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Find USGS publications on mineral resources and deposits. Search commodities and geographic names, then check source reports for geology and assessment methods.

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Titanium, vanadium, and niobium mineralization and alkali metasomatism from the Magnet Cove complex, Arkansas

The Christy Ti-V-Nb deposit is hosted by the Arkansas Novaculite, adjacent to the carbonatite-alkaline Magnet Cove Complex. Mineralized rock contains up to 8 wt percent Ti, 2.68 wt percent V, and 0.124 wt percent Nb. Minor amounts of Li and Mo are present, and there is evidence for the preferential concentration of the middle to heavy rare earth elements (REE) in altered clay-rich dikes. Mineralized rock consists of (1) thermally recrystallized novaculite that is partly replaced by actinolite, sodic amphibole, taeniolite (KLiMg 2 Si 4 O 10 F 2 ), pyrite,and siderite, (2) brookite-bearing amphibole- and taeniolite-rich rock that contains siderite and pyrite, (3) quartz-brookite aggregates, and (4) goethite-rich rocks that form the oxidized zone of the deposit. Unaltered rock is scarce at the Christy deposit. Comparison of mineralized lithologies from the Christy deposit with those from two other areas of mineralization associated with the Magnet Cove Complex, the Magnet Cove Titanium Corporation deposit ("Rutile deposit") and the Hardy-Walsh prospect, provides mineralogical and chemical evidence for the source of the mineralizing fluids at the Christy deposit.Massive clay-rich (kaolinite + or - smectite) dikes are in contact with the mineralized zones of the Christy deposit. The presence of relict K feldspar and pyrite in the least altered dikes and certain characteristic trace elements (e.g., Ba, Rb) suggest that the Christy dikes are related to less pervasively altered rutile-mineralized, pyrite-bearing carbonate-feldspar dikes fromthe Rutile deposit. The feldspar-carbonate dikes from the Rutile deposit may be the products of intense alkali metasomatism of alkaline igneous silicate rocks that were emplaced prior to the intrusion of the Magnet Cove carbonatite.The Christy deposit formed through a series of complex processes. The initial phase of mineralization is directly related to the infiltration of novaculite by alkali-rich fluids that were probably derived from carbonatite magma. Introduction of the metasomatic fluids preceded emplacement of massive feldspar- and pyrite-bearing dikes that were subsequently altered to the clay-rich masses Titanium, V, Nb, and Li were introduced by the alkali-rich fluids at temperatures that were, as indicated by fluid inclusion data (Willis et al., 1991), as high as 600 degrees C. During the initial stage of mineralization, V was concentrated in aegirine and sodic amphibole, Li was concentrated in taeniolite, minor amounts of Ti were concentrated in aegirine, and pyrite formed. The replacement of novaculite by the aforementioned minerals yielded excess silica, which precipitated as quartz in veins and as clear overgrowths on recrystallized, inclusion-rich (partly replaced) quartz. Niobium- and V-bearing brookite precipitated with the quartz. Minerals formed during the first stage reacted with a second fluid at temperatures of 100 degrees to 300 degrees C, as indicated by fluid inclusion data (Willis et al., 1991), and V was then concentrated in smectite and goethite. The isotopic composition of siderite [delta 18 O SMOW = 23.8-25.0ppm, delta 13 C PDB = -7.1 to -8.9ppm suggests that the second fluid was a mixture of low-temperature metasomatic fluid and ground water. Vanadium was further concentrated in clay minerals (Breit et al., 1992), in goethite, and in vug minerals as low-temperature alteration proceeded. Brookite is not totally resistant to weathering and it is at least partly replaced by other oxides in the oxidized zone.

Economic Geology↗

Lead isotope compositions as guides to early gold mineralization: The North Amethyst vein system, Creede district, Colorado

The North Amethyst vein system, which is hosted by approximately 27 Ma Carpenter Ridge Tuff and approximately 26 Ma Nelson Mountain Tuff, has two mineral associations separated by brecciation and sedimentation in the veins. The early association consists of quartz, rhodonite, hematite, magnetite, electrum (Au (sub 0.3-0.5) Ag (sub 0.7-0.5)) , and Mn carbonate, Au-Ag sulfide, Ag sulfosalt, and base metal sulfide minerals. The later mineral association cuts the Mn- and Au-bearing assemblages and consists of quartz, calcite, sericite, chlorite, hematite, adularia, fluorite, base metal sulfides, and Ag-bearing tetrahedrite.Our detailed studies show that the Pb isotope compositions of paragenetically early galenas associated with Au-rich mineralization in the North Amethyst vein system are relatively unradiogenic ( 206 Pb/ 204 Pb: 18.826-18.881, 207 Pb/ 204 Pb: 15.588-15.602, and 208 Pb/ 204 Pb: 37.790-37.926) compared to Pb isotope compositions of galenas formed later at about 25 Ma during Ag and base metal mineralization ( 206 Pb/ 204 Pb: 19.041-19.115, 207 Pb/ 204 Pb: 15.627- 15.672, and 208 Pb/ 204 Pb: 37.829-38.057). New Pb isotope data for the central and southern parts of the Creede district, which are located 5 to 7 km south of the North Amethyst area, agree with the results of a regional study by Doe et al. (1979) that included five samples from the main part of the Creede district. Galenas and adularia from the central and southern Creede district and galenas from the Bondholder district, 7 km north of the North Amethyst area, are similar to the Pb isotope compositions of galenas formed later in the North Amethyst area during Ag and base metal mineralization. Galenas from the Alpha-Corsair vein, which was mined for Ag prior to 1910, are isotopically similar to galenas associated with North Amethyst Au-stage mineralization. This isotopic similarity suggests that unexplored segments of the Alpha-Corsair structure may have the same mineralogy as the North Amethyst Au stage; thus, the Alpha-Corsair structure has the potential for high gold contents.Pb isotope compositions from the late stage of the North Amethyst vein system and from the Bondholder and central and southern Creede mining districts are more radiogenic than the host volcanic rocks of the central cluster of the San Juan volcanic field. Our Pb isotope results indicate that early Au mineralization of the North Amethyst area may represent the product of an older and relatively local hydrothermal system distinct from that of the younger base metal and Ag mineralization found throughout the region. Fluids that deposited Au minerals may have derived their Pb isotope composition by a greater degree of interaction with shallow, relatively less radiogenic volcanic wall rocks. The younger, base metal and Ag-rich mineralization that overprints the Au mineralization in the North Amethyst area clearly has a more radiogenic isotopic signature, which implies that the later mineralization derived a greater component of its Pb from Proterozoic source rocks, or sediments derived from them.Paragenetically early sulfide-rich vein assemblages have the least radiogenic galenas and generally also have the highest Au contents. Thus, identification of paragenetically early vein assemblages with relatively unradiogenic Pb isotope compositions similar to those of the North Amethyst area provides an additional exploration tool for Au in the central San Juan Mountains area.

