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Research about Hawaii

Source-linked reports with geographic coverage including Hawaii.

At least 397 records · Page 22Linked to original sources

Coral skeleton δ15N as a tracer of historic nutrient loading to a coral reef in Maui, Hawaii

Excess nutrient loading to nearshore environments has been linked to declining water quality and ecosystem health. Macro-algal blooms, eutrophication, and reduction in coral cover have been observed in West Maui, Hawaii, and linked to nutrient inputs from coastal submarine groundwater seeps. Here, we present a forty-year record of nitrogen isotopes (δ 15 N) of intra-crystalline coral skeletal organic matter in three coral cores collected at this site and evaluate the record in terms of changes in nitrogen sources. Our results show a dramatic increase in coral δ 15 N values after 1995, corresponding with the implementation of biological nutrient removal at the nearby Lahaina Wastewater Reclamation Facility (LWRF). High δ 15 N values are known to be strongly indicative of denitrification and sewage effluent, corroborating a previously suggested link between local wastewater injection and degradation of the reef environment. This record demonstrates the power of coral skeletal δ 15 N as a tool for evaluating nutrient dynamics within coral reef environments.

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Increased nesting success of Hawaii Elepaio in response to the removal of invasive black rats

In Hawaii and other oceanic islands with few native land mammals, black rats (Rattus rattus) are among the most damaging invasive vertebrate species to native forest bird populations and habitats, due to their arboreal behavior and generalist foraging habits and habitat use. We evaluated the nesting response of Hawaii Elepaio (Chasiempis sandwichensis; Monarchidae), a generalist insectivore, to the removal of black rats using rodenticide in a before-after-control-impact study in high- and low-elevation mesic montane habitat recovering from long-term damage from introduced ungulates and weeds. We monitored nesting success and rat abundance during 2015–2016 before applying rodenticide bait in 2017 to remove rats from two 700 × 700 m treatment plots that were paired with 2 nontreatment plots of the same size. Rat abundance was reduced by 90% during treatment, with combined variables treatment and elevation best explaining the change using GLM methods and AIC model selection. The daily survival rate (DSR) of nests (n = 191) was greater on treated plots after rodenticide application (mean ± SE = 0.980 ± 0.004 treatment; 0.964 ± 0.004 nontreatment), modeled nest success increased from 29% to 50%, and apparent nest success (number of successful nests per total nests) increased from 37% to 52%. The most informative model for predicting DSR included the effect of treatment. Predation by rats was documented at 3 of 16 nests using video surveillance, and we observed additional evidence of rat predation during in-person nest monitoring. Rats targeted adults on the nest and sometimes removed intact eggs, leaving little trace of their activity. Our results demonstrate that reducing rat predation can immediately improve the nesting success of even a common bird species in habitat with a long history of forest restoration. Sustained predator control may be critical to accelerating the recovery of native forest bird communities.

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Geologic map of the central-southeast flank of Mauna Loa Volcano, Island of Hawaii, Hawaii

