USGS Science⌕ Search

Geology topics

Research about Massachusetts

Source-linked reports with geographic coverage including Massachusetts.

At least 325 records · Page 18Linked to original sources

Feeding ecology of long-tailed ducks Clangula hyemalis wintering on the Nantucket Shoals

A substantial proportion, perhaps 30%, of the North American breeding population of Long-tailed Ducks ( Clangula hyemalis ) winter in the vicinity of Nantucket Island, Massachusetts. These birds spend the night on Nantucket Sound and commute during daylight hours to the Nantucket Shoals, which extend about 65 km offshore from the southeastern corner of Nantucket. Strip transects done from a single-engine plane in 1997 and 1998 indicated that Long-tailed Ducks foraged over the shallower (≤ 20 m depth) portions of the Nantucket Shoals, up to 70 km offshore. Diet analyses of ten birds collected in February 1999 and five in December 2006 showed that they fed principally (106.6 /- 42.0 individuals per crop) on Gammarus annulatus , a pelagic amphipod that often forms large aggregations, and is consumed by several species of fish and marine mammals. Our findings emphasize the importance of conservation of the Nantucket Shoals and the prevention of oil spills or other potentially harmful accidents.

Massachusetts↗

Large-scale natural gradient tracer test in sand and gravel, Cape Cod, Massachusetts: 1. Experimental design and observed tracer movement

A large-scale natural gradient tracer experiment was conducted on Cape Cod, Massachusetts, to examine the transport and dispersion of solutes in a sand and gravel aquifer. The nonreactive tracer, bromide, and the reactive tracers, lithium and molybdate, were injected as a pulse in July 1985 and monitored in three dimensions as they moved as far as 280 m down-gradient through an array of multilevel samplers. The bromide cloud moved horizontally at a rate of 0.42 m per day. It also moved downward about 4 m because of density-induced sinking early in the test and accretion of areal recharge from precipitation. After 200 m of transport, the bromide cloud had spread more than 80 m in the direction of flow, but was only 14 m wide and 4–6 m thick. The lithium and molybdate clouds followed the same path as the bromide cloud, but their rates of movement were retarded about 50% relative to bromide movement because of sorption onto the sediments.

Massachusetts↗

Large-scale natural gradient tracer test in sand and gravel, Cape Cod, Massachusetts: 2. Analysis of spatial moments for a nonreactive tracer

A large-scale natural gradient tracer test was conducted to examine the transport of reactive and nonreactive tracers in a sand and gravel aquifer on Cape Cod, Massachusetts. As part of this test the transport of bromide, a nonreactive tracer, was monitored for about 280 m and quantified using spatial moments. The calculated mass of bromide for each sampling date varied between 85% and 105% of the injected mass using an estimated porosity of 0.39, and the center of mass moved at a nearly constant horizontal velocity of 0.42 m per day. A nonlinear change in the bromide longitudinal variance was observed during the first 26 m of travel distance, but afterward the variance followed a linear trend, indicating the longitudinal dispersivity had reached a constant value of 0.96 m. The transverse dispersivities were much smaller; transverse horizontal dispersivity was 1.8 cm, and transverse vertical dispersivity was about 1.5 mm.

Massachusetts↗

Storm-driven sediment transport in Massachusetts Bay

Massachusetts Bay is a semi-enclosed embayment in the western Gulf of Maine about 50 km wide and 100 km long. Bottom sediment resuspension is controlled predominately by storm-induced surface waves and transport by the tidal- and wind-driven circulation. Because the Bay is open to the northeast, winds from the northeast ('Northeasters') generate the largest surface waves and are thus the most effective in resuspending sediments. The three-dimensional oceanographic circulation model Regional Ocean Modeling System (ROMS) is used to explore the resuspension, transport, and deposition of sediment caused by Northeasters. The model transports multiple sediment classes and tracks the evolution of a multilevel sediment bed. The surficial sediment characteristics of the bed are coupled to one of several bottom-boundary layer modules that calculate enhanced bottom roughness due to wave-current interaction. The wave field is calculated from the model Simulating WAves Nearshore (SWAN). Two idealized simulations were carried out to explore the effects of Northeasters on the transport and fate of sediments. In one simulation, an initially spatially uniform bed of mixed sediments exposed to a series of Northeasters evolved to a pattern similar to the existing surficial sediment distribution. A second set of simulations explored sediment-transport pathways caused by storms with winds from the northeast quadrant by simulating release of sediment at selected locations. Storms with winds from the north cause transport southward along the western shore of Massachusetts Bay, while storms with winds from the east and southeast drive northerly nearshore flow. The simulations show that Northeasters can effectively transport sediments from Boston Harbor and the area offshore of the harbor to the southeast into Cape Cod Bay and offshore into Stellwagen Basin. This transport pattern is consistent with Boston Harbor as the source of silver found in the surficial sediments of Cape Cod Bay and Stellwagen Basin.