Colorado↗

A statistical summary and listing of the spectrographic analyses of heavy mineral concentrate and conventional, sieved stream-sediment samples, Silver City area, New Mexico

Geochemical sampling of a tier of eight 7 1/2-minute quadrangles bordered by latitudes 32° 45'and 33° 00' N. and longitudes 108° 00' and 108° 30' W. was begun in the fall of 1974 and continued seasonally until completion in the fall of 1976. These quadrangles are in southwest New Mexico and include the well-known mineral deposits of the Silver City area. The sampling was designed to gain semidetailed information on the metal-anomaly characteristics of the strongly mineralized area surrounding Silver City, New Mexico, and to seek geochemical clues for the continuation of these mineral deposits beneath overlying Tertiary volcanic rocks to the north. The data obtained within areas of known mineral deposits provide information on the metallogenic processes and metal suites that both relate and distinguish metal systems. Evaluation of this information relative to the regional geologic framework and the distribution of known mineral deposits will result in the identification of additional target areas for exploration, as well as further our understanding of the geochemical characteristics of mineralized areas. Extrapolation of models developed from the study of areas of known, exposed mineralization to areas covered by Tertiary volcanic rocks, such as the northern part of this tier of quadrangles, is a promising procedure for continuing research into geochemical-anomaly characteristics of covered mineral deposits. Preliminary interpretation of the data indicates that the southern part of the area in which Paleozoic-Mesozoic rocks and mineral deposits are exposed, should be reassessed to the classification and genesis of some of the deposits and to the types of mineral commodities that may be present. Some wholly new exploration targets within these areas are also indicated by some of the data. In addition, geochemical clues to buried mineral deposits, possibly representing continuation northward of some features of the Silver City mining district, have been observed in data from the northern, Tertiary volcanic areas. The meanings of these clues are still speculative. For this study, 917 stream-sediment and 921 stream-sediment concentrate samples were collected. The stream-sediment-concentrate samples, which consist of heavy minerals, were split into magnetic and nonmagnetic fractions, each of which was analyzed. This resulted in the analysis of 1,842 heavy-mineral and 917 sieved stream-sediment samples. Analytical results for all of the sample types are summarized statistically on table 1 and tabulated in their entirety on table 2.

New Mexico↗

Mineral-deposit models for northeast Asia, Chapter 3 in Metallogenesis and tectonics of northeast Asia

The major purposes of this chapter are to provide (1) an overview of the regional geology, tectonics, and metallogenesis of Northeast Asia for readers who are unfamiliar with the region, (2) a general scientific introduction to the succeeding chapters of this volume, and (3) an overview of the methodology of metallogenic and tectonic analysis used in this study. We also describe how a high-quality metallogenic and tectonic analysis, including construction of an associated metallogenic-tectonic model will greatly benefit other mineral resource studies, including synthesis of mineral-deposit models; improve prediction of undiscovered mineral deposit as part of a quantitative mineral-resource-assessment studies; assist land-use and mineral-exploration planning; improve interpretations of the origins of host rocks, mineral deposits, and metallogenic belts, and suggest new research. Research on the metallogenesis and tectonics of such major regions as Northeast Asia (eastern Russia, Mongolia, northern China, South Korea, and Japan) and the Circum-North Pacific (the Russian Far East, Alaska, and the Canadian Cordillera) requires a complex methodology including (1) definitions of key terms, (2) compilation of a regional geologic base map that can be interpreted according to modern tectonic concepts and definitions, (3) compilation of a mineral-deposit database that enables a determination of mineral-deposit models and clarification of the relations of deposits to host rocks and tectonic origins, (4) synthesis of a series of mineral-deposit models that characterize the known mineral deposits and inferred undiscovered deposits in the region, (5) compilation of a series of metallogenic-belt belts constructed on the regional geologic base map, and (6) construction of a unified metallogenic and tectonic model. The summary of regional geology and metallogenesis presented here is based on publications of the major international collaborative studies of the metallogenesis and tectonics of Northeast Asia that have been led by the U.S. Geological Survey (USGS). These studies have produced two broad types of publications (1) a series of regional geologic, mineral-deposit, and metallogenic-belt maps, with companion descriptions of the region, and (2) a suite of metallogenic and tectonic analyses of the same region. The study area consists of eastern Russia (most of eastern Siberia and the Russian Far East), Mongolia, northern China, South Korea, Japan, and adjacent offshore areas. The major cooperative agencies are the Russian Academy of Sciences; the Academy of Sciences of the Sakha Republic (Yakutia); VNIIOkeangeologia and Ministry of Natural Resources of the Russian Federation; the Mongolian Academy of Sciences; the Mongolian University of Science and Technology; the Mongolian National University; Jilin University, Changchun, People?s Republic of China, the China Geological Survey; the Korea Institute of Geosciences and Mineral Resources; the Geological Survey of Japan/AIST; the University of Texas, Arlington, and the U.S. Geological Survey (USGS). This study builds on and extends the data and interpretations from a previous project on the Major Mineral Deposits, Metallogenesis, and Tectonics of the Russian Far East, Alaska, and the Canadian Cordillera conducted by the USGS, the Russian Academy of Sciences, the Alaska Division of Geological and Geophysical Surveys, and the Geological Survey of Canada. The major products of this project were summarized by Naumova and others (2006) and are described in appendix A.

