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Physical and chemical characteristics of Terrace Reservoir, Conejos County, Colorado, May 1994 through May 1995; interim report

Terrace Reservoir receives drainage of low-pH, metal-enriched water from mineralized areas, including the Summitville Mine, within the Alamosa River Basin. Drainage from the Summitville Mine has contributed a substantial part of the metal load to Terrace Reservoir. From May 1994 through May 1995, a study was done by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, to evaluate the physical and chemical characteristics of Terrace Reservoir. Terrace Reservoir was thermally stratified from about mid-May through August 1994. Thermal stratification was absent from September\x111994through March 1995. During periods of stratification, underflow of the Alamosa River was predominant, and residence times of the underflow were shortened by 40 to 75\x11percent of the theoretical residence times for a well-mixed reservoir. Transport and deposition of suspended solids in Terrace Reservoir varied spatially and temporally. Most of the suspended solids were deposited in Terrace Reservoir. The concentration of dissolved oxygen in the reservoir varied little spatially or temporally and generally was within a few tenths of the dissolved-oxygen concentration of the inflow. The pH of water in the reservoir generally ranged from about 4.0 to about 7.0, depending on date, depth, and location. The largest pH values were measured during May. A markeddecrease of about 1.5\x11pH units occurred at site T5 in the reservoir about mid-June. The pH of the reservoir remained at or below 5.5 from mid-June through November. Dissolved-metal concentrations varied spatially and temporally in response to several factors, which included inflow characteristics, reservoir stratification and mixing, inflow-routing and flow-through patterns, residence times, sedimentation, dissolved oxygen, and pH. Inflow chemistry is the dominant controlling factor of metal chemistry within Terrace Reservoir. During periods of stratification, large vertical variations in metal concentrations occurred. The highest metal concentrations in the reservoir generally were measured in the hypolimnion between June and August. During June, epilimnetic water of the reservoir had pH values greater than 6.0, and metal concentrations were lower than hypolimnetic concentrations. In the hypolimnion, pH values were less than 5.5. The difference between the chemistry of the epilimnion and the hypolimnion was due to differences in flow routing and residence times of water in those respective layers. The dissolved-metal concentrations were larger during July and August than during June. During September, small vertical variations in metal concentrations occurred, and the dissolved-metal concentrations were nearly equivalent to the average August metal concentrations, indicatingthat the metal concentrations measured during September resulted largely from reservoir mixing.During March, the largest metal concentrationsoccurred in the epilimnion, where pH was about 5.5; in the hypolimnion, where the pH was about 6.0, dissolved-metal concentrations were substantially lower and reflected inflow concentrations.

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Assessment of metal transport into and out of Terrace Reservoir, Conejos County, Colorado, April 1994 through March 1995

