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Groundwater & aquifers

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At least 1,675 records · Page 93Linked to original sources

USGS1998

Hydrogeology and sources of recharge to the Buffalo and Wahpeton aquifers in the southern part of the Red River of the North drainage basin, west-central Minnesota and southeastern North Dakota

Declining hydraulic heads in the Buffalo and Wahpeton aquifers are of concern to the Minnesota Department of Natural Resources and local water managers because of limited groundwater resources in the southern part of the Red River of the North drainage basin. The U.S. Geological Survey, in cooperation with the Minnesota Department of Natural Resources and Moorhead Public Service, investigated the hydrogeology of and sources of recharge to the Buffalo and Wahpeton aquifers. The Buffalo aquifer is a complex, heterogeneous outwash deposit composed of medium to coarse sand and gravel. Part of the Buffalo aquifer is unconfined and part is confined. The direction of ground water flow in the Buffalo aquifer is from east to west. Water-level declines in observation wells near the Moorhead Public Service North Well Field extend beyond the eastern and western boundaries of the Buffalo aquifer. Transmissivity and storativity calculated from the drawdown part of an aquifer test ranged from 20,870 to 23,852 feet squared per day and from 3.0 x 10 -5 to 3.2 x 10 -2 , respectively. Transmissivity and hydraulic conductivity values of 29,090 and 28,450 feet squared per day and 272 and 266 feet per day were calculated from the recovery-phase data. Potential recharge from the Buffalo River and its tributaries to the Buffalo aquifer ranged from 5 to 14 cubic feet per second. Recharge from precipitation where the Buffalo aquifer is unconfined was about 1.49 x 10 5 cubic feet per day. Recharge per unit length of the Buffalo aquifer during an aquifer test near the Moorhead Public Service North Well Field ranged from 3.9 x 10 -4 to 2.0 x 10 -2 cubic feet per day. The Wahpeton Shallow Sand, the Wahpeton Sand Plain, and the Wahpeton Buried Valley aquifers comprise the Wahpeton aquifers in order of increasing depth. All the aquifers are composed of fine- to coarse-grained sand mixed with gravel. Confining units are interleaved with the Wahpeton aquifers. Ground-water-flow directions in the Wahpeton aquifers were changed by ground-water development. Before development, ground water flowed from the Wahpeton Buried Valley aquifer upward to the Wahpeton Sand Plain aquifer and the Wahpeton Shallow Sand aquifer. After development, ground water flowed from the Wahpeton Shallow Sand aquifer to the Wahpeton Sand Plain and the Wahpeton Buried Valley aquifers. The potential sources of recharge to the Wahpeton aquifers investigated were the Red River of the North, and adjacent hydro geologic units. The volume of ground water pumped from the Wahpeton aquifers provides an estimate of the upper limit for the volume of recharge to the aquifer. Based on pumpage from all of the Wapheton aquifers from 1990 to 1993, the upper limit is about 580 million gallons per year (2.4 x 10 5 cubic feet per day).

Minnesota, North Dakota↗

USGS2000

Geohydrology and numerical simulation of groundwater flow in the central Virgin River Basin of Iron and Washington Counties, Utah

Because rapid growth of communities in Washington and Iron Counties, Utah, is expected to cause an increase in the future demand for water resources, a hydrologic investigation was done to better understand ground-water resources within the central Virgin River basin. This study focused on two of the principal ground-water reservoirs within the basin: the upper Ash Creek basin ground-water system and the Navajo and Kayenta aquifer system. The ground-water system of the upper Ash Creek drainage basin consists of three aquifers: the uppermost Quaternary basin-fill aquifer, the Tertiary alluvial-fan aquifer, and the Tertiary Pine Valley monzonite aquifer. These aquifers are naturally bounded by the Hurricane Fault and by drainage divides. On the basis of measurements, estimates, and numerical simulations of reasonable values for all inflow and outflow components, total water moving through the upper Ash Creek drainage basin ground-water system is estimated to be about 14,000 acre-feet per year. Recharge to the upper Ash Creek drainage basin ground-water system is mostly from infiltration of precipitation and seepage from ephemeral and perennial streams. The primary source of discharge is assumed to be evapotranspiration; however, subsurface discharge near Ash Creek Reservoir also may be important. The character of two of the hydrologic boundaries of the upper Ash Creek drainage basin ground-water system is speculative. The eastern boundary provided by the Hurricane Fault is assumed to be a no-flow boundary, and a substantial part of the ground-water discharge from the system is assumed to be subsurface outflow beneath Ash Creek Reservoir along the southern boundary. However, these assumptions might be incorrect because alternative numerical simulations that used different boundary conditions also proved to be feasible. The hydrogeologic character of the aquifers is uncertain because of limited data. Differences in well yield indicate that there is considerable variability in the transmissivity of the basin-fill aquifer. Field data also indicate that the basin-fill aquifer is more transmissive than the underlying alluvial-fan aquifer. Data from the Pine Valley monzonite aquifer indicate that its transmissivity may be highly variable and that it is strongly influenced by the connection of fractures. The Navajo and Kayenta aquifers provide most of the potable water to the municipalities of Washington County. Because of large outcrop exposures, uniform grain size, and large stratigraphic thickness, these formations are able to receive and store large amounts of water. In addition, structural forces have resulted in extensive fracture zones that enhance ground-water recharge and movement within these aquifers. Aquifer testing of the Navajo aquifer indicates that horizontal hydraulic-conductivity values range from 0.2 to 32 feet per day at different locations and may be primarily dependent on the extent of fracturing. Limited data indicate that the Kayenta aquifer generally is less transmissive than the Navajo aquifer. The aquifers are bounded to the south and west by the erosional extent of the formations and to the east by the Hurricane Fault, which completely offsets these formations and is assumed to be a lateral no-flow boundary. Like the Hurricane Fault, the Gunlock Fault is assumed to be a lateral no-flow boundary that divides the Navajo and Kayenta aquifers within the study area into two parts: the main part, between the Hurricane and Gunlock Faults; and the Gunlock part, west of the Gunlock Fault. Generally, the water in the Navajo and Kayenta aquifers contains few dissolved minerals. However, two distinct areas contain water with dissolved-solids concentrations greater than 500 milligrams per liter: a larger area north of the city of St. George and a smaller area a few miles west of the town of Hurricane. Mass-balance calculations indicate that in the higher-dissolved-solids area north of St. George, as much as 2.7 cubic feet per second may be entering the aquifer from underlying formations. For the area west of Hurricane, as much as 1.5 cubic feet per second may be entering the aquifer from underlying formations. On the basis of measurements, estimates, and numerical simulations, total water moving through the Navajo and Kayenta aquifers is estimated to be about 25,000 acre-feet per year for the main part and 5,000 acre-feet per year for the Gunlock part. The primary source of recharge is assumed to be infiltration of precipitation in the main part and seepage from the Santa Clara River in the Gunlock part. The primary source of discharge is assumed to be well discharge for both the main and Gunlock parts of the aquifers. Numerical simulations indicate that faults with major offset, such as the Washington Hollow Fault and an unnamed fault near Anderson Junction, may impede horizontal ground-water flow. Also, increased horizontal hydraulic conductivity along the orientation of predominant surface fracturing may be an important factor in regional ground-water flow. Simulations with increased north-south hydraulic conductivity substantially improved the match to measured water levels in the central area of the model between Snow Canyon and Mill Creek. Numerical simulation of the Gunlock part, using aquifer properties determined for the city of St. George municipal well field, resulted in a reasonable representation of regional water levels and estimated seepage from and to the Santa Clara River. To further quantify the Gunlock part of the Navajo and Kayenta aquifers, a better understanding of ground-water flow at the Gunlock Fault is needed.

