Geology topics
Research about Massachusetts
Source-linked reports with geographic coverage including Massachusetts.
Sea floor topography of quadrangle 1 in the Stellwagen Bank National Marine Sanctuary off Boston, Massachusetts
No abstract available.
Particle-tracking analysis of contributing areas of public-supply wells in simple and complex flow systems, Cape Cod, Massachusetts
Steady-state, two- and three-dimensional, ground-water-flow models coupled with particle tracking were evaluated to determine their effectiveness in delineating contributing areas of wells pumping from stratified-drift aquifers of Cape Cod, Massachusetts. Several contributing areas delineated by use of the three-dimensional models do not conform to simple ellipsoidal shapes that are typically delineated by use of two-dimensional analytical and numerical modeling techniques and included discontinuous areas of the water table.
Open-ocean boundary conditions from interior data: Local and remote forcing of Massachusetts Bay
Massachusetts and Cape Cod Bays form a semienclosed coastal basin that opens onto the much larger Gulf of Maine. Subtidal circulation in the bay is driven by local winds and remotely driven flows from the gulf. The local-wind forced flow is estimated with a regional shallow water model driven by wind measurements. The model uses a gravity wave radiation condition along the open-ocean boundary. Results compare reasonably well with observed currents near the coast. In some offshore regions, however, modeled flows are an order of magnitude less energetic than the data. Strong flows are observed even during periods of weak local wind forcing. Poor model-data comparisons are attributable, at least in part, to open-ocean boundary conditions that neglect the effects of remote forcing. Velocity measurements from within Massachusetts Bay are used to estimate the remotely forced component of the flow. The data are combined with shallow water dynamics in an inverse-model formulation that follows the theory of Bennett and McIntosh [1982], who considered tides. We extend their analysis to consider the subtidal response to transient forcing. The inverse model adjusts the a priori open-ocean boundary condition, thereby minimizing a combined measure of model-data misfit and boundary condition adjustment. A “consistency criterion” determines the optimal trade-off between the two. The criterion is based on a measure of plausibility for the inverse solution. The “consistent” inverse solution reproduces 56% of the average squared variation in the data. The local-wind-driven flow alone accounts for half of the model skill. The other half is attributable to remotely forced flows from the Gulf of Maine. The unexplained 44% comes from measurement errors and model errors that are not accounted for in the analysis.
Characterization of metal adsorption variability in a sand and gravel aquifer, Cape Cod, Massachusetts, U.S.A
Several geochemical properties of an aquifer sediment that control metal-ion adsorption were investigated to determine their potential use as indicators of the spatial variability of metal adsorption. Over the length of a 4.5-m-long core from a sand and gravel aquifer, lead (Pb2+) and zinc (Zn2+) adsorption at constant chemical conditions (pH 5.3) varied by a factor of 2 and 4, respectively. Pb2+ and Zn2+ were adsorbed primarily by Fe- and Al-oxide coatings on quartz-grain surfaces. Per unit surface area, both Pb2+ and Zn2+ adsorption were significantly correlated with the amount of Fe and Al that dissolved from the aquifer material in a partial chemical extraction. The variability in conditional binding constants for Pb2+ and Zn2+ adsorption (log KADS) derived from a simple non-electrostatic surface complexation model were also predicted by extracted Fe and Al normalized to surface area. Because the abundance of Fe- and Al-oxide coatings that dominate adsorption does not vary inversely with grain size by a simple linear relationship, only a weak, negative correlation was found between the spatial variability of Pb2+ adsorption and grain size in this aquifer. The correlation between Zn2+ adsorption and grain size was not significant. Partial chemical extractions combined with surface-area measurements have potential use for estimating metal adsorption variability in other sand and gravel aquifers of negligible carbonate and organic carbon content.
