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Research about Hawaii

Source-linked reports with geographic coverage including Hawaii.

At least 1,171 records · Page 65Linked to original sources

Mineralogy of sulfides from certain Hawaiian basalts

Polymineralic sulfide grains, composed principally of Fe sulfide and Fe-Cu sulfide, with magnetite, have been studied mineragraphically and by electron probe, and interpreted in terms of experimental data for the system Fe-Ni-Cu-S. The three main phases are monosulfide solid solution, a Cu-Fe sulfide (solid solution) with composition near cubanite, and Ti-free magnetite. The grains are believed to represent phases unmixed from an immiscible liquid phase in the basalt magma. Compositions of the two main sulfide phases suggest quenching below 700 degrees C. Most of the Ni has been retained in the monosulfide solid solution by rapid quenching.

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Mineralogy as a function of depth in the prehistoric Makaopuhi tholeiitic lava lake, Hawaii

The electron probe X-ray microanalyzer has been used to determine the compositional variability of the groundmass minerals and glass in 10 specimens from a complete 225-foot section of the prehistoric tholeiitic lava lake of Makaopuhi Crater, Hawaii. The order of beginning of crystallization was: (1) chromite, (2) olivine, (3) augite, (4) plagioclase, (5) pigeonite, (6) iron-titanium oxides and orthopyroxene, (7) alkali feldspar and apatite, and (8) glass. Although the lake is chemically tholeiitic throughout, the occurrence of ferromagnesian minerals is as though there were a gradation from alkali olivine basalt in the upper chill downwards to olivine tholeiite. Groundmass olivine decreases downwards and disappears at about 20 feet. Pigeonite is absent in the uppermost 5±2 feet, then increases in amount down to 20 feet, below which augite and pigeonite coexist in constant 2∶1 proportions. Strong zoning and metastable compositions characterize the pyroxenes of the chilled zones, but these features gradually disappear towards the interior of the lake to give way to equilibrium pyroxenes. Relatively homogeneous poikilitic orthopyroxene (≈ Ca 4 Mg 70 Fe 26 ) occurs in the olivine cumulate zone, having formed partly at the expense of pre-existing olivine, augite, and pigeonite (≈ Ca 8 Mg 66 Fe 26 ). The growth of orthopyroxene is believed to have been facilitated by the slower cooling rate and higher volatile pressure at depth, and by the rise in Mg/Fe ratio of the liquid due to the partial dissolution of settled olivine. Unlike olivine and pyroxene, feldspar is least zoned in the upper and lower chilled regions. The greatest range of compositional zoning in feldspar occurs at 160 to 190 feet, where it extends continuously from Or 1.0 Ab 22 An 77 to Or 64 Ab 33 An 3 . The feldspar fractionation trend in the An-Ab-Or triangle gradually shifts with depth toward more “equilibrium” trends, even though the zoning becomes more extreme. The variation with depth in the initial (core) composition of the plagioclase suggests the influence of either slow nucleation and growth (undercooling) or slow diffusion in the liquid, relative to the rate of cooling. Idiomorphic opaque inclusions in olivine phenocrysts are chrome-spinels showing continuous variation from 60 percent chromite to 85 percent ulvospinel and to magnetite-rich spinel. A pre-eruption trend of increasing Al with decreasing Cr can be recognized in chromites from the upper chill. Most of the inclusions show a trend of falling Cr and Al, toward an ulvospinelmagnetite solid solution which is progressively poorer in Usp with depth. This trend was produced by solid state alteration of the chromite inclusions during cooling in the lava lake. Ilmenite (average Ilm 91 Hm 9 ) coexists with variably oxidized titaniferous magnetite in the basalt groundmass. Estimated oxygen fugacities agree well with other independent determinations in tholeiitic basalt. No sulfide phase has been detected. Fractional crystallization produced a groundmass glass of granitic composition. Average, in percent, is: SiO 2 , 75.5; Al 2 O 3 , 12.5; K 2 O, 5.7; Na 2 O, 3.1; CaO, 0.3; MgO, 0.05; total FeO, 1.2; and TiO 2 , 0.8. Normative Or> Ab. Minor changes in glass composition with depth are consistent with a greater approach towards the granite minimum. Incipient devitrification precluded reliable analysis of glass from the lower half of the section. The SiO 2 -phase associated with devitrification contains alkalis and Al and is believed to be cristobalite. Needle-like apatite crystals in the groundmass glass are Siand Fe-bearing fluorapatites containing appreciable rare earths (predominantly Ce) and variable Cl. The grain-size and maximum An content of the cores of plagioclase grains were controlled by cooling rate and are at a maximum at the center of the section. The most homogeneous pyroxene (and olivine, MOORE and EVANS , 1967), most equilibrium pyroxene trends, most abundant alkali feldspar, and most equilibrium feldspar trends are found at 160 to 190 feet, which is appreciably below that part of the lake which was slowest to crystallize. Volatile pressure, increasing with depth, possibly controlled the degree of attainment of equilibrium more than cooling rate. Since they are dependent on cooling history, some of the modal criteria commonly used for recognizing basalt types, such as the absence of Ca-poor pyroxene, presence of groundmass olivine, and the presence of alkali feldspar, should be applied with caution. Petrographic comparison of basalts from one flow, volcano, or province, with another, should recognize the possible variations due to cooling history alone.

