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Research about Massachusetts

Source-linked reports with geographic coverage including Massachusetts.

At least 541 records · Page 30Linked to original sources
USGS1992

Geohydrology and simulated ground-water flow, Plymouth-Carver aquifer, southeastern Massachusetts

The Plymouth-Carver aquifer underlies an area of 140 square miles and is the second largest aquifer in areal extent in Massachusetts. It is composed primarily of saturated glacial sand and gravel. The water-table and bedrock surface were mapped and used to determine saturated thickness of the aquifer, which ranged from less than 20 feet to greater than 200 feet. Ground water is present mainly under unconfined conditions, except in a few local areas such as beneath Plymouth Harbor. Recharge to the aquifer is derived almost entirely from precipitation and averages about 1.15 million gallons per day per square mile. Water discharges from the aquifer by pumping, evapotranspiration, direct evaporation from the water table, and seepage to streams, ponds, wetlands, bogs, and the ocean. In 1985, water use was about 59.6 million gallons per day, of which 82 percent was used for cranberry production. The Plymouth-Carver aquifer was simulated by a three-dimensional, finite difference ground-water-flow model. Most model boundaries represent the natural hydrologic boundaries of the aquifer. The model simulates aquifer recharge, withdrawals by pumped wells, leakage through streambeds, and discharge to the ocean. The model was calibrated for steady-state and transient conditions. Model results were compared with measured values of hydraulic head and ground-water discharge. Results of simulations indicate that the modeled ground-water system closely simulates actual aquifer conditions. Four hypothetical ground-water development alternatives were simulated to demonstrate the use of the model and to examine the effects on the ground-water system. Simulation of a 2-year period of no recharge and average pumping rates that occurred from 1980-85 resulted in water-level declines exceeding 5 feet throughout most of the aquifer and a decrease of 54 percent in average ground-water discharge to streams. In a second simulation, four wells in the northern part of the area were pumped at 10.4 million gallons per day in excess of rates simulated in the steady-state model for the four wells. This resulted in water-level declines of 2 feet or more in an area of 25 square miles and a decline in average ground-water discharge to streams of 6 percent. When this pumpage was simulated as recharge to the aquifer, water levels beneath the recharge area rose more than 40 feet, and ground-water discharge remained equal to average discharge in the calibrated steady-state model. In a third simulation, all 21 existing production wells were pumped at nearly the design capacity of 17.8 million gallons per day; this pumping rate produced water-level declines of less than 2 feet throughout most of the aquifer. When simulated pumpage was increased to 32.8 million gallons per day from existing wells and from 15 additional wells, the area where water-level declines exceeded 2 feet significantly increased. In another set of simulations, a well field close to a stream was pumped at rates of 2, 4, and 6 million gallons per day. At a pumping rate of 6 million gallons per day, ground-water discharge to the stream decreased 34 percent during periods of normal precipitation and 56 percent during drought conditions.

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USGS1992

Tide- and wind-driven flushing of Boston Harbor, Massachusetts

The flushing of Boston Harbor, a shallow, tidally dominated embayment with little fresh water input, is investigated using a depth-averaged model. The modeled tidal currents exhibit strong spatial variability and ebb/flood asymmetry due to complex topography and coastline geometry and were verified by shipboard acoustic Doppler current profiler measurements. At the inlets to the harbor, the asymmetry between flood and ebb gives rise to a net exchange of water, which acts over successive tidal cycles to flush the harbor. The flushing is examined by tracking water that starts out in Boston Harbor for 40 M2 tidal cycles. The tidal flushing is very efficient at mixing water in the vicinity of the inlets over several tidal cycles, but efficiency decreases with time as ``tidal mixing regions'' form on either side of the harbor inlets. When wind forcing is included, the wind-driven currents act to flush the tidal mixing regions, giving rise to more efficient flushing. The exception is when the wind is from the southwest, which confines the jet-like ebb flow from the harbor and therefore reduces the flushing efficiency. In general, flushing is shown to be a two-step process: (1) rapid exchange due to tides over a large region in the vicinity of the harbor inlets and (2) flushing of this region by wind-driven flow. The model also demonstrates that flushing is not uniform over the entire harbor but occurs rapidly in the deep tidal channels and slowly in the regions of weak tidal currents around the harbor periphery. Although the depth-averaged approach to flushing is appropriate over most of the harbor due to the harbor's shallow depth and broad depth distribution, the lack of bathymetric variability and the presence of locally important density driven currents in the Boston Inner Harbor indicates that flushing of this localized area must be approached with a three-dimensional model.