Utah↗

USGS1991

Geohydrology and evaluation of water-resource potential of the Upper Floridan aquifer in the Albany area, southwestern Georgia

In the Albany area of southwestern Georgia, the Upper Floridan aquifer lies entirely within the Dougherty Plain district of the Coastal Plain physiographic province, and consists of the Ocala Limestone of late Eocene age. The aquifer is divided throughout most of the study area into an upper and a lower lithologic unit, which creates an upper and a lower water-bearing zone. The lower water-bearing zone consists of alternating layers of sandy limestone and medium-brown, recrystallized dolomitic limestone, and ranges in thickness from about 50 to 100 feet. It is highly fractured, and exhibits well-developed permeability by solution features that are responsible for transmitting most of the ground water in the aquifer. Transmissivity of the lower water-bearing zone ranges from about 90,000 to 178,000 feet squared per day. The upper water-bearing zone is a finely crystallized-to-oolitic, locally dolomitic limestone having an average thickness of about 60 feet. Transmissivities in the upper water-bearing zone are considerably less than those in the lower water-bearing zone. The Upper Floridan aquifer is overlain by about 20 to 120 feet of undifferentiated overburden consisting of fine-to-coarse quartz sand and noncalcareous clay. A clay zone about 10 to 30 feet thick may be continuous throughout the southwestern part of the Albany area, and where present, causes confinement of the Upper Floridan aquifer and creates perched ground water after periods of heavy rainfall. The Upper Floridan aquifer is confined below by the Lisbon Formation, a mostly dolomitic limestone that contains trace amounts of glauconite. The Lisbon Formation is at least 50 feet thick in the study area, and acts as an impermeable base to the Upper Floridan aquifer. The quality of ground-water in the Upper Floridan aquifer is suitable for most uses; wells generally yield water of the hard, calcium-bicarbonate type that generally meets the U.S. Environmental Protection Agency's Primary or Secondary Drinking Water Regulations. The water-resource potential of the Upper Floridan aquifer was evaluated by compiling results of test drilling and aquifer testing in the study area, and by conducting computer simulations of the ground-water-flow system under the seasonal-low conditions of November 1985, and under conditions of pumping within a 12square-mile area located southwest of Albany. Results of test drilling, aquifer testing, and water-quality analyses indicate that, in the area southwest of Albany, geohydrologic conditions in the Upper Floridan aquifer, undifferentiated overburden, and Lisbon Formation were favorable for the aquifer to provide a large quantity of water without having adverse effects on the ground-water system. The confinement of the Upper Floridan aquifer by the undifferentiated overburden and the rural setting of the area of potential development decreases the likelihood that chemical constituents will enter the aquifer during development of the ground-water resources. Computer simulations of ground-water flow in the Upper Floridan aquifer, incorporating conditions for regional flow across model boundaries, leakage from rivers and other surface-water features, and vertical leakage from the undifferentiated overburden, were conducted by using a finite-element model for groundwater flow in two dimensions. Comparison of computed and measured water levels in the Upper Floridan aquifer for November 1985 at 74 locations indicated that computed water levels generally were within 5 feet of the measured values, which is the accuracy to which measured water levels were known. Water-level altitudes ranged from about 260 feet to 130 feet above sea level in the study area during calibration. Aquifer discharge to the Flint River downstream from the Lake Worth dam was computed by the calibrated model to be about 1 billion gallons per day; about 300 million gallons per day greater than was measured for similar low-flow conditions. The excess computed discharge was attributed partially to stream withdrawals for industrial use, non-reported use, and channel evaporation, but mostly to increased gradients and increased flow from the aquifer to the river than existed during calibration. Results from the calibrated finite-element model indicate that ground-water flow is dominated by inflow from regional-flow components to the west, north, and east of the study area, and by outflow to the Flint River downstream from the Lake Worth dam. Simulation results indicated that directions of ground-water flow were not changed appreciably by pumping at the November 1985 rates. However, vertical leakage from the undifferentiated overburden caused local deviations in the regional flow pattern. A sensitivity analysis that was performed on 18 hydrologic factors affecting the flow system in the Upper Floridan aquifer showed that computed water levels changed the most (were the most sensitive) in response to changes in hydraulic conductivity of the aquifer, vertical leakage coefficient and water level in the undifferentiated overburden, and stage of the Flint River downstream from the Lake Worth dam. Computed water levels were least sensitive to changes in well pumpage, flow across the northern boundary and from Lake Worth, the boundary coefficient for the Flint River downstream from the Lake Worth dam, and flow from Cooleewahee Creek. Simulations of six pumping scenarios in the area of potential development southwest of Albany showed that the Upper Floridan aquifer is capable of providing at least 72 million gallons per day from five locations (14.4 million gallons per day each) within this area without causing adverse affects on the flow system. The 72million-gallon-per-day scenario yielded a maximum drawdown of about 9.4 feet, which placed the water level in the Upper Floridan aquifer about 50 feet above the top of the lower water-bearing zone. Hence, the likelihood of aquifer dewatering, well interference, or sinkhole development from pumping as much as 72 million gallons per day from within the area of potential development is small. All pumping scenarios showed that about 81 percent of the ground-water pumpage was derived from regional flow that would have discharged to the Flint River downstream from the Lake Worth dam. The dominant ground-water-flow direction toward the Flint River was not changed and no induced recharge from the Flint River entered the potential-development area. Induced recharge from the undifferentiated overburden contributed to about 1.5 percent of the total volume pumped during the simulations.

