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Thorium and rare earth minerals in the Powderhorn district, Gunnison County, Colorado

Thorium has been found since 1949 in at least 33 deposits in an area 6 miles wide and 20 miles long in the Powderhorn district, Gunnison County, Colo. The district is composed largely of pre-Jurassic metamorphic and igneous rocks, which are chiefly if not entirely pre-Cambrian in age. The metamorphic and igneous rocks are overlain by sandstone of the Morrison formation of Jurassic age, and by volcanic rocks of the Alboroto group and Hinsdale formation of Miocene and Pliocene (?) age, respectively. The thorium deposits occur in or near alkalic igneous rocks in which such elements as titanium, rare earths, barium, strontium, and niobium occur in greater-than-average amounts. The greatest mass of the alkalic igneous rocks the Iron Hill composite stoc,- occupies an area of 12 square miles in the southeastern part of the district. The age of the thorium deposits, like that of the alkalic igneous rocks, is not known other than pre-Jurassic. The thorium veins and mineralized shear zones range from a few inches to 18 feet in thickness and from a few feet to 3,500 feet in length. The veins are composed of calcite,.dolomite, siderite, ankerite, quartz, barite, pyrite, sphalerite, galena, goethite,. apatite, alkali feldspar, and many other minerals. The thorium occurs at least partly in thorite or hydrothorite. Sparse xenotime has been tentatively identified in one deposit. Several minerals containing rare earths of the cerium group as major constituents are found in carbonate veins near Iron Hill. Bastnaesite has been identified by X-ray methods, and cerite and synchisite are probably present also.The fluorapatite in some veins and in parts of the carbonate rock mass that occupies 2 square miles in the central part of the Iron Hill complex contains rare earths of the cerium group, generally in amounts of a fraction of a percent of the rock. The radioactivity of the deposits appears to be due almost entirely to thorium and its daughter products The ThO 2 content of selected highgrade samples from the Little Johnnie vein is as much as 4 percent. The ThO 2 content of the veins is generally less than 1 percent, however, and is only 0.05 to 0.1 percent in many of the veins studied. The little Johnnie vein, which was mapped in detail, can be traced discontinuously for a distance of more than 3,500 feet. The thoriumbearing material occurs as irregular veinlets and thin films introduced into the fault zone. The mineralized shear zone ranges from less than 6 inches to 5 feet in thickness. Near its west end the vein is broken by many faults in a zone that marks the edge of a roughly circular fault block, 1 1/2. miles in diameter, that has dropped 1,000 feet or more since the deposition of Miocene volcanic-rocks that now floor the Milkranch basin.

Colorado↗

Behavior of Colorado Plateau uranium minerals during oxidation

Uranium occurs as U(VI) and U(IV) in minerals of the Colorado Plateau ores. The number of species containing U(VI) is large, but only two U(IV) minerals are known from the Plateau: uraninite, and oxide, and coffinite, a hydroxy-silicate. These oxidize to yield U(VI) before reacting significantly with other mineral constituents. Crystal-structure analysis has shown that U(VI) invariable occurs as uranyl ion, UO 2 +2 . Uranyl ion may form complex carbonate or sulfate ions with resulting soluble compounds, but only in the absence of quinquevalent vanadium, arsenic, or phosphorous. In the presence of these elements in the +5 valence state, the uranyl ion is fixed in insoluble layer compounds formed by union of uranyl ion with orthovanadate, orthophosphate, or orthoarsenate. Under favorable conditions UO 2 +2 may react to form the relatively insoluble rutherfordine, UO 2 CO 3 , or hydrated uranyl hydroxides. These are rarely found on the Colorado Plateau as opposed to their excellent development in other uraniferous areas, a condition which is apparently related to the semiarid climate and low water table of the Plateau. Uranium may also be fixed as uranyl silicate, but little is known about minerals of this kind. In the present study emphasis has been placed on a detailing of the chemical and crystal structural changes which occur in the oxidation paragenetic sequence.