Spawning of the shortnose sturgeon the Merrimack River, Massachusetts
We tracked 10 ultrasonically tagged shortnose sturgeons Acipenser brevirostrurn during spring in the Merrimack River to investigate spawning. Seven fish in 1989 and six fish in 1990 were tracked intensively to identify the timing and location of spawning and to characterize spawning habitat. In mid‐April 1989 and 1990, fish moved upstream to just below head of tide, concentrating in a 2‐km reach at river kilometers 30–32 (measured from the mouth) at Haverhill, Massachusetts. The estimated spawning time was a 5‐d period (26–30 April) in 1989 and an 8‐d period (22–29 April) in 1990. Spawning sites covered about 10.5 ha in 1989 and 13.5 ha in 1990. Fish spawned as river temperature increased from 9.6 to 14.0°C and river discharge decreased from 390 to 240 m 3 /s. Physical characteristics of spawning sites were boulder–rubble substrate, water depth of 1.8–5.5 m, and bottom water velocity of 0.3–0.7 m/s. We captured no ovulating females but verified successful spawning in 1990 by capturing two live embryos. Gill‐net captures and telemetry during spring showed that some males moved to the spawning area annually. The low abundance estimates of spawning fish (9 in 1989 and 16 in 1990) indicate that the shortnose sturgeon population in the Merrimack River is the smallest yet identified and is likely vulnerable to extirpation.
Effectiveness of highway-drainage systems in preventing road-salt contamination of ground water, southeastern Massachusetts
Road-salt contamination of public and private water supplies has become a serious and costly problem, particularly in the Northeast and Midwest. For example, reports of road-salt contamination from 100 of the 351 municipalities in Massachusetts from 1983 through 1990 required an expenditure of about 2.5 million dollar to investigate and remediate. Nationally, an estimated 10 million dollar are spent annual ly by State and local governments to prevent and remediate road-salt contamination. One method used by State highway agencies to reduce road- salt contamination of public-water supplies is to divert the salt-laden highway runoff through drainage systems from section of highway that pass near public-water supplies to less sensitive areas. The U.S. Geological Survey (USGS), in cooperation with the Massachusetts Highway Department (MHO), has conducted an investigation of the relative effectiveness of four highway-drainage systems in preventing road-salt contamination of ground water. This fact sheet describes the highway-drainage systems tested, the general hydrogeology of the study area, and the methods used to evaluate the drainage systems; and presents preliminary findings of the effectiveness of the systems in preventing road-salt contamination of ground water. These findings are based on data collected from November 1990 through May 1992. The re ult of this investigation will have wider application than just in the snow-belt regions of the United States, Canada, and Europe, as other contaminants in highway runoff either can be diverted from sensitive areas by drainage systems or allowed to seep into the ground, potentially contaminating ground water.
Geohydrology and potential water-supply development on Bumkin, Gallops, Georges, Grape, Lovell, and Peddocks Islands, eastern Massachusetts
An investigation of the geohydrology and of the potential for water-supply development on several of the Boston Harbor Islands, eastern Massachusetts, was conducted to evaluate the possibility of developing a permanent small-capacity water supply to support recreational activities, such as camping, hiking, and swimming. The Boston Harbor Islands, including Bumkin, Gallops, Georges, Grape, Lovell, and Peddocks Islands are part of a larger group of glacially deposited drumlins, which are composed of thick, dense, homogeneous till in their core that are overlain by a thin layer of stratified-beach deposits. The surficial materials over-lie a weathered zone of the metasedimentary Cambridge Argillite in the Boston Harbor area and were deposited by continental ice sheets that covered New England twice during the late Pleistocene Epoch, and by near-shore processes in the Holocene Epoch. The thickness of these materials range from less than 1 to about 300 feet where present. The till was deposited by glacial ice and is characterized as an unsorted matrix of sand, silt, and clay with variable amounts of stones and large boulders. The stratified deposits primarily consist of sorted and layered sand and gravel that accumulated and formed the beaches and tombolos of the harbor islands. These deposits overlie the till at altitudes generally less than 10 feet above sea level. A cross-sectional, ground-water-flow model was developed to estimate depth to the water table for a hypothetical drumlin-island flow system, which was assumed to be representative of the drumlin islands in Boston Harbor. Areas were identified in each island flow system with the greatest potential for small-capacity water-supply development based on the model-calculated depth to water and surficial geology of the islands. Model-calculated depth to water estimates were used because of the lack of available hydrologic data for the islands. Model results indicate that the simulated depth to water is less than 20 feet within 240 feet from the shore of the hypothetical drumlin-island flow system. This area on the topographic maps of the six Boston Harbor Islands roughly coincides with the high transmissivity zones of stratified-beach deposits and weathered till on the lower slopes of the drumlins where ground-water discharge and surface and subsurface runoff occurs.
