Crystals of coexisting alunite and jarosite, Goldfield, Nevada
Alunite (KAl 3 (SO 4 ) 2 (OH) 6 ) and jarosite (KFe 3 (SO 4 ) 2 (OH) 6 ) coexist in optically continuous crystals in a sample from the Goldfield mining district, Esmeralda County, Nev. Beam scans with an electron microprobe indicate that no intermediate minerals of the solid-solution series alunite-jarosite occur in these crystals. An Eh-pH diagram demonstrating the equilibrium relations between alunite, jarosite, and geothite suggests the crystals most likely developed by a rise in Eh, which oxidized ferrous to ferric iron, thus allowing jarosite to precipitate.
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