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Research about Minnesota

Source-linked reports with geographic coverage including Minnesota.

At least 415 records · Page 23Linked to original sources
USGS2004

Use of borehole radar methods and borehole geophysical logs to monitor a field-scale vegetable oil biostimulation pilot project at Fridley, Minnesota

Cross-hole and surface-to-borehole radar and conventional borehole geophysical logs were used to monitor subsurface injections of vegetable oil emulsion conducted as part of a field-scale biostimulation pilot project at the Anoka County Riverfront Park (ACP), located downgradient of the Naval Industrial Reserve Ordnance Plant (NIROP), in Fridley, Minnesota. The pilot project was undertaken to evaluate biostimulation using emulsified vegetable oil for treatment of ground water contaminated with chlorinated hydrocarbons. The objectives of the geophysical investigations were to delineate the distribution of vegetable oil injected at NIROP, and evaluate the utility of adding geophysical tracers to the vegetable oil emulsions. Geophysical data were acquired by the U.S Geological Survey in five site visits over 1.5 years. This paper presents (1) level-run radar traveltime and amplitude data; (2) radar cross-hole traveltime tomograms; (3) vertical-radar profile diffraction tomograms; and (4) borehole electromagnetic induction logs. Based on comparison of pre- and postinjection data sets, a conceptual model was developed to define the distribution of emulsified vegetable oil and the extent of ground water having altered chemistry resulting from injections and, possibly, enhanced microbial degradation of chlorinated hydrocarbons. Radar slowness (reciprocal velocity) anomalies indicate that the emplaced oil emulsion remained close to the injection wells, whereas attenuation anomalies indicate changes in ground-water chemistry downgradient of all three injections.

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USGS2004

Application of cross-borehole radar to monitor fieldscale vegetable old injection experiments for biostimulation

Cross-borehole radar methods were used to monitor a field-scale biostimulation pilot project at the Anoka County Riverfront Park (ACP), located downgradient of the Naval Industrial Reserve Ordnance Plant, in Fridley, Minnesota. The goal of the pilot project is to evaluate biostimulation using emulsified vegetable oil to treat ground water contaminated with chlorinated hydrocarbons. Vegetable oil is intended to serve as substrate to naturally occurring microbes, which ultimately break down chlorinated hydrocarbons into chloride, carbon dioxide, and water through oxidation-reduction reactions. In support of this effort, cross-borehole radar data were acquired by the U.S Geological Survey in five site visits over 1.5 years. This paper presents level-run (zero-offset profile) and time-lapse radar tomography data collected in multiple planes. Comparison of pre- and post-injection data sets provides valuable insights into the spatial and temporal distribution of both emulsified vegetable oil and also the extent of ground water with altered chemistry resulting from injections — information important for understanding microbial degradation of chlorinated hydrocarbons at the site. In order to facilitate data interpretation and test the effectiveness of radar for monitoring oil-emulsion placement and movement, three injection mixtures with different radar signatures were used: (1) vegetable oil emulsion, (2) vegetable oil emulsion with a colloidal iron tracer, and (3) vegetable oil emulsion with a magnetite tracer. Based on petrophysical modeling, mixture (1) is expected to increase radar velocity and decrease radar attenuation relative to background — a water-saturated porous medium; mixtures (2) and (3) are expected to increase radar velocity and also increase radar attenuation due to their greater electrical conductivity compared to native ground water. Radar slowness (inverse radar velocity) tomograms and level-run profiles show decreases in slowness in the vicinity of injection wells. Slowness anomalies are observed only in planes connected to injection wells, indicating that the emplaced emulsified vegetable oil does not migrate far after injection. In contrast to the localization of slowness anomalies, attenuation anomalies are observed in all level-run profiles, particularly those downgradient of the injection wells. Despite the expected signatures of different tracers, increases in attenuation are observed downgradient of all three injections; thus, we infer that the attenuation changes do not result from the iron tracers. One viable explanation for the observed attenuation changes is that products of oil-enhanced biodegradation (for example, ferrous iron) increase electrical conductivity of ground water and thus radar attenuation. Application of radar methods to data from the ACP demonstrated the utility of radar for monitoring biostimulation. Results of level-run and tomographic surveys identified (1) the distribution of emulsified vegetable oil, and (2) the distribution of ground water with oil-affected chemistry. Ongoing research efforts include simultaneous tomographic inversion of radar data from multiple planes, petrophysical modeling, geostatistical interpolation, and development of an integrated interpretation considering conventional borehole logs and surface-to-borehole radar data.