Use of particle tracking to improve numerical model calibration and to analyze ground-water flow and contaminant migration, Massachusetts Military Reservation, western Cape Cod, Massachusetts
A steady-state, three-dimensional numerical model coupled with a particle-tracking algorithm was developed to simulate the complex hydrogeologic conditions affecting ground-water flow and contaminant migration in the Cape Cod aquifer beneath the Massachusetts Military Reservation, Massachusetts. The known extents of the contaminant plumes beneath the reservation were incorporated into a particle-tracking analysis to improve model calibration. Particle tracking was used to evaluate the effects of simulated changes in hydraulic properties and in simulated hydrologic boundaries such as ponds and streams. The model simulations made during the calibration process indicated that changes in simulated hydraulic properties and hydrologic boundaries resulted in small changes in the water-table and pond altitudes and in streamflows, yet had a substantial effect on model-calculated groundwater flowpaths. Therefore, the characterization of contaminant migration using a model calibrated only on the basis of ground-water heads and flux may be inaccurate. The results of model simulations for the analysis of the effects of pumping and recharge on ground-water flow and contaminant migration indicated that ground-water flowpaths were greatly affected by subtle shifts in hydraulic gradients. These changes in the ground-water-flow system in response to hydrologic stresses such as pumping and recharge can be determined by the use of a particle-tracking analysis.
Spatial and temporal distribution of specific conductance, boron, and phosphorus in a sewage-contaminated aquifer near Ashumet Pond, Cape Cod, Massachusetts
Spatial and temporal distributions of specific conductance, boron, and phosphorus were determined in a sewage-contaminated sand and gravel aquifer near Ashumet Pond, Cape Cod, Massachusetts. The source of contamination is secondarily treated sewage that has been discharged onto rapid- infiltration sand beds at the Massachusetts Military Reservation since 1936. Contaminated ground water containing as much as 2 milligrams per liter of dissolved phosphorus is discharging into Ashumet Pond, and there is concern that the continued discharge of phosphorus into the pond will accelerate eutrophication of the pond. Water-quality data collected from observation wells and multilevel samplers from June through July 1995 were used to delineate the spatial distributions of specific conductance, boron, and phosphorus. Temporal distributions were determined using sample-interval-weighted average concen- trations calculated from data collected in 1993, 1994, and 1995. Specific conductances were greater than 400 microsiemens per centimeter at 25C as far as 1,200 feet downgradient from the infiltration beds. Boron concentrations were greater than 400 micrograms per liter as far as 1,800 feet down- gradient from the beds and phosphorus concen- trations were greater than 3.0 milligrams per liter as far as 1,200 feet from the beds. Variability in distributions of specific conductance and boron concentrations is attributed to the history and distribution of sewage disposal onto the infiltration beds. The distribution of phosphorus concentrations also is related to the history and distribution of sewage disposal onto the beds but additional variability is caused by chemical interactions with the aquifer materials. Temporal changes in specific conductance and boron from 1993 to 1995 were negligible, except in the lower part of the plume (below an altitude of about 5 feet above sea level), where changes in weighted-average specific conductance were greater than 100 microsiemens per centimeter at 25C. Temporal changes in phosphorus generally were small except in the lower part of the plume, where weighted-average phosphorus concentrations decreased more than 1.3 milligrams per liter from 1993 to 1994. This decrease was accompanied by an increase in specific conductance. High concen- trations of phosphorus associated with low and moderate specific conductances possibly are the result of rapid phosphorus desorption in response to an influx of uncontaminated ground water. As a result of the cessation of sewage disposal in December 1995, clean, oxygenated water moving into contaminated parts of the aquifer may cause rapid desorption of sorbed phosphorus and temporarily result in high dissolved phosphorus concentrations in the aquifer.