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Argon-40: Excess in submarine pillow basalts from Kilauea Volcano, Hawaii

Submarine pillow basalts from Kilauea Volcano contain excess radiogenic argon-40 and give anomalously high potassium-argon ages. Glassy rims of pillows show a systematic increase in radiogenic argon-40 with depth, and a pillow from a depth of 2590 meters shows a decrease in radiogenic argon-40 inward from the pillow rim. The data indicate that the amount of excess radiogenic argon-40 is a direct function of both hydrostatic pressure and rate of cooling, and that many submarine basalts are not suitable for potassium-argon dating.

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The formation of columnar joints in the upper part of Kilauean lava lakes, Hawaii

Cracks were observed forming at the surface of Makaopuhi lava lake during the March 1965 Kilauea eruption, and were studied by repeated mapping and observations of this lake ; the 1963 Alae lava lake was similarly studied. Cracks open within a minute after molten lava is exposed at the surface, and form either random or oriented orthogonal networks which outline large plates of unjointed crust. Within a few hours, additional cracks subdivide the plates into polygons averaging 15 ft in width. The accumulation of gases trapped beneath the crust near centers of polygons, and the escape of gases from marginal parts, cause upbowing of polygon centers and downsagging of margins. As the crust cools and increases in thickness following stagnation of the lake , existing cracks extend downward and new cracks open. Some new cracks subdivide pre-existing polygons, and short cracks of shallow depth form near polygon centers. Still other cracks apparently open at depths of tens of feet within the crust, propagate upward, and finally feather out near the surface into short cracks which are concentrated in long swarms that cross several polygons. Cracks initiate at temperatures ranging from ambient to about 900°C, and propagate downward into parts of the crust near 1000°C. Cracking results from stresses induced largely by thermal contraction, but also by differential subsidence of the crust. Seismic recordings of shock vibrations due to cracking of Kilauea Iki lava lake indicate a diurnal variation in frequency, with a maximum around midnight and a minimum around noon.

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A further contribution to the petrology of Haleakala volcano, Hawaii

Sixteen new chemical analyses of the later rocks of Haleakala Volcano , on the island of Maui, Hawaii , add to the differentiation picture for that volcano . The early rocks of the volcano are tholeiitic. These are followed by dominant hawaiites with less abundant alkalic olivine basalts, picrite-basalts of ankaramite type, and a few mugearites. Still later rocks, separated from earlier ones by a profound erosional unconformity, include some hawaiites and ankaramites, but are dominantly alkalic olivine basalts (basanitoids) containing as much as 16.5 percent normative nepheline, some of them transitional to ankaramite. The progression toward ultramafic, strongly undersaturated rocks (nephelinites), characteristic of the post-erosional lavas of other Hawaiian volcanoes, appears to have just begun at Haleakala .

