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Acid-neutralizing potential of minerals in intrusive rocks of the Boulder batholith in northern Jefferson County, Montana

Experimental studies show that fresh granitic rocks of the Boulder batholith in the Boulder River headwaters near Basin, Montana have significant acid-neutralizing potential and are capable of neutralizing acidic water derived from metal-mining related wastes or mine workings. Laboratory studies show that in addition to the acidneutralizing potential (ANP) of minor amounts of calcite in these rocks, biotite, tremolite, and feldspars will contribute significantly to long-term ANP. We produced 0.45 micrometer-filtered acidic (pH = 2.95) leachate for use in these ANP experiments by exposing metal-mining related wastes to deionized water in a waste:leachate ratio of 1:20. We then exposed these leachates to finely-ground and sized fractions of batholith rocks, and some of their mineral fractions for extended and repeated periods, for which results are reported here. The intent was to understand what reactions of metal-rich acidic water and fresh igneous rocks would produce. The reactions between the acidic leachates and the bulk rocks and mineral fractions are complex. Factors such as precipitation of phases like Fe-hydroxides and Alhydroxides and the balance between dissolved cations and anions that are sulfate dominated complicate analysis of the results. Research by others of acid neutralization by biotite and tremolite attributed a rise in pH to proton (H+) adsorption in sites vacated by K, Mg, and Ca. Destruction of the silicate framework and liberation of associated structural hydroxyl ions may contribute to ANP. Studies by others have indicated that the conversion of biotite to a vermiculite-type structure by removal of K at a pH of 4 consumes about six protons for every mole of biotite, but at a pH of 3 there is pronounced dissolution of the tetrahedral lattice. The ANP of fresh granitic rocks is much higher than anticipated. The three bulk Boulder igneous rock samples studied have minimum ANP equivalent to about 10-14 weight percent calcite. This ANP is in addition to that provided by the 0.36-1.4 weight percent calcite present in these samples. The total rock ANP is thus equivalent to that of many sedimentary rocks that are generally believed to be among the most efficient for attenuation of acidic waters. The long-term ANP contributed by biotite, tremolite, feldspars, and possibly unidentified minerals in these rocks, as well as calcite, are all important with regard to their natural remediation of degraded water quality originating from Fe-sulfide rich mineral deposits and the associated mine wastes and acid-mine drainage water.

Montana↗

Geochronology and geology of late Oligocene through Miocene volcanism and mineralization in the western San Juan Mountains, Colorado

Twenty-five new 40Ar/39Ar ages from volcanic rocks and veins in the western San Juan Mountains clarify relationships between volcanism and mineralization in this classic area. Five calc-alkaline ash-flow sheets erupted from caldera sources (Ute Ridge, Blue Mesa, Dillon Mesa, Sapinero Mesa, and Crystal Lake Tuffs) from 28.6 to 27.6 Ma. This is a much more restricted time interval than previously thought and indicates that the underlying batholith rose and evolved very rapidly beneath the western San Juan Mountains. The new ages and geologic relations constrain the timing of joint resurgence of the Uncompahgre and San Juan calderas to between 28.2 and 27.6 Ma. The collapse of the Silverton caldera produced a set of strong ring fractures that intersected with graben faults on the earlier resurgent dome to produce the complex set of structures that localized the mid-Miocene epithermal gold veins. Later calc-alkaline monzonitic to quartz monzontic plutons solidified at 26.5-26.0 Ma as the underlying batholith rose through its volcanic cover. A new age from lavas near Uncompahgre Peak supports earlier interpretations that these lavas were fed by nearby 26 Ma monzonite intrusions. Nearly all of these intrusions are associated with subeconomic Mo and Cu mineralization and associated alteration, and new ages of 26.40 and 25.29 Ma from the Ute-Ulay and Lilly veins in the Lake City region show that some of the most important silver and base-metal veins were temporally and possibly genetically connected to these plutons. In addition, the Golden Fleece telluride vein cuts all of the post-Uncompahgre caldera volcanics in the area and is probably temporally related to this cycle, though its age of 27.5 ? 0.3 Ma was determined by less precise U/Pb methods. The 22.9 Ma Lake City caldera collapsed within the older Uncompahgre caldera structure but is petrologically unrelated to the older calc-alkaline activity. The distinctive suite of high-silica rhyolite tuff and alkaline resurgent intrusions indicates that it is closely related to the early stages of bimodal high-silica rhyolite-alkali basalt volcanism that accompanied the onset of extensional tectonism in the region. Both 40Ar/39Ar ages and paleomagnetic data confirm that the entire caldera sequence formed in less than 330,000 years. Only weak quartz vein mineralization is present in the center of the caldera, and it appears to be related to leaching of metals from the intracaldera tuffs above the resurgent intrusion. Massive alunitization and weak Mo and Cu mineralization along the eastern ring fracture are associated with calc-alkaline lavas and stocks related to late stages of the caldera cycle. These calc-alkaline stocks also appear to be genetically and temporally linked to a radial pattern of barite-precious metal veins on the northeastern margin of the Lake City caldera.