Utah↗

Radioactive minerals in the Yakataga beach placers, southern Alaska

Radioactivity of nine samples of beach placer deposits in the Yakataga area, southern Alaska, was studied in 1948. The samples were given to the Geological Survey by prospectors operating in the area operating in the area. The heavy-mineral fractions from the concentrates average 0.044 percent equivalent uranium. Three minerals, all members of the zircon group, contain the radioactive material in the sample; one mineral is uranium-bearing, the other two are thorium-bearing. Unless the concentration of radioactive minerals in the beach deposits is considerably higher than the present qualitative data indicate, the placers at Yakataga beach do not constitute a feasible source of supply of radioactive materials.

Alaska↗

Probability calculations for three-part mineral resource assessments

Three-part mineral resource assessment is a methodology for predicting, in a specified geographic region, both the number of undiscovered mineral deposits and the amount of mineral resources in those deposits. These predictions are based on probability calculations that are performed with computer software that is newly implemented. Compared to the previous implementation, the new implementation includes new features for the probability calculations themselves and for checks of those calculations. The development of the new implementation lead to a new understanding of the probability calculations, namely the assumptions inherent in the probability calculations. Several assumptions strongly affect the mineral resource predictions, so it is crucial that they are checked during an assessment. The evaluation of the new implementation leads to new findings about the probability calculations,namely findings regarding the precision of the computations,the computation time, and the sensitivity of the calculation results to the input.

Techniques and Methods↗

Secondary Mineral Deposits and Evidence of Past Seismicity and Heating of the Proposed Repository Horizon at Yucca Mountain, Nevada

The Drift Degradation Analysis (DDA) (BSC, 2003) for the proposed high-level radioactive waste repository at Yucca Mountain, Nevada, describes model simulations of the effects of pre- and post-closure seismicity and waste-induced heating on emplacement drifts. Based on probabilistic seismic hazard analyses of the intensity and frequency of future seismic events in the region (CRWMS M&O, 1998), the DDA concludes that future seismicity will lead to substantial damage to emplacement drifts, particularly those in the lithophysal tuffs, where some simulations predict complete collapse of the drift walls. Secondary mineral studies conducted by the U.S. Geological Survey since 1995 indicate that secondary calcite and silica have been deposited in some fractures and lithophysal cavities in the unsaturated zone (UZ) at Yucca Mountain during at least the past 10 million years (m.y.), and probably since the tuffs cooled to less than 100?C. Tuff fragments, likely generated by past seismic activity, have commonly been incorporated into the secondary mineral depositional sequences. Preliminary observations indicate that seismic activity has generated few, if any, tuff fragments during the last 2 to 4 m.y., which may be inconsistent with the predictions of drift-wall collapse described in the DDA. Whether or not seismicity-induced tuff fragmentation occurring at centimeter to decimeter scales in the fracture and cavity openings relates directly to failure of tuff walls in the 5.5-m-diameter waste emplacement drifts, the deposits do provide a potential record of the spatial and temporal distribution of tuff fragments in the UZ. In addition, the preservation of weakly attached coatings and (or) delicate, upright blades of calcite in the secondary mineral deposits provides an upper limit for ground motion during the late stage of deposition that might be used as input to future DDA simulations. Finally, bleaching and alteration at a few of the secondary mineral sites indicate that they were subjected to heated gases at approximately the temperatures expected from waste emplacement. These deposits provide at least limited textural and mineralogic analogs for waste-induced, high-humidity thermal alteration of emplacement drift wall rocks.

Water-Resources Investigations Report↗

Mineral chemistry and shrimp U-Pb Geochronology of mesoproterozoic polycrase-titanite veins in the sullivan Pb-Zn-Ag Deposit, British Columbia

