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Research about Lower Gunnison River Basin

Source-linked reports with geographic coverage including Lower Gunnison River Basin.

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Assessment of dissolved-selenium concentrations and loads in the Lower Gunnison River Basin, Colorado, as part of the Selenium Management Program, 2011–17

The Gunnison Basin Selenium Management Program implemented a water-quality monitoring network in 2011 to measure concentrations of selenium in the lower Gunnison River Basin in Colorado. Selenium is a trace element that bioaccumulates in aquatic food chains. Selenium is essential for life, but elevated amounts can cause reproductive failure, deformities, and other harmful effects. The primary goal of the Selenium Management Program is to meet the State of Colorado water-quality standard of 4.6 micrograms per liter (µg/L) for dissolved selenium at the U.S. Geological Survey (USGS) streamflow-gaging station number 09152500—Gunnison River near Grand Junction, Colorado—herein referred to as “Whitewater.” The U.S. Geological Survey, in cooperation with the Bureau of Reclamation, has completed a review of dissolved-selenium data collected from the Selenium Management Program network during Water Year (WY) 2017 (October 1, 2016 through September 30, 2017) to further the understanding of the status and trends of selenium in the basin. This report presents the percentile values for selenium because regulatory agencies in Colorado make decisions based on the U.S. Environmental Protection Agency’s Clean Water Act section 303(d), which uses percentile values for concentrations. Also presented are dissolved-selenium loads at 14 sites in the lower Gunnison River Basin for WYs 2011–17. Annual dissolved-selenium loads were calculated for six sites with continuous U.S. Geological Survey streamflow-gaging stations. These six sites are referred to as “core” sites in this report. The remaining sites, which do not have streamflow-gaging stations, are referred to as “ancillary” sites in this report. During WY 2017, the loads calculated at the six core sites ranged from 306 pounds (lb) at Uncompahgre River at Colona to 12,600 lb at Whitewater, respectively. By using discrete water-quality samples and the associated discharge measurements, instantaneous loads were calculated for 14 sites in WYs 2011–17 where discrete water-quality sampling took place. Median instantaneous loads ranged from 0.52 pounds per day (lb/d) at Uncompahgre River at Colona to 35.7 lb/d at Whitewater. Mean instantaneous loads ranged from 0.63 lb/d at Cummings Gulch at mouth to 35.5 lb/d at Whitewater. Most tributary sites in the basin had a median instantaneous dissolved-selenium load of less than 20.0 lb/d. In general, dissolved-selenium loads at Gunnison River main-stem sites showed an increase from upstream to downstream. The State of Colorado’s water-quality standard for dissolved selenium of 4.6 µg/L was compared to the 85th percentiles for dissolved selenium at selected sites. Annual 85th percentiles for dissolved selenium were calculated by using estimated dissolved-selenium concentrations from linear regression models for the six core sites with U.S. Geological Survey streamflow-gaging stations. The 85th-percentile concentrations for WY 2017 based on this method ranged from 0.68 µg/L at Uncompahgre River at Colona to 140 µg/L at Loutzenhizer Arroyo at North River Road. The 85th percentiles for concentrations of dissolved selenium also were calculated from water-quality samples collected during WY 2017 from sites with sufficient data. The annual 85th-percentile concentrations based on the discrete samples ranged from 0.75 µg/L at Uncompahgre River at Colona to 106 µg/L at Loutzenhizer Arroyo at North River Road. An analysis was completed for Whitewater to determine if an upward or downward trend exists for dissolved-selenium loads during two time periods. The first time period included all data at Whitewater, whereas the second time period focused on more recent data. The trend analysis indicates a decrease from 22,200 to 12,600 lb, which is a 43.1 percent (9,600 lb) reduction during the time period WY 1986 through WY 2017. The trend analysis for the annual dissolved-selenium load for WY 1995 through WY 2017 indicates a decrease of 6,600 lb per year, or 35.5 percent. An evaluation of laboratory bias was completed for selenium data which was used in the trend analysis. Findings indicated a potential positive bias of approximately 12 percent may exist in the data from October 2005 through August 2015.