Colorado↗

Geologic datasets for weights of evidence analysis in northeast Washington: 3. Minerals-related permits on national forests, 1967 to 1998

Permits to explore for and (or) develop mineral resources on forest land can be used to indicate locations and types of mineral-related activities on national forests. Permits for these activities require filing at the Forest Service a Notice of Intention (Notice) to conduct mineral exploration activities and (or) a Plan of Operation (Plan). A Plan of Operation is required is significant activities are anticipated. This compilation of Notices and Plans for the Colville, Kaniksu, Okanogan, and Wenatchee National Forests between 1967 and 1998 is intended for use in combination with geologic and economic information to predict future mineral-related activities in the region.

Washington↗

Geologic datasets for weights-of-evidence analysis in northeast Washington: 3. Minerals-related permits on national forests, 1967-1998

Permits to explore for and (or) develop mineral resources on forest land can be used to indicate locations and types of mineral-related activities on national forests. Permits for these activities require filing at the Forest Service a Notice of Intention (Notice) to conduct mineral exploration activities and (or) a Plan of Operation (Plan). A Plan of Operation is required is significant activities are anticipated. This compilation of Notices and Plans for the Colville, Kaniksu, Okanogan, and Wenatchee National Forests between 1967 and 1998 is intended for use in combination with geologic and economic information to predict future mineral-related activities in the region.

Washington↗

Spatial geologic data model for the Gunnison, Grand Mesa, Uncompahgre National Forests mineral resource assessment area, southwestern Colorado and digital data for the Leadville, Montrose, Durango, and Colorado parts of the Grand Junction, Moab, and Cortez 1° x 2° geologic maps

The digital geologic and geographic information system (GIS) data presented here were prepared to aid in Grand Mesa, Uncompahgre, Gunnison National Forest (GMUG) mineral resource assessment Project studies by the U.S. Geological Survey Mineral Resource Program. The goals of the GMUG Project is to provide mineral resource data and an assessment for undiscovered mineral resources in U.S. Forest Service (USFS) and Bureau of Land Management (BLM) lands in southwestern Colorado. The Project area covers a large region in southwestern Colorado that is bounded by latitudes 37o 45’ to 39o 30’ north and longitudes 106o to 109o west. The study area is covered by all or parts of six 1o x2o topographic and quadrangle geologic maps, which include geologic maps for the Leadville (Tweto and others, 1978), Montrose (Tweto and others, 1976), Durango (Steven and others, 1974), Grand Junction (Cashion, 1973), Moab (Williams, 1976), and Cortez (Haynes and others, 1972) quadrangles. These geologic maps were used inasmuch as a complete remapping and compilation effort for this study area was beyond the scope of the Project.