Mauna Loa, the largest volcano on Earth, has erupted 33 times since written descriptions became available in 1832. Some eruptions began with only brief seismic unrest, while others followed several months to a year of increased seismicity. Once underway, its eruptions can produce lava flows that may reach the sea in less than 24 hours, severing roads and utilities. For example, lava flows erupted from the Southwest Rift Zone (SWRZ) in 1950 advanced at an average rate of 9.3 km per hour, and all three lobes reached the ocean within approximately 24 hours (Finch and Macdonald, 1953). Near the eruptive vents, the flows must have traveled even faster. In terms of eruption frequency, pre-eruption warning, and rapid flow emplacement, Mauna Loa poses an enormous volcanic-hazard threat to the Island of Hawai‘i. Volcanic hazards on Mauna Loa may be anticipated, and risk substantially mitigated, by documenting the past activity to refine our knowledge of the hazards and by alerting the public and local government officials of our findings and their implications for hazards assessments and risk. From the geologic record, we may deduce several generalized facts about the geologic history of the Northeast Rift Zone (NERZ). The middle to uppermost segments of the rift zone were more active in the past 4,000 years than the lower portion of the rift zone. This may be due to buttressing of the lower east rift zone by Mauna Kea and Kīlauea volcanoes. The historical flows that erupted on the north side of the rift zone advanced toward Hilo. This flank of the volcano may be more vulnerable to inundation. Lockwood (1990) noted that the vents of historical activity are migrating to the south. The volcano appears to have a self-regulating mechanism that evenly distributes long-term activity across its flanks. The geologic record also supports this notion; the time prior to the historical period (Age Group 1, pre-A.D. 1832 to 1,000 yrs B.P.; orange units) is dominated by activity on the south side of the NERZ. Although most Mauna Loa eruptions begin in the summit area at the 12,000-ft elevation (Lockwood and Lipman, 1987), the central-southeast flank has not been the source of any activity. All flows originated from the summit or the upper reaches of the Northeast Rift Zone (NERZ) or the Southwest Rift Zone (SWRZ). The NERZ was the source of eight flank eruptions since 1843. The NERZ extends from the 13,680-ft-high summit towards Hilo (population ~60,000; second-largest city in State of Hawaii). The northern portion of the map area is built entirely on flows erupted from the NERZ. The SWRZ extends from the summit towards Kalae (South Point) at sea level. The southern portion of the map area is built entirely on flows erupted from the SWRZ. The map area extends from the 10,350 -ft elevation on Mauna Loa’s east flank toward the Hawaii Volcanoes National Park and the town of Volcano (population approx. 2,000) in the northeast. At the south boundary of the map area is the town of Pāhala (population approx. 900). This map includes areas adjacent to and downslope of the NERZ and regions east of and directly downslope of Moku‘āweoweo, Mauna Loa’s summit caldera. The map encompasses 506 km 2 of the southeast flank (fig. 1) of Mauna Loa from 10,350 -ft elevation to sea level. The map of the central-southeast flank of Mauna Loa shows the distribution and relations of volcanic and surficial sedimentary deposits separated into 15 age groups ranging from a period greater than 50,000 yr B.P. to A.D. 1984. It incorporates previously reported work published in generalized small-scale maps (Lockwood and Lipman, 1987; Lockwood, 1995; Wolfe and Morris, 1996). This map is the second in a series of five maps that will cover Mauna Loa volcano. See SIM 2932-A at https://doi.org/10.3133/sim2932A . NOTE: Map sheet 1 contains lines and type with overprint. This feature may be turned on or off in the Adobe Acrobat page display preferences.

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Digital database of the geologic map of the middle east rift geothermal subzone, Kīlauea Volcano, Hawai‘i

This database release contains all the information used to produce Geologic Investigations Series I-2614 ( https://pubs.usgs.gov/imap/2614/ ). The main component of this digital release is a geodatabase prepared using ArcGIS, but Esri shapefiles are included as well. Kīlauea is an active shield volcano in the southeastern part of the Island of Hawai‘i. The middle East Rift Zone (MERZ) map includes about 27 square kilometers of the MERZ and shows the distribution of the products of 34 separate eruptions during late Holocene time. Lava flows erupted during 1983–86 have reached the mapped area. The subaerial part of the MERZ is 3–4 km wide and about 18 km long. It is a constructional ridge, 50–150 m above the adjoining terrain, marked by low spatter ramparts and cones as high as 60 m. Lava typically flowed either northeast or southeast, depending on vent location relative to the topographic crest of the rift zone. The MERZ receives more than 100 inches of rainfall annually and is covered by tropical rain forest. Vegetation begins to grow on lava a few months after its eruption. Relative heights of trees can be a guide to relative ages of underlying lava flows, but proximity to faults, presence of easily weathered cinders, and human activity also affect the rate of growth. The rocks have been grouped into five basic age groups. The framework for the ages assigned is provided by eight radiocarbon ages from nearby mapping by the authors and a single date from within this investigation area. The numerical ages are supplemented by observations of stratigraphic relations, degree of weathering, soil development, and vegetative cover.