Professional Paper↗

Critical mineral resources of the United States—An introduction

Many changes have taken place in the mineral resource sector since the publication by the U.S. Geological Survey of Professional Paper 820, “United States Mineral Resources,” which is a review of the long-term United States resource position for 65 mineral commodities or commodity groups. For example, since 1973, the United States has continued to become increasingly dependent on imports to meet its demands for an increasing number of mineral commodities. The global demand for mineral commodities is at an alltime high and is expected to continue to increase, and the development of new technologies and products has led to the use of a greater number of mineral commodities in increasing quantities to the point that, today, essentially all naturally occurring elements have several significant industrial uses. Although most mineral commodities are present in sufficient amounts in the earth to provide adequate supplies for many years to come, their availability can be affected by such factors as social constraints, politics, laws, environmental regulations, land-use restrictions, economics, and infrastructure. This volume presents updated reviews of 23 mineral commodities and commodity groups viewed as critical to a broad range of existing and emerging technologies, renewable energy, and national security. The commodities or commodity groups included are antimony, barite, beryllium, cobalt, fluorine, gallium, germanium, graphite, hafnium, indium, lithium, manganese, niobium, platinum-group elements, rare-earth elements, rhenium, selenium, tantalum, tellurium, tin, titanium, vanadium, and zirconium. All these commodities have been listed as critical and (or) strategic in one or more of the recent studies based on assessed likelihood of supply interruption and the possible cost of such a disruption to the assessor. For some of the minerals, current production is limited to only one or a few countries. For many, the United States currently has no mine production or any significant identified resources and is largely dependent on imports to meet its needs. As a result, the emphasis in this volume is on the global distribution and availability of each mineral commodity. The environmental issues related to production of each mineral commodity, including current mitigation and remediation approaches to deal with these challenges, are also addressed. This introductory chapter provides an overview of the mineral resource classifications, terms, and definitions used in this volume. A review of the history of the use and meaning of the term “critical” minerals (or materials) is included as an appendix to the chapter.

Professional Paper↗

Chromium in minerals and selected aquifer materials

Between 1952 and 1964, hexavalent chromium, Cr(VI), was released into groundwater from a Pacific Gas and Electric Company (PG&E) compressor station in Hinkley, California, in the western Mojave Desert 80 miles northeast of Los Angeles, California. In 2015, the extent of anthropogenic Cr(VI) in groundwater in Hinkley and Water Valleys was uncertain, but some Cr(VI) in groundwater may be naturally occurring from rock and aquifer material. To evaluate potential sources of natural Cr(VI), chromium and other selected trace-element concentrations were measured by inductively coupled plasma-mass spectrometry (ICP-MS), with multi-acid digestion, on 34 samples of surficial alluvium and core material from Hinkley and Water Valleys, California, and on 2 samples of alluvium from the mafic Sheep Creek fan to the southwest. Chromium concentrations in Hinkley and Water Valleys ranged from 2 to 110 milligrams per kilogram (mg/kg), with a median concentration of 14 mg/kg; concentrations were highest in weathered mafic hornblende diorite associated with Iron Mountain. High chromium concentrations also were present within fine-textured materials and visually abundant iron- and manganese-oxide coatings on the surfaces of mineral grains. For comparison, chromium concentrations as high as 170 mg/kg were measured in mafic alluvium from the Sheep Creek fan. In contrast, chromium concentrations were lowest in Mojave-type deposits (Mojave River stream and lake margin deposits), with a median of 6 mg/kg. Chromium concentrations measured by ICP-MS compared favorably with concentrations measured by portable (handheld) X-ray fluorescence (pXRF; chapter B), on the basis of least-squares regression results and a coefficient of determination (R 2 ) of 0.97. Minerals in bulk samples and the heavy (dense) mineral fractions isolated from those samples were identified using optical techniques, X-ray diffraction (XRD), and scanning electron microscopy (SEM). Quartz and feldspar were the most abundant minerals, especially within recent and older Mojave River deposits. Chromium concentrations were as high as 1,250 mg/kg in the heavy-mineral fraction, with specific gravity greater than 3.32. Chromium was not commonly detected in the light-mineral fraction, with specific gravity less than 2.85. Most chromium within the heavy-mineral fraction was substituted within magnetite mineral grains less than 100 micrometers (μm) in diameter, and almost no chromite was present within the heavy-mineral fraction. Although magnetite is resistive to weathering, weathering of magnetite to hematite was identified (1) in Miocene materials underlying unconsolidated deposits in the western subarea of Hinkley Valley and (2) in alluvium within Water Valley that contains weathered minerals eroded from Miocene rock. Less-dense, more easily weathered chromium-containing amphiboles, such as actinolite in older Mojave River alluvium and hornblende in locally derived alluvium from Iron Mountain, were identified optically. Magnetite was not identified in weathered hornblende diorite and was less abundant in locally derived materials and in Miocene materials than in Mojave-type deposits. A comparison of ICP-MS data and sequential extraction data shows that approximately 90 percent of chromium in aquifer material within Hinkley and Water Valleys was not extractable and was interpreted to reside within unweathered mineral grains. Most extractable chromium was within the strong acid extractable fraction. Chromium within the weakly sorbed, and specifically sorbed extractable fractions in oxide accumulations within the regulatory Cr(VI) plume is potentially mobile into groundwater with changes in ionic strength or pH. Although Hinkley and Water Valleys are regionally low in chromium, natural geologic sources of chromium may be present in aquifer materials penetrated by wells completed in (1) weathered hornblende diorite bedrock underlying the western subarea; (2) Miocene deposits underlying the western subarea and unconsolidated material in the northern subarea and Water Valley containing basalt or weathered minerals eroded from Miocene deposits; (3) unconsolidated material containing visually abundant iron- and manganese-oxide coatings on the surfaces of mineral grains that are present near the water table and near lithologic or geologic contacts; and (4) brown clay and mudflat/playa deposits in the northern subarea. Brown clay and mudflat/playa deposits in the eastern subarea near Mount General have a low-chromium, felsic mineralogy similar to Mojave River deposits and do not contain high concentrations of chromium; however, manganese(IV) oxides within these materials may facilitate oxidation of trivalent chromium, Cr(III), to Cr(VI).