Small polycrase-titanite veins 0.1-2 mm thick cut the tourmalinite feeder zone in the deep footwall of the Sullivan Pb-Zn-Ag deposit, southeastern British Columbia. Unaltered, euhedral crystals of polycrase and titanite 50-100 ??m in diameter are variably replaced by a finer-grained alteration-induced assemblage composed of anhedral polycrase and titanite with local calcite, albite, epidote, allanite, and thorite or uranothorite (or both). Average compositions of the unaltered and altered polycrase, as determined by electron-microprobe analysis, are (Y0.38 REE0.49 Th0.10 Ca0.04 Pb0.03 Fe0.01U0.01) (Ti1.48 Nb0.54 W0.04 Ta0.02)O6 and (Y0.42 REE0.32 Th0.15 U0.06 Ca0.04 Pb0.01 Fe0.01) (Ti1.57 Nb0.44 W0.04 Ta0.02)O6, respectively. The unaltered titanite has, in some areas, appreciable F (to 0.15 apfu), Y (to 0.40 apfu), and Nb (to 0.13 apfu). SHRIMP U-Pb geochronology of eight grains of unaltered polycrase yields a weighted 207Pb/206Pb age of 1413 ?? 4 Ma (2??) that is interpreted to be the age of vein formation. This age is 50-60 m.y. younger than the ca. 1470 Ma age of synsedimentary Pb-Zn-Ag mineralization in the Sullivan deposit, which is based on combined geological and geochronological data. SHRIMP ages for altered polycrase and titanite suggest later growth of minerals during the ???1370-1320 Ma East Kootenay and ???1150-1050 Ma Grenvillian orogenies. The 1413 ?? 4 Ma age for the unaltered polycrase in the veins records a previously unrecognized post-ore (<1470 Ma) and premetamorphic (>1370 Ma) mineralizing event in the Sullivan deposit and vicinity. The SHRIMP U-Pb age of the polycrase and high concentrations of REE, Y, Ti, Nb, and Th in the veins, together with elevated F in titanite and the absence of associated sulfides, suggest transport of these high-field-strength elements (HFSE) by F-rich and S-poor hydrothermal fluids unrelated to the fluids that formed the older Fe-Pb-Zn-Ag sulfide ores of the Sullivan deposit. Fluids containing abundant REE, HFSE, and F may have been derived from a geochemically specialized magma such as those that form alkaline granites, pegmatites, or carbonatites. In an alternative model. preferred here, these fluids were associated with a rift-related, crustal metasomatic event in the region. Determination of a Mesoproterozoic age for the polycrase-titanite veins establishes the first known occurrence of pre-Grenvillian REE-rich mineralization in the Belt-Purcell basin.

Canadian Mineralogist↗

Application of imaging spectroscopy for mineral exploration in Alaska: A study over porphyry Cu deposits in the eastern Alaska Range

The U.S. Geological Survey tested the utility of imaging spectroscopy (also referred to as hyperspectral remote sensing) as an aid to regional mineral exploration efforts in remote parts of Alaska. Airborne imaging spectrometer data were collected in 2014 over unmined porphyry Cu deposits in the eastern Alaska Range using the HyMap™ sensor. Maps of the distributions of predominant minerals, made by matching reflectance signatures in the remotely sensed data to reference spectra in the shortwave infrared region, do not uniquely discriminate individual rock units. However, they do highlight hydrothermal alteration associated with porphyry deposits and prospects hosted mostly within the Nabesna pluton. In and around porphyry Cu deposits at Orange Hill and Bond Creek, unique spectral signatures are related to variations in chlorite and white mica abundance and their chemical composition. This is best revealed in the longer-wavelength 2,200-nm Al-OH absorption feature positions in pixels spectrally dominated by white mica proximal to porphyry deposits. Similar spectral signatures of chlorite and white mica wavelength positions were also recognized away from the porphyry deposits; follow-up sampling identified these satellite areas to also contain Cu-Mo-Au mineralized rock. Our study confirms that airborne imaging spectroscopy has application for regional mineral exploration in exposed mountainous terrain in Alaska.

Alaska↗

Magmatic-hydrothermal gold mineralization at the Lone Tree Mine, Battle Mountain district, Nevada

