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Geology, mineralization, and hydrothermal alteration and relationships to acidic and metal-bearing surface waters in the Palmetto Gulch area, southwestern Colorado

The Palmetto Gulch area is affected by low pH and metal-bearing drainage from abandoned mines, and perhaps, from natural weathering around vein zones. To investigate these anthropogenic and potential natural sources of acidity and metals, we mapped the geology, veins, and hydrothermally altered areas; conducted mine dump leachate studies; and collected reconnaissance water quality data. Several small abandoned mines are present in the Palmetto Gulch area that produced small amounts of relatively high-grade silver ore from fault-controlled polymetallic vein deposits. These veins are hosted in lavas, breccias, and related volcaniclastic sediments that ponded within the 28 Ma San Juan-Uncompahgre caldera complex. These rock units generally have conformable contacts and have shallow dips to the northwest. Lava flows of pyroxene andesite, which host the Roy-Pray mine, are massive near their base and typically grade upward into tightly jointed rock with 2-15 cm joint spacing. In general, most hydrothermally altered rock within the Palmetto Gulch area is restricted to envelopes surrounding the mineralized veins and faults. Composite zones of vein-related alteration vary from about 50 to 80 m wide along the high ridgelines and narrow to less than 10 to 15 m beneath an elevation of about 5,462 m. Where unaffected by surficial oxidation, these altered zones contain as much as 7 to 10 volume percent finely-disseminated pyrite. The majority of rocks in the area were affected by regional and vein-related propylitic alteration. These greenish-colored rocks have alteration products consisting of chlorite, illite, and calcite; and feldspars are typically weakly altered. Most of these rocks have detectable amounts of calcite, while as much as 11 percent by weight was detected in samples collected during this study. The Palmetto Gulch area is affected by low pH and metal-bearing drainage from abandoned mines, and perhaps, from natural weathering around vein zones. To investigate these anthropogenic and potential natural sources of acidity and metals, we mapped the geology, veins, and hydrothermally altered areas; conducted mine dump leachate studies; and collected reconnaissance water quality data. Several small abandoned mines are present in the Palmetto Gulch area that produced small amounts of relatively high-grade silver ore from fault-controlled polymetallic vein deposits. These veins are hosted in lavas, breccias, and related volcaniclastic sediments that ponded within the 28 Ma San Juan-Uncompahgre caldera complex. These rock units generally have conformable contacts and have shallow dips to the northwest. Lava flows of pyroxene andesite, which host the Roy-Pray mine, are massive near their base and typically grade upward into tightly jointed rock with 2-15 cm joint spacing. In general, most hydrothermally altered rock within the Palmetto Gulch area is restricted to envelopes surrounding the mineralized veins and faults. Composite zones of vein-related alteration vary from about 50 to 80 m wide along the high ridgelines and narrow to less than 10 to 15 m beneath an elevation of about 5,462 m. Where unaffected by surficial oxidation, these altered zones contain as much as 7 to 10 volume percent finely-disseminated pyrite. The majority of rocks in the area were affected by regional and vein-related propylitic alteration. These greenish-colored rocks have alteration products consisting of chlorite, illite, and calcite; and feldspars are typically weakly altered. Most of these rocks have detectable amounts of calcite, while as much as 11 percent by weight was detected in samples collected during this study.

Colorado↗

The Iron Hill (Powderhorn) carbonatite complex, Gunnison County, Colorado — A potential source of several uncommon mineral resources

A similar version of this slide show was presented on three occasions during 2008: two times to local chapters of the Society for Mining, Metallurgy, and Exploration (SME), as part of SME's Henry Krumb lecture series, and the third time at the Northwest Mining Association's 114th Annual Meeting, held December 1-5, 2008, in Sparks (Reno), Nevada. In 2006, the U.S. Geological Survey (USGS) initiated a study of the diverse and uncommon mineral resources associated with carbonatites and associated alkaline igneous rocks. Most of these deposit types have not been studied by the USGS during the last 25 years, and many of these mineral resources have important applications in modern technology. The author chose to begin this study at Iron Hill in southwestern Colorado because it is the site of a classic carbonatite complex, which is thought to host the largest known resources of titanium and niobium in the United States.