Terrace Reservoir is the primary source of water for crops and livestock in the southwestern part of the San Luis Valley in southern Colorado. Mining activities have occurred in the basin for more than 100 years, and substantial mining of gold has occurred intermittently at the Summitville Mine. Historically, the Summitville Mine site has produced highly acidic, metal-enriched water that drained from the mine site into Wightman Fork and flowed to the Alamosa River and Terrace Reservoir. In 1994, a study was begun as part of risk-assessment and remediation efforts and to evaluate metal transport into and out of Terrace Reservoir. During the study period, the pH immediately upstream from Terrace Reservoir ranged from 4.3 to 7.8. The highest pH occurred during the pre-peak snowmelt period; the lowest pH occurred during storm runoff during summer. Downstream from Terrace Reservoir, the pH ranged from 4.6 to 7.6. The highest pH occurred during the pre-peak snowmelt period, and the lowest pH occurred during summer in mid-July. A comparison of the streamflow hydrographs upstream and downstream from Terrace Reservoir indicated that there was only a small difference between the annual volume of water that entered the reservoir and the annual volume of water that was released from the reservoir. Large spatial and temporal variations in concentrations of the metals of concern occurred during the study. The median and maximum concentrations of dissolved and total aluminum, iron, copper, cadmium, manganese, and zinc were larger upstream from the reservoir than downstream from the reservoir. The largest concentrations of dissolved aluminum, iron, copper, cadmium, manganese, and zinc generally occurred between mid-June and November. Throughout the study, aluminum was transported into the reservoir predominantly in the particulate or suspended form. Downstream from the reservoir, the suspended-aluminum fraction was predominant only during the pre-peak snowmelt and peak snowmelt periods. The temporal variations in the percentage of dissolved and suspended fraction of iron and copper downstream from Terrace Reservoir were similar to the temporal variations that occurred upstream from the reservoir. During the study period, cadmium, manganese, and zinc generally were transported into and out of the reservoir predominantly in the dissolved form. Metal loads varied considerably as a result of changes in streamflow or changes in metal concentrations, or both. The largest daily loads of aluminum, iron, and manganese were transported into and out of Terrace Reservoir during the peak snowmelt period. The reservoir was a sink for an estimated 294 tons of aluminum and 596 tons of iron. However, about 68.5 tons of total aluminum and about 194 tons of total iron were transported out of the reservoir during the study period. During the study period, about 22 tons of total copper remained in the reservoir, and 39 tons was transported downstream from the reservoir. About 47 tons of total manganese and 18 tons of total-zinc loads were transported out of the reservoir; the reservoir was a sink for only a small fraction of total-manganese and -zinc.

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Geohydrology of the North Park area, Jackson County, Colorado

Increasing population in rural and suburban areas of Colorado is causing greater reliance on ground water as a source of domestic supply. In the primarily rural area of Jackson County, for example, the number of registered water wells increased from about 100 in 1972 to about 500 in 1995. Most of the new wells were drilled after 1988 and supply water to ranches and summer homes. In Jackson County, ground water is pumped from a series of shallow alluvial aquifers along principal stream valleys and from deeper, more extensive, bedrock aquifers. In much of the area, the alluvial aquifers are thin and can be dewatered by moderate water- level declines. Knowledge of the nature and extent of the alluvial and bedrock aquifers, the sources of recharge and discharge, and the effects of ground- water withdrawal on water levels in the aquifers is vital if management of the area's water resources is to ensure continued availability of a dependable water supply.

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Raton basin coalbed methane production picking up in Colorado

Coalbed methane production in the Raton basin of south-central Colorado and northeast New Mexico has gone over pilot testing and entered the development stage which is expected to last several years. The development work is restricted to roughly a 25 mile by 15 mile wide `fairway' centered about 20 miles west of Trinidad, Colorado. At last count, 85 wells were producing nearly 17.5 MMcfd of coalbed methane from the basin's Raton and Vermejo formation coals.

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The contribution of wetlands to stream nitrogen load in the Loch Vale Watershed, Colorado, USA

We explored the difference between the concentrations of different N forms and other chemical properties between stream water and riparian zone wetland soil water in the Loch Vale Watershed which is located on the eastern slope of the Continental Divide in Rocky Mountain National Park, Colorado, USA. The nitrate N concentration in stream water were significantly higher than in soil water of the three wetlands, while no significant difference appeared in ammonium N. The pH values were higher and conductivity values were lower in stream water than in wetland soil water. However, significant difference also appeared between nitrate N concentrations, pH and conductivity values in the water sampled from different positions of streams. The stream tributary water had higher nitrate N concentrations, higher pH and higher conducitity values. We also conducted experiments to compare the difference between the productivity, total N concentrations in biomass and soil of upper layers. At the end, we concluded that the wetlands distributed along the streams in Loch Vale Watershed had little effect on the nitrogen load of the stream water there.