The Lone Tree deposit is located in the northern Battle Mountain mining district, Nevada. Prior to mine closure in 2006, Santa Fe Pacific Gold and Newmont produced 4.2 Moz of gold at an average grade of 2.06 g/t at Lone Tree, primarily from the N-S– to NNW-SSE–striking Wayne zone. The ore is located between the Roberts Mountain and Golconda thrusts in siliciclastic rocks of the Ordovician Valmy Formation and in the Pennsylvanian-Permian Battle Mountain and Edna Mountain Formations, and above the Golconda thrust in siliciclastic and carbonate rocks of the Mississippian to Permian Havallah sequence. Ore is also hosted by rhyolitic dikes that were emplaced at 40.95 ± 0.06 Ma based on zircon U-Pb chemical abrasion-thermal ionization mass spectrometry. The gold is associated with sericitic and argillic alteration of the siliciclastic rocks and dikes and with decarbonatization and Fe carbonate alteration of the carbonate-bearing units, as well as in Fe-As sulfide and finegrained quartz alteration of all rock types. Oxidation affects 30 to 45% of the deposit, penetrating into the stratigraphy along numerous steeply dipping north-south, east-west, and north-northeast–south-southwest structures. Gold is positively correlated with Ag, As, Hg, and Sb. The highest Au grades occur in quartz-sulfide ore hosted in siliciclastic and carbonate sedimentary rocks and rhyolitic intrusions. In this ore style, fine-grained quartz and sericite are intergrown with disseminated sulfide minerals (quartz-sericite-pyrite alteration), constituting cores of weakly mineralized pyrite or marcasite, which are surrounded by fuzzy arsenopyrite rims that contain up to ~2,000 ppm Au. Low gold grades occur in late-stage banded pyrite breccias consisting of a finely zoned Au-poor pyrite matrix surrounding jigsaw-fit clasts of quartz-, illite-, barite-, and adularia-altered siliciclastic rock. The timing of main-stage mineralization is bracketed between the emplacement of the dikes and an adularia 40 Ar/ 39 Ar age of 40.14 ± 0.74 Ma. Sericite intergrown with arsenopyrite-rimmed pyrite in phenocrysts of the rhyolite dikes gave δ 18 O values of 1.6 to 9.5‰ and δ D values of –105 to –145‰. For temperatures of 300 ± 100°C, the calculated fluid isotopic compositions are consistent with felsic magmatic water and minor modifications by mixing with meteoric water and exchange with wall rocks. In the silica-sulfide ore, in situ isotopic laser ablation-multicollector-inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS) analyses of pyrite cores yielded δ 34 S values ranging from 3.4 to 7.7‰, with average values of 5.6‰ in the felsic dikes, 4.5‰ in the siliciclastic rocks, and 5.3‰ in the carbonate rocks. These values match conventional pyrite δ 34 S data reported for Eocene porphyry systems elsewhere in the district. Nanoscale secondary ion mass spectrometry analyses show that gold and associated trace elements occur in submicron-scale zones within arsenopyrite rims on pyrite. The average δ 34 S values of the arsenopyrite rims are 5.3 to 6.5‰ heavier than the pyrite cores, indicating cooling and an increasing H 2 S/SO 2 ratio. The highest grades resulted from episodic pulses of a gold-rich fluid that was partly derived from, or exchanged with, the sedimentary host rocks. In situ LA-MC-ICP-MS δ 34 S values for the late-stage banded pyrite breccia become progressively lighter from veinlet margin to center, reaching a low of –32‰. These veinlets indicate a shift from main-stage quartz-sericite-pyrite and intermediate argillic alteration to more neutral pH and oxidizing conditions during late-stage mineralization, indicating either increasing interaction between the fluid and sedimentary sulfur sources in the host-rock package or bacterial sulfate reduction and supergene sulfide precipitation.

Nevada↗

Paragenesis of an orogenic gold deposit: New insights on mineralizing processes at the Grass Valley District, California