Colorado↗

Field trip guide to selected studies of the Southwest Mineral and Environmental Investigations Project in southeastern Arizona

The Southwest Mineral and Environmental Investigations Project is designed to address issues raised by rapid urban development in the basins of the southwestern U.S. These issues require objective geoscientific data that can be used by land managers and stakeholders to develop informed land and water use strategies. The project integrates new and existing geologic, geophysical, and geochemical data, and imagery to provide three-dimensional visualizations of the basins of southeastern Arizona. Emphasis is on developing better knowledge of the aquifer systems of both the basins and the ranges, on acquiring background and baseline information, and on determining the distribution of metals related to mineralization and the fate of these metals in surface and subsurface environments. The products of the project will be used in resolving issues of water quality and quantity, in understanding environmental impacts such as riparian ecosystem maintenace, and in evaluating mineral resources beneath and within the basins. The field trip highlights three topics and areas (figs. 1 and 2): (1) geology and geophysics of the upper San Pedro and upper Santa Cruz basins (M.E. Gettings, M. W. Bultman, and B.B. Houser), (2) geology, geophysics, and mineral resource potential of the San Rafael basin (M.W. Bultman), and (3) hydrology and aqueous geochemistry of the Red Mountain and Sonoita Creek drainage system (Floyd Gray). The trip guide, which begins and ends in Tucson, Arizona, also includes commentary on the cultural and mining history of the area.

Arizona↗

Land and mineral ownership coverage for the Uinta Basin, Wasatch Plateau and surrounding areas, northeastern Utah

This Arc/Info coverage contains land status and Federal and State mineral ownership for approximately 25,900 square miles in northeastern Utah. The polygon coverage (which is also provided here as a shapefile) contains three attributes of ownership information for each polygon. One attribute indicates whether the surface is State owned, privately owned, consists of Tribal and Indian lands, or, if Federally owned, which Federal agency manages the land surface. Another attribute indicates where the Utah School and Institutional Trust Lands Administration (SITLA) maintains full or partial subsurface mineral rights. The third attribute indicates which energy minerals, if any, are owned by the Federal govenment. This coverage is based on land management status and Federal and State mineral ownership data compiled by the U.S. Geological Survey (USGS), the former U.S. Bureau of Mines (USBM), and the Utah School and Institutional Trust Lands Administration at a scale of 1:100,000. This coverage was compiled primarily to serve the USGS National Oil and Gas Resource Assessment Project in the Uinta-Piceance Basin Province and the USGS National Coal Resource Assessment Project in the Colorado Plateau.

Utah↗

Temporal, spatial, and chemical evolution of Quaternary high-silica rhyolites in the Mineral Mountains, Utah

The Mineral Mountains in southwestern Utah are a structurally controlled core complex at the confluence of the Colorado Plateau and the Basin and Range physiographic provinces. Aside from hosting Utah’s largest batholith, the Mineral Mountains host some of the State’s youngest high-silica rhyolites, which have been linked to a magma source that is presently being utilized as an enhanced geothermal system. The high-silica rhyolites take the form of effusive lavas and domes, and explosive products are rare. Previous K-Ar dating of these Pleistocene rhyolites placed eruptions between about 790 and 500 kilo-annum (ka) with contemporaneous basalts erupting in the valley to the east of the Mineral Mountains. Large uncertainties on these ages obscured the tempo of eruptions and thus hindered attempts to constrain the timescales of the petrogenetic processes that produced the rhyolites. In this study, we build on previous studies conducted in the 1970s and 1980s by using new geochronologic and geochemical data to investigate the temporal and spatial evolution of the youngest phase of volcanism in the Mineral Mountains. We identify two major eruptive periods, from approximately 850 to 750 ka and from approximately 590 to 480 ka. The older phase is characterized by the eruption of several basaltic lavas, two obsidian flows, and a series of coalescing porphyritic rhyolite domes. The younger phase included the eruption of six evolved high-silica rhyolite domes and one pyroclastic deposit, followed by the eruption of trachyandesite in the adjacent valley to the east. Whole-rock geochemical data indicate that the rhyolites can be divided into three chemical groups, with more evolved compositions erupting through time. The youngest rhyolites along the range crest have the lowest total iron and TiO 2 concentrations and the highest incompatible element concentrations, indicative of increasing differentiation with time and elevation. Improved precision on the eruption ages indicates a recurrence interval of approximately 20 thousand years. The eruptive flux for both periods of rhyolitic volcanism is about 0.01 cubic kilometers per thousand years, which is less than the magma resurgence flux rates for syn-caldera and post-caldera eruptions of the Valles Caldera and Yellowstone Caldera volcanic systems. Collectively, these geochemical, geochronological, and volumetric data may facilitate a better understanding of heat flux and the longevity of magmatic sources related to geothermal resources in similar small-volume, silicic systems.