Georgia↗

USGS1987

An evaluation of the bedrock aquifer system in northeastern Wisconsin

Ground water is a major source of water in northeastern Wisconsin. The lower Fox River valley, located between Lake Winnebago and Green Bay in northeastern Wisconsin, is the second largest population center in Wisconsin. By 1957, ground-water withdrawals had lowered the potentiometric surface of the aquifer system as much as 440 feet below prepumping levels. With the exception of the city of Green Bay, which converted from ground water to surface water (Lake Michigan) for their municipal water supply in 1957, ground-water withdrawals have continually increased. The report evaluates the bedrock aquifer system in northeastern Wisconsin and describes how the flow regimes in the system have been altered due to ground-water withdrawals. A three-dimensional finite-difference groundwater flow model was used to aid in evaluation of the regional flow system. In order to simplify the study of the aquifer system, the geologic units were grouped into eight geohydrologic units consisting of four aquifers and four confining beds. The aquifers are the more permeable sand and gravel layers in the surficial deposits (aquifer 4), Devonian dolomite-Silurian dolomite (aquifer 3), St. Peter Sandstone- Prairie du Chien Group-Jordan Sandstone Member of the Trempealeau Formation (aquifer 2), and the Galesville Sandstone-Eau Claire Sandstone-Mount Simon Sandstone (aquifer 1). The confining beds are the less permeable silts and clays in the surficial deposits (confining bed 4), Maquoketa Shale-Galena Dolomite-Decorah Shale-Platteville Formation (confining bed 3), St. Lawrence Member of the Trempealeau Formation-Franconia Sandstone (confining bed 2), and the Precambrian crystalline rock (confining bed 1). The following aquifer and confining-bed characteristics were determined to represent the aquifer system of northeastern Wisconsin and were used in the development of the model. Aquifer 4 acts as an upper boundary of the bedrock aquifer system. The hydraulic conductivity of aquifer 3 was 7.9 feet per day and the storage coefficient was estimated to be 0.01. Transmissivity input values to the model for aquifer 2 are based on hydraulic conductivities ranging from 3 to 8 feet per day. The storage coefficient for aquifer 2 was 0.0002. The transmissivity input values to the model for aquifer 1 are based on hydraulic conductivities ranging from 2.5 to 8 feet per day and the storage coefficient was 0.0002. Confining bed 4 acts as an upper confining unit for the underlying bedrock aquifers. A vertical hydraulic conductivity of 0.007 foot per day was assigned to represent confining bed 4. The vertical hydraulic conductivity of confining bed 3 was assigned values of 0.0001 to 0.000004 foot per day. A value of 0.00001 foot per day was used as the vertical hydraulic conductivity for confining bed 2. Confining bed 1 is a lower boundary of the system and was not modeled. Model simulations indicate that, by 1914, ground-water withdrawals from the aquifer system had already impacted the study area. Pumping in the Green Bay metropolitan area had lowered the potentiometric heads in aquifer 1 by 69 feet and in aquifer 2 by 55 feet. Model simulations indicate that, by 1981, ground-water withdrawals have caused a cone of depression centered in the city of De Pere area. The influence of the cone affects almost the entire study area and has significantly altered the horizontal and vertical flow regimes in the aquifer system. In 1981, computed drawdowns below the prepumping potentiometric surface of aquifer 1 range from 0 feet on the western side of the study area to 330 feet in the center of the cone of depression. In aquifer 2, the computed drawdown ranges from 0 feet on the western side of the study area to 253 feet in the center of the cone.

Wisconsin↗

USGS1986

Gulf Coast Regional Aquifer-System Analysis — A Mississippi perspective

The Gulf Coast Regional Aquifer-System Analysis is a study of regional aquifers in sediments of mostly Cenozoic age in an area of about 230,000 sq mi in the Central Plain of Alabama, Arkansas , Florida, Illinois, Kentucky, Louisiana, Mississippi, Missouri, Tennessee, and Texas, and an additional 60,000 sq mi offshore. Three aquifer systems have been identified: the Mississippi embayment aquifer system, the Texas coastal uplands aquifer system, and the coastal lowlands aquifer system. These aquifer systems thicken from < 100 ft near their updip limit to thousands of ft gulfward toward their downdip limits. The Mississippi embayment aquifer system exceeds 5,000 ft in thickness in central Louisiana and in southwestern Mississippi. The thickest area in southwestern Mississippi underlies most of the six Mississippi counties, centered around Jefferson County. The greatest thickness of the coastal lowlands aquifer system in Mississippi occurs in southern Hancock County where the system is composed of several individual aquifers and confining units. There are seven aquifers and three confining units in the Mississippi embayment aquifer system, five aquifers and two confining units in the Texas coastal uplands aquifer system, and five aquifers and two confining units in the coastal lowlands aquifer system. Most of the thicker parts of each aquifer system contain moderately saline to very saline water. Water in the Mississippi embayment aquifer system is moderately saline to very saline in most of a seven county area in southwestern Mississippi. About 9,600 million gal/day (gpd) of ground water was pumped from the aquifers in the study area during 1980. About 15% of that pumpage (or about 1,400 million gpd was in Mississippi, mostly from the Mississippi River Valley alluvial aquifer of the Mississippi embayment aquifer system. About 10% of the Mississippi pumpage, or 140 million gpd, was from the coastal lowlands aquifer system. Preliminary results from simulation of groundwater flow indicates that parts of Mississippi are major regional recharge areas for both the Mississippi embayment aquifer system and the coastal lowlands aquifer system.

Mississippi↗

USGS1995

Geology and hydrology of the Edwards Aquifer in the San Antonio area, Texas

The Edwards aquifer, which is the sole source of water for the city of San Antonio, is one of the most permeable and productive carbonate aquifers in the United States. The aquifer is composed of extensively faulted, fractured, and cavernous limestone and dolomite of Early Cretaceous age lying within the Balcones fault zone a series of normal en echelon strike faults that separate the Edwards Plateau from the Gulf Coastal Plain in south Texas. Along segments of some faults, the entire thickness of the aquifer is displaced vertically, and these faults then act as barriers to downdip ground-water flow. The large porosity and exceptional permeability of the unconfined part of the Edwards aquifer result from the dissolution of limestone by circulating ground water and development of a cavernous network along fractures. The large porosity and permeability of the freshwater part of the confined Edwards aquifer result primarily from dedolomitization. The small permeability of the saline-water part of the confined aquifer is caused by the limited interconnection between the pores in the rock matrix and by the lack of substantial dissolution along fractures. The large transmissivity of the Edwards aquifer is indicated by the hundreds of highyielding wells, small hydraulic gradients, and large spring discharges. The determined transmissivity throughout most of the confined freshwater aquifer ranges from 430,000 to 2,200,000 feet squared per day; the determined transmissivity of the unconfined aquifer generally is less than 430,000 feet squared per day. Faulting causes the aquifer to be highly anisotropic, and simulation indicates anisotropy ratios ranging from 0.0:1 to 1:1. The ground-water-flow system of the Edwards aquifer includes several components. These include a catchment area on the Edwards Plateau where the unconfined aquifer receives direct recharge, an area of confining beds crossed by streams draining the Edwards Plateau, a major recharge area within the Balcones fault zone where streams lose flow directly into the unconfined Edwards aquifer, and the confined Edwards aquifer that consists of the freshwater and salinewater zones. Water entering the Edwards aquifer in the Balcones fault zone moves downdip in a generally southeasterly direction into the confined parts of the aquifer. In the confined aquifer, flow is toward the east and northeast under low hydraulic gradients through fractured, highly transmissive limestone and ultimately discharges at large springs and wells. All of the base flow and some of the storm runoff of streams crossing the recharge area infiltrates to the unconfined aquifer. On the basis of streamflow losses, the average annual recharge for 1934-88 was 635,500 acre-feet. Freshwater discharges from the Edwards aquifer primarily from wells, springs, and seeps. Beginning in 1968, annual discharge from the aquifer has consistently exceeded average annual recharge largely because of a doubling of well pumpage. However, total springflow also increased because of greater-than-average recharge during most years since the late 1960's. The total volume of circulating freshwater in the Edwards aquifer is about 45 million acrefeet. Long-term hydrographs at San Antonio indicate no net decline in ground-water levels during 1911-87; thus, there was no net loss of water from storage in the freshwater zone of the Edwards aquifer during that long-term period, assuming the San Antonio hydrograph represents the entire aquifer. However, short-term changes in water levels result largely from the variability of precipitation as indicated by severe declines during the drought of the late 1940's to middle 1950's and by rises to record highs during the abnormally wet years in the 1970's and 1980's. The principal components of the groundwater budget (recharge, springflow, and pumpage) have varied greatly over 55 years (1934-88) of pertinent hydrologic records. Annual recharge varied from about 44,000 to 2,000,000 acre-feet. Annual springflow varied from about 70,000 acrefeet to about 580,000 acre-feet. Pumpage increased from about 100,000 acre-feet annually in the early 1930's to more than 500,000 acre-feet annually during some years in the 1980's. However, the average annual recharge of 635,500 acrefeet is about equal to the sum of the average annual springflow (359,500 acre-feet) and average annual pumpage (273,000 acre-feet), indicating no longterm decrease in ground-water storage because of springflow and pumpage.