Colorado

Groundwater quality and hydrology with emphasis on selenium mobilization and transport in the Lower Gunnison River Basin, Colorado, 2012–16

Dissolved selenium is a contaminant of concern in the lower Gunnison River Basin, Colorado. Selenium is naturally present in the Cretaceous Mancos Shale and is leached to groundwater and surface water by irrigation. The groundwater on the east side of the Uncompahgre River in Delta and Montrose Counties is one of the primary sources of selenium concentration and load to surface water in the lower Gunnison River Basin. Although little information about the contribution of groundwater to surface water has been historically available, groundwater has often been implicated as an appreciable source of selenium to surface water. From 2012 to 2016, the U.S. Geological Survey, in cooperation with the Bureau of Reclamation, the Colorado Water Conservation Board, and the Gunnison Basin Selenium Management Program, established a 30-well groundwater-monitoring network on irrigated land to characterize the hydrology and groundwater quality of the shallow groundwater system on the east side of the Uncompahgre River in the lower Gunnison River Basin. The installation of the 30-well network and the data collected allowed for the development of a conceptual model of selenium mobilization and transport in the shallow groundwater system. Monitoring wells were completed in surficial deposits and in weathered Mancos Shale, which generally exhibited unconfined and confined conditions, respectively. Groundwater-quality monitoring provides information on the distribution of selenium and the geochemical processes controlling selenium concentrations in shallow groundwater. Monitoring wells were sampled between August 2013 and March 2015 to understand groundwater quality, seasonality, sources of recharge, and groundwater age. Concentrations of dissolved selenium ranged from below the limit of detection to 4,100 micrograms per liter (µg/L), with a median concentration of 14 µg/L. Concentrations showed a high degree of spatial variability and no seasonal difference. Similarly, no seasonal pattern was observed in specific conductance values of groundwater despite the considerably lower specific conductance value of irrigation water. Reduction-oxidation processes are important controls on selenium mobility. Nitrate derived from geologic material was a primary control on reduction-oxidation conditions in groundwater and inhibited selenium reduction to less mobile forms. Nitrate was reduced by denitrification in groundwater, but it was not reduced to the extent necessary to allow for selenium reduction. Groundwater ages were determined for groundwater samples from eight wells and ranged from 6 to 20 years old. Isotopic data indicate groundwater was recharged by irrigation water; no information collected supported an older, deeper source of recharge to the shallow groundwater system. Data on water level in all wells showed response to irrigation practices, but the response was delayed in some wells, which may be an indication of distance from recharge source.

Colorado

Assessment of dissolved-selenium concentrations and loads in the lower Gunnison River Basin, Colorado, as part of the Selenium Management Program, from 2011 to 2016

The Gunnison Basin Selenium Management Program implemented a water-quality monitoring network in 2011 in the lower Gunnison River Basin in Colorado. Selenium is a trace element that bioaccumulates in aquatic food chains and can cause reproductive failure, deformities, and other harmful effects. This report presents the percentile values of selenium because regulatory agencies in Colorado make decisions based on the U.S. Environmental Protection Agency (EPA) Clean Water Act Section 303(d) that uses percentile values of concentration. Also presented are dissolved-selenium loads at 18 sites in the lower Gunnison River Basin for water years (WYs) 2011–2016 (October 1, 2010, through September 30, 2016). Annual dissolved-selenium loads were calculated for five sites with continuous U.S. Geological Survey (USGS) streamflow-gaging stations. Annual dissolved-selenium loads for WY 2011 through WY 2016 ranged from 179 and 391 pounds (lb) at Uncompahgre River at Colona to 11,100 and 17,300 lb at Gunnison River near Grand Junction (herein called Whitewater), respectively. Instantaneous loads were calculated for five sites with continuous U.S. Geological Survey (USGS) streamflow-gaging stations and 13 ancillary sites where discrete water-quality sampling also took place, using discrete water-quality samples and the associated discharge measurements collected during the period. Median instantaneous loads ranged from 0.01 pound per day (lb/d) at Smith Fork near Lazear to 33.0 lb/d at Whitewater. Mean instantaneous loads ranged from 0.06 lb/d at Smith Fork near Lazear to 36.2 lb/d at Whitewater. Most tributary sites in the basin had a median instantaneous dissolved-selenium load of less than 20.0 lb/day. In general, dissolved-selenium loads at Gunnison River main-stem sites showed an increase from upstream to downstream. The State of Colorado water-quality standard for dissolved selenium of 4.6 micrograms per liter (µg/L) was compared to the 85th percentiles for dissolved selenium at selected sites. Annual 85th percentiles for dissolved selenium were calculated for the five core sites having USGS streamflow-gaging stations using estimated dissolved-selenium concentrations from linear regression models. The 85th-percentile concentrations for WYs 2011–2016 based on this method ranged from 0.62 µg/L and 1.1µg/L at Uncompahgre River at Colona to 12.1 µg/L and 18.7 µg/L at Uncompahgre River at Delta. The 85th percentiles for dissolved selenium also were calculated for sites with sufficient data using water-quality samples collected during WYs 2011–2016. The annual 85th-percentile concentrations based on the discrete samples ranged from 0.16 µg/L and 0.17 µg/L at Gunnison River below Gunnison Tunnel to 62.2 µg/L and 170 µg/L at Loutzenhizer Arroyo at North River Road. A trend analysis was completed for Whitewater to determine if dissolved-selenium loads are increasing or decreasing. The trend analysis indicates a decrease of 9,100 lb from WY 1986 to WY 2016, a 40.8 percent reduction during the time period. The trend analysis for the annual dissolved-selenium load for WY 1994 to WY 2016 indicates a decrease of 6,300 lb per year, or 33.3 percent.