Utah↗

Mineral and Vegetation Maps of the Bodie Hills, Sweetwater Mountains, and Wassuk Range, California/Nevada, Generated from ASTER Satellite Data

Multispectral remote sensing data acquired by the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) were analyzed to identify and map minerals, vegetation groups, and volatiles (water and snow) in support of geologic studies of the Bodie Hills, Sweetwater Mountains, and Wassuk Range, California/Nevada. Digital mineral and vegetation mapping results are presented in both portable document format (PDF) and ERDAS Imagine format (.img). The ERDAS-format files are suitable for integration with other geospatial data in Geographic Information Systems (GIS) such as ArcGIS. The ERDAS files showing occurrence of 1) iron-bearing minerals, vegetation, and water, and 2) clay, sulfate, mica, carbonate, Mg-OH, and hydrous quartz minerals have been attributed according to identified material, so that the material detected in a pixel can be queried with the interactive attribute identification tools of GIS and image processing software packages (for example, the Identify Tool of ArcMap and the Inquire Cursor Tool of ERDAS Imagine). All raster data have been orthorectified to the Universal Transverse Mercator (UTM) projection using a projective transform with ground-control points selected from orthorectified Landsat Thematic Mapper data and a digital elevation model from the U.S. Geological Survey (USGS) National Elevation Dataset (1/3 arc second, 10 m resolution). Metadata compliant with Federal Geographic Data Committee (FGDC) standards for all ERDAS-format files have been included, and contain important information regarding geographic coordinate systems, attributes, and cross-references. Documentation regarding spectral analysis methodologies employed to make the maps is included in these cross-references.

Scientific Investigations Map↗

Porphyry copper assessment of the Tethys region of western and southern Asia: Chapter V in Global mineral resource assessment