Texas↗

USGS1985

Potential hydrologic effects of ground-water withdrawals from the Dakota Aquifer, southwestern Kansas

A study was conducted to evaluate the effects of potential development of the Dakota aquifer on the layered aquifer system above Permian rocks in a 5,000 sq mi area of southwestern Kansas. Transmissivity of the Dakota aquifer, determined from analyses of pumping tests, ranges from 100 to 7,100 sq ft/day. Water in the Dakota aquifer is a calcium bicarbonate type water, similar to water in the High Plains aquifer, in the subcrop area. However, in areas distant from the subcrop, water in the Dakota aquifer is a sodium bicarbonate type water with dissolved solids concentrations in excess of 500 mg/L. Gradual declines in the potentiometric surface of the Dakota aquifer have occurred since the onset of pumpage in the 1960's; however, water levels in some wells have risen during the late 1970's. A digital computer model of 3-D groundwater flow was developed to simulate hydrologic conditions of a five-layer hydrologic system for 1975-82 conditions. The major components of the simulated 1975-82 water budget were well discharge from the High Plains aquifer and loss of ground water from storage in the High Plains aquifer. Although downward leakage from the High Plains aquifer in the study area represented only 18,000 acre-ft of the 1,365 ,000 acre-ft discharged from the High Plains aquifer during 1982 , it was a major source of inflow to the Dakota aquifer. Changes in storage in the Dakota aquifer in the study area during 1982 were about 5,000 acre-ft. A base-line projection was made using 1982 simulated hydraulic heads from the calibrated model and 1982 rates of pumpage from both the High Plains and the Dakota aquifers for comparison with eight additional projection simulations in which maximum pumpage from the Dakota aquifer at the end of the projections ranged from about 78,000 to 294,000 acre-ft/yr. The results from the projections indicate that: (1) pumpage from the Dakota aquifer will have a limited effect on hydraulic heads in the High Plains aquifer, (2) drawdown in the hydraulic heads in the Dakota aquifer will result in conversion of much of the Dakota aquifer to unconfined conditions, (3) change in storage will become the major water-budget component for the Dakota aquifer, (4) continuation of 1982 rates of withdrawal from the High Plains aquifer will result in dewatering of a substantial part of the aquifer in the study area. (Lantz-PTT)

Open-File Report↗

USGS2013

Groundwater and surface-water interaction within the upper Smith River Watershed, Montana 2006-2010

The 125-mile long Smith River, a tributary of the Missouri River, is highly valued as an agricultural resource and for its many recreational uses. During a drought starting in about 1999, streamflow was insufficient to meet all of the irrigation demands, much less maintain streamflow needed for boating and viable fish habitat. In 2006, the U.S. Geological Survey, in cooperation with the Meagher County Conservation District, initiated a multi-year hydrologic investigation of the Smith River watershed. This investigation was designed to increase understanding of the water resources of the upper Smith River watershed and develop a detailed description of groundwater and surface-water interactions. A combination of methods, including miscellaneous and continuous groundwater-level, stream-stage, water-temperature, and streamflow monitoring was used to assess the hydrologic system and the spatial and temporal variability of groundwater and surface-water interactions. Collectively, data are in agreement and show: (1) the hydraulic connectedness of groundwater and surface water, (2) the presence of both losing and gaining stream reaches, (3) dynamic changes in direction and magnitude of water flow between the stream and groundwater with time, (4) the effects of local flood irrigation on groundwater levels and gradients in the watershed, and (5) evidence and timing of irrigation return flows to area streams. Groundwater flow within the alluvium and older (Tertiary) basin-fill sediments generally followed land-surface topography from the uplands to the axis of alluvial valleys of the Smith River and its tributaries. Groundwater levels were typically highest in the monitoring wells located within and adjacent to streams in late spring or early summer, likely affected by recharge from snowmelt and local precipitation, leakage from losing streams and canals, and recharge from local flood irrigation. The effects of flood irrigation resulted in increased hydraulic gradients (increased groundwater levels relative to stream stage) or even reversed gradient direction at several monitoring sites coincident with the onset of nearby flood irrigation. Groundwater-level declines in mid-summer were due to groundwater withdrawals and reduced recharge from decreased precipitation, increased evapotranspiration, and reduced leakage in some area streams during periods of low flow. Groundwater levels typically rebounded in late summer, a result of decreased evapotranspiration, decreased groundwater use for irrigation, increased flow in losing streams, and the onset of late-season flood irrigation at some sites. The effect of groundwater and surface-water interactions is most apparent along the North and South Forks of the Smith River where the magnitude of streamflow losses and gains can be greater than the magnitude of flow within the stream. Net gains consistently occurred over the lower 15 miles of the South Fork Smith River. A monitoring site near the mouth of the South Fork Smith River gained (flow from the groundwater to the stream) during all seasons, with head gradients towards the stream. Two upstream sites on the South Fork Smith River exhibited variable conditions that ranged from gaining during the spring, losing (flowing from the stream to the groundwater) during most of the summer as groundwater levels declined, and then approached or returned to gaining conditions in late summer. Parts of the South Fork Smith River became dry during periods of losing conditions, thus classifying this tributary as intermittent. The North Fork Smith River is highly managed at times through reservoir releases. The North Fork Smith River was perennial throughout the study period although irrigation diversions removed a large percentage of streamflow at times and losing conditions persisted along a lower reach. The lowermost reach of the North Fork Smith River near its mouth transitioned from a losing reach to a gaining reach throughout the study period. Groundwater and surface-water interactions occur downstream from the confluence of the North and South Fork Smith Rivers, but are less discernible compared to the overall magnitude of the main-stem streamflow. The Smith River was perennial throughout the study. Monitoring sites along the Smith River generally displayed small head gradients between the stream and the groundwater, while one site consistently showed strongly gaining conditions. Synoptic streamflow measurements during periods of limited irrigation diversion in 2007 and 2008 consistently showed gains over the upper 41.4 river miles of the main stem Smith River where net gains ranged from 13.0 to 28.9 cubic feet per second. Continuous streamflow data indicated net groundwater discharge and small-scale tributary inflow contributions of around 25 cubic feet per second along the upper 10-mile reach of the Smith River for most of the 2010 record. A period of intense irrigation withdrawal during the last two weeks in May was followed by a period (early June 2010 to mid-July 2010) with the largest net increase (an average of 71.1 cubic feet per second) in streamflow along this reach of the Smith River. This observation is likely due to increased groundwater discharge to the Smith River resulting from irrigation return flow. By late July, the apparent effects of return flows receded, and the net increase in streamflow returned to about 25 cubic feet per second. Two-dimensional heat and solute transport VS2DH models representing selected stream cross sections were used to constrain the hydraulic properties of the Quaternary alluvium and estimate temporal water-flux values through model boundaries. Hydraulic conductivity of the Quaternary alluvium of the modeled sections ranged from 3x10-6 to 4x10-5 feet per second. The models showed reasonable approximations of the streambed and shallow aquifer environment, and the dynamic changes in water flux between the stream and the groundwater through different model boundaries.

