of 500 and 250 milligrams per liter established by the U.S. Environmental Protection Agency. Water from two wells had concentrations of dissolved iron (1,600 and 1,300 micrograms per liter) that were higher than the Secondary Maximum Contaminant Level of 300 micrograms per liter. Water from an observation well located about 200 feet downgradient from an abandoned landfill and screened from 79 to 84 feet below land surface in a gravel aquifer had a trace amount of toluene (0.2 micrograms per liter). The presence of toluene suggested possible contamination.

Minnesota↗
USGS1995

Hydrogeology and ground-water flow of the drift and Platteville aquifer system, St. Louis Park, Minnesota

Three aquifers and two confining units have been delineated within the drift underlying the area near the site of a former coal-tar distillation and wood-preserving plant in St. Louis Park, Minnesota. The hydrogeologic units of the drift, in descending order, are the upper drift aquifer, the upper drift confining unit, the middle drift aquifer, the lower drift confining unit. and the lower drift aquifer. A contamination plume consisting of coal-tar derivatives exists in the drift aquifers and in the Platteville aquifer underlying the southern part of the plant site and areas to the south and east of the plant site. The upper drift aquifer has a maximum saturated thickness of about 25 feet. Horizontal hydraulic conductivities of the upper drift aquifer range from less than 1 to about 25 feet per day in peat areas and from about 50 to 400 feet per day in sand and gravel areas. The upper drift confining unit generally is less than 20 feet thick, with a maximum thickness of 62 feet. The saturated thickness of the middle drift aquifer generally is 20 to 30 feet in areas where the aquifer is both overlain and underlain by a confining unit. The horizontal hydraulic conductivity of the middle drift aquifer ranges from about 50 to 500 feet per day. The lower drift confining unit is as much as 50 feet thick. Model-computed vertical hydraulic conductivities for the upper and lower drift confining units ranged from 0.0002 to 5 feet per day. The lower drift aquifer consists of discontinuous sand and gravel deposits overlying Platteville Formation bedrock and has a maximum thickness of 20 feet where it is overlain by the lower drift confining unit. Water in the drift aquifers and in the Platteville aquifer generally flows from the northwest to the southeast under a hydraulic gradient of about 10 feet per mile. The drift confining units and the Glenwood confining unit. when present, control the vertical movement of water through the aquifers. Discontinuities in these confining units greatly influence patterns of ground-water flow. A numerical cross-sectional ground-water-flow model was used to test concepts of flow of ground water through the drift aquifers and the Platteville aquifer. particularly the effects of confining units and bedrock valleys on vertical flow. The model has eight layers representing, in descending order: ( 1) the upper drift aquifer. (2) the upper drift confining unit, (3) the middle drift aquifer, (4) the upper part of the lower drift confining unit, (5) the lower part of the lower drift confining unit and lower drift aquifer, (6) the Platteville aquifer and bedrock valley deposits, (7) the St. Peter aquifer, and (8) the Prairie du Chien-Jordan aquifer. A sensitivity analysis indicated that model-calculated hydraulic heads in the drift aquifers and in the Platteville aquifer were most sensitive to variations in: (1) the horizontal hydraulic conductivities of the middle drift aquifer, (2) the transmissivities of the Platteville and St. Peter aquifers, (3) the vertical hydraulic conductivities of the lower drift confining unit and the drift material filling the bedrock valley, and (4) the vertical hydraulic conductivity of the basal St. Peter confining unit. The model-calculated water budget indicated that recharge from infiltration of precipitation to the upper and middle drift aquifers and the upper drift confining unit accounts for about 41 percent of the total sources of water. The remaining 59 percent is from subsurface inflow from the west (through specified-head cells). About 70 percent of the outflow from the eastern model boundary was simulated as discharge from the model layers representing the Platteville aquifer and bedrock valley deposits and the St. Peter aquifer. The calibrated simulation indicated that about 99 percent of the total leakage of water from the drift aquifers and from the Platteville aquifer to the underlying St. Peter aquifer occurs through areas where the Glenwood confining unit is absent or discontinuous. Hypothetical changes of the hydraulic properties and the extent of confining units were simulated using the calibrated steady-state model. Increasing the vertical hydraulic conductivity of model layer 4, representing the upper part of the lower drift confining unit, by a factor of 100 in the western part of the cross section resulted in decreased model-calculated leakage to the St. Peter aquifer through the bedrock valley represented in the eastern part of the cross-sectional model. A hypothetical extension of vertical hydraulic conductivities representing the Glenwood confining unit along the entire cross-sectional model resulted in a 98 percent reduction in the model-calculated amount of water leaking from the Platteville aquifer and bedrock valley deposits to the underlying St. Peter aquifer. Model simulations indicate that vertical ground-water flow from the drift aquifers and from the Platteville aquifer to underlying bedrock aquifers is greatest through bedrock valleys. The convergence of flow paths near bedrock valleys and the greater volume of water moving through the valleys would likely result in both increased concentrations and greater vertical movement of contaminants in areas underlain by bedrock valleys as compared to areas not underlain by bedrock valleys. Model results also indicate that field measurements of hydraulic head might not help locate discontinuities in confining units and additional test drilling to locate discontinuities might be necessary.