Massachusetts↗

Time-series photographs of the sea floor in western Massachusetts Bay, version 2, 1989 - 1996

Time-series photographs of the sea floor were obtained from an instrumented tripod deployed in western Massachusetts Bay at LT-A (42° 22.6' N, 70° 47.0' W; nominal water depth of 32 m; fig. 1) from December 1989 through September 2005. The photographs provide time-series observations of physical changes of the sea floor, near-bottom water turbidity, and life on the sea floor. Several reports present these photographs in digital form (table 1). This report, U.S. Geological Survey Data Series 265, Version 2.0, contains the photographs obtained from December 1989 to October 1996, adding to (and replacing) Version 1 of Data Series 265 (Butman and others, 2007a) that contained photographs from 1989 through 1993. Data Series 266 (Butman and others, 2008b) contains photographs obtained from October 1996 through September 2005. The photographs are published in separate reports because the data files are too large for distribution on a single DVD. These reports present the photographs, originally collected on 35-mm film, in digital form to enable easy viewing and to provide a medium-resolution digital archive. The photographs, obtained every 4 or every 6 hours, are presented as individual photographs (in .png format) and as a movie (in .avi format). The time-series photographs taken at LT-A were collected as part of a U.S. Geological Survey (USGS) study to understand the transport and fate of sediments and associated contaminants in Massachusetts Bay and Cape Cod Bay (Bothner and Butman, 2007). This long-term study was carried out by the USGS in partnership with the Massachusetts Water Resources Authority (MWRA) (https://www.mwra.state.ma.us/) and with logistical support from the U.S. Coast Guard (USCG). Long-term oceanographic observations help to identify the processes causing bottom sediment resuspension and transport and provide data for developing and testing numerical models. The observations document seasonal and interannual changes in currents, hydrography, suspended-matter concentration, and the importance of infrequent catastrophic events, such as major storms, in sediment resuspension and transport. LT-A is approximately 1 km south of the ocean outfall that began discharging treated sewage effluent from the Boston metropolitan area into Massachusetts Bay in September 2000. See Butman and others (2004d) for a description of the oceanographic measurements at LT-A, and Butman and others (2007c) and Warner and others (2008) for discussion of sediment transport in Massachusetts Bay.

Massachusetts↗

Sea-floor character and sedimentary processes in the vicinity of Woods Hole, Massachusetts

Continuous-coverage multibeam bathymetric models and sidescan-sonar imagery have been verified with high-resolution seismic-reflection profiles, sediment sampling, and bottom photography. Together these data layers provide detailed base maps that yield topographic, compositional, and environmental perspectives of the sea floor in the vicinity of Woods Hole, an important harbor and major passage between the Elizabeth Islands and Cape Cod, Massachusetts. Tidally dominated high-energy environments within Woods Hole have prevented deposition of Holocene marine sediments, exposed underlying glacial drift of the Buzzards Bay moraine, and winnowed finer grained sediments, leaving lag deposits of boulders and gravel. These conditions have also enlarged and preserved depressions in the moraine surface that were originally kettle holes and formed ebb-tidal deltas at the entrances to passages. Fields of transverse and barchanoid sand waves dominate across the southern part of the study area in Vineyard Sound, where benthic environments are characterized by processes associated with coarse-bedload transport. Transverse sand waves dominate near shoals where sediment supply is greater and have asymmetries that indicate that the shoals are shaped and maintained by clockwise gyres of net sediment transport. Barchanoid sand waves, which are most common where Holocene sediments are thinner, commonly align into elongate fields that have smaller isolated waves concentrated at the eastern ends and that progressively widen and have waveforms that increase in amplitude, wavelength, and complexity westward. The northern, protected parts of the Little and Inner Harbors are characterized by muddy sediment and processes associated with deposition. A pockmark field in Little Harbor and the muddy, organic-rich sediments that form a scarp along the edge of Parker Flat are evidence for the presence of submerged marsh deposits formed during the Holocene rise in sea level.