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USGS2003

Inorganic nitrogen transformations in the bed of the Shingobee River, Minnesota: Integrating hydrologic and biological processes using sediment perfusion cores

Inorganic N transformations were examined in streambed sediments from the Shingobee River using sediment perfusion cores. The experimental design simulated groundwater-stream water mixing within sediment cores, which provided a well-defined one-dimensional representation of in situ hydrologic conditions. Two distinct hydrologic and chemical settings were preserved in the sediment cores: the lowermost sediments, perfused with groundwater, remained anaerobic during the incubations, whereas the uppermost sediments, perfused with oxic water pumped from the overlying water column, simulated stream water penetration into the bed. The maintenance of oxic and anoxic zones formed a biologically active aerobic-anaerobic interface. Ammonium (NH4+) dissolved in groundwater was transported conservatively through the lower core zone but was removed as it mixed with aerated recycle water. Concurrently, a small quantity of nitrate (NO3-) equaling ???25% of the NH4+ loss was produced in the upper sediments. The NH4+ and NO3- profiles in the uppermost sediments resulted from coupled nitrification-denitrification, because assimilation and sorption were negligible. We hypothesize that anaerobic microsites within the aerated upper sediments supported denitrification. Rates of nitrification and denitrification in the perfusion cores ranged 42-209 and 53-160 mg N m-2 day-1, respectively. The use of modified perfusion cores permitted the identification and quantification of N transformations and verified process control by surface water exchange into the shallow hyporheic zone of the Shingobee River.

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USGS2003

Characterization of lake water and ground water movement in the littoral zone of Williams Lake, a closed-basin lake in North central Minnesota

Williams Lake, Minnesota is a closed‐basin lake that is a flow‐through system with respect to ground water. Ground‐water input represents half of the annual water input and most of the chemical input to the lake. Chemical budgets indicate that the lake is a sink for calcium, yet surficial sediments contain little calcium carbonate. Sediment pore‐water samplers (peepers) were used to characterize solute fluxes at the lake‐water–ground‐water interface in the littoral zone and resolve the apparent disparity between the chemical budget and sediment data. Pore‐water depth profiles of the stable isotopes δ 18 O and δ 2 H were non‐linear where ground water seeped into the lake, with a sharp transition from lake‐water values to ground‐water values in the top 10 cm of sediment. These data indicate that advective inflow to the lake is the primary mechanism for solute flux from ground water. Linear interstitial velocities determined from δ 2 H profiles (316 to 528 cm/yr) were consistent with velocities determined independently from water budget data and sediment porosity (366 cm/yr). Stable isotope profiles were generally linear where water flowed out of the lake into ground water. However, calcium profiles were not linear in the same area and varied in response to input of calcium carbonate from the littoral zone and subsequent dissolution. The comparison of pore‐water calcium profiles to pore‐water stable isotope profiles indicate calcium is not conservative. Based on the previous understanding that 40–50 % of the calcium in Williams Lake is retained, the pore‐water profiles indicate aquatic plants in the littoral zone are recycling the retained portion of calcium. The difference between the pore‐water depth profiles of calcium and δ 18 O and δ 2 H demonstrate the importance of using stable isotopes to evaluate flow direction and source through the lake‐water–ground‐water interface and evaluate mechanisms controlling the chemical balance of lakes.