California↗

Spatial mapping of mineralization with manganese-enhanced magnetic resonance imaging

Paramagnetic manganese can be employed as a calcium surrogate to sensitize the magnetic resonance imaging (MRI) technique to the processing of calcium during the bone formation process. At low doses, after just 48h of exposure, osteoblasts take up sufficient quantities of manganese to cause marked reductions in the water proton T1 values compared with untreated cells. After just 24h of exposure, 25??M MnCl2 had no significant effect on cell viability. However, for mineralization studies 100??M MnCl2 was used to avoid issues of manganese depletion in calvarial organ cultures and a post-treatment delay of 48h was implemented to ensure that manganese ions taken up by osteoblasts is deposited as mineral. All specimens were identified by their days in vitro (DIV). Using inductively coupled plasma optical emission spectroscopy (ICP-OES), we confirmed that Mn-treated calvariae continued to deposit mineral in culture and that the mineral composition was similar to that of age-matched controls. Notably there was a significant decrease in the manganese content of DIV18 compared with DIV11 specimens, possibly relating to less manganese sequestration as a result of mineral maturation. More importantly, quantitative T1 maps of Mn-treated calvariae showed localized reductions in T1 values over the calvarial surface, indicative of local variations in the surface manganese content. This result was verified with laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). We also found that ??R1 values, calculated by subtracting the relaxation rate of Mn-treated specimens from the relaxation rate of age-matched controls, were proportional to the surface manganese content and thus mineralizing activity. From this analysis, we established that mineralization of DIV4 and DIV11 specimens occurred in all tissue zones, but was reduced for DIV18 specimens because of mineral maturation with less manganese sequestration. In DIV25 specimens, active mineralization was observed for the expanding superficial surface and ??R1 values were increased due to the mineralization of small, previously unmineralized areas. Our findings support the use of manganese-enhanced MRI (MEMRI) to study well-orchestrated mineralizing events that occur during embryonic development. In conclusion, MEMRI is more sensitive to the study of mineralization than traditional imaging approaches. ?? 2011.

Bone↗

Beyond temperature: Clumped isotope signatures in dissolved inorganic carbon species and the influence of solution chemistry on carbonate mineral composition

“Clumped-isotope” thermometry is an emerging tool to probe the temperature history of surface and subsurface environments based on measurements of the proportion of 13 C and 18 O isotopes bound to each other within carbonate minerals in 13 C 18 O 16 O 2 2- groups (heavy isotope “clumps”). Although most clumped isotope geothermometry implicitly presumes carbonate crystals have attained lattice equilibrium (i.e., thermodynamic equilibrium for a mineral, which is independent of solution chemistry), several factors other than temperature, including dissolved inorganic carbon (DIC) speciation may influence mineral isotopic signatures. Therefore we used a combination of approaches to understand the potential influence of different variables on the clumped isotope (and oxygen isotope) composition of minerals. We conducted witherite precipitation experiments at a single temperature and at varied pH to empirically determine 13 C- 18 O bond ordering (Δ 47 ) and δ 18 O of CO 3 2- and HCO 3 - molecules at a 25 °C equilibrium. Ab initio cluster models based on density functional theory were used to predict equilibrium 13 C- 18 O bond abundances and δ 18 O of different DIC species and minerals as a function of temperature. Experiments and theory indicate Δ 47 and δ 18 O compositions of CO 3 2- and HCO 3- ions are significantly different from each other. Experiments constrain the Δ 47- δ 18 O slope for a pH effect (0.011 ± 0.001; 12 ⩾ pH ⩾ 7). Rapidly-growing temperate corals exhibit disequilibrium mineral isotopic signatures with a Δ 47- δ 18 O slope of 0.011 ± 0.003, consistent with a pH effect. Our theoretical calculations for carbonate minerals indicate equilibrium lattice calcite values for Δ 47 and δ 18 O are intermediate between HCO 3 − and CO 3 2− . We analyzed synthetic calcites grown at temperatures ranging from 0.5 to 50 °C with and without the enzyme carbonic anhydrase present. This enzyme catalyzes oxygen isotopic exchange between DIC species and is present in many natural systems. The two types of experiments yielded statistically indistinguishable results, and these measurements yield a calibration that overlaps with our theoretical predictions for calcite at equilibrium. The slow-growing Devils Hole calcite exhibits Δ 47 and δ 18 O values consistent with lattice equilibrium. Factors influencing DIC speciation (pH, salinity) and the timescale for DIC equilibration, as well as reactions at the mineral–solution interface, have the potential to influence clumped-isotope signatures and the δ 18 O of carbonate minerals. In fast-growing carbonate minerals, solution chemistry may be an important factor, particularly over extremes of pH and salinity. If a crystal grows too rapidly to reach an internal equilibrium (i.e., achieve the value for the temperature-dependent mineral lattice equilibrium), it may record the clumped-isotope signature of a DIC species (e.g., the temperature-dependent equilibrium of HCO 3 − ) or a mixture of DIC species, and hence record a disequilibrium mineral composition. For extremely slow-growing crystals, and for rapidly-grown samples grown at a pH where HCO 3 - dominates the DIC pool at equilibrium, effects of solution chemistry are likely to be relatively small or negligible. In summary, growth environment, solution chemistry, surface equilibria, and precipitation rate may all play a role in dictating whether a crystal achieves equilibrium or disequilibrium clumped-isotope signatures.