Massachusetts↗

Use of inverse-modeling methods to improve ground-water-model calibration and evaluate model-prediction uncertainty, Camp Edwards, Cape Cod, Massachusetts

Historical weapons testing and disposal activities at Camp Edwards, which is located on the Massachusetts Military Reservation, western Cape Cod, have resulted in the release of contaminants into an underlying sand and gravel aquifer that is the sole source of potable water to surrounding communities. Ground-water models have been used at the site to simulate advective transport in the aquifer in support of field investigations. Reasonable models developed by different groups and calibrated by trial and error often yield different predictions of advective transport, and the predictions lack quantitative measures of uncertainty. A recently (2004) developed regional model of western Cape Cod, modified to include the sensitivity and parameter-estimation capabilities of MODFLOW-2000, was used in this report to evaluate the utility of inverse (statistical) methods to (1) improve model calibration and (2) assess model-prediction uncertainty. Simulated heads and flows were most sensitive to recharge and to the horizontal hydraulic conductivity of the Buzzards Bay and Sandwich Moraines and the Buzzards Bay and northern parts of the Mashpee outwash plains. Conversely, simulated heads and flows were much less sensitive to vertical hydraulic conductivity. Parameter estimation (inverse calibration) improved the match to observed heads and flows; the absolute mean residual for heads improved by 0.32 feet and the absolute mean residual for streamflows improved by about 0.2 cubic feet per second. Advective-transport predictions in Camp Edwards generally were most sensitive to the parameters with the highest precision (lowest coefficients of variation), indicating that the numerical model is adequate for evaluating prediction uncertainties in and around Camp Edwards. The incorporation of an advective-transport observation, representing the leading edge of a contaminant plume that had been difficult to match by using trial-and-error calibration, improved the match between an observed and simulated plume path; however, a modified representation of local geology was needed to simultaneously maintain a reasonable calibration to heads and flows and to the plume path. Advective-transport uncertainties were expressed as about 68-, 95-, and 99-percent confidence intervals on three dimensional simulated particle positions. The confidence intervals can be graphically represented as ellipses around individual particle positions in the X-Y (geographic) plane and in the X-Z or Y-Z (vertical) planes. The merging of individual ellipses allows uncertainties on forward particle tracks to be displayed in map or cross-sectional view as a cone of uncertainty around a simulated particle path; uncertainties on reverse particle-track endpoints - representing simulated recharge locations - can be geographically displayed as areas at the water table around the discrete particle endpoints. This information gives decisionmakers insight into the level of confidence they can have in particle-tracking results and can assist them in the efficient use of available field resources.

Massachusetts↗

Distribution and migration of ordnance-related compounds and oxygen and hydrogen stable isotopes in ground water near Snake Pond, Sandwich, Massachusetts

