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Geochemical and isotopic composition of ground water with emphasis on sources of sulfate in the upper Floridan Aquifer in parts of Marion, Sumter, and Citrus counties, Florida

In inland areas of northwest central Florida, sulfate concentrations in the Upper Floridan aquifer are extremely variable and sometimes exceed drinking water standards (250 milligrams per liter). This is unusual because the aquifer is unconfined and near the surface, allowing for active recharge. The sources of sulfate and geochemical processes controlling ground-water composition were evaluated in this area. Water was sampled from thirty-three wells in parts of Marion, Sumter, and Citrus Counties, within the Southwest Florida Water Management District; these included at least a shallow and a deep well at fifteen separate locations. Ground water was analyzed for major ions, selected trace constituents, dissolved organic carbon, and stable isotopes (sulfur-34 of sulfate and sulfide, carbon-13 of inorganic carbon, deuterium, and oxygen-18). Sulfate concentrations ranged from less than 0.2 to 1,400 milligrams per liter, with higher sulfate concentrations usually in water from deeper wells. The samples can be categorized into a low sulfate group (less than 30 milligrams per liter) and a high sulfate group (greater than 30 milligrams per liter). For the high sulfate waters, concentrations of calcium and magnesium increased concurrently with sulfate. Chemical and isotopic data and mass-balance modeling indicate that the composition of high sulfate waters is controlled by dedolomitization reactions (dolomite dissolution and calcite precipitation, driven by dissolution of gypsum). Gypsum occurs deeper in the aquifer than open intervals of sampled wells. Upward flow has been documented in deeper parts of the aquifer in the study area, which may be driven by localized discharge areas or rapid flow in shallow parts of the aquifer. Mixing between shallow ground water and sulfate-rich water that dissolved gypsum at the base of the aquifer is probably responsible for the range of concentrations observed in the study area. Other solutes that increased with sulfate apparently originate from the gypsum itself, from other mineral assemblages found deeper in the aquifer in association with gypsum, and from residual seawater from less-flushed, deeper parts of the aquifer. These ions are subsequently transported with sulfate to shallower parts of the aquifer where gypsum is not present. The composition of low sulfate ground water is controlled by differences in the extent of microbially mediated reactions, which produce carbon dioxide. This, in turn, influences the extent of calcite dissolution. Ground waters which underwent limited microbial reactions contained dissolved oxygen and were usually in ridge areas where recharge typically is rapid. Anaerobic waters were in lower lying areas of Sumter County, where soils are poorly drained and aquifer recharge is slow. Anaerobic waters had higher concentrations of calcium, bicarbonate, sulfide, dissolved organic carbon, iron, manganese, and silica, and had lower concentrations of nitrate than aerobic ground waters. For low sulfate waters, sulfate generally originates from meteoric sources (atmospheric precipitation), with variable amounts of oxidation of reduced sulfur and sulfate reduction. Sulfide is sometimes removed from solution, probably by precipitation of a sulfide minerals such as pyrite. In areas where deep ground water has low sulfate concentrations, the shallow flow system is apparently deeper than where high sulfate concentrations occur, and upwelling of sulfate-rich water is negligible. The range of sulfate concentrations observed in the study area and differences in sulfate concentrations with depth indicate a complex interaction between shallow and deep ground-water flow systems.

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Simulation of subsurface storage and recovery of treated effluent injected in a saline aquifer, St. Petersburg, Florida

The potential for subsurface storage and recovery of treated effluent into the uppermost producing zone (zone A) of the Upper Floridan aquifer in St. Petersburg, Florida, is being studied by the U.S. Geological Survey, in cooperation with the city of St. Petersburg and the Southwest Florida Water Management District. A measure of the success of this practice is the recovery efficiency, or the quantity of water relative to the quantity injected, that can be recovered before the water that is withdrawn fails to meet water-quality standards. The feasibility of this practice will depend upon the ability of the injected zone to receive, store, and discharge the injected fluid. A cylindrical model of ground-water flow and solute transport, incorporating available data on aquifer properties and water quality, was developed to determine the relation of recovery efficiency to various aquifer and fluid properties that could prevail in the study area. The reference case for testing was a base model considered representative of the saline aquifer underlying St. Petersburg. Parameter variations in the tests represent possible variations in aquifer conditions in the area. The model also was used to study the effect of various cyclic injection and withdrawal schemes on the recovery efficiency of the well and aquifer system. A base simulation assuming 15 days of injection of effluent at a rate of 1.0 million gallons per day and 15 days of withdrawal at a rate of 1.0 million gallons per day was used as reference to compare changes in various hydraulic and chemical parameters on recovery efficiency. A recovery efficiency of 20 percent was estimated for the base simulation. For practical ranges of hydraulic and fluid properties that could prevail in the study area, the model analysis indicates that (1) the greater the density contrast between injected and resident formation water, the lower the recovery efficiency, (2) recovery efficiency decreases significantly as dispersion increases, (3) high formation permeability favors low recovery efficiencies, and (4) porosity and anisotropy have little effect on recovery efficiencies. In several hypothetical tests, the recovery efficiency fluctuated between about 4 and 76 percent. The sensitivity of recovery efficiency to variations in the rate and duration of injection (0.25, 0.50, 1.0, and 2.0 million gallons per day) and withdrawal cycles (60, 180, and 365 days) was determined. For a given operational scheme, recovery efficiency increased as the injection and withdrawal rate is increased. Model results indicate that recovery efficiencies of between about 23 and 37 percent can be obtained for different subsurface storage and recovery schemes. Five successive injection, storage, and recovery cycles can increase the recovery efficiency to about 46 to 62 percent. There is a larger rate of increase at smaller rates than at larger rates. Over the range of variables studied, recovery efficiency improved with successive cycles, increasing rapidly during initial cycles then more slowly at later cycles. The operation of a single well used for subsurface storage and recovery appears to be technically feasible under moderately favorable conditions; however, the recovery efficiency is highly dependent upon local physical and operational parameters. A combination of hydraulic, chemical, and operational parameters that minimize dispersion and buoyancy flow, maximizes recovery efficiency. Recovery efficiency was optimal where resident formation water density and permeabilities were relatively similar and low.