Colorado↗

Field survey and damage assessment of the Mineral, Virginia, earthquake of August 23, 2011

The town of Mineral, Virginia (Va.), underwent an M=5.8 earthquake on August 23, 2011. A U.S. Geological Survey team was sent to visually inspect and document the damage in the cities of Richmond, Charlottesville, Louisa, and Mineral, Va. Our inspection concluded that the Modified Mercalli Intensity rating of moderate (V) to very strong (VII) is consistent with the expected and observed damage at these locations. Louisa County, Va., sustained the most extensive damage. We photographed fallen chimneys, collapsed walls, and cracked foundations. From visual inspection of the above-listed locations, this report catalogs the range and extent of damage from the August 23, 2011, earthquake for future reference and analysis.

Virginia↗

Landsat maps (phase V, deliverable 60), ASTER maps (phase V, deliverable 62), ASTER_DEM maps (phase V, deliverable 63), and spectral remote sensing in support of PRISM-II mineral resource assessment project, Islamic Republic of Mauritania (phase V, deliverables 61 and 64)

Multispectral satellite data acquired by the Landsat 5 Thematic Mapper (TM), Landsat 7 Enhanced Thematic Mapper Plus (ETM+), and Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) sensors were processed and interpreted in support of the PRISM-II project (Second Projet de Renforcement Institutionnel du Secteur Minier de la Republique Islamique de Mauritanie). This report and accompanying maps constitute project deliverables 60–64. All digital data for use in Geographic Information System (GIS) and image processing software will be included in the GIS deliverable 92. Image maps in PDF format of the processed Landsat and ASTER scenes are referenced in the appendixes. Samples of rock, alluvium, colluvium, and (or) eolian sediments were collected at 41 locations during the 2007 field campaign. A point shapefile (“IRM07_sample_gps_points.shp”) containing these locations will be included in GIS deliverable 92. Most of the samples were characterized in the laboratory using a full-range ASD™ (Analytical Spectral Devices) FieldSpec II spectrometer. The image products derived from Landsat TM and ASTER data enable the delineation of mineral groups across wide areas based on color response. Guides are provided that allow users to interpret these colors as to mineral group occurrence over lithologic units and known deposits. This information can be extrapolated to other geologically permissive tracts for various deposit types in the search for similar mineralogic responses that may be indicative of concealed deposits.

Open-File Report↗

Noble gas isotopes in mineral springs within the Cascadia Forearc, Washington and Oregon

This U.S. Geological Survey report presents laboratory analyses along with field notes for a pilot study to document the relative abundance of noble gases in mineral springs within the Cascadia forearc of Washington and Oregon. Estimates of the depth to the underlying Juan de Fuca oceanic plate beneath the sample sites are derived from the McCrory and others (2012) slab model. Some of these springs have been previously sampled for chemical analyses (Mariner and others, 2006), but none currently have publicly available noble gas data. Helium isotope values as well as the noble gas values and ratios presented below will be used to determine the sources and mixing history of these mineral waters.

Oregon;Washington↗

Noble gas isotopes in mineral springs and wells within the Cascadia forearc, Washington, Oregon, and California

Introduction This U.S. Geological Survey report presents laboratory analyses along with field notes for an exploratory study to document the relative abundance of noble gases in mineral springs and water wells within the Cascadia forearc of Washington, Oregon, and California (fig. 1). This report describes 14 samples collected in 2014 and 2015 and complements a previous report that describes 9 samples collected in 2012 and 2013 (McCrory and others, 2014b). Estimates of the depth to the underlying Juan de Fuca oceanic plate beneath sample sites are derived from the McCrory and others (2012) slab model. Some of the springs have been previously sampled for chemical analyses (Mariner and others, 2006), but none of the springs or wells currently has publicly available noble gas data. The helium and neon isotope values and ratios presented below are used to determine the sources and mixing history of these mineral and well waters (for example, McCrory and others, 2016).