The Grass Valley orogenic gold district in the Sierra Nevada foothills province, central California, is the largest historical gold producer of the North American Cordillera. Gold mineralization is associated with shallowly dipping north-south veins hosted by the 160 Ma Grass Valley granodiorite to the southwest of the Grass Valley fault and steeply dipping east-west veins in accreted oceanic rocks to the northeast of this major fault. Quartz veins from both vein types show well-preserved primary textural relationships. Using a combination of petrographic and microanalytical techniques, the paragenetic sequence of minerals within the veins and the compositions of ore minerals were determined to constrain the mechanisms of quartz vein formation and gold deposition. The veins are composed of early quartz that formed through cooling of hydrothermal fluids derived from a geopressured reservoir at depth. The early quartz shows growth zoning in optical cathodoluminescence and contains abundant growth bands of primary inclusions. The primary inclusion assemblages and myriads of crosscutting secondary fluid inclusions have been affected by postentrapment modification, suggesting that early quartz formation was postdated by pronounced pressure fluctuations. These pressure fluctuations, presumably involving changes from lithostatic to hydrostatic conditions, may be related to fault failure of the host structure as predicted by the fault-valve model. Fluid flow associated with pressure cycling took place along microfractures and grain boundaries resulting in extensive recrystallization of the early quartz. Deposition of pyrite, arsenopyrite, and first-generation gold from these hydrothermal fluids causing recrystallization of the early quartz occurred as a result of wall-rock sulfidation. The gold forms invisible gold in the compositionally zoned pyrite or micron-sized inclusions within pyrite growth zones. The latest growth zones in euhedral quartz crystals that formed in association with this stage of the paragenesis contain very rare primary fluid inclusions that have not been affected by postentrapment modification. The hydrothermal system transitioned entirely to hydrostatic conditions immediately after formation of the latest quartz, explaining the preservation of the primary fluid inclusions. The formation of minor quartz in open spaces was followed by the deposition of second-generation native gold and telluride minerals that are commonly associated with base metal sulfides. Ore formation at this stage of the paragenesis is attributed to the rapid decompression of hydrothermal fluids escaping from the geopressured part of the crust into the overlying hydrostatic realm. There is no fluid inclusion evidence that this pressure drop resulted in fluid immiscibility of the hydrothermal fluids. Fluid inclusion evidence suggests that the north-south veins formed at a paleodepth of ~8 km, whereas the east-west veins appear to have formed at ~10 to 11 km below surface, confirming previous inferences that the NE-dipping Grass Valley reverse fault accommodated a large displacement. The findings of the study at Grass Valley have significant implications for the model for orogenic gold deposits, as the reconstruction of the paragenetic relationships provides evidence for the occurrence of two discrete events of gold introduction that occurred at different conditions during the evolution of the hydrothermal system.

California↗

Geologic setting and characteristic of mineral deposits in the central Wasatch Mountains, Utah

Base- and precious-metal deposits in the central Wasatch Mountains southeast of Salt Lake City were mined for more than 100 years beginning in 1868. Deposits present in the Park City, Little Cottonwood, and Big Cottonwood mining districts include Ag-Pb-Zn ± Cu ± Au replacements and veins, a low-grade porphyry Cu-Au deposit, Cu-bearing skarns, a quartz monzonite-type (low F) porphyry Mo deposit, and high sulfidation (quartz-alunite) Au deposits. Most production came from polymetallic replacement and vein deposits in the Park City mining district, which has a recorded production of more than 1.4 million oz Au, 253 million oz Ag, 2.7 billion lbs Pb, 1.5 billion lbs Zn, and 129 million lbs Cu from 1872 to 1978. Production in the Little and Big Cottonwood districts, mostly from Pb-Ag replacement deposits, was much smaller. Most mineral deposits in the central Wasatch Mountains are genetically related to the Wasatch igneous belt, a series of high-K calc-alkaline stocks and cogenetic volcanic rocks that formed about 41(?) to 30 Ma. The mineral deposits mostly formed near the end of magmatic activity between about 36 to 31.4 Ma. A subeconomic porphyry Mo deposit in the Little Cottonwood stock is notably younger having formed about 26 to 23.5 Ma. The intrusive rocks were emplaced mostly along the westward extension of the west-trending Uinta arch during a period of NW-SE-directed extension, and much of the mineralization in the Park City district was controlled by ENE-striking normal faults. About 15 degrees of eastward tilting of the central Wasatch Mountains during Late Cenozoic Basin and Range extension has resulted in progressively deeper levels of exposure from <1 km on the east to about 11 km on the west and in profound variations in the types of mineral deposits exposed in different parts of the range. Most deposits formed at paleodepths ≤5 km, and the most productive deposits in the Park City district formed at depths of 1 to 2 km. The porphyry Mo deposit in the Little Cottonwood stock formed at greater depths of about 6 km.

Utah↗

New K-Ar and 40Ar/39Ar ages of plutonism, hydrothermal alteration, and mineralization in the central Wasatch Mountains, Utah