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Hydraulic characteristics and nutrient transport and transformation beneath a rapid infiltration basin, Reedy Creek Improvement District, Orange County, Florida

The Reedy Creek Improvement District disposes of about 7.5 million gallons per day (1992) of reclaimed water through 85 1-acre rapid infiltration basins within a 1,000-acre area of sandy soils in Orange County, Florida. The U.S. Geological Survey conducted field experiments in 1992 at an individual basin to examine and better understand the hydraulic characteristics and nutrient transport and transformation of reclaimed water beneath a rapid infiltration basin. At the time, concentrations of total nitrogen and total phosphorus in reclaimed water were about 3 and 0.25 milligrams per liter, respectively. A two-dimensional, radial, unsaturated/saturated numerical flow model was applied to describe the flow system beneath a rapid infiltration basin under current and hypothetical basin loading scenarios and to estimate the hydraulic properties of the soil and sediment beneath a basin. The thicknesses of the unsaturated and saturated parts of the surficial aquifer system at the basin investigated were about 37 and 52 feet, respectively. The model successfully replicated the field-monitored infiltration rate (about 5.5 feet per day during the daily flooding periods of about 17 hours) and ground-water mounding response during basin operation. Horizontal and vertical hydraulic conductivity of the saturated part of the surficial aquifer system were estimated to be 150 and 45 feet per day, respectively. The field-saturated vertical hydraulic conductivity of the shallow soil, estimated to be about 5.1 feet per day, was considered to have been less than the full-saturation value because of the effects of air entrapment. Specific yield of the surficial aquifer was estimated to be 0.41. The upper 20 feet of the basin subsurface profile probably served as a system control on infiltration because of the relatively low field-saturated, vertical hydraulic conductivity of the sediments within this layer. The flow model indicates that, in the vicinity of the basin, flow in the deeper, saturated zone was relatively slow compared to the more vigorous flow in the shallow saturated zone. The large radial component of flow below the water table in the vicinity of the basin implies that reclaimed water moves preferentially in the shallow part of the saturated zone upon reaching the water table. Therefore, there may be some vertical stratification in the saturated zone, with recently infiltrated water overlying ambient water. The infiltration capacity at the basin would be unaffected by a small (less than 10 feet) increase in background water-table altitude, because the water table would remain below the system control on infiltration. However, water-table rises of 15 and 20 feet were estimated to reduce the infiltration capacity of the basin by 8 and 25 percent, respectively. Model simulations indicate that increasing ponded depth within the basin from 4 to 12 inches and from 4 to 24 inches would increase basin infiltration capacity by less than 6 and 11 percent, respectively. A loading strategy at the basin that relies on long, uninterrupted flooding was shown to offer the possibility of inducing a more anaerobic environment conducive to denitrification while maintaining reclaimed-water disposal capacity. Field measurements indicated that transient, elevated concentrations or "spikes" of nitrate (as high as 33 milligrams per liter as nitrogen) occurred at the leading edge of the infiltrating water and in the shallow saturated zone following a prolonged basin rest period. This phenomenon probably is the result of mineralization and nitrification of organic nitrogen retained within the subsurface during earlier basin loading events. The organic nitrogen was retained in the shallow soil (due to adsorption/straining) and the shallow saturated zone (due to deposition under slacking pore-water velocity). The magnitude of the nitrate spikes appears to be influenced by the scheduling of basin loading, with short flooding and resting periods being most favorable to minimization of nitrate spikes. Removal of nitrogen by denitrification from the percolating reclaimed water is minimal in the vicinity of the basin, probably because of the lack of reducing conditions and a relative paucity of organic carbon substrates. It is speculated that longer flooding periods could induce reducing conditions that would be favorable for nitrogen removal from the system, but probably would lead to more pronounced nitrate spiking. Phosphorus concentrations were decreased by about 90 percent from concentrations in reclaimed water after moving through the upper 15 feet of the soil profile. This most likely was a result of adsorption onto abundant iron and aluminum hydrous oxyhydroxide coatings on sand grains. However, some phosphorus (coarse fraction, organic) passes through the shallow soil and accumulates below the water table under slacking pore-water velocity. This phosphorus is immobilized by adsorption, fixation, or precipitation reactions during basin rest periods.

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The potential for water-quality degradation of interconnected aquifers in west-central Florida

Thousands of deep artesian wells were drilled into the Upper Floridan aquifer in west-central Florida prior to well-drilling regulations adopted in the 1970's. The wells were usually completed with a short length of casing through the unconsolidated sediments and were left open to multiple aquifers containing water of varying quality. These open boreholes serve as a potential source of water-quality degradation within the aquifers when vertical internal borehole flow is induced by hydraulic-head differences. This potential for water-quality degradation exists in west-central Florida where both the intermediate aquifer system and Upper Floridan aquifer exist. Measurements of caliper, temperature, gamma, fluid conductivity, and flow were obtained in 87 wells throughout west-central Florida to determine the occurrence of interaquifer borehole flow between the intermediate aquifer system and the Upper Floridan aquifer. Flow measurements were made using an impeller flowmeter, a heat-pulse flowmeter, and a video camera with an impeller flowmeter attachment. Of the 87 wells measured with the impeller flowmeter, 17 had internal flow which ranged from 10 to 300 gallons per minute. A heat-pulse flowmeter was used in 19 wells in which flow was not detected using the impeller flowmeter. Of these 19 wells, 18 had internal flow which ranged from 0.3 to 10 gallons per minute. Additionally, water-quality samples were collected from specific contributing zones in wells that had internal flow. Analysis of geophysical and water-quality data indicates degradation of water quality has occurred from mineralized ground water flowing upward from the Upper Floridan aquifer into the intermediate aquifer system through both uncased boreholes and corroded black-iron well casings. In areas where there is a downward component of flow, data indicate that potable water from the intermediate aquifer system is artificially recharging the Upper Floridan aquifer through open boreholes. A geographical area was defined where there is a potential for water-quality degradation due to improperly cased wells. This area was delineated based on where there is an upward component of ground-water flow and where there is an occurrence of poor-quality water. The delineated area includes parts of Hillsborough, Manatee, Sarasota, Charlotte, De Soto, and Hardee Counties. To prevent further contamination of the aquifers, the Southwest Florida Water Management District began the Quality of Water Improvement Program in 1974 to restore hydrologic conditions altered by improperly constructed wells or deteriorating casings. As of May 1994, more than 3,000 wells have been inspected and approximately 1,350 have been plugged. To minimize interaquifer contamination, existing wells, especially ones with black-iron casing, should be inspected and, if necessary, repaired with new casing or plugged.