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Ground-water exploration using the resistivity method on the Hawaiian Islands of Oahu and Hawaii

Thirty-six resistivity soundings were made on the islands of Oahu and Hawaii to determine the applicability of galvanic resistivity methods for locating fresh-water aquifers in the State of Hawaii. Soundings were made on the northwestern part of the island of Oahu near the town of Waialua and on the island of Hawaii on the "saddle" area near Pohekuloa and the Humuula sheep station. On Oahu, the geoelectrical study indicates that correlation among four stratigraphic units underlain by a vesicular basalt basement is possible. The electrical soundings indicate that it is feasible to determine the approximate depth to the fresh-saline water interface within the basalt. Two Schlumberger soundings with electrode spacings, AB/2, reaching 6,000 feel give sounding curves of the maximum and minimum type whose terminal branches indicate that the true resistivity of basalts saturated with sea water, in the survey area on Oahu, is about 30-40 ohm-m. On the island of Hawaii, an exploratory well drilled in basalt to a depth of 1,001 feet proved to be dry. In the area of this well, two deep soundings were made using the Schlumberger and the equatorial arrays. Although additional soundings at various orientations and larger spacings are needed, there appears to be a conductive layer below 1,600 feet which may represent basalt saturated with fresh water.

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The role of olivine in the crystallization of the prehistoric Makaopuhi tholeiitic lava lake, Hawaii

On eruption, the tholeiitic basalt lava of the prehistoric Makaopuhi lake contained nearly seven percent euhedral olivine phenocrysts of approximately Fa 14 composition. In the center of the 225 foot vertical section of the lake, the lava became more than 90 percent solid at 1000° C after about 30 years. At the surface the lava was quenched to air temperature, whereas, at the bottom, quenching to 800° C was followed by a 40 year period before the temperature reached 700° C. The olivine phenocrysts settled at an average rate of about 4 × 10 −6 cm Sec −1 to form a zone that contains 21 percent olivine 75 feet above the base. Sinking of olivines continued until some time after the beginning of the crystallization of augite and plagioclase. Thin rims of iron-rich olivine (up to Fa 55 ) surrounding the phenocrysts, and a second generation of fine-grained olivines (Fa 20 Fa 48 ) restricted to the uppermost 20 feet indicate local extensions of the period of crystallization of olivine. During crystallization of the groundmass and later subsolidus cooling in the range 1000° C to at least as low as 800° C, the olivine phenocrysts were converted to Fa 30–40 by interdiffusion of Fe, Mg, Ni, and Mn. Homogenization of Mg-rich cores and Fe-rich margins and equilibration of olivine composition with the groundmass phases was progressively less well achieved toward the top of the lake. Reaction rims around the olivines are composed primarily of Ca-rich pyroxene. Pigeonite crystallized alongside augite except in the uppermost 5 feet where there is abundant ground mass olivine. Poikilitic hypersthene grew at the expense of pre-existing ferromagnesian minerals in the cumulate zone.

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Drilling on Midway Atoll, Hawaii

Two holes drilled through reef sediments into basalt have established a geologic section through the Miocene. Midway was built above the sea by flows that were weathered and partially truncated in pre-Miocene time. After submergence, volcanic clays were reworked and covered by limestones. Overall submergence was interrupted at least twice by emergence. The limestones have been leached, recrystallized, and partially dolomitized.