A probabilistic mineral resource assessment of undiscovered resources in porphyry copper deposits in the Tethys region of western and southern Asia was carried out as part of a global mineral resource assessment led by the U.S. Geological Survey (USGS). The purpose of the study was to delineate geographic areas as permissive tracts for the occurrence of porphyry copper deposits at a scale of 1:1,000,000 and to provide probabilistic estimates of amounts of copper likely to be contained in undiscovered porphyry copper deposits in those tracts. The team did the assessment using the USGS three-part form of mineral resource assessment, which is based on (1) mineral deposit and grade-tonnage models constructed from known deposits as analogs for undiscovered deposits, (2) delineation of permissive tracts based on geoscientific information, and (3) estimation of numbers of undiscovered deposits. The assessment area includes the Asian part of Turkey and Georgia, Armenia, Azerbaijan, Iran, western Pakistan, and southwestern Afghanistan. Selected tracts also extend marginally into southwesternmost Russia and northeasternmost Iraq. This region is located in the central part of the larger Tethyan Eurasian Metallogenic Belt, which extends from western Europe to eastern Asia. Mining in this part of the Tethyan Eurasian Metallogenic Belt has occurred for thousands of years; in 2011 the region produced 420,000 metric tons (t) of copper (2.6 percent of global production), 8,300 t of molybdenum (3 percent), and 29,600 kilograms of gold (1 percent). The assessment team defined 26 tracts permissive for Late Triassic to Holocene porphyry copper-molybdenum and porphyry copper-gold deposits. Permissive tracts range in extent from 2,960 to 194,000 square kilometers (km 2 ) and cover a total area of 924,000 km 2 . Younger tracts overlap older tracts in several areas. Three permissive tracts include sub-tracts in order to separate tract segments on the basis of geography, data quality, or likelihood of occurrence of undiscovered deposits. About 65 percent of all known porphyry sites occur in only five tracts, which also host most of the identified copper resources. In terms of tectonic setting, 58 percent of the permissive tracts are related to continental arcs; 19 percent to island arcs or back arcs; and 24 percent to postcollisional settings. Of the known porphyry copper deposits, subequal fractions are spread among these three settings. The spatial distribution of known porphyry deposits and prospects is also related to the level of erosion. Magmatic belts with numerous known porphyry sites exhibit subequal areas of coeval plutonic and volcanic units and lesser amounts of cover rocks. Belts with fewer known porphyry sites display either high or low volcanic-to-plutonic ratios and (or) greater cover, indicating crustal levels that are too shallow or too deep for exposure of porphyry deposits. Probabilistic estimates of numbers of undiscovered porphyry copper deposits were made for 18 of the 26 tracts. The undiscovered porphyry copper endowment for 8 tracts is discussed qualitatively. The assessment estimates that the Tethys region contains 47 undiscovered deposits within 1 kilometer of the surface. Probabilistic estimates of numbers of undiscovered deposits were combined with grade and tonnage models in a Monte Carlo simulation to estimate probable amounts of contained metal. The 47 undiscovered deposits are estimated to contain a mean of 180 million metric tons (Mt) of copper distributed among the 18 tracts for which probabilistic estimates were made, in addition to the 62 Mt of copper already identified in the 42 known porphyry deposits in the study area. Results of Monte Carlo simulations show that 80 percent of the estimated undiscovered porphyry copper resources in the Tethys region are located in four tracts or sub-tracts.

Scientific Investigations Report↗

Qualitative assessment of selected areas of the world for undiscovered sediment-hosted stratabound copper deposits: Chapter Y in Global mineral resource assessment

A qualitative mineral resource assessment of sediment-hosted stratabound copper mineralized areas for undiscovered copper deposits was performed for 10 selected areas of the world. The areas, in alphabetical order, are (1) Belt-Purcell Basin, United States and Canada; (2) Benguela and Cuanza Basins, Angola; (3) Chuxiong Basin, China; (4) Dongchuan Group rocks, China; (5) Egypt–Israel–Jordan Rift, Egypt, Israel, and Jordan; (6) Maritimes Basin, Canada; (7) Neuquén Basin, Argentina; (8) Northwest Botswana Rift, Botswana and Namibia; (9) Redstone Copperbelt, Canada; and (10) Salta Rift System, Argentina. This assessment (1) outlines the main characteristics of the areas, (2) classifies known deposits by deposit model subtypes, and (3) ranks the areas according to their potential to contain undiscovered copper deposits. An analytic hierarchy process (AHP) was used to rank assessment areas according to their potential for undiscovered copper deposits. Once the main characteristics of each area were compiled (age of host rock, geologic setting, stratigraphy, host lithology, deposit subtype(s), known deposits and occurrences, and mineral system components), three criteria (mineralization, extent of study area, and lithostratigraphic framework, each with multiple subcriteria) were scored for all assessment areas. Relative weights and scores were assigned to all criteria by three geologists. In addition, the assessment areas were ranked for comparison exclusively on the basis of professional opinion. The AHP and professional opinion lists are similar but not the same. Both the professional opinion and the cumulative AHP lists rate the Northwest Botswana Rift in Botswana and Namibia as the area most likely to contain the most undiscovered copper deposits. The Salta Rift System in Argentina is rated lowest among the 10 qualitatively assessed areas.