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Hydrogeology of the surficial and intermediate aquifer systems in Sarasota and adjacent counties, Florida

From 1991 to 1995, the hydrogeology of the surficial aquifer system and the major permeable zones and confining units of the intermediate aquifer system in southwest Florida was studied. The study area is a 1,400-square-mile area that includes Sarasota County and parts of Manatee, De Soto, Charlotte, and Lee Counties. Lithologic, geophysical, hydraulic property, and water-level data were used to correlate the hydrogeology and map the extent of the aquifer systems. Water chemistry was evaluated in southwest Sarasota County to determine salinity of the surficial and intermediate aquifer systems. The surficial aquifer is an unconfined aquifer system that overlies the intermediate aquifer system and ranges from a few feet to over 60 feet in thickness in the study area. Hydraulic properties of the surficial aquifer system determined from aquifer and laboratory tests, and model simulations vary considerably across the study area. The intermediate aquifer system, a confined aquifer system that lies between the surficial and the Upper Floridan aquifers, is composed of alternating confining units and permeable zones. The intermediate aquifer system has three major permeable zones that exhibit a wide range of hydraulic properties. Horizontal flow in the intermediate aquifer system is northeast to southwest. Most of the study area is in a discharge area of the intermediate aquifer system. Water ranges naturally from fresh in the surficial aquifer system and upper permeable zones of the intermediate aquifer system to moderately saline in the lower permeable zone. Water-quality data collected in coastal southwest Sarasota County indicate that ground-water withdrawals from major pumping centers have resulted in lateral seawater intrusion and upconing into the surficial and intermediate aquifer systems.

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Methods for estimating low-flow characteristics of ungaged streams in selected areas, northern Florida

Methods for estimating low-flow frequency characteristics at ungaged sites were developed for two areas in northern Florida. In the Yellow, Blackwater, Escambia, and Perdido River Basins study area (northwestern Florida), regional regression equations were developed for estimating the 7- and 30-day, 2- and 10-year low-flow characteristic (Q7,2, Q7,10, Q30,2, and Q30,10) by determining values of basin characteristics from digital Geographical Information System (GIS) coverages or hardcopy maps. A GIS, ARC-INFO, was used to quantify basin characteristics that were used in regression equations. Sources of digital data used in this analysis are elevation data, from a digital elevation model, stream length and location data from a digital hydrography coverage, and watershed boundaries digitized from topographic maps. The most accurate regression equations employed a basin characteristic that was based on a simple conceptual model of one- dimensional ground-water flow using Darcy's law. Slightly less accurate equations were obtained using drainage area as the only explanatory variable. The standard error of prediction for the Darcy and drainage area equations of Q7,2 was 65 and 74 percent, respectively; Q7,10, 58 and 62 percent, respectively; Q30,2, 51 and, 54 percent, respectively; and Q30,10, 44 and 51 percent, respectively. In the Santa Fe River Basin study area (northeastern Florida), a flow-routing method was used to estimate low-flow characteristics at ungaged sites from low stream- flow analyses based on records at gaged sites. The use of the flow-routing method is suggested for areas where regression analysis proves unsuccessful, where low-flow characteristics have been defined at a significant number of sites, and where information about the basin characteristics has been thoroughly researched. Low-flow frequency characteristics determined at 40 sites and measurements made during five synoptic runs in 1989-91 were used to develop a flow-routing method. Low-flow frequency characteristics and drainage areas were used to define river profiles for major streams within the Santa Fe River Basin. These river profiles serve as indicators of changes in a stream's low-flow characteristics with respect to change in drainage area. Unit low flows were also determined for each site where low-flow characteristics were determined. Areas of zero flow were defined for Q7,2 and Q7,10 conditions based on measurements made during synoptic runs and from low-flow frequency analyses. The flow-routing method uses the drainage areas to interpolate low-flow values between or near gaged sites on the same stream. Low-flow values are transferred from a gaged site, either upstream or downstream, to the ungaged site. A step-by-step process for flow routing must be made when tributary or other inflow enter a stream. The strength of the flow-routing method is that the values at gaged sites reflect the overall basin characteristics in the vicinity of the gaged sites. However, the accuracy of low-flow estimates may be less in areas of decreasing and increasing flow if sufficient data are not available to assess changing hydraulic and hydrologic conditions.

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Geochemical and isotopic composition of ground water, with emphasis on sources of sulfate, in the upper Floridan aquifer and intermediate aquifer system in southwest Florida

In southwest Florida, sulfate concentrations in water from the Upper Floridan aquifer and overlying intermediate aquifer system are commonly above 250 milligrams per liter (the drinking water standard), particularly in coastal areas. Possible sources of sulfate include dissolution of gypsum from the deeper part of the Upper Floridan aquifer or the middle confining unit, saltwater in the aquifer, and saline waters from the middle confining unit and Lower Floridan aquifer. The sources of sulfate and geochemical processes controlling ground-water composition were evaluated for the Peace and Myakka River Basins and adjacent coastal areas of southwest Florida. Samples were collected from 63 wells and a saline spring, including wells finished at different depth intervals of the Upper Floridan aquifer and intermediate aquifer system at about 25 locations. Sampling focused along three ground-water flow paths (selected based on a predevelopment potentiometric-surface map). Ground water was analyzed for major ions, selected trace constituents, dissolved organic carbon, and stable isotopes (delta deuterium, oxygen-18, carbon-13 of inorganic carbon, and sulfur-34 of sulfate and sulfide); the ratio of strontium-87 to strontium-86 was analyzed for waters along one of the flow paths. Chemical and isotopic data indicate that dedolomitization reactions (gypsum and dolomite dissolution and calcite precipitation) control the chemical composition of water in the Upper Floridan aquifer in inland areas. This is confirmed by mass-balance modeling between wells in the shallowest interval in the aquifer along the flow paths. However, gypsum occurs deeper in the aquifer than these wells. Upwelling of sulfate-rich water that previously dissolved gypsum in deeper parts of the aquifer is a more likely source of sulfate than gypsum dissolution in shallow parts of the aquifer. This deep ground water moves to shallower zones in the aquifer discharge area. Saltwater from the Upper Floridan aquifer has not dissolved significant amounts of gypsum compared to fresher water in the aquifer. This is consistent with a shallow seawater source for the saltwater, rather than a deeper source from the underlying middle confining unit or Lower Floridan aquifer, which would have elevated sulfate concentrations. Ion exchange and dolomitization may be important reactions for saltwater in the aquifer. According to geochemical modeling, the freshwater end member for water in the saltwater mixing zone in the southwestern part of the study area is not upgradient water from the Upper Floridan aquifer that dissolved gypsum. Instead, this water appears to be isolated from the regional freshwater flow system and may be part of a more localized flow system. The chemical and isotopic composition of water in the intermediate aquifer system is controlled by differences in extent of reactions with aquifer minerals, upward leakage from the Upper Floridan aquifer, and saltwater mixing. In inland areas, water generally is characterized by relatively low sulfate concentrations (less than 250 milligrams per liter) and differences in extent of carbonate mineral dissolution. Some inland waters have elevated chloride concentrations, which may be related to evaporation prior to recharge. In coastal Sarasota County and in isolated inland areas, water from the intermediate aquifer system has high sulfate concentrations characteristic of dedolomitization waters from the Upper Floridan aquifer. The chemical and isotopic composition of these waters is controlled by upward leakage from the Upper Floridan aquifer, which naturally occurs in the discharge area but may be locally enhanced by pumping or interconnection of wells open to both aquifer systems. In western Charlotte County, the waters are dominated by sodium and chloride, and their compositions are consistent with mixing between saltwater and inland intermediate aquifer system water that has not been influenced by discharge from the

