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Research about Catoctin Mountain

Source-linked reports with geographic coverage including Catoctin Mountain.

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Comparison of mineral weathering and biomass nutrient uptake in two small forested watersheds underlain by quartzite bedrock, Catoctin Mountain, Maryland, USA

To quantify chemical weathering and biological uptake, mass-balance calculations were performed on two small forested watersheds located in the Blue Ridge Physiographic Province in north-central Maryland, USA. Both watersheds, Bear Branch (BB) and Fishing Creek Tributary (FCT), are underlain by relatively unreactive quartzite bedrock. Such unreactive bedrock and associated low chemical-weathering rates offer the opportunity to quantify biological processes operating within the watershed. Hydrologic and stream-water chemistry data were collected from the two watersheds for the 9-year period from June 1, 1990 to May 31, 1999. Of the two watersheds, FCT exhibited both higher chemical-weathering rates and biomass nutrient uptake rates, suggesting that forest biomass aggradation was limited by the rate of chemical weathering of the bedrock. Although the chemical-weathering rate in the FCT watershed was low relative to the global average, it masked the influence of biomass base-cation uptake on stream-water chemistry. Any differences in bedrock mineralogy between the two watersheds did not exert a significant influence on the overall weathering stoichiometry. The difference in chemical-weathering rates between the two watersheds is best explained by a larger proportion of reactive phyllitic layers within the bedrock of the FCT watershed. Although the stream gradient of BB is about two-times greater than that of FCT, its influence on chemical weathering appears to be negligible. The findings of this study support the biomass nutrient uptake stoichiometry of K 1.0 Mg 1.1 Ca 0.97 previously determined for the study site. Investigations of the chemical weathering of relatively unreactive quartzite bedrock may provide insight into critical zone processes.

Maryland

Comparison of hydrochemical tracers to estimate source contributions to peak flow in a small, forested, headwater catchment

Three-component (throughfall, soil water, groundwater) hydrograph separations at peak flow were performed on 10 storms over a 2-year period in a small forested catchment in north-central Maryland using an iterative and an exact solution. Seven pairs of tracers (deuterium and oxygen 18, deuterium and chloride, deuterium and sodium, deuterium and silica, chloride and silica, chloride and sodium, and sodium and silica) were used for three-component hydrograph separation for each storm at peak flow to determine whether or not the assumptions of hydrograph separation routinely can be met, to assess the adequacy of some commonly used tracers, to identify patterns in hydrograph-separation results, and to develop conceptual models for the patterns observed. Results of the three-component separations were not always physically meaningful, suggesting that assumptions of hydrograph separation had been violated. Uncertainties in solutions to equations for hydrograph separations were large, partly as a result of violations of assumptions used in deriving the separation equations and partly as a result of improper identification of chemical compositions of end-members. Results of three-component separations using commonly used tracers were widely variable. Consistent patterns in the amount of subsurface water contributing to peak flow (45-100%) were observed, no matter which separation method or combination of tracers was used. A general conceptual model for the sequence of contributions from the three end-members could be developed for 9 of the 10 storms. Overall results indicated that hydrochemical and hydrometric measurements need to be coupled in order to perform meaningful hydrograph separations.

Maryland

Hydrologic and water-quality data for two small watersheds on Catoctin Mountain, North-Central Maryland, 1987-93

Hydrologic and water-quality data were collected from a precipitation-collection station and from two small watersheds on Catoctin Mountain, north-central Maryland, as part of investigations of acidic deposition and episodic acidification, and their effects on streamwater quality. Detailed descriptions of the site instrumentation in the watersheds, field data-collection techniques, and laboratory methods used to conduct the studies are included. Data that were collected on precipitation, throughfall, soil water, ground water, streamwater, and other surface and ground waters sampled during biannual synoptic surveys are given in tables. Data collected since October 1987 from one of the streamwater-quality monitoring sites and data collected since March 1988 from one of the ground-water quality monitoring sites are presented. Additional data collected since January 1987 from the precipitation station and data collected since June 1990 from all of the other water-quality monitoring sites are presented. Hydrologic data include tables of precipitation and throughfall quantities, streamflow, and synoptic measurements of ground-water levels. Selected hydrologic data are shown in graphs.