Explosive compounds, such as RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine) and HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine), and the propellant compound perchlorate are present in ground water near Snake Pond, a ground-water flow-through glacial kettle pond in the glacial sand and gravel aquifer on western Cape Cod near Camp Edwards on the Massachusetts Military Reservation. The contaminants originate from the J-3 Range ordnance training and testing area. Ground-water samples were collected at 10 sites near the pond to determine the paths of the contaminants as they underflow or completely or partially discharge into the pond. Water-quality profiles were developed for sites on opposite ends of a 200-foot-long intermittent island near the northern, upgradient end of the pond by collecting water samples from two temporary drive-point borings. RDX was detected at both locations between 60 and 90 feet below the pond level. The highest RDX concentration was 0.99 micrograms per liter. Perchlorate was detected at only one location on the island, between 95 and 100 feet below the pond level at a concentration of 0.61 micrograms per liter. Profiles of oxygen and hydrogen stable isotopes were developed for seven sites spaced 300 to 600 feet apart along the southern, downgradient shore of the pond. A transition from heavier to lighter oxygen and hydrogen isotopes was observed at an altitude of about -50 feet. This transition most likely is the boundary between evaporation-affected pond water that is seeping into the aquifer and ground water that has passed beneath the pond. RDX was not detected in the ground-water samples collected south of the pond. Perchlorate was detected only in one sample from a shallow depth in one boring. The results of these analyses indicate that the J-3 Range plume contains low concentrations of RDX and perchlorate (less than 1 microgram per liter) as it passes beneath the northern end of Snake Pond. Results of ground-water-flow modeling indicate that ground water containing these low levels of RDX and perchlorate discharges into the pond south of the island. If the contaminated ground water should travel as far as the southern shore of the pond, it would be overlain near the shore by a zone of pond water seeping into the aquifer that is about 100 feet thick.

Massachusetts↗

Comparison of pumped and diffusion sampling methods to monitor concentrations of perchlorate and explosive compounds in ground water, Camp Edwards, Cape Cod, Massachusetts, 2004-05

Laboratory and field tests were conducted at Camp Edwards on the Massachusetts Military Reservation on Cape Cod to examine the utility of passive diffusion sampling for long-term monitoring of concentrations of perchlorate and explosive compounds in ground water. The diffusion samplers were constructed of 1-inch-diameter rigid, porous polyethylene tubing. The results of laboratory tests in which diffusion samplers were submerged in containers filled with ground water containing perchlorate, RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine), and HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine) indicate that concentrations inside the diffusion samplers equilibrated with concentrations in the containers within the 19-day-long test period. Field tests of the diffusion samplers were conducted in 15 wells constructed of 2- or 2.5-inch-diameter polyvinyl chloride pipe with 10-foot-long slotted screens. Concentrations of perchlorate, RDX, and HMX in the diffusion samplers placed in the wells for 42 to 52 days were compared to concentrations in samples collected by low-flow pumped sampling from 53 days before to 109 days after retrieval of the diffusion samples. The results of the field tests indicate generally good agreement between the pumped and diffusion samples for concentrations of perchlorate, RDX, and HMX. The concentration differences indicate no systematic bias related to contaminant type or concentration levels.

Massachusetts↗

Prevalence of tumors in brown bullhead from three lakes in southeastern Massachusetts, 2002

The Massachusetts Military Reservation (MMR) has been a military base on western Cape Cod since the early 1900s. Contaminated surface water and ground water from the MMR have discharged into several kettle lakes on or near the base. To discover whether the prevalences of tumors and other lesions in brown bullhead (Ameiurus nebulosus) in these lakes, particularly Ashumet Pond, were elevated above normal, the U.S. Geological Survey (USGS), assisted by the U.S. Environmental Protection Agency (USEPA) and the Massachusetts Division of Fisheries and Wildlife (MADFW), conducted a study in 2002 of brown bullhead in Ashumet Pond and in two reference lakes, Santuit Pond (on Cape Cod) and Great Herring Pond (on the mainland of Massachusetts). Brown bullhead from Great Herring Pond had few external raised lesions (2.8 percent), a low prevalence of liver neoplasms (5 percent), and little genetic damage to their red blood cell nuclei. Brown bullhead from Ashumet Pond had a high prevalence of raised lesions (62.1 percent), which included histopathologically verified papillomas and squamous carcinoma; an elevated incidence of liver neoplasms (16.7 percent); and an elevated level of genetic damage to their red blood cell nuclei. Because red blood cells in fish have a lifespan of about 100 days, these results indicate an ongoing exposure to genotoxins in Ashumet Pond. Brown bullhead from Santuit Pond also had elevated prevalences of raised lesions (48.3 percent) and liver neoplasms (15 percent), although the prevalences of large and multiple lesions were significantly lower than those in fish from Ashumet Pond. These differences may indicate differing causes of pathology in the two lakes. The high prevalence of melanistic lesions on brown bullhead from Ashumet Pond, combined with the tumor pathology and genetic damage, implicates chemical carcinogens as one of the causal factors in that lake.