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Evaluation and modification of five techniques for estimating stormwater runoff for watersheds in west-central Florida

Several traditional techniques have been used for estimating stormwater runoff from ungaged watersheds. Applying these techniques to watersheds in west-central Florida requires that some of the empirical relations be extrapolated beyond tested ranges. As a result, there is uncertainty as to the accuracy of these estimates. Sixty-six storms occurring in 15 west-central Florida watersheds were initially modeled using the Rational Method, the U.S. Geological Survey Regional Regression Equations, the Natural Resources Conservation Service TR-20 model, the U.S. Army Corps of Engineers HEC-1 model, and the U.S. Environmental Protection Agency Storm Water Management Model. The techniques were applied according to the guidelines specified in the user manuals or standard engineering textbooks as though no field data were available and the selection of input parameters was not influenced by observed data. Computed estimates were compared with observed runoff to evaluate the accuracy of the techniques. One watershed was eliminated from further evaluation when it was determined that the area contributing runoff to the stream varies with the amount and intensity of rainfall. Therefore, further evaluation and modification of the input parameters were made for only 62 storms in 14 watersheds. Runoff ranged from 1.4 to 99.3 percent of rainfall. The average runoff for all watersheds included in this study was about 36 percent of rainfall. The average runoff for the urban, natural, and mixed land use watersheds was about 41, 27, and 29 percent of rainfall, respectively. Initial estimates of peak discharge using the Rational Method produced average watershed errors that ranged from an underestimation of 50.4 percent to an overestimation of 767 percent. The coefficient of runoff ranged from 0.20 to 0.60. Calibration of the technique produced average errors that ranged from an underestimation of 3.3 percent to an over estimation of 1.5 percent. The average calibrated coefficient of runoff for each watershed ranged from 0.02 to 0.72. The average values of the coefficient of runoff necessary to calibrate the urban, natural, and mixed land use watersheds were 0.39, 0.16, and 0.08, respectively. The U.S. Geological Survey regional regression equations for determining peak discharge produced errors that ranged from an underestimation of 87.3 percent to an overestimation of 1,140 percent. The regression equations for determining runoff volume produced errors that ranged from an underestimation of 95.6 percent to an overestimation of 324 percent. Regression equations developed from data used for this study produced errors that ranged between an underestimation of 82.8 percent and an overestimation of 328 percent for peak discharge and from an underestimation of 71.2 percent to an overestimation of 241 percent for runoff volume. Use of the equations developed for west-central Florida streams produced average errors for each type of watershed that were lower than errors associated with use of the U.S. Geological Survey regional equations. Initial estimates of peak discharges and runoff volumes using the Natural Resources Conservation Service TR-20 model, produced average errors of 44.6 and 42.7 percent, respectively, for all the watersheds. Curve numbers and times of concentration were adjusted to match estimated and observed peak discharges and runoff volumes. The average change in the curve number for all the watersheds was a decrease of 2.8 percent. The average change in the time of concentration was an increase of 59.2 percent. The shape of the input dimensionless unit hydrograph also had to be adjusted to match the shape and peak time of the estimated and observed flood hydrographs. Peak rate factors for the modified input dimensionless unit hydrographs ranged from 162 to 454. The mean errors for peak discharges and runoff volumes were reduced to 18.9 and 19.5 percent, respectively, using the average calibrated input parameters for each watershed. Initial estimates of peak discharges and runoff volumes using the U.S. Army Corp of Engineers Hydrologic Engineering Center-1 model, produced average errors of 105 and 26.8 percent respectively, for all the watersheds. Curve numbers and lag times were adjusted to match estimated and observed peak discharges and runoff volumes. The average change in the curve number for all the watersheds was a decrease of 2.5 percent. The average change in the lag time was an increase of 169 percent. The mean errors for peak discharges and runoff volumes were reduced to 5.8 and 1.4 percent, respectively, using the average calibrated input parameters for each watershed. The observed and estimated peak discharges and runoff volumes could be matched by adjusting curve numbers and lag time using the U.S. Army Corp of Engineers Hydrologic Engineering Center-1 model; however, the shape of the estimated flood hydrograph and timing of the peak could not be matched. The input dimensionless unit hydrograph must also be changed to increase the accuracy of the Hydrologic Engineering Center-1 model for watersheds in west-central Florida. The source code has to be modified and recompiled to enter different dimensionless unit hydrographs into the HEC-1 program. During application of the U.S. Environmental Protection Agency Storm Water Management Model, two separate infiltration methods were evaluated. Initial estimates of peak discharges and runoff volumes produced mean errors of 46.5 and 6.8 percent, respectively, for all watersheds using the Green-Ampt infiltration method, and 48.8 and 9.5 percent, respectively, using the Horton infiltration method. The mean errors were reduced to 18 and 0.3 percent for the Green-Ampt method and 20.9 and 7.2 percent for the Horton method using the average calibrated input parameters for each watershed. Estimates of peak discharges and runoff volumes were initially made for watersheds in west-central Florida using recommended procedures, then compared to observed peak discharges and runoff volumes. Subsequently, the procedures were modified to increase accuracy for this area. The same methods used during the study could be used in other parts of the world to evaluate the accuracy of standard methods for estimating stormwater runoff.

