USGS ScienceSearch

Geology topics

Research about Farmington River watershed

Source-linked reports with geographic coverage including Farmington River watershed.

4 recordsLinked to original sources

An ecosystem-scale model of PFAS dynamics in stream-to-riparian food webs

Per- and polyfluoroalkyl substances (PFAS) are widespread contaminants in aquatic ecosystems, where they bioaccumulate and trophically transfer through food webs. We derived an ecosystem-scale model assessing Σ 12 PFAS partitioning, bioaccumulation by larval aquatic insects, bioamplification by adult aquatic insects, and trophic transfer from aquatic insects to riparian spiders using data collected across five streams in a mildly impacted watershed. Partitioning involved the greatest PFAS enrichments (range in posterior median log 10 k d values = 1.5–2.1), with lesser concentration increases from particulates to larval aquatic insects and from larval to adult aquatic insects, and Σ 12 PFAS concentration decreases from adult aquatic insects to spiders. Among the 12 compounds, PFOS had the largest proportional contribution to Σ 12 PFAS concentrations for all sample types, with consistently increasing concentrations from surface water to adult aquatic insects. Σ 12 PFAS concentrations (5.4–51 ppb wet weight), body burdens (0.44–5.2 ng per individual), and bioamplification factors (0.15–4.9) differed considerably among five common aquatic insect taxa. This study presents a robust modeling framework for PFAS trophodynamics and offers insights into the biological controls that contribute to the context dependency of PFAS at the interfaces of aquatic and terrestrial food webs.

Connecticut, Massachusetts

Where the past meets the present: Connecting nitrogen from watersheds to streams through groundwater flowpaths

Groundwater discharge to streams is a nonpoint source of nitrogen (N) that confounds N mitigation efforts and represents a significant portion of the annual N loading to watersheds. However, we lack an understanding of where and how much groundwater N enters streams and watersheds. Nitrogen concentrations at the end of groundwater flowpaths are the culmination of biogeochemical and physical processes from the contributing land area where groundwater recharges, within the aquifer system, and in the near-stream riparian area where groundwater discharges to streams. Our research objectives were to quantify the spatial distribution of N concentrations at groundwater discharges throughout a mixed land-use watershed and to evaluate how relationships among contributing and riparian land cover, modeled aquifer characteristics, and groundwater discharge biogeochemistry explain the spatial variation in groundwater discharge N concentrations. We accomplished this by integrating high-resolution thermal infrared surveys to locate groundwater discharge, biogeochemical sampling of groundwater, and a particle tracking model that links groundwater discharge locations to their contributing area land cover. Groundwater N loading from groundwater discharges within the watershed varied substantially between and within streambank groundwater discharge features. Groundwater nitrate concentrations were spatially heterogeneous ranging from below 0.03–11.45 mg-N/L, varying up to 20-fold within meters. When combined with the particle tracking model results and land cover metrics, we found that groundwater discharge nitrate concentrations were best predicted by a linear mixed-effect model that explained over 60% of the variation in nitrate concentrations, including aquifer chemistry (dissolved oxygen, Cl − , SO 4 2− ), riparian area forested land cover, and modeled physical aquifer characteristics (discharge, Euclidean distance). Our work highlights the significant spatial variability in groundwater discharge nitrate concentrations within mixed land-use watersheds and the need to understand groundwater N processing across the many spatiotemporal scales within groundwater cycling.

Connecticut

Where groundwater seeps: Evaluating modeled groundwater discharge patterns with thermal infrared surveys at the river-network scale

Predicting baseflow dynamics, protecting aquatic habitat, and managing legacy contaminants requires explicit characterization and prediction of groundwater discharge patterns throughout river networks. Using handheld thermal infrared (TIR) cameras, we surveyed 47 km of stream length across the Farmington River watershed (1,570 km 2 ; CT and MA, USA), mapping locations of bank and waterline groundwater discharges based on their thermal signature. Using the observed groundwater discharge locations and predicted groundwater discharge rates from 6 variations of a numerical groundwater-flow model (MODFLOW-NWT), we compared 1) predicted groundwater-discharge rates in areas with and without observed groundwater discharge, 2) spatial patterns of observed and predicted groundwater discharge locations, and 3) density of observed groundwater discharge locations with predicted discharge rates. Five of six models reasonably predicted the spatial patterns of discharge locations along the 5th order mainstem, but fewer models predicted groundwater discharge patterns in smaller streams. Our results highlight 1) the feasibility of using TIR observations to evaluate groundwater models, 2) model parameters that influence discharge prediction accuracy (riverbed sediment and bedrock hydraulic conductivity and river-aquifer connections), and 3) current strengths and future opportunities for improved modeling of groundwater-discharge patterns.

Connecticut, Massachusetts

Improved prediction of management-relevant groundwater discharge characteristics throughout river networks

Groundwater discharge zones connect aquifers to surface water, generating baseflow and serving as ecosystem control points across aquatic ecosystems. The influence of groundwater discharge on surface flow connectivity, fate and transport of contaminants and nutrients, and thermal habitat depends strongly on hydrologic characteristics such as the spatial distribution, age, and depth of source groundwater flow paths. Groundwater models have the potential to predict spatial discharge characteristics within river networks, but models are often not evaluated against these critical characteristics and model equifinality with respect to discharge processes is a known challenge. We quantify discharge characteristics across a suite of groundwater models with commonly used frameworks and calibration data. We developed a base model (MODFLOW‐NWT) for a 1,570‐km 2 watershed in the northeastern United States and varied the calibration data, control of river‐aquifer exchange directionality, and resolution. Most models ( n = 11 of 12) fit similarly to calibration metrics, but patterns in discharge location, flow path depth, and subsurface travel time varied substantially. We found (1) a 15% difference in the percent of discharge going to first‐order streams, (2) threefold variations in flow path depth, and (3) sevenfold variations in the subsurface travel times among the models. We recalibrated three models using a synthetic discharge location data set. Calibration with discharge location data reduced differences in simulated discharge characteristics, suggesting an approach to improved equifinality based on widespread field‐based mapping of discharge zones. Our work quantifying variation across common modeling approaches is an important step toward characterizing and improving predictions of groundwater discharge characteristics.

Connecticut, Massachusetts