Geochimica et Cosmochimica Acta↗

Assessing the influence of reacting pyrite and carbonate minerals on the geochemistry of drainage in the Coeur d'Alene mining district

The relative abundance of minerals that react to generate or consume acid in mineralized areas is critical in determining the quality of water draining from such areas. This work examines the fundamental reactions that influence the pH and composition of drainage from mine adits and tailings piles. We construct triangle diagrams that predict stoichiometric relationships between concentrations of dissolved SO4 dissolved Ca and Mg, and either alkalinity or acidity by considering reactions involving the oxidation of pyrite, dissolution of carbonate minerals, and precipitation of iron oxide and iron hydroxysulfate minerals. Drainage data from the Coeur d'Alene mining district are used to test our stoichiometric approach. Comparisons between theoretical predictions and drainage data indicate that the range of pH values in the mining district is due to reacting pyrite to carbonate mineral ratios that range from near 0/1 to 1/1. Calcite and ankerite are the dominant carbonate minerals that buffer the acid produced during pyrite oxidation and ferrihydrite or schwertmannite precipitation.The relative abundance of minerals that react to generate or consume acid in mineralized areas is critical in determining the quality of water draining from such areas. This work examines the fundamental reactions that influence the pH and composition of drainage from mine adits and tailings piles. We construct triangle diagrams that predict stoichiometric relationships between concentrations of dissolved SO4, dissolved Ca and Mg, and either alkalinity or acidity by considering reactions involving the oxidation of pyrite, dissolution of carbonate minerals, and precipitation of iron oxide and iron hydroxysulfate minerals. Drainage data from the Coeur d'Alene mining district are used to test our stoichiometric approach. Comparisons between theoretical predictions and drainage data indicate that the range of pH values in the mining district is due to reacting pyrite to carbonate mineral ratios that range from near 0/1 to 1/1. Calcite and ankerite are the dominant carbonate minerals that buffer the acid produced during pyrite oxidation and ferrihydrite or schwertmannite precipitation.

Idaho↗

Uranium redox and deposition transitions embedded in deep-time geochemical models and mineral chemistry networks

Uranium (U) is an important global energy resource and a redox sensitive trace element that reflects changing environmental conditions and geochemical cycling. The redox evolution of U mineral chemistry can be interrogated to understand the formation and distribution of U deposits and the redox processes involved in U geochemistry throughout Earth history. In this study, geochemical modeling using thermodynamic data, and mineral chemistry network analysis are used to investigate U geochemistry and deposition through time. The number of U 6+ mineral localities surpasses the number of U 4+ mineral localities in the Paleoproterozoic. Moreover, the number of sedimentary U 6+ mineral localities increases earlier in the Phanerozoic than the number of U 4+ sedimentary mineral localities, likely due to the necessity of sufficient sedimentary organic matter to reduce U 6+ –U 4+ . Indeed, modeling calculations indicate that increased oxidative weathering due to surface oxygenation limited U 4+ uraninite (UO 2 ) formation from weathered granite and basalt. Louvain network community detection shows that U 6+ forms minerals with many more shared elements and redox states than U 4+ . The range of weighted Mineral Element Electronegativity Coefficient of Variation (wMEE CV ) values of U 6+ minerals increases through time, particularly during the Phanerozoic. Conversely, the range of wMEE CV values of U 4+ minerals is consistent through time due to the relative abundance of uraninite, coffinite, and brannerite. The late oxidation and formation of U 6+ minerals compared to S 6+ minerals illustrates the importance of the development of land plants, organic matter deposition, and redox-controlled U deposition from ground water in continental sediments during this time-period.

Geochemistry, Geophysics, Geosystems↗

Proceedings for a workshop on deposit modeling, mineral resource assessment, and their role in sustainable development

The world's use of nonfuel mineral resources continues to increase to support a growing population and increasing standards of living. The ability to meet this increasing demand is affected especially by concerns about possible environmental degradation associated with minerals production and by competing land uses. What information does the world need to support global minerals development in a sustainable way? Informed planning and decisions concerning sustainability and future mineral resource supply require a long–term perspective and an integrated approach to resource, land use, economic, and environmental management worldwide. Such perspective and approach require unbiased information on the global distribution of identified and especially undiscovered resources, the economic and political factors influencing their development, and the potential environmental consequences of their exploitation. The U.S. Geological Survey and the former Deposit Modeling Program of the International Union of Geological Sciences (IUGS) of the United Nations Educational, Scientific and Cultural Organization (UNESCO) sponsored a workshop on "Deposit Modeling, Mineral Resource Assessment, and Their Role in Sustainable Development" at the 31st International Geological Congress (IGC) in Rio de Janeiro, Brazil, on August 18–19, 2000. The purpose of the workshop was to review the state-of-the-art in mineral deposit modeling and resource assessment and to examine the role of global assessments of nonfuel mineral resources in sustainable development. The workshop addressed questions such as the following: Which of the available mineral deposit models and assessment methods are best suited for predicting the locations, deposit types, and amounts of undiscovered nonfuel mineral resources remaining in the world? What is the availability of global geologic, mineral deposit, and mineral exploration information? How can mineral resource assessments be used to address economic and environmental issues? Presentations included overviews of assessment methods applied in previous national and other small-scale assessments of large regions and of the resulting assessment products and their uses. Twenty-seven people from Canada, China, Finland, Germany, Japan, Peru, Slovenia, South Africa, United States, and Venezuela participated in the 2-day post-Congress workshop. The attendees represented academia, government, environmental organizations, and the mining industry.