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USGS2003

Inverse modeling of BTEX dissolution and biodegradation at the Bemidji, MN crude-oil spill site

The U.S. Geological Survey (USGS) solute transport and biodegradation code BIOMOC was used in conjunction with the USGS universal inverse modeling code UCODE to quantify field-scale hydrocarbon dissolution and biodegradation at the USGS Toxic Substances Hydrology Program crude-oil spill research site located near Bemidji, MN. This inverse modeling effort used the extensive historical data compiled at the Bemidji site from 1986 to 1997 and incorporated a multicomponent transport and biodegradation model. Inverse modeling was successful when coupled transport and degradation processes were incorporated into the model and a single dissolution rate coefficient was used for all BTEX components. Assuming a stationary oil body, we simulated benzene, toluene, ethylbenzene, m , p -xylene, and o -xylene (BTEX) concentrations in the oil and ground water, respectively, as well as dissolved oxygen. Dissolution from the oil phase and aerobic and anaerobic degradation processes were represented. The parameters estimated were the recharge rate, hydraulic conductivity, dissolution rate coefficient, individual first-order BTEX anaerobic degradation rates, and transverse dispersivity. Results were similar for simulations obtained using several alternative conceptual models of the hydrologic system and biodegradation processes. The dissolved BTEX concentration data were not sufficient to discriminate between these conceptual models. The calibrated simulations reproduced the general large-scale evolution of the plume, but did not reproduce the observed small-scale spatial and temporal variability in concentrations. The estimated anaerobic biodegradation rates for toluene and o -xylene were greater than the dissolution rate coefficient. However, the estimated anaerobic biodegradation rates for benzene, ethylbenzene, and m , p -xylene were less than the dissolution rate coefficient. The calibrated model was used to determine the BTEX mass balance in the oil body and groundwater plume. Dissolution from the oil body was greatest for compounds with large effective solubilities (benzene) and with large degradation rates (toluene and o -xylene). Anaerobic degradation removed 77% of the BTEX that dissolved into the water phase and aerobic degradation removed 17%. Although goodness-of-fit measures for the alternative conceptual models were not significantly different, predictions made with the models were quite variable.

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USGS2003

Numerical modeling of coupled nitrification-denitrification in sediment perfusion cores from the hyporheic zone of the Shingobee River, MN

Nitrification and denitrification kinetics in sediment perfusion cores were numerically modeled and compared to experiments on cores from the Shingobee River MN, USA. The experimental design incorporated mixing groundwater discharge with stream water penetration into the cores, which provided a well-defined, one-dimensional simulation of in situ hydrologic conditions. Ammonium (NH 4 + ) and nitrate (NO 3 − ) concentration gradients suggested the upper region of the cores supported coupled nitrification–denitrification, where groundwater-derived NH 4 + was first oxidized to NO 3 − then subsequently reduced via denitrification to N 2 . Nitrification and denitrification were modeled using a Crank–Nicolson finite difference approximation to a one-dimensional advection–dispersion equation. Both processes were modeled using first-order reaction kinetics because substrate concentrations (NH 4 + and NO 3 − ) were much smaller than published Michaelis constants. Rate coefficients for nitrification and denitrification ranged from 0.2 to 15.8 h −1 and 0.02 to 8.0 h −1 , respectively. The rate constants followed an Arrhenius relationship between 7.5 and 22 °C. Activation energies for nitrification and denitrification were 162 and 97.3 kJ/mol, respectively. Seasonal NH 4 + concentration patterns in the Shingobee River were accurately simulated from the relationship between perfusion core temperature and NH 4 + flux to the overlying water. The simulations suggest that NH 4 + in groundwater discharge is controlled by sediment nitrification that, consistent with its activation energy, is strongly temperature dependent.

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USGS2003

Effects of Holocene climate change on mercury deposition in Elk Lake, Minnesota: The importance of eolain transport in the mercury cycle

Sediments in Elk Lake , Minnesota , consist of 10,400 varve layers that provide a precise chronology for Holocene fluctuations in climate and biota recorded in the strata. Progressively greater concentrations and accumulation rates of mercury since ca. A.D. 1875 reflect deposition of anthropogenic mercury additions to the atmosphere. Within the Holocene record are numerous short intervals in which mercury concentrations and accumulation rates exceed the modern values. The highest mercury concentrations formed ca. 8 ka, coincident with a rapid change from cool, moist conditions to warm, dry conditions. A related change in flora from pine forest to prairie caused destruction of organic forest soils and the release of mercury that had been sequestered in them, resulting in a short- lived pulse of mercury to the lake . Accumulation rates of mercury were highest during the 4 k.y. mid- Holocene dry interval and show a correlation with periods of rapid deposition of eolian dust. The mercury was probably bound to wind-borne mineral particles, which were derived from an unidentified mercury -rich source region west of Elk Lake .