Montana↗

USGS2014

Hydrology and numerical simulation of groundwater movement and heat transport in Snake Valley and surrounding areas, Juab, Miller, and Beaver Counties, Utah, and White Pine and Lincoln Counties, Nevada

Snake Valley and surrounding areas, along the Utah-Nevada state border, are part of the Great Basin carbonate and alluvial aquifer system. The groundwater system in the study area consists of water in unconsolidated deposits in basins and water in consolidated rock underlying the basins and in the adjacent mountain blocks. Most recharge occurs from precipitation on the mountain blocks and most discharge occurs from the lower altitude basin-fill deposits mainly as evapotranspiration, springflow, and well withdrawals. The Snake Valley area regional groundwater system was simulated using a three-dimensional model incorporating both groundwater flow and heat transport. The model was constructed with MODFLOW-2000, a version of the U.S. Geological Survey’s groundwater flow model, and MT3DMS, a transport model that simulates advection, dispersion, and chemical reactions of solutes or heat in groundwater systems. Observations of groundwater discharge by evapotranspiration, springflow, mountain stream base flow, and well withdrawals; groundwater-level altitudes; and groundwater temperatures were used to calibrate the model. Parameter values estimated by regression analyses were reasonable and within the range of expected values. This study represents one of the first regional modeling efforts to include calibration to groundwater temperature data. The inclusion of temperature observations reduced parameter uncertainty, in some cases quite significantly, over using just water-level altitude and discharge observations. Of the 39 parameters used to simulate horizontal hydraulic conductivity, uncertainty on 11 of these parameters was reduced to one order of magnitude or less. Other significant reductions in parameter uncertainty occurred in parameters representing the vertical anisotropy ratio, drain and river conductance, recharge rates, and well withdrawal rates. The model provides a good representation of the groundwater system. Simulated water-level altitudes range over almost 2,000 meters (m); 98 percent of the simulated values of water-level altitudes in wells are within 30 m of observed water-level altitudes, and 58 percent of them are within 12 m. Nineteen of 20 simulated discharges are within 30 percent of observed discharge. Eighty-one percent of the simulated values of groundwater temperatures in wells are within 2 degrees Celsius (°C) of the observed values, and 55 percent of them are within 0.75 °C. The numerical model represents a more robust quantification of groundwater budget components than previous studies because the model integrates all components of the groundwater budget. The model also incorporates new data including (1) a detailed hydrogeologic framework, and (2) more observations, including several new water-level altitudes throughout the study area, several new measurements of spring discharge within Snake Valley which had not previously been monitored, and groundwater temperature data. Uncertainty in the estimates of subsurface flow are less than those of previous studies because the model balanced recharge and discharge across the entire simulated area, not just in each hydrographic area, and because of the large dataset of observations (water-level altitudes, discharge, and temperatures) used to calibrate the model and the resulting transmissivity distribution. Groundwater recharge from precipitation and unconsumed irrigation in Snake Valley is 160,000 acre-feet per year (acre-ft/yr), which is within the range of previous estimates. Subsurface inflow from southern Spring Valley to southern Snake Valley is 13,000 acre-ft/yr and is within the range of previous estimates; subsurface inflow from Spring Valley to Snake Valley north of the Snake Range, however, is only 2,200 acre-ft/yr, which is much less than has been previously estimated. Groundwater discharge from groundwater evapotranspiration and springs is 100,000 acre-ft/yr, and discharge to mountain streams is 3,300 acre-ft/yr; these are within the range of previous estimates. Current well withdrawals are 28,000 acre-ft/yr. Subsurface outflow from Snake Valley moves into Pine Valley (2,000 acre-ft/yr), Wah Wah Valley (23 acre-ft/yr), Tule Valley (33,000 acre-ft/yr), Fish Springs Flat (790 acre-ft/yr), and outside of the study area towards Great Salt Lake Desert (8,400 acre-ft/yr); these outflows, totaling about 44,000 acre-ft/yr, are within the range of previous estimates. The subsurface flow amounts indicate the degree of connectivity between hydrographic areas within the study area. The simulated transmissivity and locations of natural discharge, however, provide a better estimate of the effect of groundwater withdrawals on groundwater resources than does the amount and direction of subsurface flow between hydrographic areas. The distribution of simulated transmissivity throughout the study area includes many areas of high transmissivity within and between hydrographic areas. Increased well withdrawals within these high transmissivity areas will likely affect a large part of the study area, resulting in declining groundwater levels, as well as leading to a decrease in natural discharge to springs and evapotranspiration.

Nevada, Utah↗

USGS2021

Characterization of groundwater quality and discharge with emphasis on selenium in an irrigated agricultural drainage near Delta, Colorado, 2017–19