California, Oregon, Washington↗

Mineral investigations in northeastern Thailand

Fifty-eight mineral prospects of base metals (copper, lead, zinc), iron, manganese, gold, limestone (cement grade), barite, gypsum, and salt were investigated by geological, geophysical, and geochemical surveys, and by pitting, exploratory mining, and diamond drilling from January 1963 to May 1966. Fifty-six of the prospects are in the Loei-Chiengkarn area of northeast Thailand where regional geological, aeromagnetic, and geochemical studies were also performed; the other two prospects are on the Khorat Plateau. The base-metal prospects are in volcanic or carbonate rocks. Four prospects have been tested by diamond drilling; disseminated copper deposits were found at two prospects and local lead-zinc mineralization at the other two.The two copper deposits have estimated proven and probable reserves of 16million tons containing about 1 percent copper, and possible reserves of 62 million tons. The iron prospects are mostly metasomatic, at contacts of granodiorite with sedimentary and volcanic rocks. Four of the iron prospects were tested by diamond drilling; proven, probable, and possible reserves of about 27million tons containing 52 percent iron were developed predominantly in two deposits. Twelve manganese and two gold prospects were investigated, but all are small or low grade. Nonmetallic deposits of barite, gypsum, and limestone (cement grade) were examined in the Loei-Chiengkarn area, and salt was studied at Chaiyaphum. Reserves of approximately 5.5 million tons of barite, half a million tons of gypsum, 12 million tons of limestone (cement grade), and 2,000 million tons of salt were estimated to be present. Economic development of these deposits must await recommended economic feasibility studies and additional geological work, including diamond drilling.

Open-File Report↗

Mineral investigations in the Jabal Radwa quadrangle, northwest Hijaz, Saudi Arabia

Wadi sediments in the Jabal Radwa quadrangle in the Northwest Hijaz were sampled for trace element analysis as part of a mineral reconnaissance of Western Saudi Arabia that is being made by the Ministry of Petroleum and Mineral Resources and the U.S. Geological Survey. The Jabal Radwa quadrangle lies between 24?30? and 25?N. latitude and between 38? and 39? longitude. A photomosaic base at a scale of 1:100,000 was used for map compilation. Except for basalt flows of Tertiary or Quaternary age all the rocks of the area are believed to be of Precambrian age. An older group of slightly metamorphosed mafic and felsic volcanic rocks with interbedded metasedimentary rocks is unconformably overlain by argillite and slightly metamorphosed sandstone and conglomerate. The bedded rocks are cut by many intrusions that range in composition from olivine gabbro to syenite but are predominantly granite, granodiorite, and diorite. Little is known of the structure of the rocks. The layered rocks are strongly folded and commonly dip at high angles. Faults are common and many appear to be large; some contacts have been offset several hundred meters. Most of the larger faults trend northeasterly or northwesterly but some trend east and others nearly north.

Open-File Report↗

Mineral exploration between Bi'ir Idimah and Wadi Haraman, Asir quadrangle, Saudi Arabia

An area of 10,000 sq. km between Bi'r Idimah and Wadi Haraman in southern Saudi Arabia was investigated for mineral deposits during the period May 8, 1965, to June 27, 1965. At least 25 different minerals and industrial rocks occur in the area, but of these materials only asbestos seems to have a real possibility for industrial development. Twenty occurrences of asbestos were found around the Higera gold mine and between Hamdah and Bi'r El Marwahs A favorable area for asbestos exists north and east of Tathlith, but none was discovered there. It is recommended that the Hamdah-Bi'r El Marwah area be examined in detail, and the Higera and Tathlith areas receive reconnaissance studies for asbestos. Asbestos is a high-value commodity which can be processed by air separation, thereby freeing its benefitiation from dependence on water. Examination of the asbestos deposits would have as a by-product an appraisal of the resources of soapstone, anthophyllite, talc, vermiculite, chromite, calcite, gold, and copper in the three asbestos districts. Thirty-six occurrences of marble were found in the area. Several have favorable characteristics for industrial or architectural use. One ancient mine, the Ishaaib (19°15'N.x 43°40'E.), may contain copper.

Open-File Report↗

Recommended geophysical investigations of mineral occurrences at Jabal Samran, Al Marasia, and Wutaileh

A familiarization and reconnaissance trip was made in the vicinity of Jabal Samran during 7-8 April 1968. The trip was suggested by E. Heaton and W. Liddicoat, Ministry of Petroleum and Mineral Resources for the purpose of inspecting the mineral occurrences at Jabal Samran, Al Marasia, and Wutaileh, and recommending feasible geophysical methods which should be applied to the study of these occurrences.