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USGS2003

Home range and residency status of Northern Goshawks breeding in Minnesota

We used radio-telemetry to estimate breeding season home - range size of 17 male and 11 female Northern Goshawks (Accipiter gentilis) and combined home ranges of 10 pairs of breeding goshawks in Minnesota . Home - range sizes for male and female goshawks were 2593 and 2494 ha, respectively, using the minimum convex polygon, and 3927 and 5344 ha, respectively, using the 95% fixed kernel. Home ranges of male and female members of 10 goshawk pairs were smaller than combined home - range size of those pairs (mean difference = 3527 ha; 95% CI = 891 to 6164 ha). Throughout the nonbreeding season, the maximum distance from the nest recorded for all but one goshawk was 12.4 km. Goshawks breeding in Minnesota have home ranges similar to or larger than those reported in most other areas. Home - range overlap between members of breeding pairs was typically ≤50%, and both members of breeding pairs were associated with breeding home ranges year round. Goshawk management plans based on estimated home - range size of individual hawks may substantially underestimate the area actually used by a nesting pair.

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USGS2003

Factors affecting gadwall brood and duckling survival in prairie pothole landscapes

Waterfowl biologists need reliable predictors of brood and duckling survival to accurately estimate recruitment rates. We examined 30-day survival rates of gadwall (Anas strepera) broods (1992-1994) and ducklings (1990-1994) in eastern North Dakota, USA, during years when water conditions ranged from extremely dry to extremely wet. We evaluated effects of several variables on brood survival : (1) percent of seasonal wetland basins containing water, (2) occurrence of rain on the current or 2 previous exposure days, (3) minimum ambient temperature averaged over the current and 2 previous exposure days, (4) hatch date, (5) duckling age, and (6) brood size. Only 9 of 58 radiomarked females lost their entire broods; Kaplan-Meier 30-day survival rate for broods was 0.84. Brood size (adjusted for hatch date) was a better brood - survival predictor than were any of the environmental variables. Risk of total brood loss decreased by 24% for each additional duckling in the brood . We monitored fates of 212 radiomarked ducklings from 94 broods. Daily risk of death for ducklings was twice as high when seasonal ponds were scarce as when ponds were abundant. Duckling survival rate was lower during the first 7 days of life whether it rained or not; survival rate was greater for 8- to 30-day-old ducklings, but was reduced by rain. Thirty-day duckling survival was greatest when minimum daily temperatures exceeded 10°C and no rain occurred. We attributed 86% of 87 deaths of radiomarked ducklings to predation; American mink (Mustela vison) accounted for ≥68% of the 40 deaths for which predator type could be ascertained. Despite apparent resilience of gadwall populations during drought, our study documented a positive effect of seasonal wetland availability on gadwall duckling survival . Management efforts to improve recruitment will be more effective in years when most seasonal basins contain water.

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USGS2003

Sampling designs for carnivore scent-station surveys

Scent stations usually are deployed in clusters to expedite data collection and increase the number of stations that can be operated for a given cost. Presumed benefits of cluster sampling may not be realized, however, unless cluster sizes are chosen with respect to sampling variation within and among clusters. To encourage and facilitate the use of efficient designs and reporting standards, we used data collected in Minnesota, USA, during 1986-1991 to (1) compare the performance of survey designs with various numbers of stations/cluster; (2) estimate relations between required sample sizes and visitation rates, changes in visitation rates, and error rates; and (3) compare 2 measures of carnivore response: proportions of scent stations ( station index) and proportions of clusters (line index) visited by red foxes (Vulpes vulpes) and striped skunks (Mephitis mephitis). Despite broad ecological differences between the species, results were similar for foxes and skunks. Foxes visited 2-21% of stations and 15-84% of lines. Skunks visited 1-16% of stations and 3-54% of lines. Station and line indices were closely related (r 2 > 0.86) and were similarly sensitive indicators of change in visitation rates. Low visitation rates greatly limited the potential usefulness of scent - station surveys because required minimum sample sizes increased exponentially as visitation rates decreased. For visitation rates below 5-10%, required minimum sample sizes were very large and difficult to anticipate. Relative to single-stage sampling , cluster sampling with 10 stations/cluster inflated sample variances, hence sample sizes required to achieve a fixed level of precision, by a factor of 1.6-2.2. Cluster sampling is advantageous only when cost savings permit increases in sample sizes that outweigh concomitant increases in sampling variability. Costs and sampling variation both should be considered when choosing survey designs , and designs should be evaluated and refined as data accumulate.