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Assessment of the fresh- and brackish-water resources underlying Dunedin and adjacent areas of northern Pinellas County, Florida

The city of Dunedin is enhancing their potable ground-water resources through desalination of brackish ground water. An assessment of the fresh- and brackish-water resources in the Upper Floridan aquifer was needed to estimate the changes that may result from brackish-water development. The complex hydrogeologic framework underlying Dunedin and adjacent areas of northern Pinellas County is conceptualized as a multilayered sequence of permeable zones and confining and semiconfining units. The permeable zones contain vertically spaced, discrete, water-producing zones with differing water quality. Water levels, water-level responses, and water quality are highly variable among the different permeable zones. The Upper Floridan aquifer is best characterized as a local flow system in most of northern Pinellas County. Pumping from the Dunedin well field is probably not influencing water levels in the aquifer outside Dunedin, but has resulted in localized depressions in the potentiometric surface surrounding production-well clusters. The complex geologic layering combined with the effects of production-well distribution probably contribute to the spatial and temporal variability in chloride concentrations in the Dunedin well field. Chloride concentrations in ground water underlying the Dunedin well field vary both vertically and laterally. In general, water-quality rapidly changes below depths of 400 feet below sea level. Additionally, randomly distributed water-producing zones with higher chloride concentrations may occur at shallow, discrete intervals above 400 feet. A relation between chloride concentration and distance from St. Joseph Sound is not apparent; however, a possible relation exists between chloride concentration and production-well density. Chloride-concentration data from production wells show a consistently increasing pattern that has accelerated since the late 1980's. Chloride-concentration data from 15 observation wells show increasing trends for 6 wells, decreasing trends for 3 wells, and no trend for 6 wells. The current and future, fresh- and brackish-water resources were evaluated using a numerical ground-water flow and solute-transport model. Simulation results indicate that the hydraulic conductivity of the uppermost permeable zone (upper zone A) of the Upper Floridan aquifer is four times greater than the two underlying permeable zones (lower zone A and zone B). The simulated hydraulic conduc- tivities of the semiconfining units are four orders of magnitude less than the permeable zones. Simulation results show the importance of semiconfining units as a mechanism for retarding the vertical movement of higher salinity ground water. Simulation results indicate that pumping from the brackish-water zone does not negatively influence the chloride-concentration trends in the overlying fresh-water zone; however, chloride changes in the fresh-water zone will continue to occur due to the continuation of current fresh-water withdrawals. Chloride changes in the brackish-water zone will occur from pumping brackish water.

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Magnitude and frequency of floods in the Suwannee River Water Management District, Florida

Flood-frequency statistics for 2-, 5-, 10-, 25-, 50-. 100-, 200-, and 500-year recurrence intervals, based on three methods of analysis, are presented for 25 continuous-record and seven peak flow partial-record gaging stations in the Suwannee River Water Management District. The first method, for gaged stations, utilizes station records; the second method, for ungaged sites, utilizes regional regression analysis; and the third method uses a weighted combination of the station and regional values. Because the weighted values utilize two more or less independent estimates of the peak flow statistic, they are considered more accurate than the station estimates or the regression estimates alone. Also, the use of another weighting scheme to improve estimates of flood frequency statistics at ungaged sites is demonstrated. The karstic nature of much of the Suwannee River Water Management District significantly attenuates flood peaks in some streams by providing substantial subsurface storage when river stages are high. At such times, springs discharging into rivers may reverse flow temporarily and become sinks.

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Water-quality assessment of southern Florida: An overview of available information on surface- and ground-water quality and ecology

This report summarizes water-quality conditions, issues of concern, and management efforts underway in southern Florida. The report is designed to provide a conceptual framework for the Southern Florida National Water Quality Assessment (NAWQA) study that began in 1994. The report makes reference to the most important water-quality literature pertaining to southern Florida, to water-quality studies that are underway or planned, and to topics which are of high priority in the study unit. These topics include: the availability and suit ability of water for competing demands; nutrient enrichment of the Everglades; transport, degradation, and effects of pesticides; and the sources and cycling of mercury in the ecosystem. The report also includes a retrospective analysis and conceptual presentation of nutrient loading, which is a high priority for the national NAWQA Program and for regional water-quality managers. Nutrient contributions from point and nonpoint sources are estimated for nine basins in the study area and are discussed in relation to land use. Fertilizer is the dominant source of phosphorus in eight basins and the dominant source of nitrogen in at least five basins. Atmospheric sources of nitrogen contribute more than 20 percent of the total nitrogen input to all basins and are the dominant source of nitrogen input to Lake Okeechobee and the Everglades. Nutrient loads are also estimated in selected canal and river outflows in southern Florida to provide a spatial overview of the magnitude of nutrient loading to coastal waters. Annual phosphorus loads from the Peace River are the highest in the study unit; annual phosphorus loads from the Caloosahatchee River and the major Palm Beach canals are also high, compared to other parts of southern Florida. Estimated annual loads of phosphorus from parts of the Big Cypress Basin and the S-12 water-control structures of the Tamiami Canal are low compared with estimated phosphorus loads in outflows in the northern part of the study unit. Annual nitrogen loads in southern Florida were highest in outflows from the Caloosahatchee River Basin and the major Palm Beach canals. Nitrogen loads in outflows from parts of the Big Cypress subbasin were lower than those estimated to the north.

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Assessment of saltwater intrusion in southern coastal Broward County, Florida