Circular↗

Historical statistics for mineral and material commodities in the United States

The U.S. Geological Survey (USGS) provides information to the public and to policy-makers concerning the current use and flow of minerals and materials in the United States economy. The USGS collects, analyzes, and disseminates minerals information on most nonfuel mineral commodities. This USGS digital database is an online compilation of historical U.S. statistics on mineral and material commodities. The database contains information on approximately 90 mineral commodities, including production, imports, exports, and stocks; reported and apparent consumption; and unit value (the real and nominal price in U.S. dollars of a metric ton of apparent consumption). For many of the commodities, data are reported as far back as 1900. Each commodity file includes a document that describes the units of measure, defines terms, and lists USGS contacts for additional information. End-use tables complement these statistics by supplying, for most of these commodities, information about the distribution of apparent consumption. This publication draws on more than 125 years of minerals information experience. At the request of the 47th Congress of the United States (1882; 22 Stat. 329), the U.S. Government began the collection and public distribution of these types of data. The Federal agencies responsible for the collection of the data have changed through time. For the years 1882-1924, the USGS collected and published these data; the U.S. Bureau of Mines (USBM) performed these tasks from 1925-95; and in 1996, the responsibilities once again passed to the USGS (following the closure of the USBM) (Mlynarski, 1998). The USGS collects data on a monthly, quarterly, semiannual, and annual basis from more than 18,000 minerals-related producer and consumer establishments that cooperate with the USGS. These companies voluntarily complete about 40,000 canvass forms that survey production, consumption, recycling, stocks, shipments, and other essential information. Data are also gathered from site visits, memberships on domestic and international minerals-related committees, and coordination with other government organizations and trade associations. The USGS makes this information available through published products, including monthly, quarterly, and annual Mineral Industry Surveys, the annual Minerals Yearbook (MYB), the annual Mineral Commodity Summaries (MCS), and special mineral commodity studies, including the history of metal prices and materials flow studies.

Data Series↗

Conflict minerals from the Democratic Republic of the Congo: global tantalum processing plants, a critical part of the tantalum supply chain

The U.S. Geological Survey (USGS) analyzes mineral and metal supply chains to identify and describe major components of mineral and metal material flows from ore extraction, through intermediate forms, to a final product. Supply chain analyses may be used (1) to identify risks to the United States associated with the supply of critical and strategic minerals and metals and (2) to provide greater supply chain transparency so that policymakers have the fact-based information needed to formulate public policy. This fact sheet focuses on the post-mining/pre-consumer-product part of the tantalum supply chain. The USGS National Minerals Information Center (NMIC) has been asked by governmental and non-governmental organizations to provide information about tantalum, tin, tungsten, and gold (collectively known as “3TG minerals”) processing facilities worldwide in response to U.S. legislation aimed at identifying and removing the supply chain links between the trade in these minerals and civil unrest in the Democratic Republic of the Congo and adjacent countries. Post-beneficiation processing plants (generally called smelters and refineries) for 3TG mineral ores and concentrates were identified by company and industry association representatives as being the link in the 3TG mineral supply chain through which these minerals can be traced to their source of origin (mine). The determination of the source of origin is critical to the development of a complete and transparent conflict-free mineral supply chain. Tungsten processing plants were the subject of the first fact sheet in this series published by USGS NMIC in August 2014. Background information about historical conditions and multinational stakeholders’ voluntary due diligence guidance for minerals from conflict-affected and high-risk areas is presented in the tungsten fact sheet. This fact sheet, the second in a series about 3TG minerals, focuses on the tantalum supply chain by listing selected processors that produced tantalum materials commercially worldwide during 2013–14. It does not provide any information regarding the sources of material processed in these facilities.

Fact Sheet↗

Conflict minerals from the Democratic Republic of the Congo—Gold supply chain

The U.S. Geological Survey (USGS) analyzes mineral and metal supply chains to identify and describe major components of material flows from ore extraction, through intermediate forms, to a final product. Supply chain analyses may be used to identify risks to the United States associated with the supply of critical and strategic minerals and metals and to provide greater supply chain transparency so that policymakers have the fact-based information needed to formulate public policy. This fact sheet focuses on the gold supply chain. The USGS National Minerals Information Center (NMIC) has been asked by governmental and non-governmental organizations to provide information about tantalum, tin, tungsten, and gold (collectively known as “3TG minerals” ) processing facilities worldwide in response to U.S. legislation aimed at identifying and removing the supply chain links associated with the trade of these metals and minerals among armed groups in the Democratic Republic of the Congo (DRC) and adjacent countries. Post-beneficiation processing plants (generally called smelters and refineries) for tantalum, tin, and tungsten (3T) mineral ores and concentrates were identified by company and industry association representatives as being the link in the 3T mineral supply chain through which these minerals can be traced to their source of origin (mine). Tungsten processing plants were the subject of the first fact sheet in a series of USGS reports about 3TG minerals, which was published by the NMIC in August 2014 (Bermúdez-Lugo, 2014). Background information about historical conditions and the voluntary due diligence of multinational stakeholders for minerals from conflict-affected and high-risk areas is presented in the tungsten fact sheet. The current fact sheet, the fourth and last in the series about 3TG minerals, focuses on the gold supply chain. Processing of the 3T mineral concentrates requires substantial infrastructure and capital and generally is done at relatively few specialized facilities that are not located at the mine site; primary and secondary processors typically are at separate locations. Gold, however, can easily be processed into semi-refined products at or near the mine site and has a high unit value in any form, which allows it to be readily exported through undocumented channels, making it more difficult to track to the mine or region of origin. To put this in perspective, 30 kilograms (66 pounds) of 83 percent pure gold (20 carat) would form a cube measuring 12 centimeters per side (about the size of a small tissue box) and, at a price of $1,200 per ounce, would be worth nearly $1 million. By contrast, the equivalent value of tungsten concentrates would weigh about 45 metric tons (t) (100,000 pounds). Once conflict sourced gold has been combined with gold from other mines and scrap at a refiner, there is no feasible way to distinguish the source of the gold. Thus, once the gold leaves the immediate area of production, it is nearly indistinguishable from gold products mined in other areas.