Hydrogeology and analysis of ground-water-flow system, Sagamore Marsh area, southeastern Massachusetts
A study of the hydrogeology and an analysis of the ground-water-flow system near Sagamore Marsh, southeastern Massachusetts, was undertaken to improve the understanding of the current (1994 95) hydrogeologic conditions near the marsh and how the ground-water system might respond to proposed changes in the tidal-stage regime of streams that flood and drain the marsh. Sagamore Marsh is in a coastal area that is bounded to the east by Cape Cod Bay and to the south by the Cape Cod Canal. The regional geology is characterized by deltaic and glaciolacustrine sediments. The sediments consist of gravel, sand, silt, and clay and are part of the Plymouth-Carver regional aquifer system. The glacial sediments are hounded laterally by marine sand, silt, and clay along the coast. The principal aquifer in the area consists of fine to coarse glacial sand and is locally confined by fine-grained glaciolacustrine deposits consisting of silt and sandy clay and fine-grained salt-marsh sediments consisting of peat and clay. The aquifer is underlain by finer grained glaciolacustrine sediments in upland areas and by marine clay along the coast. Shallow ground water discharges primarily along the edge of the marsh, whereas deeper ground water flows beneath the marsh and discharges to Cape Cod Bay. Tidal pulses originating from Cape Cod Bay and from tidal channels in the marsh are rapidly attenuated in the subsurface. Tidal ranges in Cape Cod Bay and in the tidal channels were on the order of 9 and 1.5 feet, respectively, whereas tidal ranges in the ground-water levels were less than 0.2 foot. Tidal pulses measured in the water table beneath a barrier beach between the marsh and Cape Cod Bay were more in phase with tidal pulses from Cape Cod Bay than with tidal pulses from the tidal channels in Sagamore Marsh, whereas tidal pulses in the regional aquifer were more in phase with tidal pulses from the tidal channels. A 5-day aquifer test at a public-supply well adjacent to the marsh gave a transmissivity of the regional aquifer of 9,300 to 10,900 feet squared per day and a hydraulic conductivity of 181 to 213 feet per day, assuming a saturated thickness of the aquifer of 51.3 feet. The regional aquifer became unconfined near the pumped well during the test. The ratio of tidal ranges in the tidal channel to the ranges in the underlying aquifer at two sites (the lower and upper marsh) indicated aquifer diffusivities for the marsh sediments of 380 and 170 feet squared per day; these values correspond to hydraulic conductivities of 2.5 x 10 -3 and 1.7 x 10 -3 feet per day, respectively. The maximum distances from the tidal channel at the lower and upper marsh sites where tidal ranges would exceed 0.01 foot, as calculated from aquifer diffusivities and current (1995) tidal ranges in the tidal channels, were 24.4 and 26.7 feet, respectively. The maximum distances from the tidal channel where tidal pulses in the ground water would exceed 0.01 foot, using potential increased tidal stages resulting from proposed tidal-stage modifications and predicted by the U.S. Army Corps of Engineers, were 37.1 and 42.0 feet, respectively. A numerical model of the marsh and surrounding aquifer system indicated that the contributing area for the supply well adjacent to the marsh, for current (1994) pumping conditions, extends toward Great Herring Pond, about 2 miles northwest (upgradient) of the well, and does not extend beneath the marsh. The model also indicates that the predicted increases in tidal stages in the marsh will have a negligible effect on local ground-water levels.
Geochemical and hydrologic controls on phosphorus transport in a sewage-contaminated sand and gravel aquifer near Ashumet Pond, Cape Cod, Massachusetts
Currently (1993), about 170 kg/yr of phosphorus discharges into Ashumet Pond on Cape Cod from a plume of sewage-contaminated ground water. Phosphorus in the plume is mobile in two distinct geochemical environments--an anoxic zone containing dissolved iron and a suboxic zone containing dissolved oxygen. Phosphorus mobility in the suboxic zone is due to saturation of available sorption sites. Phosphorus loading to Ashumet Pond may increase significantly after sewage disposal is stopped due to phosphorus desorption from sediment surfaces.