Massachusetts↗

Long-term performance of Aanderaa optodes and sea-bird SBE-43 dissolved-oxygen sensors bottom mounted at 32 m in Massachusetts Bay

A field evaluation of two new dissolved-oxygen sensing technologies, the Aanderaa Instruments AS optode model 3830 and the Sea-Bird Electronics, Inc., model SBE43, was carried out at about 32-m water depth in western Massachusetts Bay. The optode is an optical sensor that measures fluorescence quenching by oxygen molecules, while the SBE43 is a Clark polarographic membrane sensor. Optodes were continuously deployed on bottom tripod frames by exchanging sensors every 4 months over a 19-month period. A Sea-Bird SBE43 was added during one 4-month deployment. These moored observations compared well with oxygen measurements from profiles collected during monthly shipboard surveys conducted by the Massachusetts Water Resources Authority. The mean correlation coefficient between the moored measurements and shipboard survey data was >0.9, the mean difference was 0.06 mL L −1 , and the standard deviation of the difference was 0.15 mL L −1 . The correlation coefficient between the optode and the SBE43 was >0.9 and the mean difference was 0.07 mL L −1 . Optode measurements degraded when fouling was severe enough to block oxygen molecules from entering the sensing foil over a significant portion of the sensing window. Drift observed in two optodes beginning at about 225 and 390 days of deployment is attributed to degradation of the sensing foil. Flushing is necessary to equilibrate the Sea-Bird sensor. Power consumption by the SBE43 and required pump was 19.2 mWh per sample, and the optode consumed 0.9 mWh per sample, both within expected values based on manufacturers’ specifications.

Massachusetts↗

Generation and propagation of nonlinear internal waves in Massachusetts Bay

During the summer, nonlinear internal waves (NLIWs) are commonly observed propagating in Massachusetts Bay. The topography of the area is unique in the sense that the generation area (over Stellwagen Bank) is only 25 km away from the shoaling area, and thus it represents an excellent natural laboratory to study the life cycle of NLIWs. To assist in the interpretation of the data collected during the 1998 Massachusetts Bay Internal Wave Experiment (MBIWE98), a fully nonlinear and nonhydrostatic model covering the generation/shoaling region was developed, to investigate the response of the system to the range of background and driving conditions observed. Simplified models were also used to elucidate the role of nonlinearity and dispersion in shaping the NLIW field. This paper concentrates on the generation process and the subsequent evolution in the basin. The model was found to reproduce well the range of propagation characteristics observed (arrival time, propagation speed, amplitude), and provided a coherent framework to interpret the observations. Comparison with a fully nonlinear hydrostatic model shows that during the generation and initial evolution of the waves as they move away from Stellwagen Bank, dispersive effects play a negligible role. Thus the problem can be well understood considering the geometry of the characteristics along which the Riemann invariants of the hydrostatic problem propagate. Dispersion plays a role only during the evolution of the undular bore in the middle of Stellwagen Basin. The consequences for modeling NLIWs within hydrostatic models are briefly discussed at the end.

Massachusetts↗

Revisiting the cape cod bacteria injection experiment using a stochastic modeling approach