Of the counties in southeastern Florida, Broward County has experienced some of the most severe effects of saltwater intrusion into the surficial Biscayne aquifer because, before 1950, most public water-supply well fields in the county were constructed near the principal early population centers located less than 5 miles from the Atlantic Ocean. The construction of major regional drainage canals in the early 20th century caused a lowering of the water table and a gradual inland movement of the saltwater front toward the well fields. The U.S. Geological Survey began field investigations of saltwater intrusion in the Biscayne aquifer of southeastern Broward County in 1939. As part of the present study, the positions of the saltwater front in 1945, 1969, and 1993 were estimated using chloride concentrations of water samples collected between 1939 and 1994 from various monitoring and exploratory wells. The data indicate that, between 1945 and 1993, the saltwater front has moved as much as 0.5 mile inland in parts of the study area. The position and movement of the saltwater front were simulated numerically to help determine which of the various hydrologic factors and water-management features characterizing the coastal subsurface environment and its alteration by man are of significance in increasing or decreasing the degree of saltwater intrusion. Two representational methods were applied by the selection and use of appropriate model codes. The SHARP code simulates the position of the saltwater front as a sharp interface, which implies that no transition zone (a zone in which a gradational change between freshwater and saltwater occurs) separates freshwater and saltwater. The Subsurface Waste Injection Program (SWIP) code simulates a two-fluid, variable-density system using a convective-diffusion approach that includes a representation of the transition zone that occurs between the freshwater and saltwater bodies. The models were applied to: (1) approximately replicate predevelopment and current positions of the interface in the study area; and (2) study the relative importance of various factors affecting the interface position. The model analyses assumed a conceptual model of uniform easterly flow in the aquifer toward points of offshore discharge to tidewater. Measurements of water-table altitude and the depth to the interface in the study area exhibit an interrelation that differes substantially from the classical Ghyben-Herzberg relation. However, both model codes simulated water-table altitudes and interface positions that were generally consistent with the Ghyben-Herzberg relation but differed substantially from observed data. The simulate interface positions were inland of the known positions, and simulate water-table altitudes were higher than measured ones. The SHARP and SWIP simulations were in general agreement with each other when a low value of longitudinal dispersivity was specified in the SWIP simulation and also for higher values of longitudinal dispersivity when modified dispersion algorithms were used in SWIP that greatly reduced the simulated degree of vertical dispersion. Sensitivity analyses performed using the SHARP code indicated simulation results to be relatively insensitive to a substantial change in the specified slope of the base of the aquifer and moderately sensitive to a 150-percent change in net atmospheric recharge to the aquifer (rainfall minus evapotranspiration). Representing well-field pumping by the City of hallandale had only a minor, localized influence on the simulated regional interface position. Using various cross-sectional grid designs in applications of the SWIP code, near convergence of all lines of equal concentrations in the transition zone was achieved within a simulation time of 10 years. The simulated equilibrium interface location was sensitive to substantial spatial variations in the specified hydraulic conductivity values, but was relatively insensitive to seasonal varying

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Evapotranspiration from successional vegetation in a deforested area of the Lake Wales Ridge, Florida

The suitability of three evapotranspiration models (Penman-Monteith, Penman, and a modified Priestley-Taylor) was evaluated at a site of successional vegetation in a deforested area of the Lake Wales Ridge, Florida. Eddy correlation measurements of evapotranspiration made during 22 approximately 1-day periods at a temporal resolution of 20 minutes from September 1993 to August 1994 were used to calibrate the evapotranspiration models. Three variants of the eddy correlation method that ascribe measurement error to three different sources were considered in the analysis. The Penman-Monteith and modified Priestley- Taylor models were successful in approximating measured 20-minute values of evapotranspiration (r 2 ≥0.918). The most successful approaches were the modified Priestley-Taylor model (r 2 =0.972) and a nontraditional and simplified form of the Penman-Monteith model (r 2 =0.967). The Penman approach was unsuccessful as a predictor of evapotranspiration. The evapotranspiration models were used to estimate evapotranspiration between measurements. When evapotranspiration values measured with a Bowen ratio variant of the eddy correlation method were used for model calibration, estimated daily evapotranspiration rates varied seasonally ranging from 0.2 millimeters per day (0.008 inch per day) in late December 1993 to 5 millimeter per day (0.2 inch per day) in mid-July 1994. Annual evapotranspiration (September 15, 1993, to September 15, 1994) was estimated to be about 680 millimeters (27 inches). Evapotranspiration models calibrated to the standard eddy correlation method and to an energy-balance residual variant provided estimates of annual evapotranspiration that were about 10 per cent lower and higher, respectively. These data indicate that of the 1,320 millimeters (52 inches) of precipitation during the 1-year period, about 570 to 700 millimeters (22 to 28 inches) recharged the surficial aquifer. Evapotranspiration at this study site probably defines the lower limit of evapotranspiration from vegetated surfaces in central Florida because of the shallow-rooted plants, rapidly-drained soils, and relatively deepwater table.

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Magnitude and frequency of low flows in the Suwannee River Water Management District, Florida

Low-flow frequency statistics for 20 gaging stations having at least 10 years of continuous record and 31 other stations having less than 10 years of continu ous record or a series of at least two low- flow measurements are presented for unregulated streams in the Suwannee River Water Management District in north-central Florida. Statistics for the 20 continuous-record stations included are the annual and monthly minimum consecutive-day average low- flow magnitudes for 1, 3, 7, 14, and 30 consecutive days for recurrence intervals of 2, 5, 10, 20, and, for some long-term stations, 50 years, based on records available through the 1994 climatic year.Only theannual statistics are given for the 31 other stations; these are for the 7- and 30-consecutive day periods only and for recurrence intervals of 2 and 10 years only. Annual low-flow frequency statistics range from zero for many small streams to 5,500 cubic feet per second for the annual 30- consecutive-day average flow with a recurrenceinterval of 2 years for the Suwannee River near Wilcox (station 02323500). Monthly low-flow frequency statistics range from zero for many small streams to 13,800 cubic feet per second for the minimum 30-consecutive-day average flow with a 2-year recurrence interval for the month of March for the same station. Generally, low-flow characteristics of streams in the Suwannee River Water Management District are controlled by climatic, topographic, and geologic fac tors. The carbonate Floridan aquifer system underlies, or is at the surface of, the entire District. The terrane's karstic nature results in many sinkholes and springs. In some places, springs may contribute greatly to low streamflow and the contributing areas of such springs may include areas outside the presumed surface drainage area of the springs. In other places, water may enter sinkholes within a drainage basin, then reappear in springs downstream from a gage. Many of the smaller streams in the District go dry or have no flow for several months in many years. In addition to the low-flow statistics, four synoptic low-flow measurement surveys were conducted on 161 sites during 1990, 1995, and 1996. The measurements were made to provide "snapshots" of flow conditions of streams throughout the Suwannee River Water Management District. Magnitudes of low flows during the 1990 series of measurements were in the range associated with minimum 7-consecutive-day 50-year recurrence interval to the minimum 7-consecutive-day 20-year recurrence interval, except in Taylor and Dixie Counties, where the magnitudes ranged from the minimum 7-consecutive-day 5-year flow level to the7-consecutive-day 2-year flow level. The magnitudes were all greater than the minimum 7- consecutive-day 2-year flow level during 1995 and 1996. Observations of no flow were recorded at many of the sites for all four series of measurements.