Twenty-one new K-Ar and 10 new 40 Ar/ 39 Ar ages are reported for igneous and hydrothermal minerals from intrusive rocks of the Wasatch igneous belt in the central Wasatch Mountains. Interpretation of our new data combined with previously published K-Ar ages and with new 40 Ar/ 39 Ar and U-Pb ages reported by Vogel et al. (1997) suggests that the Clayton Peak stock was emplaced at about 36 to 35 Ma, the Alta stock at about 35 to 33 Ma, and the Little Cottonwood stock at about 31 to 30 Ma. Biotite K-Ar ages progressively increase from west to east in the Little Cottonwood stock, which is consistent with more rapid cooling of the eastern part of the stock and with other evidence suggesting about 15 degrees of eastward tilting of the central Wasatch Mountains following emplacement of the Wasatch igneous belt. Most porphyry stocks in the Park City mining district were emplaced at about 41 to 40 Ma; the Ontario stock was emplaced at about 36 Ma. Vein deposits in the Park City mining district formed at about 36 to 33 Ma. The Park Premier stock was emplaced in several pulses between about 35 to 32 Ma. Alteration related to porphyry copper mineralization in the Park Premier stock formed at 33.5 Ma and advanced argillic alteration and gold mineralization formed at 31.4 Ma. Molybdenum mineralization in the eastern part of the Little Cottonwood stock formed between 26 to 23.5 Ma.

Utah↗

Chapter 10: Regional- to deposit-scale geologic controls on copper-silver mineralization in the Kalahari Copperbelt, Botswana

The Kalahari Copperbelt in northwestern Botswana is characterized by structurally controlled, stratabound, mineralogically zoned copper-silver deposits hosted along a major redox boundary within a late Mesoproterozoic rift succession. Copper-silver mineralized rocks occur on the limbs and in the hinge positions of regional-scale folds that characterize the Pan-African Ghanzi-Chobe zone fold-and-thrust belt. Regional facies changes along the base of the transgressive marine D’Kar Formation, the host to the majority of mineralized rocks, delineate a series of synsedimentary basin highs and lows. The facies changes were identified through both lithostratigraphic analysis of drill holes and along-strike variations in magnetic lithostratigraphy, a technique that correlates the magnetic fabrics of second vertical derivative aeromagnetic maps with changes in lithostratigraphy. Basin highs controlled the development and distribution of favorable lithostratigraphic and lithogeochemical trap sites for later sulfide precipitation. Major facies changes across the Ghanzi Ridge area straddle a significant crustal structure identified in gravity datasets that appears to have influenced extensional activity during basin development. During basin inversion, the basin highs, cored by rheologically stronger bimodal volcanic rocks, localized strain within mechanically weaker rock types of the Ghanzi Group metasedimentary rocks, leading to the development of locally significant permeability and the formation of structural trap sites for mineralization by hot (250°–300°C), oxidizing, metalliferous Na-Ca-Cl brines. Structural permeability was maintained within trap sites due to silicification and/or feldspar alteration during progressive deformation and associated hydrothermal mineralizing events.

Kalahari Copperbelt↗

SURVEY OF ASBESTOS-RELATED DISEASES IN TRADES AND MINING OCCUPATIONS AND IN FACTORY AND MINING COMMUNITIES AS A MEANS OF PREDICTING HEALTH RISKS OF NONOCCUPATIONAL EXPOSURE TO FIBROUS MINERALS.

A review based on 36 published epidemiological studies is given of disease patterns that have developed among industrial workers, miners, and millers who had been exposed to dusts of one or more of the commercial asbestos minerals or to dusts from minerals perceived to be asbestos-like. Health data are also reviewed for individuals exposed to asbestos dusts in nonoccupational settings. From the published reports it is clear that there are very significant differences in the health effects of the several asbestos or asbestos-like minerals.

Conference Paper↗

A new occurrence of telluride minerals in South Carolina

A study of drill cores from the Haile gold mine, Lancaster County, South Carolina, has revealed grains containing large amounts of Te with various combinations of Pb, Ag and Au in pyrite. These telluride minerals have so far not been identified. The nearby Brewer mine, on the basis of chemical evidence, also contains tellurides. The probable telluride localities in South Carolina are now expanded to three, significantly increasing the few reports of Te minerals from the Au deposits of the southeastern Piedmont, many of which are now considered to be volcanogenic. The occurrence of telluride minerals in gold ore from the Haile-Brewer area may help to explain the divergence in Au/Ag ratios reported in chemical analyses of drill core, ore samples and production records. Te, in addition, may be useful in geochemical exploration programmes in the SE Piedmont, including programmes using heavy mineral concentrates derived from stream alluvium. -R.S.M.

South Carolina↗

Nature and distribution of potential heavy-mineral resources offshore of the Atlantic Coast of the United States.