Selenium is a water-quality constituent of concern for aquatic ecosystems in the lower Gunnison River Basin. Selenium is derived from bedrock of the Mancos Shale and is mobilized and transported to groundwater and surface water by application of irrigation water. Although it is recognized that groundwater contributes an appreciable amount of selenium to surface water, few studies have addressed interactions between the two. The U.S. Geological Survey in cooperation with the Colorado Water Conservation Board conducted a study during 2017–19 to characterize the quality and quantity of groundwater discharging to an agricultural drainage near Delta, Colorado, locally known as Sunflower Drain. Water quality in the study area is characterized by high dissolved solids with elevated concentrations of selenium and nitrate resulting from dissolution of soluble salts in the Mancos Shale. Selenium concentrations have decreased by 50 percent since the early 2000s, possibly in response to irrigation system improvements. Stable water isotopes indicate streamflow is dominated by canal water during the irrigation season (April to October) and, during the nonirrigation season (November to March), is dominated by groundwater that has undergone some degree of evaporation. Pesticide and pharmaceutical compounds were infrequently detected, and results indicate they were derived from sources outside the study area such that they do not appear to be useful as tracers of groundwater sources. Stable isotopes of nitrate indicate that nitrate originates from the Mancos Shale, and the isotopic composition is enriched by denitrification in the groundwater system. Using a mass-balance approach, estimated groundwater discharge rates to Sunflower Drain ranged from 0.15 to 0.27 cubic feet per second per mile with one losing reach identified. Selenium, sulfate, and nitrate concentrations in groundwater estimated by mass-balance calculations were similar to concentrations measured in the Poly 17 observation well, located in a largely irrigated area in east tributary. One tributary reach had higher concentrations of selenium, sulfate, and nitrate likely reflecting localized inputs of more concentrated groundwater, similar to the concentrations in the Poly 7 observation well, which is downgradient from a residential area in the west tributary. Three pilot studies were conducted, including fiber optic distributed temperature sensing to detect groundwater discharge zones in the stream channel, a passive seismic technique to estimate depth to bedrock, and use of radon-222 as a geochemical tracer of groundwater discharge. All three techniques show promise as additional approaches for investigating groundwater discharge surface-water systems in irrigated drainage areas on Mancos Shale. The factors that affect groundwater movement mainly include when and where irrigation water is transported and applied, and the distribution of bedrock of the Mancos Shale and overlying alluvial deposits. The average groundwater recharge rate for the study area was estimated at 8.1 inches per year, based on mass balance calculations from synoptic survey data. Along the western tributary of Sunflower Drain, there was evidence that spills from the East Canal may recharge the groundwater aquifer adjacent to the stream channel. Groundwater movement to the stream channel may be controlled by the topography of the alluvial/bedrock interface or focused along human-made features, such as tile drains and ditches constructed around irrigated fields. On larger scales, the top of bedrock was also important, creating a topographic constriction that caused a zone of groundwater discharge. The groundwater system is complex, and further study could better define the system, possibly through application of a groundwater flow model and more extensive studies using some of the exploratory methods evaluated in this study.

Colorado↗

USGS2024

Simulated mean monthly groundwater-transported nitrogen loads in watersheds on the north shore of Long Island Sound, 1993–2022

Elevated nitrogen loads are pervasive in the Long Island Sound, an estuary that receives freshwater and nutrients from both surface-water and groundwater discharge. Surface-water nitrogen loads to the Long Island Sound are relatively well characterized, but less is known about groundwater-transported nitrogen loads. Prior work on the northern shore of Long Island Sound (Connecticut and areas of New York and Rhode Island) suggested that groundwater travel times are relatively short (median less than 2 years) and that decade-long nutrient legacies are not widespread. Because the travel times are short, groundwater flow and nutrient loads likely vary substantially between months. In the current study, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency’s Long Island Sound Study and the Connecticut Department of Energy and Environmental Protection, developed a set of models to better characterize spatial and temporal patterns of groundwater-transported nitrogen loading from atmospheric deposition, septic systems, and fertilizers within the study area. The models provide an estimate, with uncertainty, of groundwater-transported nitrogen loads in the study area, filling a key gap in the nitrogen budget for Long Island Sound. The models also highlight the spatial and temporal variation in nitrogen loading throughout the study area. The modeling workflow involved four models. (1) A soil-water-balance model was developed by using the Soil-Water-Balance software to simulate groundwater recharge across the study area for water years 2005 through 2022. The simulated mean monthly recharge from the soil-water-balance model was used as input into a groundwater-flow model. (2) The groundwater-flow model was developed by using the MODFLOW 6 software and data for water years 1993 through 2022 and simulates average monthly hydrologic conditions. The groundwater-flow model was calibrated by using the Iterative Ensemble Smoother method within the PEST++ software. The Iterative Ensemble Smoother method generates an ensemble of sets of parameter values, with each set producing reasonable simulated hydrologic parameter values. (3) An ensemble of MODPATH particle-tracking simulations were run to generate particle flow paths and travel times, with each simulation using a different set of the flow model parameters. (4) A nitrogen load model uses the MODPATH simulation outputs to track nitrogen from the land surface through multiple attenuation zones until it discharges into fresh or saline surface water. As with the groundwater-flow model, the nitrogen model simulated average monthly groundwater-transported nitrogen loads for water years 1993 through 2022. One novel aspect of the nitrogen load model is that the nitrogen attenuation parameters were calibrated to observed nitrogen loads. Across the ensemble of simulated nitrogen loads, the median study-area-wide monthly simulated nitrogen loads from the aquifer to Long Island Sound throughout the year ranged from 900 to 18,600 kilograms of nitrogen per day, with a median load of 5,100 kilograms of nitrogen per day. The simulated loads were based on average monthly conditions for water years 1993 through 2022. Loads were highest during the winter and early spring and lowest during the late summer. However, simulated travel times for groundwater and nitrogen loads discharged to Long Island Sound during summer were longer than travel times for groundwater and loads discharged during the winter, indicating that, on average, groundwater discharged during summer traveled along different, and longer, flow paths, than groundwater discharged during winter. This indicates that summer loads would respond more slowly to changes in nitrogen inputs at the water table than winter loads. Over the entire study area, approximately 15 percent of the simulated load is from atmospheric deposition sources, 30 to 40 percent is from fertilizer, and 50 to 60 percent is from septic systems. The final analysis of the study involved simulating the change in groundwater-transported nitrogen load in response to upgrading septic systems or reducing fertilizing inputs to areas of turf grass. Both management interventions reduced the groundwater-transported nitrogen load, and reductions were greater in areas with greater loads from septic systems or turf-grass fertilizers. The delay between management actions and substantial reductions in groundwater-transported nitrogen loads varied seasonally; loads during the late summer months remained elevated longer than the winter loads.

Connecticut, Rhode Island↗

USGS1989

Hydrogeology, ground-water movement, and subsurface storage in the Floridan aquifer system in southern Florida

The Floridan aquifer system of southern Florida is composed chiefly of carbonate rocks that range in age from early Miocene to Paleocene. The top of the aquifer system in southern Florida generally is at depths ranging from 500 to 1,000 feet, and the average thickness is about 3,000 feet. It is divided into three general hydrogeologic units: (1) the Upper Floridan aquifer, (2) the middle confining unit, and (3) the Lower Floridan aquifer. The Upper Floridan aquifer contains brackish ground water, and the Lower Floridan aquifer contains salty ground water that compares chemically to modern seawater. Zones of high permeability are present in the Upper and Lower Floridan aquifers. A thick, cavernous dolostone in the Lower Floridan aquifer, called the Boulder Zone, is one of the most permeable carbonate units in the world (transmissivity of about 2.5 x 107 feet squared per day). Ground-water movement in the Upper Floridan aquifer is generally southward from the area of highest head in central Florida, eastward to the Straits of Florida, and westward to the Gulf of Mexico. Distributions of natural isotopes of carbon and uranium generally confirm hydraulic gradients in the Lower Floridan aquifer. Groundwater movement in the Lower Floridan aquifer is inland from the Straits of Florida. The concentration gradients of the carbon and uranium isotopes indicate that the source of cold saltwater in the Lower Floridan aquifer is seawater that has entered through the karat features on the submarine Miami Terrace near Fort Lauderdale. The relative ages of the saltwater suggest that the rate of inland movement is related in part to rising sea level during the Holocene transgression. Isotope, temperature, and salinity anomalies in waters from the Upper Floridan aquifer of southern Florida suggest upwelling of saltwater from the Lower Floridan aquifer. The results of the study support the hypothesis of circulating relatively modern seawater and cast doubt on the theory that the saltwater in the Floridan aquifer system probably is connate or unflushed seawater from high stands of sea level. The principal use of the Floridan aquifer system in southern Florida is for subsurface storage of liquid waste. The Boulder Zone of the Lower Floridan aquifer is extensively used as a receptacle for injected treated municipal wastewater, oil field brine, and, to a lesser extent, industrial wastewater. Pilot studies indicate a potential for cyclic storage of freshwater in the Upper Floridan aquifer in southern Florida.