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Evapotranspiration from areas of native vegetation in west-central Florida

A study was conducted to evaluate the suitability of three micrometeorological methods for estimating evapotranspiration from selected areas of native vegetation in west-central Florida and to estimate annual evapotranspiration from areas having a specific vegetation type. Evapotranspiration was estimated using the methods of energy-balance Bowen ratio (EBBR) and eddy correlation. Potential evapotranspiration was computed using the Penman equation. Field measurements were made intermittently from February 1988 through September 1990. The EBBR method was used to estimate evapotranspiration from unforested and forested sites. A mean-gradient Bowen ratio system was used to measure and average vertical air temperature and vapor-pressure gradients, and the Bowen ratio was computed using the mean air temperature and vapor-pressure gradients. The Bowen ratio estimated in this manner was then used to compute evapotranspiration by the EBBR method. Computations that were based on objective review criteria indicated that the Bowen ratio that was computed using measurements that were made using the mean-gradient Bowen ratio system was not always realistic. During a period of extended operation at a dry prairie site, 9 percent of measured available energy during the daytime occurred when the Bowen ratio obtained using the mean-gradient Bowen ratio system was unrealistic. During 5 out of 14 days of continuous operation at a marsh site, more than 30 percent of measured available energy during the daytime occurred when the Bowen ratio obtained using the mean-gradient Bowen ratio system was unrealistic. One of the primary causes of unrealistic Bowen ratios at the unforested sites was condensation of moisture within the tubing of the mean-gradient Bowen ratio system. Measurements made using the mean-gradient Bowen ratio system at a forested pine flatwood site indicated that vapor-pressure gradients were too weak to be resolved by the system. As a result, the Bowen ratio computed for the forested sites was unreliable when it was obtained using the mean-gradient Bowen ratio system. Direct estimates of sensible and latent heat flux that were computed from eddy correlation measurements were generally insufficient to account for measured available energy at all sites. Analysis of eddy correlation and energy-balance data indicated that the sum of sensible and latent heat fluxes accounted for 68 percent of available energy at dry prairie and marsh sites, 74 percent of available energy at a pine flatwood site, and 45 percent of available energy at a cypress swamp site. Because specific causes of the energy-balance discrepancies could not be quantified, corrections to the direct eddy correlation flux estimates could not be made, and eddy correlation data were combined with other energy-balance data to yield two alternative evapotranspiration estimates. The first alternative evapotranspiration estimate was computed by combining sensible heat flux obtained from eddy correlation with measurements of available energy to compute latent heat flux as the residual of the equation for the surface energy balance. The second alternative evapotranspiration estimate was computed by using direct sensible and latent heat flux estimates that were obtained from eddy correlation measurements to compute the Bowen ratio. The Bowen ratio obtained from eddy correlation measurements was then combined with measurements of available energy to compute evapotranspiration by the EBBR method. Of the three alternative evapotranspiration estimates that were obtained from eddy correlation measurements, the estimate that was computed using the EBBR method, with the Bowen ratio computed from eddy correlation measurements, agreed most strongly with the corresponding evapotranspiration estimate that was computed using the EBBR method with the Bowen ratio obtained from the mean-gradient Bowen ratio system. It is probable that actual evapo-transpiration was within a range defined by the standard eddy correlation computation, which consistently indicated the smallest evapotranspiration, and the energy-balance residual computation, which consistently indicated the largest evapotranspiration. Daily potential evapotranspiration, as computed by the Penman method, and daily evapotranspiration, as computed by the EBBR method, did not seem to correlate with each other at a dry prairie site during late spring and summer; however, the two were correlated with each other at a marsh site during late spring and summer. Evapotranspiration was approximately 57 percent of potential evapotranspiration at the marsh site. The correlation between evapotranspiration and potential evapotranspiration at the marsh site, and the fact that evapotranspiration approached potential evapotranspiration, indicated that the Penman method can be useful for estimating evapotranspiration from marshes in west-central Florida. Annual evapotranspiration estimates were developed for each vegetation type by pooling EBBR and eddy correlation measurements among sites and among the 3 years during which field measurements were made. Three different estimates, which correspond to the three eddy correlation computation methods, were made for each vegetation type. The centric estimates, which were calculated by using the EBBR method with the Bowen ratio obtained from either a mean-gradient system or from eddy correlation measurements, were 1,010 millimeters per year for the dry prairie type, 990 millimeters per year for the marsh vegetation type, 1,060 millimeters per year for the pine flatwood type, and 970 millimeters per year for the cypress swamp type.

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Descriptions of anisotropy and heterogeneity and their effect on ground-water flow and areas of contribution to public supply wells in a karst carbonate aquifer system

Delineation of areas of contribution to wells tapping a karst carbonate aquifer system can be extremely difficult using conventional approaches designed for isotropic and homogeneous aquifers, because ground-water flow tends to be through solution-enhanced conduits. Nonradial flow along preferential zones can result in inaccurate estimates of flow paths and traveltimes. Because of the large variability in factors affecting contributing areas and an imperfect understanding of how these factors can vary, the estimation of contributing areas is an approximation at best. To better understand the effects of aquifer anisotropy and heterogeneity on areas of contribution, an exploratory modeling approach was used. MODFLOW, a numerical flow model, and MODPATH, a particle tracking program, were used to generate time-related areas of contribution for six hypothetical carbonate aquifer system types. The six types were conceptualized to approximate different types of aquifer anisotropy and heterogeneity. These include: (1) an isotropic and homogeneous single-layer system; (2) an anisotropic in a horizontal plane single layer system; (3) a discrete vertically fractured single-layer system; (4) a multilayered system; (5) a doubly porous single-layer system; and (6) a vertically and horizontally interconnected heterogeneous system. The simulated aquifer anisotropy was 5:1 (Kxx/Kyy) determined from TENSOR2D results. The simulated discrete vertical fracture network represents locations inferred from mapped photolineaments. The simulated enhanced flow zones were determined from borehole video and geophysical logs. Areas of contribution were simulated for two prototype regions. The two prototypes were selected to be representative of the hydrologic diversity within the study area and were designated the Central Swamp and Lake Terrace regions. Localized conditions in pumping, production well distribution, and aquifer transmissivity affect the size, shape, and orientation of areas of contribution to public supply wells. The simulated areas of contribution are 60 percent larger in the Central Swamp region where pumpage is more than double and transmissivity is about half that of the Lake Terrace region. Although these factors are important, this study focused on the effects from hydrogeologic factors common to karst carbonate aquifer systems. This study indicates that the distribution and type of aquifer anisotropy and heterogeneity will affect the size, shape, and orientation of areas of contribution in a karst carbonate aquifer system. The size of the 50-year time-related areas of contribution ranged from 8.2 to 39.1 square miles in the Central Swamp region and from 4.0 to 18.3 square miles in the Lake Terrace region. Simulations showed that the size of areas of contribution is primarily affected by simulated withdrawal rates, effective porosity of the carbonate rock, and transmissivity. The shape and orientation of the simulated areas of contribution primarily result from aquifer anisotropy, well distribution, flow along solution-enhanced zones, and short-circuiting of flow through fracture networks. Comparisons also were made between protection zones delineated using analytical models and areas of contribution delineated using numerical models. The size of the 5-year time-related protection zone in the Central Swamp region using an analytical model was almost twice as large as the numerically simulated area of contribution, and more than eight times larger than the numerically simulated area of contribution in the Lake Terrace region. The differences in size are primarily the result of how the flow field is approximated. The analytical method assumes only lateral flow to wells but numerical methods allow particles to move laterally and vertically. Additionally, multiple-well-interference effects resulting from the close proximity of several pumping wells cause individual capture zones to converge or diverge, depending on the difference in pumping rates and orientation among the wells. Such an interpretation is not available from analytical methods. The simulated distributions of aquifer anisotropy and heterogeneity, in this study, were highly conceptualized, but were based on plausible occurrences of anisotropy and heterogeneity inherent in carbonate aquifer systems.