The US is dependent on foreign imports of placer heavy minerals for a majority of its ilmenite and rutile, and virtually all of its monazite requirements. Although sand deposits in the SE US are important domestic sources of these heavy minerals (HM) and a number of other less well-known heavy-mineral species, global onshore reserves of placer minerals may fall short of demand in as few as 20 years. Insofar as they are important commodities for the future, offshore HM placers will become more important, but much research on them remains to be done. Results of recent offshore studies, based on surficial grab samples, indicate an average of about 2 weight percent HM in surficial Atlantic Continental Shelf (ACS) sediments, in strong contrast with previous estimates of an average of 0.16% HM. Although provocative, the information from these grab samples does not include the thickness of the HM deposits and thus their volume and tonnage cannot be estimated.-from Author

Marine Mining↗

Availability of a library of infrared (2.1-25.0 μm) mineral spectra

All previously published libraries of infrared mineral spectra are in the form of transmittance. Reflectance spectra are, however, more useful for remote sensing and some potential laboratory applications, such as the use of an infrared microscope for mineral identification on polished sections. This note points out that construction of a new library of infrared (2.1-25.0 &mu; m) mineral spectra is in progress. Both transmittance and reflectance measurements of a selection of 63 different, well-characteized minerals have been published to date. These data are available in both hard copy and digital form.

American Mineralogist↗

The role of conflict minerals, artisanal mining, and informal trading networks in African intrastate and regional conflicts

The relationship between natural resources and armed conflict gained public and political attention in the 1990s, when it became evident that the mining and trading of diamonds were connected with brutal rebellions in several African nations. Easily extracted resources such as alluvial diamonds and gold have been and continue to be exploited by rebel groups to fund their activities. Artisanal and small-scale miners operating under a quasi-legal status often mine these mineral deposits. While many African countries have legalized artisanal mining and established flow chains through which production is intended to travel, informal trading networks frequently emerge in which miners seek to evade taxes and fees by selling to unauthorized buyers. These networks have the potential to become international in scope, with actors operating in multiple countries. The lack of government control over the artisanal mining sector and the prominence of informal trade networks can have severe social, political, and economic consequences. In the past, mineral extraction fuelled violent civil wars in Sierra Leone, Liberia, and Angola, and it continues to do so today in several other countries. The significant influence of the informal network that surrounds artisanal mining is therefore an important security concern that can extend across borders and have far-reaching impacts.

Small Wars Journal↗

Halogen contents of igneous minerals as indicators of magmatic evolution of rocks associated with the Ray porphyry copper deposit, Arizona

The contents of Cl, F, and H 2 O+ (calculated) in some hydrous igneous minerals in intrusive rocks of Laramide age (70-60 m.y.) near Ray, Ariz., appear to be related to the age and the chemistry of the whole-rock samples. Apatite and biotite in younger, more silicic rocks contain more F but less Cl and H 2 O+ than apatite and biotite in older, more mafic rock; the same relations hold for F and H 2 O+ in sphene. Correlations of the abundance of Cl, F, and H 2 O+ in hornblende with rock chemistry and age are not as strong as for apatite, biotite, and sphene; igneous (?) epidote does not contain Cl and F in amounts detectable by electron microprobe analysis. The contents of Cl, F, and H 2 O+ in whole-rock samples decrease with increasing differentiation index and decreasing age. Data for a single pluton of variable composition mirror the results for a suite of different plutons and dikes. The data are satisfactorily although not exclusively explained by postulating that the melts each contained progressively less Cl, F, and H 2 O and that the hydrons minerals consumed most of the Cl, F, and H 2 O in the magmas. The data may also be explained by postulating that (1) the stocks evolved Cl-bearing water during their ascent and crystallization, or that (2) Cl and H 2 O were concentrated during differentiation of the stocks but the minerals failed to record their buildup. Both alternative explanations find problems with and require special conditions to satisfy field, chemical, and experimental data. If many of the special conditions are not met, a nearby batholithic parent to the stocks is not a favorable source of the mineralized fluids at Ray. Propylitic alteration of biotite results in Cl-poor chlorites and may have provided some Cl to hydrothermal fluids; biotite may have also supplied some F to propylitizing fluids through alteration.

Arizona↗