Fact Sheet↗

Global maps of critical mineral production in 2023

Introduction The global production of many mineral commodities, especially critical minerals, is concentrated in a few countries that have mineral resources and the infrastructure necessary to mine and process those resources. For this reason, the type and amount of mineral production differ by country. For example, many countries produce such metallic ores as gold and silver, whereas only a few countries produce magnesium, niobium, platinum-group metals, and rare earths. The concentration of mining and processing in certain countries necessitates the existence of a global supply chain. A mineral supply chain is the sequence of mining and processing of minerals and manufacturing of products. Mineral supply chains are global in scale, complex, and dynamic. Supply chain data can be used to understand how a country’s mineral resources and various economic, technical, and environmental factors affect the complexity of global supply chains. This fact sheet summarizes the world’s leading countries (those accounting for 5 percent or more of a commodity’s global production in 2023) for production of select mineral commodities (mainly critical minerals) in the mining and processing stages. These countries and the minerals they produce are synthesized on global maps to communicate the status of, and potential risk to, mineral commodity supply chains from geographic production concentration. Trade data from United Nations Statistics Division (2025) is used to support assessments of the observed production data.

Fact Sheet↗

Mineral potential tracts for orogenic, Carlin-like, and epithermal gold deposits in the Islamic Republic of Mauritania, (phase V, deliverable 68): Chapter H1 in Second projet de renforcement institutionnel du secteur minier de la République Islamique de Mauritanie (PRISM-II)

In 1996, at the request of the Government of the Islamic Republic of Mauritania, a team of U.S. Geological Survey (USGS) scientists produced a strategic plan for the acquisition, improvement and modernization of multidisciplinary sets of data to support the growth of the Mauritanian minerals sector and to highlight the geological and mineral exploration potential of the country. In 1999, the Ministry of Petroleum, Energy, and Mines of the Islamic Republic of Mauritania implemented a program for the acquisition of the recommended basic geoscientific information, termed the first Projet de Renforcement Institutionnel du Secteur Minier (Project for Institutional Capacity Building in the Mining Sector, PRISM-I). As a result of the PRISM-I efforts, a great deal of new geological, geophysical, geochemical, remote sensing, and hydrological data became available for evaluation and synthesis. However, the Ministry of Petroleum, Energy, and Mines recognized that additional work was required to extract the full benefit of the data before it could be of greatest use to the international community and of benefit to the Mauritanian minerals and development sector. To achieve this benefit, the Ministry of Petroleum, Energy, and Mines implemented a second Projet de Renforcement Institutionnel du Secteur Minier (PRISM-II) in 2006 to consolidate, synthesize, and interpret all of the existing data, create a new 1:1,000,000 scale geologic map, and define the mineral resource potential of the country. A consortium in which the USGS was the lead scientific agency carried out the majority of the PRISM-II work. In 2008, the USGS Mauritania Minerals Project was interrupted due to political changes in Mauritania. PRISM-II work resumed in 2011, and was completed in 2013 with the delivery of over 40 separate written reports and plates, an access file containing the Mauritanian National Mineral Deposits Database, and an interactive GIS containing all of the multi-disciplinary data and interpretive areas of mineral resource potential in Mauritania. This report contains the USGS results of the PRISM-II Mauritania Minerals Project and is presented in cooperation with the Ministry of Petroleum, Energy, and Mines of the Islamic Republic of Mauritania. The Report is composed of separate chapters consisting of multidisciplinary interpretive reports with accompanying plates on the geology, structure, geochronology, geophysics, hydrogeology, geochemistry, remote sensing (Landsat TM and ASTER), and SRTM and ASTER digital elevation models of Mauritania. The syntheses of these multidisciplinary data formed the basis for additional chapters containing interpretive reports on 12 different commodities and deposit types known to occur in Mauritania, accompanied by countrywide mineral resource potential maps of each commodity/deposit type. The commodities and deposit types represented include: (1) Ni, Cu, PGE, and Cr deposits hosted in ultramafic rocks; (2) orogenic, Carlin-like, and epithermal gold deposits; (3) polymetallic Pb-Zn-Cu vein deposits; (4) sediment-hosted Pb-Zn-Ag deposits of the SEDEX and Mississippi Valley-type; (5) sediment-hosted copper deposits; ( 6) volcanogenic massive sulfide deposits; (7) iron oxide copper-gold deposits; (8) uranium deposits; (9) Algoma-, Superior-, and oolitic-type iron deposits; (10) shoreline Ti-Zr placer deposits; (11) incompatible element deposits hosted in pegmatites, alkaline rocks, and carbonatites, and; (12) industrial mineral deposits. Additional chapters include the Mauritanian National Mineral Deposits Database are accompanied by an explanatory text and the Mauritania Minerals Project GIS that contains all of the interpretive layers created by USGS scientists. Raw data not in the public domain may be obtained from the Ministry of Petroleum, Energy, and Mines in Nouakchott, Mauritania.