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Physical, chemical, and biological characteristics of the Charlotte Harbor basin and estuarine system in southwestern Florida: A summary of the 1982-89 U.S. Geological Survey Charlotte Harbor assessment and other studies

The Charlotte Harbor estuarine system, having a surface area of about 270 square miles, averages about 7 feet in depth and is connected to deep water of the Gulf of Mexico through several passes and inlets between barrier islands. Three major rivers flow into the estuary--the Peace, the Myakka, and the Caloosahatchee. Freshwater and tidal flushing transport nutrients and other constituents from the basin through the estuary into the gulf. Flushing characteristics were evaluated using a two-dimensional hydrodynamic model. The model indicated that the time required to flush injected dye (simulated) from some subareas of the harbor was longer for reduced freshwater inflow than for typical freshwater inflow. After 30 days of simulation of reduced freshwater inflow, 42 percent of the dye injected into the upper harbor remained in the upper harbor, compared to 28 percent for typical freshwater inflow. The Charlotte Harbor estuary is usually well mixed or partially mixed in the vertical, but vertical salinity stratification does occur, primarily during late summer when freshwater inflows are greatest. A box model was developed that incorporated vertically averaged salinities to account indirectly for three-dimensional transport processes associated with vertical stratification. The box model predicts that under high (7,592 cubic feet per second) and average (2,470 cubic feet per second) freshwater inflows from the Peace and Myakka Rivers, 50 percent of the original water (present at the start of the model run) would be flushed from the northern part of the estuarine system into the Gulf of Mexico in 10 days and 20 days, respectively. The distribution of plant nutrients in the Charlotte Harbor Estuary is affected by nutrient inputs, freshwater and tidal flushing, mixing, and recycling processes in the estuary. The distributions of total phosphorus and orthophosphate are affected mainly by river input and physical mixing. The distribution of ammonia nitrogen is variable and is related more to recycling within the estuary than to input from the rivers. Ammonia concentrations increase in deeper water, probably in response to vertical salinity stratification and low concentrations of dissolved oxygen that foster regeneration of ammonia from bottom sediments. The distribution of nitrite plus nitrate nitrogen is nonconservative--concentrations are high in the rivers and decrease more rapidly in the estuary than expected due to dilution with sea water, probably because of phytoplankton uptake. Phytoplankton productivity and biomass are usually greatest during late summer near the mouths of the tidal rivers when freshwater inflow and nutrient loading are greatest. The highly colored freshwater runoff reduces light penetration and phytoplankton productivity in regions of the estuary where salinity is less than about 10 parts per thousand, but the nutrient-rich, colored water is diluted by seawater at midsalinities (10-20 parts per thousand) so that availability of light increases and inorganic nitrogen concentrations are still high enough to stimulate productivity and growth of phytoplankton. In much of the estuary, salinity is greater than 20 parts per thousand, and availability of inorganic nitrogen, not light, limits productivity and growth. Although the Charlotte Harbor estuarine system is relatively undisturbed, much of its basin has been altered by human activities. Streamflow decreased substantially during 1931-84 in parts of the Peace River, probably because of ground-water withdrawals in the basin. Nutrient concentrations generally increased in the rivers during 1970-85, because of an increase in the flow of wastewater and agricultural runoff. The concentrations of phosphorus are naturally high in the Peace River because of extensive phosphate deposits in the basin. The phosphate deposits also are relatively rich in radionuclides of the uranium-238 series, including radium-226. In the upper basin, these deposits are exposed in the riverbed. Extensive phosphate mining and processing have exposed additional deposits to surface runoff. Periodic spills of phosphate sediments (slimes) have contributed additional phosphorus and radium-226 to the river and estuary. A single spill can contribute a phosphorus load equal to the annual loading in the Peace River at Arcadia. The projected increase in population in the basin by the year 2020 would generate an additional 60 million gallons per day of domestic wastewater over that generated during 1980, which would increase nitrogen loading in the basin by more than 3 tons per day. Intensified agricultural and industrial developments, particularly expanding citrus production and phosphate mining, could generate additional loads of nutrients and a variety of inorganic and organic contaminants. Increased inputs of nutrients, particularly nitrogen, could encourage growth and increase abundance of phytoplankton and benthic and epiphytic algae. If water were less colored as a result of reduced freshwater inflow, undesirable algal growth could be exacerbated because of increased availability of light. Increased abundance of phytoplankton and other algae could likely change dissolved-oxygen concentrations in the estuary, resulting in greater day-to-night fluctuations and the possible depletion of dissolved oxygen in deep water. At the present time, near-anaerobic conditions occur for days or weeks in the deep water (more than 9 feet) of the northern harbor during late summer. These conditions could become more persistent with time and over wider areas, if phytoplankton and other algae increase in abundance and in their contribution to benthic oxygen demand. An increased abundance of phytoplankton and other algae also would reduce light penetration and adversely affect seagrasses.

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