Florida↗

USGS2017

Hydrology and numerical simulation of groundwater flow and streamflow depletion by well withdrawals in the Malad-Lower Bear River Area, Box Elder County, Utah

The Malad-Lower Bear River study area in Box Elder County, Utah, consists of a valley bounded by mountain ranges and is mostly agricultural or undeveloped. The Bear and Malad Rivers enter the study area with a combined average flow of about 1,100,000 acre-feet per year (acre-ft/yr), and this surface water dominates the hydrology. Groundwater occurs in consolidated rock and basin fill. Groundwater recharge occurs from precipitation in the mountains and moves through consolidated rock to the basin fill. Recharge occurs in the valley from irrigation. Groundwater discharge occurs to rivers, springs and diffuse seepage areas, evapotranspiration, field drains, and wells. Groundwater, including springs, is a source for municipal and domestic water supply. Although withdrawal from wells is a small component of the groundwater budget, there is concern that additional groundwater development will reduce the amount of flow in the Malad River. Historical records of surface-water diversions, land use, and groundwater levels indicate relatively stable hydrologic conditions from the 1960s to the 2010s, and that current groundwater development has had little effect on the groundwater system. Average annual recharge to and discharge from the groundwater flow system are estimated to be 164,000 and 228,000 acre-ft/yr, respectively. The imbalance between recharge and discharge represents uncertainties resulting from system complexities, and the possibility of groundwater inflow from surrounding basins. This study reassesses the hydrologic system, refines the groundwater budget, and creates a numerical groundwater flow model that is used to analyze the effects of groundwater withdrawals on surface water. The model uses the detailed catalog of locations and amounts of groundwater recharge and discharge defined during this study. Calibrating the model to adequately simulate recharge, discharge, and groundwater levels results in simulated aquifer properties that can be used to understand the relation between pumping and the reduction in discharge to rivers, springs, natural vegetation, and field drains. Simulations run by the calibrated model were used to calculate the reduction of groundwater discharge to the Malad River (stream depletion) in response to a well withdrawal of 360 acre-ft/yr at any location within the study area. Modeling results show that streamflow depletion in the Malad River depends on both depth and location of groundwater withdrawal, and varies from less than 1 percent to 96 percent of the well withdrawal. The relation between simulated withdrawal and reductions in Malad River streamflow, Bear River streamflow, and spring discharge are shown on capture maps.

Utah↗

USGS2000

Hydrogeology of the regional aquifer near Flagstaff, Arizona, 1994-97

Sandstones, siltstones, and limestones that are Pennsylvanian to Permian in age underlie the southern part of the Colorado Plateau near Flagstaff, Arizona, and contain a complex regional aquifer that has become increasingly important as a source of water for domestic, municipal, and recreational uses. Ground-water flow in the regional aquifer is poorly understood in this area because (1) depth of the aquifer limits exploratory drilling and testing and (2) the geologic structure increases the complexity of the aquifer characteristics and the ground-water flow system. Four methods were used to improve the understanding of the hydrogeology of the regional aquifer near Flagstaff. • Remote-sensing techniques and geologic mapping provided data to identify many structural features that indicate a more complex structural environment and history than previously realized. • Data from surface-geophysical techniques that included ground-penetrating radar, seismic reflection and seismic refraction, and square-array resistivity, verified that some of the geologic structures expressed at land surface propagate deep into the subsurface and through the principal water-bearing zones of the regional aquifer at near-vertical angles. • A well and spring inventory, borehole-geophysical methods, and well and aquifer tests provided additional information relating aquifer and ground-water flow characteristics to geologic structure. • Water-chemistry data, which included major ion, nutrient, trace-element, and radioactive and stable-isotope analyses, provided an independent means of verifying the hydrogeologic characteristics of the aquifer and were used to determine recharge and discharge areas, groundwater movement, and ground-water age. Ground-water recharge occurs throughout the area but is greatest at higher altitudes where precipitation is greater and in areas where heavily fractured rock units of the aquifer are exposed. The estimated annual average recharge to the regional aquifer in the study area is about 290,000 acre-feet. Ground water flows laterally and vertically through pore spaces in the rock and along faults and other fractures from high-altitude areas in the southern part of the study area to regional drains north of the study area along the Little Colorado and Colorado Rivers, and to drains south of the study area along Oak Creek and the Verde Valley. Ground-water discharge in these areas—about 400,000 acre-feet per year—exceeds the annual recharge to the aquifer in the Flagstaff area, but ground water from areas outside the study area contributes to this discharge as well. The saturated thickness of the regional aquifer averages about 1,200 feet, and the amount of water in storage could be as much as 4,800,000 acrefeet, or about 10 percent of the total volume of the aquifer. The quality of water in the regional aquifer in terms of dissolved-solids concentrations is good for most uses throughout the area. Dissolvedsolids concentrations generally are less than 500 milligrams per liter. Water in the regional aquifer is primarily a calcium magnesium bicarbonate type. In some areas near the Rio de Flag, the water has significant nitrate and chloride components, which indicate direct recharge in these areas from the Rio de Flag. Oxygen and deuterium data indicate a common recharge source for water in the aquifer and that some sites receive recharge from surface waters where evaporation has occurred. Estimated carbon-14 ages and tritium activities indicate ground-water ages from less than 200 years in the Lake Mary area to more than 5,000 years in the Wupatki area. The regional aquifer is heterogeneous and anisotrophic and has a complex ground-water flow system. The most productive water-bearing material tends to be fine- to medium-grained sandstones, and ground-water flow and potential well yields are related to geologic structure. Fracturing associated with structural deformation increases recharge locally and also increases the potential for high well yields. Surface-geophysical techniques provided information on the orientation of high-angle, deep-seated structure in the saturated zone. Borehole-geophysical data identified horizontal to near-horizontal fractures as significant components of the fracture-flow system not apparent in the surface-geophysical data. Structural features that strike northwest appear to be areas that have the greatest potential for high well yields. A north-northeastward-striking structure may be just as promising, but additional data are needed to verify this relation.