Al Marasia, Jabal Samran, Wutaileh↗

Heavy-minerals reconnaissance in the Fatimah Formation, near Jiddah, Saudi Arabia

Near Jiddah, Saudi Arabia, a heavy-minerals survey was made in the Precambrian sediments o# the Fatima Formation. Samples measuring 0.25 cubic meters were taken in a net related to the drainage system and. washed in a sluice. The concentrates were tested. for 29 elements which included precious and. base metals, rare earths, and. radioactive elements. Only 17 elements were detected in the samples and all values were normal. The concentrates contained only common species o# heavy density resistate minerals. The survey showed that the area is not a favorable one in which to search for ores of the elements tested.

Open-File Report↗

Geology and mineral deposits of the Wadi an Nuqumi quadrangle, Kingdom of Saudi Arabia

The rocks, structures, and mineral deposits of the Wadi an Nuqumi quadrangle were formed during three periods of deformation, two of Precambrian age and one of Tertiary and Recent age. The older Precambrian Halaban cycle produced the thick eugeosynclinal suite of interlayered metasedimentary and metavolcanic rocks comprising the Halaban Formation, the numerous synorogenic granitic masses which intrude the layered rocks, and the northward-trending tectonic, plutonic, and metamorphic features of all these rocks which constitute the basic grain of the area. The older Halaban features are everywhere strongly transected, but only slightly deformed and offset, by many eastward-northeastward-, and northwestward-striking fractures and strike-slip faults. Silicic dikes are emplaced in these fractures, and several kinds of barren and metalliferous veins are closely associated with them. All these features are here thought to have formed during a period of deformation of late Precambrian age which produced the Najd Wrench Fault Zone; therefore, these features are named for it. Sporadic remnants of once far more extensive basaltic lava fields and the north-northwestward-striking vertical fractures which occur in them and contain volcanic vents from which they were extruded are the youngest rocks and structures in the Wadi an Nuqumi area. They are thought to have formed during the period of tectonic and volcanic activity which also produced the Red Sea graben. The principal mineral deposits of the Wadi an Nuqumi area are silicified-carbonate breccia veins which occur in structures of the Najd Wrench Fault deformation and metalliferous quartz veins which are closely associated with them. Only the latter possesses any economic potential, the most promising being the gold and silver-bearing quartz-base metal veins of the Al Numrahniyah and Muthaheel ancient mines.

Open-File Report↗

Aeromagnetic interpretation and mineral investigations in the Bolu, Canakkale-Karabiga, Demirkoy, Ezine, and Orhaneli areas of northwestern Turkey in 1968

This report reviews progress made during 1968 in the continuing Joint Haden Tetkik ve Arama Enstitusu (MSA)-U. S. Geological Survey (USGS) Mineral Exploration and Training Project, Subproject 2. Subproject 2 is concerned with aeromagnetic interpretation of MTA's aeromagnetic surveys, and ground investigations of selected aeromagnetic anomalies. This report includes new aeromagnetic maps for the Bolu, Canakkale-Karabiga, Demirkoy, and Orhaneli areas and reviews ground investigations in five areas. Activities for each area are sunmarized below: 1. Bolu area: The aeromagnetic map shows two belts of anomalies related to regional magnetite-bearing formations and a group of discrete anomalies, some of which may reflect significant concentrations of magnetite. To date three of these anomalies have been checked on the ground and at one a metamorphic rock containing 14 percent magnetite was observed. 2. Canakkale-Karabiga area: Ground checks were made of six aeromagnetic anomalies. At one locality (Cakirly-Koyu) 6 km south of Nazmara Sea a small magnetite deposit was found. The magnetic anomaly over the area is 150 meters long, and about 3 meters deep in the center of the anomaly exposed massive magnetite boulders. 3. Demirkoy area: The aeromagnetic map shows only one significant anomaly which was checked on the ground and found to be caused by minor magnetite at an intrusive contact. 4. Ezine area: A ground survey of 4.5 sq km area was made where magnetite boulders are locally present on the surface. No significant magnetic anomaly or iron mineralization were found. 5. Orhaneli area: The aeromagnetic map o# the area showed regional magnetic anomaly patterns related to magnetite in mafic intrusives, ultramafic rocks, and mafic flow rocks. In addition 16 localized anomalies were identified. Most of these anomalies were checked on the ground but no significant iron deposits were found. The largest deposit found was a one-meter wide magnetite vein. During the 1969 field season further investigation of anomalies in the Bolu and Orhaneli areas is planned.