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Crystallization of tholeiitic basalt in Alae Lava Lake, Hawaii

The eruption of Kilauea Volcano August 21–23, 1963, left 600,000 cubic meters of basaltic lava in a lava lake as much as 15 meters deep in Alae pit crater. Field studies of the lake began August 27 and include repeated core drilling, measurements of temperature in the crust and melt, and precise level surveys of the lake surface. The last interstitial melt in the lake solidified late in September 1964; by mid August 1965 the maximum temperature was 690°C at a depth of 11.5 meters. Pumice air-quenched from about 1140°C contains only 5 percent crystals — clinopyroxene, cuhedral olivine ( Fo 80 ), and a trace of plagioclase, ( An 70 ). Drill cores taken from the zone of crystallization in the lake show that olivine continued crystallizing to about 1070°C; below that it reacts with the melt, becoming corroded and mantled by pyroxene and plagioclase. Below 1070°C, pyroxene and plagioclase crystallized at a constant ratio. Ilmenite first appeared at about 1070°C and was joined by magnetite at about 1050°C; both increased rapidly in abundance to 1000°C. Apatite first appeared as minute needles in interstitial glass at 1000°C. Both the abundance and index of refraction of glass quenched from melt decreased nearly linearly with falling temperature. At 1070°C the quenched lava contains about 65 percent dark-brown glass with an index of 1.61; at 980°C it contains about 8 percent colorless glass with an index of 1.49. Below 980°C, the percentage of glass remained constant. Progressive crystallization forced exsolution of gases from the melt fraction; these formed vesicles and angular pores, causing expansion of the crystallizing lava and lifting the surface of the central part of the lake an average of 19.5 cm. The solidified basalt underwent pneumatolitic alteration, including deposition of cristobalite at 800°C, reddish alteration of olivine at 700°C, tarnishing of ilmenite at 550°C, deposition of anhydrite at 250°C, and deposition of native sulfur at 100°C. Ferric-ferrous ratios suggest that oxidation with maximum intensity between 550°C and 610°C moved downward in the crust as it cooled; this was followed by reduction at a temperature of about 100°C. The crystallized basalt is a homogeneous fine-grained rock containing on the average 48.3 percent by volume intergranular pyroxene (augite > pigeonite), 34.2 percent plagioclase laths (An 60 70 ), 7.9 percent interstitial glass, 6.9 percent opaques (ilmenite > magnetite), 2.7 percent olivine (Fo 70 80 ), and a trace of apatite. Chemical analyses of 18 samples, ranging from initially quenched pumice to lava cored more than a year after the eruption from the center and from near the base of the lake, show little variation from silica-saturated tholeiitic basalt containing 50.4 percent SiO 2 , 2.4 percent Na 2 O, and 0.54 percent K 2 O. Apparently there was no significant crystal settling and no appreciable vapor-phase transport of these components during the year of crystallization. However, seven samples of interstitial liquid that had been filter-pressed into gash fractures and drill holes from partly crystalline mush near the base of the crust show large differences from the bulk composition of the solidified crust—lower MgO, CaO, and Al 2 O 3 ; and higher total iron, TiO 2 , Na 2 O, K 2 O, P 2 O 5 , and F, and, in most samples, SiO 2 . The minor elements Ba, Ga, Li, Y, and Yb and possibly Cu tend to be enriched in the filter-pressed liquids, and Cr and possibly Ni tend to be depleted.

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Deformation measurements on Kilauea volcano, Hawaii

Repeated electronic distance measurements across Kilauea Caldera with Tellurometers and Geodimeter show definite horizontal expansion related to the vertical uplift and outward tilting of the summit prior to an eruption, and contraction during and after a flank eruption. Measurements started in October 1964, along a 3098 meter line between Uwekahuna and Keanakakoi, indicate a relatively uniform lengthening of 12 centimeters during the interval October 22, 1964 to March 1, 1965. Rapid shortening of the line by 28 centimeters was measured 4 days after the beginning of a flank eruption which involved emission of approximately 29 million cubic meters of lava during the period March 5 to March 15, 1965. During the expansion, the standard deviation of 10 Tellurometer measurements from a least-squares srtaight line solution is ± 2.0 centimeters (6.5 ppm) whereas 9 Geodimeter measurements have a standard deviation of ± 1.1 (3.6 ppm) centimeters. Absolute distance readings between the two instruments differ by 4 centimeters (13 ppm), but relative changes in distance were the same on both instruments. Changes in distance across Kilauea Caldera can, therefore, be easily measured to accuracies of 4 to 7 parts per million with standard electronic distance measuring systems. On active volcanoes where ground surface deformation exceeds 10–100 parts per million with changes in subsurface magma pressure or volume, repeated horizontal distance measurements can be a most useful technique.