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Undocumented late 18th- to early 19th-century volcanic eruptions in the Southwest Rift Zone of Kīlauea Volcano, Hawai‘i

The historical record of volcanic activity at Kīlauea Volcano on the Island of Hawaiʻi begins with the phreatomagmatic blasts of 1790. Three decades later, in 1823, the first party of non-Hawaiian visitors, organized by the English Reverend William Ellis, reached Kīlauea’s summit. A detailed narrative by Ellis includes an account of an eruption in Kīlauea’s Southwest Rift Zone that occurred shortly before his visit. In the absence of other source materials, the interval between the eruptions of 1790 and 1823 has been overlooked by geologists working at Kīlauea, with the presumption that little if anything took place volcanically outside of the summit caldera during that time. Careful stratigraphic observations combined with radiocarbon dating demonstrate that during these years a set of Southwest Rift Zone eruptions took place, including two that were long-lasting (weeks to months). Inclusion of these events gives a more complete historical (post-1790) record for Kīlauea and a better understanding of its eruptive behavior.

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Stream sediment geochemistry of four small drainages on the north shore of Kauai west of Hanalei

Geochemical compositions of fine-grained stream sediment from four drainages on the north shore of the island of Kauai, Hawaii, west of Hanalei and two back-beach sites were explored to increase understanding about land-based runoff and ecological risk from runoff to nearshore coral communities. Stream and beach sediment were collected between July 30 and August 2, 2016, and major, minor, and trace elements in the less than 63 micrometer-diameter fraction were analyzed by inductively coupled plasma optical emission spectroscopy and mass spectroscopy. The potentially toxic metals Cr, Cu, Ni, and Zn exceeded levels at which adverse biological effects could be observed; however, these metals seemed to be largely mineral-bound and thus were unlikely to harm organisms. Cd and Pb were below levels of ecological concern. Only a small amount of fine-grained sediment was retained on beaches west of Hanalei sampled in summer 2016 (mean=8.8 percent, median=0.4 percent, range=0–92.8 percent, n=41). Although the scarcity of fine-grained sediment precluded land-based runoff sourcing to the nearshore region, it did indicate that fine-grained sediment and associated contaminants did not accumulate over the long term in the sampled intertidal, subtidal, and reef-flat environments, which would reduce sediment-related pressures on coral communities there.

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The rupture process of the 2018 Mw 6.9 Hawaiʻi earthquake as imaged by a genetic algorithm-based back-projection technique

An episode of unrest began at Kīlauea in April 2018 that produced both significant volcanic output and high rates of seismicity, including a M w 6.9 earthquake on 4 May 2018. In this study, we image the rupture process of this earthquake using a genetic algorithm-based back-projection technique. The dominant feature of the earthquake is a slowly propagating western rupture, which shares similar characteristics with the region's largest recorded event in 1975 ( M w 7.7). The location of this western segment suggests that small asperities on this section of the décollement that frequently fail as slow slip events may achieve seismic slip rates when rupture is initiated on adjacent sections of the fault. Given the interaction between volcanic and seismic activity in this region, imaging the rupture properties of these events can improve our understanding of future geologic hazards in this region.

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Groundwater inflow toward a preheated volcanic conduit: Application to the 2018 eruption at Kīlauea Volcano, Hawai’i

The many successes in volcano forecasting over the past several decades owe mainly to pattern recognition, both in monitoring data and the geologic record. During the early stages of the 2018 Kīlauea eruption, the conceptual model of Stearns (1925), based on the explosive 1924 Kīlauea eruption, was highly influential. This model postulates that explosions are triggered by liquid-water inflow into a recently vacated magma conduit. Modern quantitative modeling approaches, supplemented by hydrogeologic data unavailable in 1925, yield a more nuanced view. Results demonstrate that liquid-water inflow would likely be delayed by months to years, owing to the inability of liquid water to transit a zone of very hot rock surrounding the conduit. The exercise demonstrates the use of physically based modeling to supplement traditional volcano-forecasting approaches during an ongoing event.