Comparison of the in situ and desorption sediment-water partitioning of polycyclic aromatic hydrocarbons and polychlorinated biphenyls
In situ sediment−porewater partitioning of polycyclic aromatic hydrocarbons (PAHs) measured in three cores from Boston Harbor, MA, has led us to suggest that only a fraction of the total measured sediment PAH concentration is a vailable for e quilibrium p artitioning (AEP fraction). To test this, aqueous PAH concentrations were measured in laboratory desorption experiments using subsamples of the same Boston Harbor sediments. The observed concentrations were consistent with what we predicted from the field-derived AEP values: C aqueous = ( C sediment × AEP)/( f oc × K oc ) where f oc is the fraction organic carbon in the sediment and K oc is the organic carbon normalized sediment−water partition coefficient. Equilibrium partitioning models based on the total measured sediment PAH concentrations overestimated the measured aqueous PAH concentrations by as much as 100 times in some cases. Only a small fraction of the sediment phenanthrene and pyrene concentrations (1−40%) appeared to be available for equilibrium partitioning. Both in situ and laboratory desorption aqueous polychlorinated biphenyl (PCB) concentrations were consistent with equilibrium partitioning models and the assumption that 100% of these compounds was available for equilibrium partitioning. These results are particularly important to efforts to predict the environmental mobility and bioavailability of the PAHs.
Transport behavior of groundwater protozoa and protozoan-sized microspheres in sandy aquifer sediments
Transport behaviors of unidentified flagellated protozoa (flagellates) and flagellate-sized carboxylated microspheres in sandy, organically contaminated aquifer sediments were investigated in a small-scale (1 to 4-m travel distance) natural-gradient tracer test on Cape Cod and in flow-through columns packed with sieved (0.5-to 1.0-mm grain size) aquifer sediments. The minute (average in situ cell size, 2 to 3 μ m) flagellates, which are relatively abundant in the Cape Cod aquifer, were isolated from core samples, grown in a grass extract medium, labeled with hydroethidine (a vital eukaryotic stain), and coinjected into aquifer sediments along with bromide, a conservative tracer. The 2- μ m flagellates appeared to be near the optimal size for transport, judging from flowthrough column experiments involving a polydispersed (0.7 to 6.2 μ m in diameter) suspension of carboxylated microspheres. However, immobilization within the aquifer sediments accounted for a log unit reduction over the first meter of travel compared with a log unit reduction over the first 10 m of travel for indigenous, free-living groundwater bacteria in earlier tests. High rates of flagellate immobilization in the presence of aquifer sediments also was observed in the laboratory. However, immobilization rates for the laboratory-grown flagellates (initially 4 to 5 μ m) injected into the aquifer were not constant and decreased noticeably with increasing time and distance of travel. The decrease in propensity for grain surfaces was accompanied by a decrease in cell size, as the flagellates presumably readapted to aquifer conditions. Retardation and apparent dispersion were generally at least twofold greater than those observed earlier for indigenous groundwater bacteria but were much closer to those observed for highly surface active carboxylated latex microspheres. Field and laboratory results suggest that 2- μ m carboxylated microspheres may be useful as analogs in investigating several abiotic aspects of flagellate transport behavior in groundwater.
Composition, abundance, biomass, and production of macrofauna in a New England estuary: Comparisons among eelgrass meadows and other nursery habitats
Quantitative suction sampling was used to characterize and compare the species composition, abundance, biomass, and secondary production of macrofauna inhabiting intertidal mud-flat and sand-flat, eelgrass meadow, and salt-marsh-pool habitats in the Nauset Marsh complex, Cape Cod, Massachusetts (USA). Species richness and abundance were often greatest in eelgrass habitat, as was macroinvertebrate biomass and production. Most striking was the five to fifteen times greater rate of annual macrofaunal production in eelgrass habitat than elsewhere, with values ranging from approximately 23–139 g AFDW m 2 yr −1 . The marsh pool containing widgeon grass ( Ruppia maritima ) supported surprisingly low numbers of macroinvertebrates, probably due to stressfully low dissolved oxygen levels at night during the summer. Two species of macroinvertebrates, blue mussels ( Mytilus edulis ) and to a lesser extent bay scallops ( Argopecten irradians ), used eelgrass as “nursery habitat.” Calculations showed that macroinvertebrate production is proportionally much greater than the amount of primary production attributable to eelgrass in the Nauset Marsh system, and that dramatic changes at all trophic levels could be expected if large changes in seagrass abundance should occur. This work further underscores the extraordinarily large impact that seagrass can have on both the structure and function of estuarine ecosystems.