Open-File Report↗

Radioactive mineral springs in Delta County, Colorado

The system of springs in Delta County, Colo., contains geochemical clues to the nature and location of buried uranium-mineralized rock. The springs, which occur along the Gunnison River and a principal tributary between Delta and Paonia, are regarded as evidence of a still-functioning hydrothermal system. Associated with the springs are hydrogen sulfide and sulfur dioxide gas seeps, carbon dioxide gas-powered geysers, thick travertine deposits including radioactive travertine, and a flowing warm-water (41?C) radioactive well. Geochemical study of the springs is based on surface observations, on-site water-property measurements, and sampling of water, travertine, soft precipitates, and mud. The spring deposits are mostly carbonates, sulfates, sulfides, and chlorides that locally contain notable amounts of some elements, such as arsenic, barium, lithium, and radium. Samples from five localities have somewhat different trace element assemblages even though they are related to the same hydrothermal system. All the spring waters but one are dominated by sodium chloride or sodium bicarbonate. The exception is an acid sulfate water with a pH of 2.9, which contains high concentrations of aluminum and iron. Most of the detectable radioactivity is due to the presence of radium-226, a uranium daughter product, but at least one spring precipitate contains abundant radium-228, a thorium daughter product. The 5:1 ratio of radium-228 to radium-226 suggests the proximity of a vein-type deposit as a source for the radium. The proposed locus of a thorium-uranium mineral deposit is believed to lie in the vicinity of Paonia, Colo. Exact direction and depth are not determinable from data now available.

Open-File Report↗

Depositional environments as a guide to uranium mineralization in the Chinle Formation, San Rafael Swell, Utah

Uranium deposits in the San Rafael Swell are related to sedimentary depositional environments in the Triassic Chinle Formation. The sedimentary textures resulting from depositional processes operating in lower energy environments appear to have influenced uranium mineralization. The Chinle consists of three fining-upward, fluvial-lacustrine sequences. Uranium mineralization is concentrated in the lower part of the lowest sequence in areas where sediments of lower energy environments are complexly interbedded with sediments of other environments. Areas favorable for uranium exploration exist in the subsurface to the north, west, and south of the Chinle outcrop in the Swell. This determination is based on the spatial distribution of depositional environments and the pattern of Chinle deposition through time.

Open-File Report↗

Recent and projected changes in Dead Sea level and effects on mineral production from the sea

Hydrologic data for the Dead Sea area were reviewed to assess the probable magnitude and rate of change of the water level of the Dead Sea. Historical average annual Dead Sea levels range from a minimum of 399.4 meters below sea level in about 1818 to a maximum of 388.6 meters below in 1896. Present levels are rapidly approaching the historical low. There is a close correlation between Dead Sea level and accumulated departure from the mean of long-term rainfall except for the most recent period since 1964. During that period rainfall has been near the long-term average but water levels have continued to decline, in part due to abstractions for irrigation in the Jordan River basin. The dissolved-solids concentration of Dead Sea water presently is approximately 322,000 milligrams per liter and is generally well mixed throughout. This concentration is at the saturation level, resulting in continuous precipitation of some salts. The increase in dissolved solids to the present high concentration has resulted in an evaporation rate less than that estimated in previous reports. Evaporation rate from the North Basin is estimated at 1,310 millimeters per year at present. The evaporation rate from the South Basin was not estimated due to extensive existing or planned modifications for mineral production facilities. Water budget computations were performed at various inflow rates in order to project water-level changes for 50 years. Computations assumed closure of the South Basin by existing and proposed mineral extraction facilities. The projected 50-year changes ranged from a decline of 51 meters with no inflow from any sources to a rise of 10.2 meters when average annual inflow from the Jordan River was 750 cubic hectometers. An average annual inflow to the Sea of 900 cubic hectometers from all sources is required to stabilize the Sea at the present level. Principal impact of declining water levels on proposed potash production facilities in Jordan would be an increase in power requirements. A cursory review of a proposed plan to divert water from the Mediterranean Sea into the Dead Sea to generate electric power and stabilize water levels indicates a very limited impact on chemical, physical, and ecological characteristics of the Dead Sea in the near future. Water-budget computations indicate that if all but 200 cubic hectometers of tributaries' waters were utilized for irrigation and other purposes, a maximum diversion of 700 cubic hectometers per year into the Dead Sea would be possible without significantly raising long-term average water levels.