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USGS1991

Denitrification in nitrate-contaminated groundwater: Occurrence in steep vertical geochemical gradients

A relatively narrow vertical zone (5–6 m thick) of NO 3 − containing groundwater was identified using multilevel sampling devices in a sand and gravel aquifer on Cape Cod, MA, USA. The aquifer has been chronically contaminated by surface disposal of treated sewage 0.3 km upgradient from the study area. The NO 3 − zone was anoxic and contained high concentrations of N 2 O (16.5 μM), suggesting that it was a zone of active denitrification. Denitrifying activity was confirmed with direct measurement using acetylene block incubations with aquifer core material; the peak rate was 2.4 nmol N reduced (g sed) −1 day −1 . Concentrations of dissolved inorganic carbon and N 2 were close to atmospheric equilibrium in uncontaminated groundwater, but were more than 2 times higher within the contaminant plume. Excess CO 2 and N 2 suggested in situ formation with a stoichiometry of C and N mineralized via denitrification of 0.8 (C/N). Denitrification within the aquifer resulted in an increase in the natural δ 15 N of NO 3 − (from +13.6 to +42.0%.) and the N 2 produced, with an isotopic enrichment factor, ϵ, of −13.9%.. Vertical profiles of NH 4 + and δ 15 N of NH 4 + indicated that dissimilatory reduction of NO 3 − to NH 4 + was also occurring but mass balance calculations indicated that denitrification was the predominant process. These results demonstrate that a combination approach using field mass balance, stable isotope analysis, and laboratory incubations yields useful insight as to the significance of denitrification in aquifer sediments and that closely spaced vertical sampling is necessary to adequately quantify the processes controlling C and N transport and transformation within these environments.

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USGS1991

In situ measurement of methane oxidation in groundwater by using natural-gradient tracer tests

Methane oxidation was measured in an unconfined sand and gravel aquifer (Cape Cod, Mass.) by using in situ natural-gradient tracer tests at both a pristine, oxygenated site and an anoxic, sewage-contaminated site. The tracer sites were equipped with multilevel sampling devices to create target grids of sampling points; the injectate was prepared with groundwater from the tracer site to maintain the same geochemical conditions. Methane oxidation was calculated from breakthrough curves of methane relative to halide and inert gas (hexafluoroethane) tracers and was confirmed by the appearance of 13 C-enriched carbon dioxide in experiments in which 13 C-enriched methane was used as the tracer. A V max for methane oxidation could be calculated when the methane concentration was sufficiently high to result in zero-order kinetics throughout the entire transport interval. Methane breakthrough curves could be simulated by modifying a one-dimensional advection-dispersion transport model to include a Michaelis-Menten-based consumption term for methane oxidation. The K m values for methane oxidation that gave the best match for the breakthrough curve peaks were 6.0 and 9.0 μ M for the uncontaminated and contaminated sites, respectively. Natural-gradient tracer tests are a promising approach for assessing microbial processes and for testing in situ bioremediation potential in groundwater systems.