Colorado

2014 annual summary of the lower Gunnison River Basin Selenium Management Program water-quality monitoring, Colorado

Dissolved-selenium loading analyses of data collected at 18 water-quality sites in the lower Gunnison River Basin in Colorado were completed through water year (WY) 2014. A WY is defined as October 1–September 30. Selenium is a trace element that bioaccumulates in aquatic food chains and can cause reproductive failure, deformities, and other harmful effects. This report presents information on the dissolved-selenium loads at 18 sites in the lower Gunnison River Basin for WYs 2011–2014. Annual dissolved-selenium loads were calculated at 5 sites with continuous U.S. Geological Survey (USGS) streamflow gages, whereas instantaneous dissolved-selenium loads were calculated for the remaining 13 sites using water-quality samples that had been collected periodically during WYs 2011–2014. Annual dissolved-selenium loads for WY 2014 ranged from 336 pounds (lb) at Uncompahgre River at Colona to 13,300 lb at Gunnison River near Grand Junction (Whitewater). Most sites in the basin had a median instantaneous dissolved-selenium load of less than 20.0 lb per day. In general, dissolved-selenium loads at Gunnison River main-stem sites showed an increase from upstream to downstream. The State of Colorado water-quality standard for dissolved selenium of 4.6 micrograms per liter (µg/L) was compared to the 85th percentiles for dissolved selenium at selected water-quality sites. Annual 85th percentiles for dissolved selenium were calculated for the five core USGS sites having streamflow gages using estimated dissolved-selenium concentrations from linear regression models. These annual 85th percentiles in WY 2014 ranged from 0.97 µg/L at Uncompahgre River at Colona to 16.7 µg/L at Uncompahgre River at Delta. Uncompahgre River at Delta and Whitewater were the only core sites where water samples exceeded the State of Colorado water-quality standard for dissolved selenium of 4.6 µg/L. Instantaneous 85th percentiles for dissolved selenium were calculated for sites with sufficient data using water-quality samples collected during WYs 2011–2014. The instantaneous 85th percentiles for samples for WY 2014 ranged from 1.1 µg/L at Uncompahgre River at Colona to 125 µg/L at Loutzenhizer Arroyo at North River Road. A trend analysis was completed for Whitewater to determine if dissolved-selenium loads are increasing or decreasing. The trend analysis indicates a decrease of 8,000 lb from WY 1986 to WY 2014, a 34.8 percent reduction during the time period, and an additional 6.2 percent reduction from a reported 28.6 percent reduction during WYs 1986–2008. The trend analysis for WY 1992 to WY 2014 indicates a decrease of 5,800 lb per year, or 27.9 percent.

Colorado