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Tertiary igneous rocks and Laramide structure and stratigraphy of the Spanish Peaks Region, South-Central Colorado: Road log and descriptions from Walsenburg to La Veta

The Spanish Peaks are located in the western part of the Raton basin in south-central Colorado, southwest of Walsenburg. The two peaks, West Spanish Peak (WSP, 13,626 feet) and East Spanish Peak (ESP, 12,683 feet), are located on the upland part of the far western edge of the Great Plains physiographic region. East of Spanish Peaks, a deeply dissected plateau extends into the Great Plains. The Raton basin, an asymmetric structure of Laramide age, underlies and surrounds the Spanish Peaks. The basin extends north from Ute Park, New Mexico, to Huerfano Park, Colorado. The juncture of steeply dipping western and gently dipping eastern limbs of the Raton basin forms the basin axis, known locally as the La Veta syncline. The La Veta syncline extends north-northwest into Huerfano Park, between the Sangre de Cristo and Wet Mountains. These features and others such as the Laramide orogeny, igneous rocks, and an overview of petrology are discussed.

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Spatial and temporal patterns of late Quaternary eolian deposition, eastern Colorado, USA

Eolian sediment covers about 60% of Colorado east of the Rocky Mountains; about 30% of the sediment is sand and 70% is loess. Initially, flood plains were the principal sources of eolian sediment, but during the Holocene, dunes formed from older eolian sand and alluvium on uplands. Since latest Pleistocene time, dominant dune-forming winds have been northwesterly in the northern part of the region and southwesterly in the southern part. At present, sand sheets and dunes, mainly parabolic types, are stable and covered with vegetation. In dunes, sand is commonly 20–30 m thick but elsewhere averages < 10 m. Three sand units are recognized on the basis of bedforms, topographic expression, and soil development. Preliminary age limits for the three units, based on 26 numerical ages, are 22.5–9 ka, 8−1 ka, and l.0−0. 15 ka. The middle unit is the product of multiple episodes of eolian activity that are not yet accurately dated. Loess is widespread but thin (generally < 2.4 m). Three units — middle Pleistocene, late Pleistocene. and Holocene — are recognized on the basis of differences in soil-profile development and stratigraphic position; late Pleistocene loess is by far the most common loess.

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Uraniferous waters of the Arkansas River valley, Colorado, U.S.A.: A function of geology and land use

The effect of local geology and land-use practices on dissolved U was investigated by analysis of surface water and some springs in the Arkansas River valley of southeastern Colorado. Water samples were collected during a 2 week period in April, 1991. The rate of increase of U concentration with distance downriver increased markedly as the river flowed from predominantly undeveloped lands underlain by igneous and metamorphic rocks to agriculturally developed lands underlain by marine shale and limestone. An additional abrupt increase in dissolved U was observed along the section of river where discharge is often greatly reduced because of extensive diversions for irrigation and where remaining flow is largely composed of irrigation return water. Dissolved U in this last section of river and in most of its tributaries exceeded the proposed U.S. drinking water standard of 20 μ/L In water samples collected from agricultural areas dissolved U showed strong positive correlation with major dissolved constituents Na, Ca, Mg, and SO 4 that increase as a result of sulfate mineral dissolution and clay mineral ion-exchange reactions in weathered shale bedrock and shaley soils. Highly soluble minor and trace elements Cl, Li, B, Sr, and Se that are not subject to strong sorptive uptake or precipitation in this setting also correlated positively with U. These combined observations indicate that natural leaching of U-bearing shale bedrock and derivative soils, additional leaching of rock and soil by irrigation water, and evaporative concentration in a semi-arid climate can produce concentrations of dissolved U in surface water and shallow ground water that may threaten nearby drinking water supplies. Other agriculturally developed areas of the semi-arid Western U.S. with similar geology are likely to contain high concentrations of U in irrigation drain water.

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Effects of colloids on metal transport in a river receiving acid mine drainage, upper Arkansas River, Colorado, U.S.A.