Bromide and resting-cell bacteria tracer tests conducted in a sandy aquifer at the U.S. Geological Survey Cape Cod site in 1987 were reinterpreted using a three-dimensional stochastic approach. Bacteria transport was coupled to colloid filtration theory through functional dependence of local-scale colloid transport parameters upon hydraulic conductivity and seepage velocity in a stochastic advection - dispersion/attachment - detachment model. Geostatistical information on the hydraulic conductivity (K) field that was unavailable at the time of the original test was utilized as input. Using geostatistical parameters, a groundwater flow and particle-tracking model of conservative solute transport was calibrated to the bromide-tracer breakthrough data. An optimization routine was employed over 100 realizations to adjust the mean and variance ofthe natural-logarithm of hydraulic conductivity (InK) field to achieve best fit of a simulated, average bromide breakthrough curve. A stochastic particle-tracking model for the bacteria was run without adjustments to the local-scale colloid transport parameters. Good predictions of mean bacteria breakthrough were achieved using several approaches for modeling components of the system. Simulations incorporating the recent Tufenkji and Elimelech (Environ. Sci. Technol. 2004, 38, 529-536) correlation equation for estimating single collector efficiency were compared to those using the older Rajagopalan and Tien (AIChE J. 1976, 22, 523-533) model. Both appeared to work equally well at predicting mean bacteria breakthrough using a constant mean bacteria diameter for this set of field conditions. Simulations using a distribution of bacterial cell diameters available from original field notes yielded a slight improvement in the model and data agreement compared to simulations using an average bacterial diameter. The stochastic approach based on estimates of local-scale parameters for the bacteria-transport process reasonably captured the mean bacteria transport behavior and calculated an envelope of uncertainty that bracketed the observations in most simulation cases.

Massachusetts↗

Reply to discussion by Michael A. Collins, "Fresh ground water stored in aquifers under the continental shelf: implications from a deep test, Nantucket Island, Massachusetts"

We appreciate the comments made in the discussion by Michael A. Collins , regarding o ur paper about the anomalously low salinity of water underlying Nantucket Island. However, we feel that in his effort to justify the mathematical approach for solving salt water intrusion problems, he has overlooked several of the major points in this paper. We will try to amplify these points to establish that, indeed, the situation at Nantucket is anomalous, contrary to Collins’ negative conclusion (Collins, 1978).

Massachusetts↗

Sea-floor character and surface processes in the vicinity of Quicks Hole, Elizabeth Islands, Massachusetts

The U.S. Geological Survey (USGS), in cooperation with the National Oceanic and Atmospheric Administration (NOAA) and the Massachusetts Office of Coastal Zone Management (MA CZM), is producing detailed geologic maps of the coastal sea floor. The imagery, interpretive data layers, and data presented herein were derived from multibeam echo-sounder and sidescan sonar surveys conducted in the vicinity of Quicks Hole, a passage through the Elizabeth Islands, which extend in a chain southwest off Cape Cod, Massachusetts, and from the stations occupied to verify these acoustic data (fig. 1). Basic data layers show sea-floor topography, sun-illuminated shaded relief, and backscatter intensity; interpretive layers show the distributions of surficial sediment, sedimentary environments, and sea-floor features. Presented verification data include sediment grain-size analyses and a gallery of still photographs of the seabed. The multibeam and sidescan data, which cover an approximately 22.9-km 2 area of sea floor that extends from Vineyard Sound on the south to Buzzards Bay on the north, were collected during NOAA hydrographic survey H11076 (fig. 1). Although originally collected for charting purposes, these data provide a fundamental framework for research and management activities along this part of the Massachusetts coastline (Noji and others, 2004), show the composition and terrain of the seabed, and provide information on sediment transport and benthic habitat.

Massachusetts↗

Adult tree swallow (Tachycineta bicolor) survival on the polychlorinated biphenyl-contaminated Housatonic River, Massachusetts, USA

Tree swallows ( Tachycineta bicolor ) were captured and banded at six sites that differed in polychlorinated biphenyl (PCB) contamination levels in the Housatonic River watershed, western Massachusetts, USA, from 2000 through 2004 to test the prediction that apparent survival rates of females in more contaminated areas were lower than those from less contaminated areas. We also tested whether plumage coloration affected over-winter survival and whether concentrations of PCBs in eggs differed between birds that did and that did not return the following year. Apparent survival rates were calculated using mark-recapture methods and compared using Akaike's Information Criterion. Model-adjusted survival rates ranged from 0.365 to 0.467 for PCB-contaminated females and between 0.404 and 0.476 for reference females. Models with either survival or capture probability modeled as functions of treatment (degree of PCB contamination), year, and age received some support. The model-averaged parameter estimate reflecting a treatment effect for high-PCB birds was negative ( = −0.046, SE( ) = 0.0939) . Fifty-four percent of the total model weights involved models in which survival was a function of PCB treatment. Eggs were collected for contaminant analyses from a random sample of females that did and that did not return the following year. Concentrations of total PCBs were the same or higher in the eggs of females that returned compared to the eggs of those that did not return at both the highly and the moderately contaminated PCB sites. This may have resulted from higher-quality females with higher lipid reserves being more likely than lower-quality females to return the following year. Percentage lipid was positively correlated with total PCBs in eggs. Survival rates were similar among swallows with brown versus blue plumage.