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USGS1991

Modern sedimentary environments in Boston Harbor, Massachusetts

Analyses of sidescan-sonar records supplemented by available bathymetric, sedimentary, subbottom, and bottom-current data reveal the distributions of the following three categories of sedimentary environments within the glaciated, topographically complex Boston Harbor estuary in Massachusetts. 1) Environments of erosion appear on the sonographs either as patterns with isolated strong reflections or as uniform patterns of strong reflectivity. These patterns define outcrops of bedrock or till and coarse lag deposits that are being scoured and winnowed by tidal- and wave-induced currents. Erosional areas are located primarily along mainland and insular shores, within large channels that have strong tidal currents, atop submerged ridges and knolls, and across much of the harbor entrance. 2) Environments of deposition are depicted on the sidescan-sonar records as smooth, featureless surfaces that have low to moderate reflectivity. Depositional environments are found predominantly over shallow subtidal flats and in broad bathymetric lows where tidal currents are weak. Sediments within depositional areas are organic-rich sandy and clayey silts that are accumulating at rates ranging from 0.01 to 0.11 g/cm 2 /yr or 4000 to 46,100 metric tons/yr. The cumulative mass of modern mud in harbor depocenters is 24.3 million metric tons. 3) Environments of sediment reworking constitute areas affected by a combination of erosional and depositional processes. They are characterized on the sonographs by mosaics of light and dark patches produced by relatively subtle and gradational changes in reflectivity. Reworked sediments have diverse grain sizes that overlap and are transitional between those of the other two sedimentary environments, and they are indicative of highly variable bottom currents.

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USGS1991

Summer oxygen depletion in a diked New England estuary

The diked and freshened Herring River estuary (Wellfleet, Massachusetts) experiences regular summer hypoxia and one- to three-week periods of main stream anoxia, often accompanied by fish kills. Stream hypoxia results from the temperature-dependent increase in oxygen demand of organic matter released by diked salt marsh deposits; periods of total anoxial are induced by heavy rains which increase the runoff of wetland organic matter. Historic reductions in tidal flushing have extended the low salinity region of the estuary normally characterized by high organic loads and minimal flushing. Recurrent main stream anoxia has depressed both migratory and resident aquatic fauna.

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USGS1990

Breeding biology of the spotted salamander Ambystoma maculatum (Shaw) in acidic temporary ponds at Cape Cod, USA

The relationship between water chemistry and breeding success of spotted salamanders Ambystoma maculatum (Shaw) was examined in temporary woodland ponds on outer Cape Cod, Massachusetts in 1985 and 1986. Most pond waters were dilute (3median coductivity = 57 umhos cm −1 (1 umhos cm −1 = 0·1 mSm −1 )), acidic (median pH = 4·82), and highly colored (median = 140 Pt-Co units). Most acidity was due to abundant organic acids. Salamander survival to hatching was over 80% at 8 of 12 ponds monitored. Complete mortality, preceded by gross abnormalities, was observed only among embryos in the most acidic spawning pond (pH 4·3−4·5) in both years. Embryo transfers between ponds and laboratory studies indicated that reduced survival was due to the interaction of low pH with high tannin-lignin concentration. The use of amphibian embryonic survival to indicate acid rain effects is complicated by multiple habitat parameters and should only be attempted in conjunction with long-term population monitoring.

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USGS1990

Intragranular diffusion: An important mechanism influencing solute transport in clastic aquifers?

Quantification of intragranular porosity in sand-size material from an aquifer on Cape Cod, Massachusetts, by scanning electron microscopy, mercury injection, and epifluorescence techniques shows that there are more reaction sites and that porosity is greater that indicated by standard short-term laboratory tests and measurement techniques. Results from laboratory and field tracer tests show solute nonequilibrium for a reacting ion consistent with a model of diffusion into, and exchange within, grain interiors. These data indicate that a diffusion expression needs to be included in transport codes, particularly for simulation of the transport of radioactive and toxic wastes.

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USGS1990

Soil-vegetation correlations in the Connecticut River floodplain of Western Massachusetts

As part of a national study analyzing the relation between hydric soils and wetland vegetation, the vegetation associated with a series of known soils was sampled along the Connecticut River floodplain in Massachusetts. Weighted average and index average (presence/absence) values were calculated for vegetation using wetland ecological index values from the National List of Plant Species that Occur in Wetlands developed by the U.S. Fish and Wildlife Service and procedures developed by T. R. Wentworth and G. P. Johnson at North Carolina State University. Good correspondence between soils and vegetation was recorded with two exceptions. Two typically nonhydric soils were determined to be hydric based on vegetation analyses. Examination of the groundwater hydrology of these two soils confirmed their hydric nature. The authors suggested that one of these soils may need to be redefined and they also suggested that the assigned index values for a few species of vegetation should be reexamined. However, in general the index average values of vegetation based on published wetland index values corresponded with the hydric and nonhydric nature of soils.