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Disequilibrium of the 238U series in basalt

Radioisotope analyses of basalt samples from Hawaii, Japan, and Iwo Jima show that: (1) 234 U and 238 U are virtually in radioactive equilibrium, (2) 230 Th exceeds equilibrium values in all these samples, (3) 210 Pb concentrations range from 10–200% of the equilibrium values and average 30% deficient, and (4) 226 Ra is probably not in equilibrium with 234 U. The source regions of the basalts or magma forming processes are open systems, chemically. The enrichment of some of the uranium-daughter nuclides is insufficient to account for the excess 206 Pb in volcanic rocks. The isotopic composition of lead and specific activity of 210 Pb in sublimates from Showa-shinzan, Japan are also reported.

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Oxygen fugacities directly measured in magmatic gases

An electrochemical device was used to measure the fugacity of oxygen ( f O2 ) in holes drilled through the crust of Makaopuhi lava lake, Kilauea Volcano, Hawaii. Results obtained within 6 months of the lake formation show that log f O2 normally varies linearly with the reciprocal of the absolute temperature, and that chemical changes occurring in the cooling tholeiitic basalt are reflected in the f O2 values measured in the holes.

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Hawaiian Volcano Observatory record book 1960, 1965, and 1966

The Hawaiian Volcano Observatory (HVO) record books are annual journals in which field observations of eruptive activity at Kīlauea and Mauna Loa volcanoes, on the Island of Hawaiʻi, were compiled by HVO staff for most years from 1912 through early 1966. In addition to descriptive observations, the record books also contain hundreds of annotated photographs and sketches, as well as temperature and transit measurements. When photographs are included, the camera settings and film types used are noted. The field notes, sketches, and photographs used to compile the record books provide an unparalleled record of eruptive activity and were the basis for published newspaper reports and periodic bulletins, such as the Hawaiian Volcano Observatory bulletins and The volcano letter . HVO staff also painstakingly prepared a second copy of each early record book, virtually identical to the original, complete with photographs and sketches. The original version of the record book was kept at HVO, while the duplicate went to the Hawaiian Volcano Research Association, which was created by a group of Honolulu, Hawaiʻi, businessmen to promote HVO’s work. The Hawaiian Volcano Research Association, which dissolved decades ago, held the duplicate books in Honolulu, where they were more readily accessible to the public. After 1923, HVO stopped duplicating the books—at least, no duplicate records for subsequent years have been found. During the decade of the 1940s, preparation of the record books stopped altogether. In 1952, compilation of the record books resumed and continued, with long gaps, until early 1966. Entries in these later volumes are sparse, and these books are little more than photo albums of the episodic eruptions of Kīlauea. The original record books were held at HVO and, later, at Hawai‘i Volcanoes National Park. In 1972, the original record books for the years 1912 through 1939 were transferred to the Bishop Museum, in Honolulu, for safekeeping. These record books are now stored in archival boxes at that institution (accession number 172.265). The duplicate set of record books held by the Hawaiian Volcano Research Association were bound into volumes at an unknown date and turned over to the U.S. Geological Survey. This set of record books, spanning 1912 through 1923, is now housed in the rare book room of the U.S. Geological Survey Library in Reston, Virginia (catalog number 220(950) H3d). The record books for 1952 through early 1966 remain in storage at HVO. After 1955, typed annotations were no longer placed in the record books, and only photographs, most with captions, were included. Although the volumes titled “Record Book” end with the 1955 volume, the photograph albums that followed are similar, and the record book designation is retained for simplicity. Note that the photographs in these albums were not all originally arranged in chronological order.

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