Belt-Purcell Basin, Benguela Basin, Cuanza Basin, ↗

Carbon dioxide mineralization feasibility in the United States

Geologic carbon dioxide (CO 2 ) storage is one of many methods for stabilizing the increasing concentration of CO 2 in the Earth’s atmosphere. The injection of CO 2 in deep subsurface sedimentary reservoirs is the most commonly discussed method; however, the potential for CO 2 leakage can create long-term stability concerns. This report discusses the feasibility of an alternative form of geologic CO 2 storage: CO 2 mineralization. In this method, CO 2 reacts with rocks and minerals to form solid and stable carbonate rocks. New pilot projects and laboratory-based kinetics experiments have revealed that this method, both in situ and ex situ, may be a viable option for storage. In situ storage targets in-place rocks at the surface or subsurface. Ex situ storage targets industrial byproducts at the surface like mine tailings. Environmental risks include induced seismicity for in situ methods if pressure is not managed properly, as well as potential water and land use effects. However, there are fewer long-term CO 2 -leakage concerns for mineralization methods compared to saline storage methods and therefore potentially lower long-term monitoring costs. The costs and benefits of CO 2 mineralization are compared to those of CO 2 storage in saline reservoirs using estimates of pressure-limited dynamic storage capacity. This report highlights the regional potential of areas in the United States for in situ and ex situ storage, as well as their proximity to potential sources of CO 2 . Especially suitable targets include asbestos or other ultramafic mine tailings, in situ ultramafic rocks on the East and West Coasts, the Columbia River basalts in the Pacific Northwest, the Midcontinent Rift basalts in the midcontinent, and the basaltic Hawaiian Islands.

Scientific Investigations Report↗

Occurrences of uranium-bearing minerals in the St. Kevin District, Lake County, Colorado

Two hundred and seventy-one prospect pits, mine dumps, or mine workings within the Sugar Loaf-St. Kevin mining districts and vicinity were tested for radioactivity by the U.S. Geological Survey in 1951 during six weeks of investigation on behalf of the Division of Raw Materials of the U.S. Atomic Energy Commission. One hundred and twenty-two weak radioactivity anomalies were found in the St. Kevin district and vicinity, and eight slight anomalies were noted in the Sugar Loaf district, which adjoins the St. Kevin district on the south. Most of the radioactivity anomalies were found in igneous and metamorphic rocks of pre-Cambrian age, but some were found in metalliferous veins of Tertiary age. Samples of altered granite or schist contain as much as 0.065 percent uranium, probably in the form of secondary uranium minerals. Samples of vein material contain as much as 0.013 percent uranium, also probably in the form of secondary uranium minerals. At only a few localities has the identity of the uranium-bearing minerals been determined. Torbernite, associated with turquoise, malachite, and chrysocolla, occurs as disseminations and fracture coatings in altered granite at the Josie May turquoise mine; metatobernite is disseminated in granite at the Turquoise Chief mine. Commonly the limonite-stained fractures in the altered granite and schist are radioactive; metatorbernite has been identified in limonite stain at one locality. A uranium-variety of florencite, a hydrous cerium aluminum phosphate, is disseminated in the granite on the dump of a mine just west of the St. Kevin district, and autunite (?) is disseminated in fine-grained, highly silicified rock in the northeastern part of the St. Kevin district. None of the uranium occurrences are of commercial importance. They are for the most part in non-glaciated terrane, which has been subjected to a very long period of weathering. Thus, chemical leaching within the zone of weathering may have greatly reduced the uranium content of material near the surface, and occurrences of even small quantities of secondary uranium minerals might be related to stronger, primary concentrations at depth.