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Regeneration of Metrosideros polymorpha forests in Hawaii after landscape‐level canopy dieback

Questions (a) Have Metrosideros polymorpha trees become re‐established in Hawaiian forests previously impacted by canopy dieback in the 1970s? (b) Has canopy dieback expanded since the 1970s? (c) Can spatial patterns from this dieback be correlated with habitat factors to model future dieback in this area? Study Site An 83,603 ha study area on the eastern slopes of Mauna Loa and Mauna Kea volcanoes on the island of Hawaii, USA. Methods We analyzed very‐high‐resolution imagery to assess status of Metrosideros polymorpha forests across the eastern side of the island of Hawaii. We generated 1,170 virtual vegetation plots with a 100‐m radius; 541 plots in areas mapped in 1977 with trees dead or mostly defoliated (dieback), and 629 plots in adjacent wet forest habitat, previously mapped as non‐dieback condition. In each plot we estimated the frequency of M. polymorpha trees that were dead or mostly defoliated, and the frequency of trees with healthy crowns. These results were combined with habitat data to produce a spatial model depicting probability of canopy dieback within the study area. Results Seventy‐nine percent of plots mapped in 1977 in dieback condition recovered their canopy and were now considered in non‐dieback condition. Ninety‐one percent of plots in previous non‐dieback areas were found to still have a healthy M. polymorpha canopy in 2015. A spatial model allowed us to identify areas within the study area with high, medium, and low probability of experiencing this same type of canopy dieback in the future. Conclusions Most former dieback areas mapped within the study area in 1977 now show recovery of the tree canopy through growth of new cohorts of young M. polymorpha trees. This suggests these forest communities are resilient to this type of canopy loss and tree death so long as other factors do not disrupt the natural regeneration process.

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Controls on lava lake level at Halema‘uma‘u Crater, Kīlauea Volcano

The height of the lava column is a fundamental measure of open-vent volcanic activity, but little continuous long-term data exist to understand this parameter. The recent (2008-2018) lava lake activity at the summit of Kīlauea Volcano provides a unique opportunity to track and understand the processes that control lava level over timescales ranging from minutes to years. We review recently published data as well as analyze the long-term record of lava level at Kīlauea’s summit during 2009-2017. Longer timescale fluctuations, over days to months, have a strong positive linear correlation with ground deformation, suggesting they reflect pressure changes in the summit magma reservoir. Shorter timescale fluctuations, over minutes to hours, have an inverse relationship with spattering (i.e. outgassing) intensity at the lake surface – increased outgassing lowers the lake level and vice versa. Our analysis of the long-term lava level data thus confirms that lava level at Halemaʻumaʻu is controlled by these two types of processes: 1) those related to magma reservoir pressure changes (such as magma supply rate) and 2) shallow outgassing fluctuations (such as gas pistoning). Frequency filtering can isolate pressure- and outgassing-driven components of lava level change. Time series analysis indicates that there was no large, persistent periodicity in the lava level; a minor fortnightly oscillation might be related to Earth tides but was not continuously present. The remarkable correlation between lava level and deformation of the summit indicates that the lava lake acts as a reliable “piezometer”; tracking lava level over time may thus provide an indication of flank eruptive potential. We show that long-term interdisciplinary monitoring is necessary to discriminate the processes that control lava level.

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Long-term streamflow trends in Hawai‘i and implications for native stream fauna

Climate change has fundamentally altered the water cycle in tropical islands, which is a critical driver of freshwater ecosystems. To examine how changes in streamflow regime have impacted habitat quality for native migratory aquatic species, we present a 50‐year (1967–2016) analysis of hydrologic records in 23 unregulated streams across the five largest Hawaiian Islands. For each stream, flow was separated into direct run‐off and baseflow and high‐ and low‐flow statistics (i.e., Q10 and Q90) with ecologically important hydrologic indices (e.g., frequency of flooding and low flow duration) derived. Using Mann–Kendall tests with a running trend analysis, we determined the persistence of streamflow trends through time. We analysed native stream fauna from ~400 sites, sampled from 1992 to 2007, to assess species richness among islands and streams. Declines in streamflow metrics indicated a general drying across the islands. In particular, significant declines in low flow conditions (baseflows), were experienced in 57% of streams, compared with a significant decline in storm flow conditions for 22% of streams. The running trend analysis indicated that many of the significant downward trends were not persistent through time but were only significant if recent decades (1987–2016) were included, with an average decline in baseflow and run‐off of 10.90% and 8.28% per decade, respectively. Streams that supported higher native species diversity were associated with moderate discharge and baseflow index, short duration of low flows, and negligible downward trends in flow. A significant decline in dry season flows (May–October) has led to an increase in the number of no‐flow days in drier areas, indicating that more streams may become intermittent, which has important implications for mauka to makai (mountain to ocean) hydrological connectivity and management of Hawai'i's native migratory freshwater fauna.