Open-File Report↗

Reported industrial minerals occurrences and permissive areas for other occurrences in the Islamic Republic of Mauritania (phase V deliverable 88): Chapter R1 in Second projet de renforcement institutionnel du secteur minier de la République Islamique de Mauritanie (PRISM-II)

In 1996, at the request of the Government of the Islamic Republic of Mauritania, a team of U.S. Geological Survey (USGS) scientists produced a strategic plan for the acquisition, improvement and modernization of multidisciplinary sets of data to support the growth of the Mauritanian minerals sector and to highlight the geological and mineral exploration potential of the country. In 1999, the Ministry of Petroleum, Energy, and Mines of the Islamic Republic of Mauritania implemented a program for the acquisition of the recommended basic geoscientific information, termed the first Projet de Renforcement Institutionnel du Secteur Minier (Project for Institutional Capacity Building in the Mining Sector, PRISM-I). As a result of the PRISM-I efforts, a great deal of new geological, geophysical, geochemical, remote sensing, and hydrological data became available for evaluation and synthesis. However, the Ministry of Petroleum, Energy, and Mines recognized that additional work was required to extract the full benefit of the data before it could be of greatest use to the international community and of benefit to the Mauritanian minerals and development sector. To achieve this benefit, the Ministry of Petroleum, Energy, and Mines implemented a second Projet de Renforcement Institutionnel du Secteur Minier (PRISM-II) in 2006 to consolidate, synthesize, and interpret all of the existing data, create a new 1:1,000,000 scale geologic map, and define the mineral resource potential of the country. A consortium in which the USGS was the lead scientific agency carried out the majority of the PRISM-II work. In 2008, the USGS Mauritania Minerals Project was interrupted due to political changes in Mauritania. PRISM-II work resumed in 2011, and was completed in 2013 with the delivery of over 40 separate written reports and plates, an access file containing the Mauritanian National Mineral Deposits Database, and an interactive GIS containing all of the multi-disciplinary data and interpretive areas of mineral resource potential in Mauritania. This report contains the USGS results of the PRISM-II Mauritania Minerals Project and is presented in cooperation with the Ministry of Petroleum, Energy, and Mines of the Islamic Republic of Mauritania. The Report is composed of separate chapters consisting of multidisciplinary interpretive reports with accompanying plates on the geology, structure, geochronology, geophysics, hydrogeology, geochemistry, remote sensing (Landsat TM and ASTER), and SRTM and ASTER digital elevation models of Mauritania. The syntheses of these multidisciplinary data formed the basis for additional chapters containing interpretive reports on 12 different commodities and deposit types known to occur in Mauritania, accompanied by countrywide mineral resource potential maps of each commodity/deposit type. The commodities and deposit types represented include: (1) Ni, Cu, PGE, and Cr deposits hosted in ultramafic rocks; (2) orogenic, Carlin-like, and epithermal gold deposits; (3) polymetallic Pb-Zn-Cu vein deposits; (4) sediment-hosted Pb-Zn-Ag deposits of the SEDEX and Mississippi Valley-type; (5) sediment-hosted copper deposits; ( 6) volcanogenic massive sulfide deposits; (7) iron oxide copper-gold deposits; (8) uranium deposits; (9) Algoma-, Superior-, and oolitic-type iron deposits; (10) shoreline Ti-Zr placer deposits; (11) incompatible element deposits hosted in pegmatites, alkaline rocks, and carbonatites, and; (12) industrial mineral deposits. Additional chapters include the Mauritanian National Mineral Deposits Database are accompanied by an explanatory text and the Mauritania Minerals Project GIS that contains all of the interpretive layers created by USGS scientists. Raw data not in the public domain may be obtained from the Ministry of Petroleum, Energy, and Mines in Nouakchott, Mauritania.

Open-File Report↗

Critical mineral resources of the United States—Economic and environmental geology and prospects for future supply

Summary Mineral commodities are vital for economic growth, improving the quality of life, providing for national defense, and the overall functioning of modern society. Minerals are being used in larger quantities than ever before and in an increasingly diverse range of applications. With the increasing demand for a considerably more diverse suite of mineral commodities has come renewed recognition that competition and conflict over mineral resources can pose significant risks to the manufacturing industries that depend on them. In addition, production of many mineral commodities has become concentrated in relatively few countries (for example, tungsten, rare-earth elements, and antimony in China; niobium in Brazil; and platinum-group elements in South Africa and Russia), thus increasing the risk for supply disruption owing to political, social, or other factors. At the same time, an increasing awareness of and sensitivity to potential environmental and health issues caused by the mining and processing of many mineral commodities may place additional restrictions on mineral supplies. These factors have led a number of Governments, including the Government of the United States, to attempt to identify those mineral commodities that are viewed as most “critical” to the national economy and (or) security if supplies should be curtailed. This book presents resource and geologic information on the following 23 mineral commodities currently among those viewed as important to the national economy and national security of the United States: antimony (Sb), barite (barium, Ba), beryllium (Be), cobalt (Co), fluorite or fluorspar (fluorine, F), gallium (Ga), germanium (Ge), graphite (carbon, C), hafnium (Hf), indium (In), lithium (Li), manganese (Mn), niobium (Nb), platinum-group elements (PGE), rare-earth elements (REE), rhenium (Re), selenium (Se), tantalum (Ta), tellurium (Te), tin (Sn), titanium (Ti), vanadium (V), and zirconium (Zr). For a number of these commodities—for example, graphite, manganese, niobium, and tantalum—the United States is currently wholly dependent on imports to meet its needs. The first two chapters (A and B) deal with general information pertinent to the study of mineral resources. Chapters C through V describe individual mineral commodities and include an overview of current uses of the commodity, identified resources and their distribution nationally and globally, the state of current geologic knowledge, the potential for finding additional deposits nationally and globally, and geoenvironmental issues that may be related to the production and uses of the commodity. These chapters are updates of the commodity chapters published in 1973 in U.S. Geological Survey Professional Paper 820, “United States Mineral Resources.”

Professional Paper↗