Colorado↗

Thorium and rare earth minerals in the Powderhorn district, Gunnison County, Colorado

Thorium has been found since 1949 in at least 33 deposits in an area 6 miles wide and 20 miles long in the Powderhorn district, Gunnison County, Colo. The district is composed largely of pre-Jurassic metamorphic and igneous rocks, which are chiefly if not entirely pre-Cambrian in age. The metamorphic and igneous rocks are overlain by sandstone of the Morrison formation of Jurassic age, and by volcanic rocks of the Alboroto group and Hinsdale formation of Miocene and Pliocene (?) age, respectively. The thorium deposits occur in or near alkalic igneous rocks in which such elements as titanium, rare earths, barium, strontium, and niobium occur in greater-than-average amounts. The greatest mass of the alkalic igneous rocks the Iron Hill composite stoc,- occupies an area of 12 square miles in the southeastern part of the district. The age of the thorium deposits, like that of the alkalic igneous rocks, is not known other than pre-Jurassic. The thorium veins and mineralized shear zones range from a few inches to 18 feet in thickness and from a few feet to 3,500 feet in length. The veins are composed of calcite,.dolomite, siderite, ankerite, quartz, barite, pyrite, sphalerite, galena, goethite,. apatite, alkali feldspar, and many other minerals. The thorium occurs at least partly in thorite or hydrothorite. Sparse xenotime has been tentatively identified in one deposit. Several minerals containing rare earths of the cerium group as major constituents are found in carbonate veins near Iron Hill. Bastnaesite has been identified by X-ray methods, and cerite and synchisite are probably present also.The fluorapatite in some veins and in parts of the carbonate rock mass that occupies 2 square miles in the central part of the Iron Hill complex contains rare earths of the cerium group, generally in amounts of a fraction of a percent of the rock. The radioactivity of the deposits appears to be due almost entirely to thorium and its daughter products The ThO 2 content of selected highgrade samples from the Little Johnnie vein is as much as 4 percent. The ThO 2 content of the veins is generally less than 1 percent, however, and is only 0.05 to 0.1 percent in many of the veins studied. The little Johnnie vein, which was mapped in detail, can be traced discontinuously for a distance of more than 3,500 feet. The thoriumbearing material occurs as irregular veinlets and thin films introduced into the fault zone. The mineralized shear zone ranges from less than 6 inches to 5 feet in thickness. Near its west end the vein is broken by many faults in a zone that marks the edge of a roughly circular fault block, 1 1/2. miles in diameter, that has dropped 1,000 feet or more since the deposition of Miocene volcanic-rocks that now floor the Milkranch basin.

Colorado↗

Behavior of Colorado Plateau uranium minerals during oxidation

Uranium occurs as U(VI) and U(IV) in minerals of the Colorado Plateau ores. The number of species containing U(VI) is large, but only two U(IV) minerals are known from the Plateau: uraninite, and oxide, and coffinite, a hydroxy-silicate. These oxidize to yield U(VI) before reacting significantly with other mineral constituents. Crystal-structure analysis has shown that U(VI) invariable occurs as uranyl ion, UO 2 +2 . Uranyl ion may form complex carbonate or sulfate ions with resulting soluble compounds, but only in the absence of quinquevalent vanadium, arsenic, or phosphorous. In the presence of these elements in the +5 valence state, the uranyl ion is fixed in insoluble layer compounds formed by union of uranyl ion with orthovanadate, orthophosphate, or orthoarsenate. Under favorable conditions UO 2 +2 may react to form the relatively insoluble rutherfordine, UO 2 CO 3 , or hydrated uranyl hydroxides. These are rarely found on the Colorado Plateau as opposed to their excellent development in other uraniferous areas, a condition which is apparently related to the semiarid climate and low water table of the Plateau. Uranium may also be fixed as uranyl silicate, but little is known about minerals of this kind. In the present study emphasis has been placed on a detailing of the chemical and crystal structural changes which occur in the oxidation paragenetic sequence.

Utah↗

Radioactive minerals in the Yakataga beach placers, southern Alaska

Radioactivity of nine samples of beach placer deposits in the Yakataga area, southern Alaska, was studied in 1948. The samples were given to the Geological Survey by prospectors operating in the area operating in the area. The heavy-mineral fractions from the concentrates average 0.044 percent equivalent uranium. Three minerals, all members of the zircon group, contain the radioactive material in the sample; one mineral is uranium-bearing, the other two are thorium-bearing. Unless the concentration of radioactive minerals in the beach deposits is considerably higher than the present qualitative data indicate, the placers at Yakataga beach do not constitute a feasible source of supply of radioactive materials.