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Facilitated adaptation for conservation – Can gene editing save Hawaii's endangered birds from climate driven avian malaria?

Avian malaria has played a significant role in causing extinctions, population declines, and limiting the elevational distribution of Hawaiian honeycreepers. Most threatened and endangered honeycreepers only exist in high-elevation forests where the risk of malaria infection is limited. Because Culex mosquito vectors and avian malaria dynamics are strongly influenced by temperature and rainfall, future climate change is predicted to expand malaria infection to high-elevation forests and intensify malaria infection at lower elevations, likely resulting in future extinctions and loss of avian biodiversity in Hawaii. Novel, landscape-level mosquito control strategies are promising, but are logistically challenging and require costly long-term efforts. As an alternative or supplemental strategy, we evaluated the potential of releasing a gene-edited malaria-resistant honeycreeper (Iiwi, Drepanis coccinea) in Hawaiian rainforests; a strategy known as facilitated adaptation. While this approach also has significant technical challenges and costs, it may offer a more permanent solution to increasing malaria threats. If malaria-resistant honeycreepers can be developed, facilitated adaptation may provide a practical strategy for the reestablishment of abundant avian populations in Hawaiian forests. A successful strategy could be the release of malaria-resistant Iiwi in mid-elevation forests where development of a resistant population has the best chance of success. Establishment of a resistant Iiwi population could provide a source for dispersal and development of resistant populations in high-elevation forests and a permanent source of resistant individuals for translocation to other vulnerable areas.

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Bryophyte abundance, composition and importance to woody plant recruitment in natural and restoration forests

Restoration of tropical forests can lead to enhanced ecosystem services and increases in native biodiversity. Bryophytes may be an integral part of the forest restoration process and can serve a critical role in forest functioning. However, the recovery of bryophytes and their ability to facilitate woody plant establishment during restoration remains poorly studied, especially in the tropics. We investigate how bryophyte abundance and community composition, as well as woody plant seedling associations with bryophyte mats and other ground cover types change from under the canopy of intact forest to under trees in restoration corridor plantings in Hawaii. Restoration corridors consisted of corridors of koa (Acacia koa) trees that were planted roughly 30 years ago. Some corridors were planted around remnant ʻōhiʻa trees (Metrosideros polymorpha) that can be several hundred years old. We sampled under ʻōhiʻa in intact forest and both koa and ʻōhiʻa trees in restoration corridors. In restoration corridors, bryophyte abundance was low relative to intact forest and species diversity was a subset of that found in intact forest despite restoration corridors being several decades old. Seedlings strongly associated with bryophytes across all habitats suggesting that bryophytes may significantly enhance forest seedling establishment when present in restoration corridors. Other ground cover types like woody litter and nurse logs also had a positive association with forest seedlings but were rare in restoration corridors. Grass remained a dominant ground cover type in restoration corridors under koa and remnant ʻōhiʻa trees and only a single seedling was ever found growing in this grass. Enhancing bryophyte growth and recovery within restoration plantings through the reduction of grass cover could facilitate native plant establishment.

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The evolving threat of rapid Ohia death (ROD) to Hawaii’s native ecosystems and rare plant species