Inflows of metal-rich, acidic water that drain from mine dumps and tailings piles in the Leadville, Colorado, area enter the non-acidic water in the upper Arkansas River. Hydrous iron oxides precipitate as colloids and move downstream in suspension, particularly downstream from California Gulch, which has been the major source of metal loads. The colloids influence the concentrations of metals dissolved in the water and the concentrations in bed sediments. To determine the role of colloids, samples of water, colloids, and fine-grained bed sediment were obtained at stream-gaging sites on the upper Arkansas River and at the mouths of major tributaries over a 250-km reach. Dissolved and colloidal metal concentrations in the water column were operationally defined using tangential-flow filtration through 0.001-pm membranes to separate the water and the colloids. Surface-extractable and total bed sediment metal concentrations were obtained on the <60-μm fraction of the bed sediment. The highest concentrations of metals in water, colloids, and bed sediments occurred just downstream from California Gulch. Iron dominated the colloid composition, but substantial concentrations of As, Cd, Cu, Mn, Pb, and Zn also occurred in the colloidal solids. The colloidal load decreased by one half in the first 50 km downstream from the mining inflows due to sedimentation of aggregated colloids to the streambed. Nevertheless, a substantial load of colloids was transported through the entire study reach to Pueblo Reservoir. Dissolved metals were dominated by Mn and Zn, and their concentrations remained relatively high throughout the 250-km reach. The composition of extractable and total metals in bed sediment for several kilometers downstream from California Gulch is similar to the composition of the colloids that settle to the bed. Substantial concentrations of Mn and Zn were extractable, which is consistent with sediment-water chemical reaction. Concentrations of Cd, Pb, and Zn in bed sediment clearly result from the influence of mining near Leadville. Concentrations of Fe and Cu in bed sediments are nearly equal to concentrations in colloids for about 10 km downstream from California Gulch. Farther downstream, concentrations of Fe and Cu in tributary sediments mask the signal of mining inflows. These results indicate that colloids indeed influence the occurrence and transport of metals in rivers affected by mining.

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Photogeologic map showing distribution of sinkholes south of Fairplay, Park County, Colorado — A possible geologic hazard

A large group of at least 50, and perhaps significantly more, sinkholes partially surrounds Black Mountain 6-10 mi south Fairplay in South Park, Park County, Colorado. The sinkholes occur in bedrock in the evaporite facies of the Middle Pennsylvania Minturn Formation, and in Quaternary soil, alluvium, and glacial outwash gravels that overlie the evaporite beds. Sinkholes range in size from small depressions a few feet across to large holes several hundred feet across. Measured sinkholes range in size from about 25 ft in diameter and 2 ft deep to about 235 ft in diameter and 25 ft deep. In places, several sinkholes have coalesced to form depressions as much as 750 ft long and 400 ft wide. One large cluster of small craters is about 1,8000 ft long and 600 ft wide. As reported to us by a resident rancher, one small sinkhole collapsed about 10 years ago. The area of sinkholes extends into land now under development for residences, and the sinkholes thus pose a potential hazard that needs to be considered in future development. Also, they might jeopardize existing farmland, structures, ans roads (including U.S. Highway 285), as well as projected roads and airstrips. This report is not a comprehensive evaluation of the distribution and origin of the sinkholes; its intent is to call attention to their presence and to encourage further study. Many by not all of the sinkholes were visited; the geologic map is based mainly on the interpretation of aerial photographs by D.R. Shawe.

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Map showing potential metal-mine drainage hazards in Colorado, based on mineral-deposit geology

This map, compiled by the U.S. Geological Survey (USGS) in cooperation with the Colorado Geological Survey (CGS) and the U. S. Bureau of Land Management (BLM), shows potential mine-drainage hazards that may exist in Colorado metal-mining districts, as indicated by the geologic characteristics of the mineral deposits that occur in the respective districts. It was designed to demonstrate how geologic and geochemical information can be used on a regional scale to help assess the potential for mining-related and natural drainage problems in mining districts, unmined mineralized areas, and surrounding watersheds. The map also provides information on the distribution of different mineral deposit types across Colorado. A GIS (Geographic Information System) format was used to integrate geologic, geochemical, water-quality, climate, landuse, and ecological data from diverse sources. Likely mine-drainage signatures were defined for each mining district based on: (1) a review of the geologic characteristics of the mining district, including mineralogy, trace-element content, host-rock lithology, and wallrock alteration, and; (2) results of site specific studies on the geologic controls on mine-drainage composition.

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