Alaska↗

Probability calculations for three-part mineral resource assessments

Three-part mineral resource assessment is a methodology for predicting, in a specified geographic region, both the number of undiscovered mineral deposits and the amount of mineral resources in those deposits. These predictions are based on probability calculations that are performed with computer software that is newly implemented. Compared to the previous implementation, the new implementation includes new features for the probability calculations themselves and for checks of those calculations. The development of the new implementation lead to a new understanding of the probability calculations, namely the assumptions inherent in the probability calculations. Several assumptions strongly affect the mineral resource predictions, so it is crucial that they are checked during an assessment. The evaluation of the new implementation leads to new findings about the probability calculations,namely findings regarding the precision of the computations,the computation time, and the sensitivity of the calculation results to the input.

Techniques and Methods↗

Mineral chemistry and shrimp U-Pb Geochronology of mesoproterozoic polycrase-titanite veins in the sullivan Pb-Zn-Ag Deposit, British Columbia

Small polycrase-titanite veins 0.1-2 mm thick cut the tourmalinite feeder zone in the deep footwall of the Sullivan Pb-Zn-Ag deposit, southeastern British Columbia. Unaltered, euhedral crystals of polycrase and titanite 50-100 ??m in diameter are variably replaced by a finer-grained alteration-induced assemblage composed of anhedral polycrase and titanite with local calcite, albite, epidote, allanite, and thorite or uranothorite (or both). Average compositions of the unaltered and altered polycrase, as determined by electron-microprobe analysis, are (Y0.38 REE0.49 Th0.10 Ca0.04 Pb0.03 Fe0.01U0.01) (Ti1.48 Nb0.54 W0.04 Ta0.02)O6 and (Y0.42 REE0.32 Th0.15 U0.06 Ca0.04 Pb0.01 Fe0.01) (Ti1.57 Nb0.44 W0.04 Ta0.02)O6, respectively. The unaltered titanite has, in some areas, appreciable F (to 0.15 apfu), Y (to 0.40 apfu), and Nb (to 0.13 apfu). SHRIMP U-Pb geochronology of eight grains of unaltered polycrase yields a weighted 207Pb/206Pb age of 1413 ?? 4 Ma (2??) that is interpreted to be the age of vein formation. This age is 50-60 m.y. younger than the ca. 1470 Ma age of synsedimentary Pb-Zn-Ag mineralization in the Sullivan deposit, which is based on combined geological and geochronological data. SHRIMP ages for altered polycrase and titanite suggest later growth of minerals during the ???1370-1320 Ma East Kootenay and ???1150-1050 Ma Grenvillian orogenies. The 1413 ?? 4 Ma age for the unaltered polycrase in the veins records a previously unrecognized post-ore (<1470 Ma) and premetamorphic (>1370 Ma) mineralizing event in the Sullivan deposit and vicinity. The SHRIMP U-Pb age of the polycrase and high concentrations of REE, Y, Ti, Nb, and Th in the veins, together with elevated F in titanite and the absence of associated sulfides, suggest transport of these high-field-strength elements (HFSE) by F-rich and S-poor hydrothermal fluids unrelated to the fluids that formed the older Fe-Pb-Zn-Ag sulfide ores of the Sullivan deposit. Fluids containing abundant REE, HFSE, and F may have been derived from a geochemically specialized magma such as those that form alkaline granites, pegmatites, or carbonatites. In an alternative model. preferred here, these fluids were associated with a rift-related, crustal metasomatic event in the region. Determination of a Mesoproterozoic age for the polycrase-titanite veins establishes the first known occurrence of pre-Grenvillian REE-rich mineralization in the Belt-Purcell basin.

Canadian Mineralogist↗