Hawai‘i’s most widespread native tree, ‘ōhi‘a lehua ( Metrosideros polymorpha ), has been dying across large areas of Hawai‘i Island mainly due to two fungal pathogens ( Ceratocystis lukuohia and Ceratocystis huliohia ) that cause a disease collectively known as Rapid ‘Ōhi‘a Death (ROD). Here we examine patterns of positive detections of C. lukuohia as it has been linked to the larger mortality events across Hawai‘i Island. Our analysis compares the environmental range of C. lukuohia and its spread over time through the known climatic range and distribution of ‘ōhi‘a. Analyses show this fungal pathogen generally encompassed the core, but not the extremes of the climatic range of ‘ōhi‘a. We further modeled the potential distribution of C. lukuohia across the Hawaiian Archipelago to estimate the risk of ROD to other islands. Given the potential for C. lukuohia to alter the structure of ‘ōhi‘a dominated forests, we used our projected potential distribution of C. lukuohia to assess the risk of ROD to threatened and endangered plant species across Hawai‘i. Many native plants are likely vulnerable to these types of large ‘ōhi‘a mortality events: of 234 endangered native plant species considered, 147 (62.8%) have more than half of their range within current and expanding C. lukuohia suitable areas. We also found evidence that protecting habitat by fencing out introduced feral ungulates reduces the prevalence of the disease likely by reducing physical damage caused by these animals to ‘ōhi‘a trees, a precondition for Ceratocystis infection. Given the ongoing spread of C. lukuohia , we developed a dynamic web portal to host our results online, where models and analyses are updated with new lab-confirmed detections to provide managers with a useful tool to help monitor and assess the risk of C. lukuohia as it continues to spread.

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A high carbon content of the Hawaiian mantle from olivine-hosted melt inclusions

The deep mantle carbon content and flux are fundamental quantities in understanding global volatile cycles and distributions. Here, we present CO2 concentrations measured in 407 olivine-hosted melt inclusions from Hualalai, Kilauea, Koolau, Loihi, and Mauna Loa to constrain the Hawaiian mantle CO2 content and flux. Quantification of melt inclusion CO2 is complicated by the ubiquitous presence of vapor or “shrinkage” bubbles. The contribution from exsolved shrinkage bubble CO2 was determined from the measured bubble size and a CO2 equation of state, and added to the dissolved CO2 to reconstruct total melt inclusion CO2 concentrations. Bubbles typically contain ~90% of melt inclusion C, much of which may be sequestered in precipitated phases on bubble walls, and thus not amenable to measurement by Raman spectroscopy. Based on our dataset of total (dissolved + bubble) CO2 concentrations, we estimate that parental melts from the five Hawaiian volcanoes have CO2 concentrations ranging from 3900 to 10,000 ppm CO2. Among the active volcanoes, CO2 concentrations decrease to the northwest, likely reflecting mantle source heterogeneity, although differences in the depths of the magma chambers may also play a role. Mantle sources of the Hawaiian volcanoes range from 380 to 480 ppm CO2 suggesting that the Hawaiian plume is at least a factor of ~4 more C-rich than the MORB mantle. This enrichment is likely due to the presence of recycled surficial C and/or C-rich primitive material in the Hawaiian mantle.

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Explosive summit collapse of Kīlauea Volcano in 1924 preceded by a decade of crustal contamination and anomalous Pb isotope ratios

A geochemical time-series analysis of lavas from frequently active basaltic volcanoes has the potential to reveal the enigmatic mantle controls on volcanic behavior and hazards. In May 1924, the century-long lava lake within Halemaʻumaʻu pit crater at the summit of Kīlauea Volcano drained and the floor of Halemaʻumaʻu collapsed, triggering ∼3 weeks of phreatic explosions due to the interaction of groundwater with hot rock. For the next three decades, eruptions at Kīlauea were sporadic (the longest hiatus was from 1934 to 1952), small in volume, and short (typically <1 month long). Here, we show that the Pb isotope ratios of Kīlauea lava groundmass and tephra glass samples erupted from 1912 to 1954 are anomalous and unusually variable. Many of the samples have elevated 207 Pb/ 204 Pb ratios (at a given 206 Pb/ 204 Pb), ranging up to ∼0.05 higher than is typical for Kīlauea lavas. The variations in 206 Pb/ 204 Pb for samples from 1912–1913 (∼0.055), 1917–1921 (∼0.120), 1923 (∼0.065), and 1952–1954 (∼0.037) are larger over short time periods (∼1–4 yr) than observed during the Puʻu ʻŌʻō rift eruption (only ∼0.031 from 1986 to 2012). These Pb isotopic signatures resulted from variable amounts of crustal contamination (most likely by Pb-rich hydrothermal sulfide minerals with high 207 Pb/ 204 Pb ratios) as the parental magmas transited the ∼110 Ma Pacific oceanic crust. This crustal contamination was not directly related to the shallow volcanic events of 1924. Instead, mantle-driven processes at Kīlauea during the previous century—a factor of ∼2 decrease in the degree of partial melting of an increasingly refractory source—led to a decline in the magma supply rate, a major disruption of the magmatic plumbing system, and, for at least a decade prior to 1924, crustal contamination at or below the base of the volcanic edifice (>10 km). The Pb isotopic heterogeneity of the samples on short length (hand specimen to lava flow) and time (∼1–4 yr) scales can be explained by inefficient mixing as small batches of contaminated magma were delivered to the remnants of Kīlauea’s summit magma storage reservoir. Our results confirm that the Pb isotope ratios of basalts from ocean-island volcanoes may be significantly modified by assimilation of materials from the underlying oceanic crust. In particular, the 207 Pb/ 204 Pb ratio may be a sensitive tracer of such crustal contamination at Hawaiian shield volcanoes. Mauna Loa lavas display a factor of ∼5 more scatter towards higher 207 Pb/ 204 Pb at a given 206 Pb/ 204 Pb ratio than most Kīlauea lavas (excluding the samples from 1912 to 1954). This might be caused by more pervasive crustal contamination at Mauna Loa due to its lower magma supply rate over the last ∼4 kyr.