Massachusetts↗

Role of sediment resuspension in the remobilization of particulate-phase metals from coastal sediments

The release of particulate-phase trace metals due to sediment resuspension has been investigated by combining erosion chamber experiments that apply a range of shear stresses typically encountered in coastal environments with a shear stress record simulated by a hydrodynamic model. Two sites with contrasting sediment chemistry were investigated. Sediment particles enriched in silver, copper, and lead, 4−50 times greater than the bulk surface-sediment content, were the first particles to be eroded. As the shear-stress level was increased in the chamber, the total mass eroded increased, but the enrichment of these trace metals fell, approaching the bulk-sediment content. From the temporal distribution of shear stress generated by the hydrodynamic model for a site in Boston Harbor, resuspension fluxes were estimated. The erosion threshold of this site is exceeded during spring tides, releasing the particles enriched in trace metals into the water column. Due to the higher trace metal content and the regularity of resuspension, low-energy resuspension events (up to a shear stress of 0.2 N/m 2 ) contribute up to 60% of the resuspension metal flux in an average year. The estimated annual quantity of copper and lead resuspended into the water column is higher than estimates of the total riverine flux for these metals. These results indicate that sediment resuspension is a very important mechanism for releasing metals into the water column and provide new insight into the chemical and physical processes controlling the long-term fate of trace metals in contaminated sediments.

Massachusetts↗

Ecological observations on the colonial ascidian Didemnum sp. in a New England tide pool habitat

The colonial ascidian Didemnum sp. has colonized northwestern Atlantic coastal habitats from southern Long Island, New York, to Eastport, Maine. It is also present in offshore habitats of the Georges Bank fishing grounds. It threatens to alter fisheries habitats and shellfish aquacultures. Observations in a tide pool at Sandwich, MA from December 2003 to February 2006 show that Didemnum sp. tolerates water temperatures ranging from ≤ 1 to > 24 °C, with daily changes of up to 11 °C. It attaches to pebbles, cobbles, and boulders, and it overgrows other tunicates, seaweeds, sponges, and bivalves. From May to mid July, colonies appear as small patches on the bottoms of rocks. Colonies grow rapidly from July to September, with some growth into December, and they range in color from pink to pale yellow to pale orange. Colony health declines from October through April, presumably in response to changes in water temperatures, and this degenerative process is manifested by color changes, by the appearance of small dark brown spots that represent clumps of fecal pellets in the colony, by scavenging by periwinkles, and by a peeling-away of colonies from the sides of cobbles and boulders. At Sandwich, colonies died that were exposed to air at low tide. The species does not exhibit this seasonal cycle of growth and decline in subtidal habitats (40–65 m) on the Georges Bank fishing grounds where the daily climate is relatively stable and annual water temperatures range from 4 to 15 °C. Experiments in the tide pool with small colony fragments (5 to 9 cm 2 ) show they re-attach and grow rapidly by asexual budding, increasing in size 6- to 11-fold in the first 15 days. Didemnum sp. at Sandwich has no known predators except for common periwinkles ( Littorina littorea ) that graze on degenerating colonies in the October to April time period and whenever colonies are stressed by desiccation. The tendencies of the ascidian (1) to attach to firm substrates, (2) to rapidly overgrow other species, (3) to tolerate a wide temperature range, (4) to be free from predation, and (5) to spread by colony fragmentation combine to make it a potential threat to benthic marine habitats and aquacultures. Didemnum sp. is known to overgrow mussels, oysters, and sea scallops, and it likely envelops other bivalves too.

Massachusetts↗