Maryland

Hydrologic and geochemical factors affecting the chemistry of small headwater streams in response to acidic deposition on Catoctin Mountain, north-central Maryland

Hydrologic and water-quality data were collected at a precipitation-collection station and from two small watersheds on Catoctin Mountain, north- central Maryland, as part of an investigation of episodic acidification and its effects on streamwater quality. Data were collected from June 1990 through December 1993. Descriptions of the water shed instrumentation, data-collection techniques, and laboratory methods used to conduct the studies are included. Data that were collected on precipitation, throughfall, soil water, ground water, and streamwater during base flow and stormflow indicate that the streams undergo episodic acidification during storms. Both streams showed decreases in pH to less than 5.0 standard units during stormflow. The acid-neutralizing capacity (ANC) of both streams decreased during stormflow, and the ANC of one of the streams, Bear Branch, became negative. The chemistries of the different types of waters that were sampled indicate that shallow subsurface water with minimal residence time in the watersheds is routed to the streams to become stormflow and is the cause of the episodic acidification observed. Three-component hydrograph separations were performed on the data collected during several storms in each watershed. The hydrograph separations of all of the storms indicate that throughfall contributed 0 to 50 percent of the stormflow, soil water contributed 0 to 80 percent, and ground water contributed 20 to 90 percent. The results of the hydrograph separations indicate that, in general, the watershed with higher hydraulic gradients tends to have shallower and shorter flow paths than the watershed with lower hydraulic gradients.

Maryland

Seasonal cycles of dissolved constituents in streamwater in two forested catchments in the mid-Atlantic region of the eastern U.S.A.

Streamwater discharge and chemistry of two small catchments on Catoctin Mountain in north-central Maryland have been monitored since 1982. Repetitive seasonal cycles in stream-water chemistry have been observed each year, along with seasonal cycles in the volume of stream discharge and in groundwater levels. The hypothesis that the observed streamwater chemical cycles are related to seasonal changes in the hydrological flow paths that contribute to streamflow is examined using a combination of data on groundwater levels, shallow and deep groundwater chemistry, streamwater discharge, streamwater chemistry, soil-water chemistry, and estimates of water residence times. The concentrations of constituents derived from rock weathering, particularly bicarbonate and silica, increase in streamwater during the summer when the water table is below the regolith-bedrock interface and stream discharge consists primarily of deep groundwater from the fractured-bedrock aquifer. Conversely, the concentrations in streamwater of atmospherically derived components, particularly sulfate, increase in winter when the water table is above the regolith-bedrock interface and stream discharge consists primarily of shallow groundwater from the regolith. Tritium and chlorofluorocarbon (CFC) measurements suggest that the groundwater in these systems is young, with a residence time of less than several years. The results of this study have implications for the design of large-scale water-quality monitoring programs.

Maryland

Seasonal cycles in streamwater quality on Catoctin Mountain, Maryland

In 1980, the U.S. Congress mandated the National Acid Precipitation Assessment Program (NAPAP) to study the effects of acidic precipitation (acid rain). In 1982, the U.S. Geological Survey (USGS) was selected to be the lead Federal agency under NAPAP to monitor the composition of precipitation and its effects on the environment. In 1982, the USGS began to monitor precipitation and streamwater on Catoctin Mountain in north-central Maryland (fig. 1); the effort has continued through the present. Beginning in 1990, funding for these data-collection and interpretation activities was supplemented by the Maryland Department of the Environment and the Maryland Department of Natural Re- sources. The collection and interpretation of long-term precipitation and streamwater-quality records, such as those at Catoctin Mountain, provide valuable information for management decisions. At the local level, the information can be used to identify periods when streamwater quality may pose a danger to aquatic resources, such as finfish; at the national level, the information can be used to assess the effectiveness of the Clean Air Act Amendments.

Maryland

Hydrologic, chemical, and isotopic characterization of two small watersheds on Catoctin Mountain, north-central Maryland, U.S.A.

Two small (100 ha) watersheds located on Catoctin Mountain in north-central Maryland were intensively instrumented in 1990 and have been hydrologically, chemically, and isotopically monitored for 3 years. Dissolved concentrations of major ions (Ca 2+ , Mg 2+ , Na + , K + , total AI, CI - , NO 3 - , SO 4 2- , HCO 3 - , and SiO 2 ) and stable isotopic (D and 18 O) values have been analyzed for most types of water (precipitation, throughfall, two depths of soil water, shallow groundwater, and streamwater) that enter, travel through, and exit each watershed. The major objectives of the study were to characterize the chemical and isotopic signatures of all aqueous components of the watersheds and to interpret the causes of the changes in chemical and isotopic compositions of streamwater during storm runoff. This paper describes selected results of the study.

Maryland

Data on the quantity and chemical quality of precipitation, Catoctin Mountain, north-central Maryland, 1982-91

This report presents data on the quantity and chemical quality of precipitation collected by the U.S. Geological Survey (USGS) from the USGS precipitation-collection station at Catoctin Mountain, in Cunningham Falls State Park, near Thurmont, Maryland, from January 1982 through December 1991. Data on the quantity of precipitation are presented as daily, monthly, and annual totals of precipitation, in inches. Data on the chemical quality of precipitation are presented in tables as concentrations, in microequivalents/L. Data on the quantity and chemical quality of precipitation and statistical information about the data are summarized in tables. Data for annual precipitation-weighted mean concentrations of constituents in precipitation are summarized in tables. Annual precipitation-weighted mean concentrations of selected constituents are illustrated in graphs.

Maryland