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Direct measurements of copper speciation in basaltic glasses: Understanding the relative roles of sulfur and oxygen in copper complexation in melts

Micro-analytical determination of copper (Cu) speciation in natural magmatic glasses, equilibrated below the nickel – nickel oxide (NNO) buffer, reveals that two copper species are commonly stabilized in such basaltic melts. X-ray absorption fine structure (XAFS) spectroscopic analysis of basaltic matrix glasses and melt inclusions (MI) from samples of mid-ocean ridge basalt (MORB), and from Nyamuragira, Etna and Kīlauea volcanoes show that both Cu(I)-sulfide and Cu(I)-oxide species are stabilized. The proportion of each species correlates with the measured sulfur (S) abundance of the glass. In glasses with S abundances greater than ~1000 ppm, Cu(I)-sulfide species are dominant, whereas in glasses with S abundances between 500 and 1000 ppm, both species are found to coexist. The Cu(I)-oxide species dominate at S concentrations below 500 ppm. In 1 atm S-free experimental glasses of basaltic composition that we analyzed, only Cu(I)-oxide species are detectable, regardless of the oxygen fugacity (fO2), even at relatively high fO2 values well above the NNO buffer. Our results demonstrate that XAFS techniques are highly sensitive in measuring Cu speciation in reduced (below NNO) basaltic glasses and that both oxide and sulfide complexes can be stabilized. The relative proportion of these two species is highly dependent on the concentration of S in the melt, and thus the Cu speciation in natural melts changes as S is lost from the melt by low pressure degassing.

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Factors promoting the recolonization of Oahu, Hawaii, by Bristle-thighed Curlews

Suitable habitat for Arctic-breeding migratory shorebirds is decreasing at their traditional wintering islands and atolls in the Central Pacific Flyway (i.e., Oceania) due to habitat degradation, reclamation, and sea-level rise. To maintain the size and resiliency of their populations, migratory shorebirds will need to expand their winter ranges by either colonizing new sites or recolonizing old sites from which they were extirpated. Bristle-thighed Curlews (Numenius tahitiensis) are long-distance migratory shorebirds that breed only in Alaska and winter across a vast region of the Central Pacific, typically on remote, unpopulated islands and atolls. Historically, Bristle-thighed Curlews were considered uncommon transients on the main Hawaiian Islands, but in the mid-1990s, curlews became regular visitors to Oahu and subsequently began wintering at the James Campbell National Wildlife Refuge on Oahu Island in Hawaii. Curlew numbers at this site grew steadily from <5 birds in the mid-1990s to an estimated 126 winter residents (95%CI 108–147) in 2013–2014. Timing of the recolonization event coincided with the establishment of a fenced pond complex that was managed for endangered waterbirds by maintaining areas of shallow water and low vegetation. High rates of apparent annual survival exhibited by adults and subadults (0.86–0.95) confirmed the suitability of the Refuge to curlews. Our results suggest that curlews in Oceania can naturally recolonize wintering islands, a trait that may be key to the survival of this species of conservation concern in an era of rising sea levels.

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