Dead Sea↗

Radioactivity and geochemistry of selected mineral-spring waters in the Western United States; basic data and multivariate statistical analysis

Multivariate statistical analyses were performed on data from 156 mineral-spring sites in nine Western States to analyze relationships among the various parameters measured in the spring waters. Correlation analysis and R-mode factor analysis indicate that three major factors affect water composition in the spring systems studied: (1) duration of water circulation, (2) depth of water circulation, and (3) partial pressure of carbon dioxide. An examination of factor scores indicates that several types of hydrogeologic systems were sampled. Most of the samples are (1) older water from deeper circulating systems having relatively high salinity, high temperature, and low Eh or (2) younger water from shallower circulating systems having relatively low salinity, low temperature, and high Eh. The rest of the samples are from more complex systems. Any of the systems can have a relatively high or low content of dissolved carbonate species, resulting in a low or high pH, respectively. Uranium concentrations are commonly higher in waters of relatively low temperature and high Eh, and radium concentrations are commonly higher in waters having a relatively high carbonate content (low pH) and, secondarily, relatively high salinity. Water samples were collected and (or) measurements were taken at 156 of the 171 mineral-spring sites visited. Various samples were analyzed for radium, uranium, radon, helium, and radium-228 as well as major ions and numerous trace elements. On-site measurements for physical properties including temperature, specific conductance, pH, Eh, and dissolved oxygen were made. All constituents and properties show a wide range of values. Radium concentrations range from less than 0.01 to 300 picocuries per liter; they average 1.48 picocuries per liter and have an anomaly threshold value of 171 picocuries per liter for the samples studied. Uranium concentrations range from less than 0.01 to 120 micrograms per liter and average 0.26 micrograms per liter; they have an anomaly threshold value of 48.1 micrograms per liter. Radon content ranges from less than 10 to 110,000 picocuries per liter, averages 549 picocuries per liter and has an anomaly threshold of 20,400 picocuries per liter. Helium content ranges from -1,300 to +13,000 parts per billion relative to atmospheric helium; it averages +725 parts per billion and has an anomaly threshold of 10,000 parts per billion. Radium-228 concentrations range from less than 2.0 to 33 picocuries per liter; no anomaly threshold was determined owing to the small number of samples. All of the anomaly thresholds may be somewhat high because the sampling was biased toward springs likely to be radioactive. The statistical variance in radium and uranium concentrations unaccounted for by the identified factors testifies to the complexity of some hydrogeologic systems. Unidentified factors related to geologic setting and the presence of uranium-rich rocks in the systems also affect the observed concentrations of the radioactive elements in the water. The association of anomalous radioactivity in several springs with nearby known uranium occurrences indicates that other springs having anomalous radioactivity may also be associated with uranium occurrences as yet undiscovered.

Open-File Report↗

Chemical and isotopic composition of water from thermal springs and mineral springs of Washington

Water from thermal springs of Washington range in chemical composition from dilute NaHC03, to moderately saline C02-charged NaHC03-Cl waters. St. Martin 's Hot Spring which discharges a slightly saline NaCl water, is the notable exception. Mineral springs generally discharge a moderately saline C02-charged NaHC03-Cl water. The dilute Na-HC03 waters are generally associated with granite. The warm to hot waters charged with C02 issue on or near the large stratovolcanoes and many of the mineral springs also occur near the large volcanoes. The dilute waters have oxygen isotopic compositions which indicate relatively little water-rock exchange. The C02-charged waters are usually more enriched in oxygen-18 due to more extensive water-rock reaction. Carbon-13 in the C02-charged thermal waters is more depleted (-10 to -12 permil) than in the cold C02-charged soda springs (-2 to -8 permil) which are also scattered throughout the Cascades. The hot and cold C02-charged waters are supersaturated with respect to CaC03, but only the hot springs are actively depositing CaC03. Baker, Gamma, Sulphur , and Ohanapecosh seem to be associated with thermal aquifers of more than 100C. (USGS)

Open-File Report↗