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USGS1989

Impacts of exploratory drilling for oil and gas on the benthic environment of Georges Bank

A 3-year monitoring program was performed to assess the impacts of exploratory drilling for oil and gas on the benthic environment of Georges Bank, an important commercial fishery region in the North Atlantic east of Massachusetts, USA. Surficial sediments were sampled for chemical and benthic infaunal analysis and bottom still photographs were taken to document bottom microtopography and epifauna at 46 stations during 12 field surveys. The surveys were performed quarterly from just before drilling began, during drilling, and for nearly 2 years after completion of drilling. Two of the eight drilling sites were selected for monitoring. Twenty-nine stations were positioned in a tight radial array around a drilling site in 80 m of water. A second group of three stations was positioned near another drilling site in 140 m of water. The remaining stations covered a broad expanse of the Bank and adjacent suspected sites of deposition of fine-grained sediments.\ Of the 12 elements analyzed in bulk sediments, only barium increased in concentration during the period when drilling was taking place (July 1981 to September 1982). The concentration of barium in surficial sediment increased 4·7-fold from 28 ppm before drilling to 131·7 ppm after drilling at the station closest to the drilling site in 80 m of water and 5·9-fold from 32 ppm before drilling to 172 ppm after drilling at the station closest to the drilling site in 140 m of water. The concentrations of both barium and chromium increased in the fine (silt/clay) fraction (usually less than 5% by weight of sediment from most stations) of sediments from several stations around one or both rig sites monitored during the period of drilling. Elevated concentrations of chromium (about two-fold) occurred only in sediments near the drilling site in 140 m of water. Statistically significant increases in the concentration of barium in the fine fraction to sediment were detected approximately 65 km west (downcurrent) and 35 km east of the drilling site in 80 m of water after drilling was completed. The benthic fauna were abundant and diverse throughout the study area. At most stations, the dominant species remained nearly the same from one season to another over the 3 years of sampling. Polychaetes were the most abundant, followed by crustaceans. The number of individuals of some species, particularly the amphipods Erichthonius fasciatus and Unciola inermis , showed large seasonal variations. Cluster analysis revealed a strong relationship between community structure and both sediment type and water depth. Little seasonal variation was detected, but some interannual differences were revealed by cluster analysis and correspondence analysis. The replicates from a station always resembled each other more than they resembled any replicates from other stations. In addition, the combined replicates from a station always clustered with samples from that station taken on other cruises. This excellent replication and uniformity of the benthic infaunal community at a station over time made it possible to detect very subtle changes in community parameters that might be related to discharges of drilling fluid and drill cuttings. Nevertheless, no changes were detected in benthic communities of Georges Bank that could be attributed to drilling activities.

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USGS1988

Denitrification in a sand and gravel aquifer

Denitrification was assayed by the acetylene blockage technique in slurried core material obtained from a freshwater sand and gravel aquifer. The aquifer, which has been contaminated with treated sewage for more than 50 years, had a contaminant plume greater than 3.5-km long. Near the contaminant source, groundwater nitrate concentrations were greater than 1 mM, whereas 0.25 km downgradient the central portion of the contaminant plume was anoxic and contained no detectable nitrate. Samples were obtained along the longitudinal axis of the plume (0 to 0.25 km) at several depths from four sites. Denitrification was evident at in situ nitrate concentrations at all sites tested; rates ranged from 2.3 to 260 pmol of N 2 O produced (g of wet sediment) −1 h −1 . Rates were highest nearest the contaminant source and decreased with increasing distance downgradient. Denitrification was the predominant nitrate-reducing activity; no evidence was found for nitrate reduction to ammonium at any site. Denitrifying activity was carbon limited and not nitrate limited, except when the ambient nitrate level was less than the detection limit, in which case, even when amended with high concentrations of glucose and nitrate, the capacity to denitrify on a short-term basis was lacking. These results demonstrate that denitrification can occur in groundwater systems and, thereby, serve as a mechanism for nitrate removal from groundwater.

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