Minnesota↗
USGS1995

Hydrology and relation of selected water-quality constituents to selected physical factors in Dakota County, Minnesota, 1990-91

Selected water-quality constituents were determined in water from 5 surface-water sites and 29 wells in Dakota County, Minnesota, to search for possible relations to selected physical factors, including waste-water discharge, agricultural land, Quaternary deposits, bedrock, soil-leaching potential, and water-table depth. All surface-water samples were from the Vermillion River Basin, whose hydrologic setting was studied to determine its relation to the ground-water flow in the surrounding surficial sand aquifer. Each site was sampled from 1 to 12 times during 1990- 91. A total of 198 samples were collected; selected samples were analyzed for major inorganic ions, nutrients, and triazine content. Physical factors within the area of land assumed to be contributing water to each sampling site were determined from existing mapped or digitized sources. Nitrate concentrations in ground water were related to agricultural land and soil-leaching potential. Nitrate concentrations were large (median 13.2 milligrams per liter as nitrogen) where the percentage of agricultural land in the contributing area was large (equal to or greater than 75 percent) and where the soils had a large soil-leaching potential. Nitrate concentrations were small (median 3.2 milligrams per liter as nitrogen) where the soils had a small soil-leaching potential, despite a large percentage of agricultural land. The statistical relation was not particularly strong, however: the null hypothesis that sites with different soil-leaching potentials had the same nitrate concentrations in ground water was rejected by the Kruskal-Wallis test at only the probability P = 0.15 level. Water-table depth was not an important factor in the relation between nitrate concentrations in ground water and agricultural land. Discharge from a waste-water treatment plant provided most of the downstream loading of nitrate into the Vermillion River mainstem. Triazines were found in small concentrations (less than 2 micrograms per liter) in the Vermillion River and its tributaries. No relation was apparent between selected water-quality constituents and either Quaternary deposits or bedrock.

Minnesota↗
USGS1995

Ground-water quality in agricultural areas, Anoka Sand Plain Aquifer, east-central Minnesota, 1984-90