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USGS2003

Mercury data from small lakes in Voyageurs National Park, northern Minnesota, 2000-02

Mercury contamination of aquatic ecosystems is a resource concern in Voyageurs National Park. High concentrations of mercury in fish pose a potential risk to organisms that consume large amounts of those fish. During 2000–02, the U.S. Geological Survey measured mercury in water collected from 20 lakes in Voyageurs National Park. Those lakes span a gradient in fish-mercury concentrations, and also span gradients in other environmental variables that are thought to influence mercury cycling. During 2001, near surface methylmercury concentrations ranged from below the method detection limit of 0.04 nanograms per liter (ng/L) to 0.41 ng/L. Near surface total mercury concentrations ranged from 0.34 ng/L to 3.74 ng/L. Hypolimnetic methylmercury ranged from below detection to 2.69 ng/L, and hypolimnetic total mercury concentrations ranged from 0.34 ng/L to 7.16 ng/L. During 2002, near surface methylmercury concentrations ranged from below the method detection limit to 0.46 ng/L, and near surface total mercury ranged from 0.34 ng/L to 4.81 ng/L.

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USGS2003

Water resources data Minnesota water year 2002

Water resources data for the 2002 water year for Minnesota consist of records of stage, discharge, and water quality of streams; stage of lakes and reservoirs; ground-water quality; and water quality in wells. This report contains discharge records for 101 stream-gaging stations; stage for 11 lakes and reservoirs; water quality for 6 stream-gaging stations; peak flow data for 89 highflow partial-record stations, and water levels for 3 groundwater observation wells. Additional water data were collected at various sites that are not part of the systematic data collection program, and are published as miscellaneous measurements. These data represent that part of the National Water Data System operated by the U.S. Geological Survey for cooperating State and Federal agencies in Minnesota.

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USGS2003

Attenuation of runoff and chemical loads in grass filter strips at two cattle feedlots, Minnesota, 1995-98

Attenuation of cattle feedlot runoff in two grass-covered filter strips in Minnesota was estimated by measuring chemical loads into and out of the strips. Filter strips of the Bock and Sanborn sites were 60-m long and 20-m wide and received runoff from cattle feedlots that supported 35 and 225 cattle, respectively. Feedlot and filter-strip runoff were measured using flumes with stage sensors. Water samples were collected using automated samplers. Attenuation values were calculated from four storm-runoff events. Ground water sampled beneath and outside the filter strips indicated some infiltration losses of sulfate, chloride, and nitrogen at the Bock site where soil permeability was greater than at the Sanborn site. Chemical constituents in filter-strip runoff, and their corresponding ranges of attenuation were as follows: chemical oxygen demand, 30–81 percent; dissolved chloride, 6–79 percent; dissolved sulfate, -3–82 percent; dissolved ammonia nitrogen, 33–80 percent; suspended ammonia plus organic nitrogen, 29–85 percent; dissolved organic nitrogen, 14–75 percent; suspended phosphorus, 24–82 percent; dissolved phosphorus, 14–72 percent; and fecal coliform bacteria, 18–79 percent. The ranges seem to be affected by barriers of direct contact of the runoff water with the soil. This varies seasonally by coverage of the soil by ice in winter and vegetation in summer months. Greater attenuation values occurred in October and May when mats of wilted, flat-lying grass covered the filter strips; attenuation values were less during the summer when tall growing grass covered the filter strips.

Minnesota↗
USGS2002

Effects of topography on the transport of agricultural chemicals to groundwater in a sand-plain setting

Geochemical data were collected to investigate the effects of topography and focused recharge on the transport of agricultural chemicals to groundwater through sandy soils. The research was done at a topographically high (upland) site and a depressional (lowland) site within a corn field. Agricultural chemicals that move readily with water were most directly affected by focused recharge to the lowland site. Surface runoff of water to the lowland site was the primary cause for the generally greater flux of chloride, nitrate nitrogen, and sulfate compared with the upland site. Based on data from the unsaturated zone, for example, the average annual fluxes of these chemicals in 1992–1993 were 5.1, 3.4, and 1.7 times greater, respectively, at the lowland site. Study results indicate that consideration should be given to modifying site-specific management farming technology to account for varying recharge rates in different topographic settings. By reducing chemical application rates in topographic depressions, where focused recharge of chemicals occurs because of surface runoff, farmers could improve ground-water quality as well as reduce expenditures for agricultural chemicals.

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USGS2002

Early Holocene change in atmospheric circulation in the Northern Great Plains: An upstream view of the 8.2 ka cold event

Elk Lake, in northwestern Minnesota, contains numerous proxy records of climatic and environmental change contained in varved sediments with annual resolution for the last 10,000 years. These proxies show that about 8200 calendar years ago (8.2 cal. ka; 7300 radiocarbon years) Elk Lake went from a well-stratified lake that was wind-protected in a boreal forest to a well-mixed lake in open prairie savanna receiving northwesterly wind-blown dust, probably from the dry floor of Lake Agassiz. This change in climate marks the initiation of the widely recognized mid-Holocene “altithermal” in central North America. The coincidence of this change with the so-called 8.2 cal. ka cold event, recognized in ice-core and other records from the circum-North Atlantic, and thought by some to be caused by catastrophic discharge of freshwater from proglacial lakes Agassiz and Ojibway, suggests that the two “events” might be related. Our interpretation of the Elk Lake proxy records, and of other records from less accurately dated sites, suggests that change in climate over North America was the result of a fundamental change in atmospheric circulation in response to marked changes in the relative proportions of land, water, and, especially, glacial ice in North America during the early Holocene. This change in circulation probably post-dates the final drainage of proglacial lakes along the southern margin of the Laurentide ice sheet, and may have produced a minor perturbation in climate over Greenland that resulted in a brief cold pulse detected in ice cores.

Minnesota↗
USGS2002

Methylmercury in flood-control impoundments and natural waters of northwestern Minnesota, 1997-99

We studied methylmercury (MeHg) and total mercury (HgT) in impounded and natural surface waters in northwestern Minnesota, in settings ranging from agricultural to undeveloped. In a recently constructed (1995) permanent-pool impoundment, MeHg levels typically increased from inflow to outflow during 1997; this trend broke down from late 1998 to early 1999. MeHg levels in the outflow reached seasonal maxima in mid-summer (maximum of 1.0 ng L −1 in July 1997) and late-winter (maximum of 6.6 ng L −1 in February 1999), and are comparable to high levels observed in new hydroelectric reservoirs in Canada. Spring and autumn MeHg levels were typically about 0.1–0.2 ng L −1 . Overall, MeHg levels in both the inflow (a ditch that drains peatlands) and outflow were significantly higher than in three nearby reference natural lakes. Eleven older permanent-pool impoundments and six natural lakes in northwestern Minnesota were sampled five times. The impoundments typically had higher MeHg levels (0.071–8.36 ng L −1 ) than natural lakes. Five of six lakes MeHg levels typical of uncontaminated lakes (0.014–1.04 ng L −1 ) with highest levels in late winter, whereas a hypereutrophic lake had high levels (0.37–3.67 ng L −1 ) with highest levels in mid-summer. Seven temporary-pool impoundments were sampled during summer high-flow events. Temporary-pool impoundments that retained water for about 10–15 days after innundation yielded pronounced increases in MeHg from inflow to outflow, in one case reaching 4.6 ng L −1 , which was about 2 ng L −1 greater than the mean inflow concentration during the runoff event.

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