Ground-water quality in the Anoka Sand Plain aquifer was studied as part of the multiscale Management Systems Evaluation Area (MSEA) study by collecting water samples from shallow wells during August through November 1990. The sampling was conducted to: (1) aid in selection of the MSEA research area; (2) facilitate comparison of results at the MSEA research area to the regional scale; and (3) evaluate changes in ground-water quality in the Anoka Sand Plain aquifer since a previous study during 1984 through 1987. Samples were collected from 34 wells screened in the upper 6 meters of the surficial aquifer and located in cultivated agricultural areas. Water temperature, pH, specific conductance, and presence or absence of triazine herbicides were determined at all sites and samples from selected wells were analyzed for concentrations of dissolved oxygen, alkalinity, major cations and anions, nutrients, and selected herbicides and herbicide metabolites. The results of the study indicate that the water-quality of some shallow ground water in areas of predominantly agricultural land use has been affected by applications of nitrogen fertilizers and the herbicide atrazine. Concentrations of nitrite plus nitrate nitrogen (nitrate-N) in 19 samples ranged from less than the detection limit of 0.1 to 21 milligrams per liter (mg/L) with a median of 10 mg/L. Concentrations of nitrate-N were not significantly correlated with depth below the water table or dissolved oxygen but were significantly correlated with concentrations of chloride. Concentrations of nitrate-N during 1990 were generally similar to concentrations measured during 1984 through 1987. Changes in concentrations of nitrate-N during 1984 through 1990 were likely related to variations in recharge or other site-specific factors. Immunoassay analyses were used as screening tools to detect the presence of triazine herbicides. All samples in which triazine herbicides were detected by immunoassay, and selected samples in which triazine herbicides were not detected by immunoassay, were analyzed for selected herbicides and herbicide metabolites by gas chromatography/mass spectroscopy (GC/MS). There was an excellent correspondence between concentrations of triazine herbicides indicated by immunoassay and concentrations of atrazine measured by GC/MS, indicating that the immunoassay method was a valuable qualitative to semi-quantitative tool for evaluating the presence and approximate concentration of atrazine. The combined results of immunoassay and GC/MS analyses indicate that atrazine was detected in 11 of the 34 wells with a median concentration less than the immunoassay detection limit of 0.1 micrograms per liter ( &mu; g/L). Atrazine was detected in 11 of the 17 samples analyzed by GC/MS at concentrations ranging from the detection limit of 0.05 to 0.81 &mu; g/L with a median of 0.09 &mu; g/L. Atrazine metabolite de-ethylatrazine (DEA) was the most frequently detected herbicide or herbicide metabolite and generally was present at the greatest concentrations. There were detections of DEA in 13 of the 17 samples analyzed at concentrations ranging from the detection limit of 0.05 to 1.12 &mu; g/L with a median of 0.15 &mu; g/L. Concentrations of DEA were significantly correlated with concentrations of calcium, magnesium, and specific conductance. The atrazine metabolite de-isopropylatrazine and the herbicide metolachlor both were detected in 1 of the 17 wells. The frequency of detection and the concentrations of atrazine in shallow ground water during 1990 were very similar to results of sampling conducted in 1984. Concentrations of atrazine and DEA generally were greater near the water table and decreased or were not detected in deeper wells. All of the samples in which atrazine and DEA were detected also had increased (greater than 3 mg/L) nitrate-N concentrations. However, not all samples with increased concentrations of nitrate-N had detections of atrazine or DEA. This likely indicates either that there were sources of nitrate-N other than cultivated fields on which both atrazine and nitrogen were applied or that nitrate-N reached ground water more readily than atrazine or DEA.

Minnesota↗
USGS1995

Discharge ratings for tainter gates and roller gates at Lock and Dam No. 7 on the Mississippi River, La Crescent, Minnesota

The water-surface elevations on the Inland Waterway Navigation System of the upper Mississippi River are controlled during normal operating conditions by various flow controls at 29 locks and dams. The headwater (navigation pool) and tailwater elevations at Lock and Dam No. 7 are controlled by the regulation of 11 tainter gates and 5 roller gates. Discharge ratings for these tainter and roller gates were developed for use in computing discharge through Dam No. 7 and to aid in regulating the navigation pool within its normal operating limits of 639.00 &plusmn; 0.20 feet (NGVD 1912). Hydraulic-control variables and discharges were measured at the tainter and roller gates and analyzed for this report. Fifty-two current-meter measurements of discharges that ranged from discharges too low to measure to 12,600 cubic feet per second were made in the forebays of the tainter and roller gates. The measured discharges were used to define flow regimes as a function of static-headwater depth (hi), static-tailwater depth (03), and vertical height of tainter or roller gate opening (hg). Submerged-orifice flow is the predominant flow regime at Lock and Dam No. 7. Twenty-four discharge measurements were used to develop submerged-orifice discharge coefficient relations for the 11 tainter gates. Twenty discharge measurements were used to develop a submerged-orifice discharge coefficient relation for the five roller gates. Coefficients of discharge (Cgs) ranged fron 0.126 (hg = 1 foot) to 1.089 (hg = 10 feet) for tainter gates and from 0.050 (hg = 1 foot) to 0.302 (hg = 14 feet) for roller gates. Disch^ge was measured at three different tainter gates with the gates closed (hg = 0) to evaluate tH tainter-gate leakage-discharge relations. No measurable leakage was observed. The resulting equations can be used to compute discharge at Lock and Dam No. 7 for the tainter and re Her gates under normal flow conditions. Discharge rating tables for the tainter and roller gates are given with a headwater elevation of 639.00 feet normal pool elevation for selected tailwate" elevations and gate openings.

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