Arizona↗

USGS1993

Geohydrology and evaluation of water-resource potential of the upper Floridan Aquifer in the Albany area, southwestern Georgia

Georgia↗

USGS2007

Vertical gradients in water chemistry and age in the Northern High Plains Aquifer, Nebraska, 2003

The northern High Plains aquifer is the primary source of water used for domestic, industrial, and irrigation purposes in parts of Colorado, Kansas, Nebraska, South Dakota, and Wyoming. Despite the aquifer’s importance to the regional economy, fundamental ground-water characteristics, such as vertical gradients in water chemistry and age, remain poorly defined. As part of the U.S. Geological Survey’s National Water-Quality Assessment Program, water samples from nested, short-screen monitoring wells installed in the northern High Plains aquifer were analyzed for major ions, nutrients, trace elements, dissolved organic carbon, pesticides, stable and radioactive isotopes, dissolved gases, and other parameters to evaluate vertical gradients in water chemistry and age in the aquifer. Chemical data and tritium and radiocarbon ages show that water in the aquifer was chemically and temporally stratified in the study area, with a relatively thin zone of recently recharged water (less than 50 years) near the water table overlying a thicker zone of older water (1,800 to 15,600 radiocarbon years). In areas where irrigated agriculture was an important land use, the recently recharged ground water was characterized by elevated concentrations of major ions and nitrate and the detection of pesticide compounds. Below the zone of agricultural influence, major-ion concentrations exhibited small increases with depth and distance along flow paths because of rock/water interactions. The concentration increases were accounted for primarily by dissolved calcium, sodium, bicarbonate, sulfate, and silica. In general, the chemistry of ground water throughout the aquifer was of high quality. None of the approximately 90 chemical constituents analyzed in each sample exceeded primary drinking-water standards. Mass-balance models indicate that changes in groundwater chemistry along flow paths in the aquifer can be accounted for by small amounts of feldspar and calcite dissolution; goethite and clay-mineral precipitation; organic-carbon and pyrite oxidation; oxygen reduction and denitrification; and cation exchange. Mixing with surface water affected the chemistry of ground water in alluvial sediments of the Platte River Valley. Radiocarbon ages in the aquifer, adjusted for carbon mass transfers, ranged from 1,800 to 15,600 14C years before present. These results have important implications with respect to development of ground-water resources in the Sand Hills. Most of the water in the aquifer predates modern anthropogenic activity so excessive removal of water by pumping is not likely to be replenished by natural recharge in a meaningful timeframe. Vertical gradients in ground-water age were used to estimate long-term average recharge rates in the aquifer. In most areas, the recharge rates ranged from 0.02 to 0.05 foot per year. The recharge rate was 0.2 foot per year in one part of the aquifer characterized by large downward hydraulic gradients. Nitrite plus nitrate concentrations at the water table were 0.13 to 3.13 milligrams per liter as nitrogen, and concentrations substantially decreased with depth in the aquifer. Dissolved-gas and nitrogen-isotope data indicate that denitrification in the aquifer removed 0 to 97 percent (average = 50 percent) of the nitrate originally present in recharge. The average amount of nitrate removed by denitrification in the aquifer north of the Platte River (Sand Hills) was substantially greater than the amount removed south of the river (66 as opposed to 0 percent), and the extent of nitrate removal appears to be related to the presence of thick deposits of sediment on top of the Ogallala Group in the Sand Hills that contained electron donors, such as organic carbon and pyrite, to support denitrification. Apparent rates of dissolved-oxygen reduction and denitrification were estimated on the basis of decreases in dissolved-oxygen concentrations and increases in concentrations of excess nitrogen gas and ground-water ages along flow paths from the water table to deeper wells. Median rates of dissolved-oxygen reduction and denitrification south of the Platte River were at least 10 times smaller than the median rates north of the river in the Sand Hills. The relatively large denitrification rates in the Sand Hills indicate that the aquifer in that area may have a greater capacity to attenuate nitrate contamination than the aquifer south of the river, depending on rates of ground-water movement in the two areas. Small denitrification rates south of the river indicate that nitrate contamination in that part of the aquifer would likely persist for a longer period of time.

Nebraska↗

USGS2010

Groundwater-quality monitoring program in Chester County, Pennsylvania, 1980-2008

The U.S. Geological Survey in cooperation with the Chester County Water Resources Authority and the Chester County Health Department began a groundwater-quality monitoring program in 1980 in Chester County, Pa., where a large percentage of the population relies on wells for drinking-water supply. This report documents the program and serves as a reference for data collected through the program from 1980 through 2008. The initial focus of the program was to collect data on groundwater quality near suspected localized sources of contamination, such as uncontrolled landfills and suspected industrial wastes, to determine if contaminants were present that might pose a health risk to those using the groundwater. Subsequently, the program was expanded to address the effects of widely distributed contaminant sources associated with agricultural and residential land uses on groundwater quality and to document naturally occurring constituents, such as radium, radon, and arsenic, that are potential hazards in drinking water. Since 2000, base-flow stream samples have been collected in addition to well-water and spring samples in a few small drainage areas to investigate the relation between groundwater quality measured in well samples and streams. The program has primarily consisted of spatial assessment with limited temporal data collected on groundwater quality. Most data were collected through the monitoring program for reconnaissance purposes to identify and locate groundwater-quality problems and generally were not intended for rigorous statistical analyses that might determine land-use or geochemical factors affecting groundwater quality in space or through time. Results of the program found several contaminants associated with various land uses and human activities in groundwater in Chester County. Volatile organic compounds (such as trichloroethylene) were measured in groundwater near suspected localized contaminant sources in concentrations that exceeded drinking-water standards. Groundwater in some agricultural areas had concentrations of nitrate and some pesticides that exceeded drinking-water standards. Elevated concentrations of chloride were measured near salt storage areas and highways. Formaldehyde was detected in groundwater near cemeteries. In residential areas with on-site wastewater disposal, effects on groundwater quality included elevated nitrate concentrations and low concentrations of volatile organic compounds and wastewater compounds, such as antibiotics and detergents. Base-flow samples indicated that groundwater discharge to streams carried contaminants such as nitrate, pesticides, wastewater compounds, and other contaminants. Radionuclides, including radium-226, radium-228, radium-224, and radon-222, and gross alpha-particle activity were measured in groundwater at levels above established and proposed drinking-water standards in some geologic units, particularly in quartzite and quartzite schists. Arsenic concentrations above drinking-water standards were measured in a few samples and were most likely to occur in groundwater in the shales and sandstones in the northern part of the county. Other potential natural hazards, such as lead from aquifer materials or leached from plumbing because of pH, were present in concentrations above drinking-water standards infrequently (less than 10 percent of samples). Limited temporal sampling suggested that chloride concentrations in groundwater increased in the county since the program began in 1980 through 2008, reflecting increasing population and urbanization in that period.

Scientific Investigations Report↗

USGS2002

Effects of highway-deicer application on ground-water quality in a part of the Calumet Aquifer, northwestern Indiana

The effects of highway-deicer application on ground-water quality were studied at a site in northwestern Indiana using a variety of geochemical indicators. Site characteristics such as high snowfall rates; large quantities of applied deicers; presence of a high-traffic highway; a homogeneous, permeable, and unconfined aquifer; a shallow water table; a known ground-water-flow direction; and minimal potential for other sources of chloride and sodium to complicate source interpretation were used to select a study area where ground water was likely to be affected by deicer application. Forty-three monitoring wells were installed in an unconfined sand aquifer (the Calumet aquifer) near Beverly Shores in northwestern Indiana. Wells were installed along two transects that approximately paralleled groundwater flow in the Calumet aquifer and crossed US–12. US–12 is a highway that receives Indiana’s highest level of maintenance to maintain safe driving conditions. Ground-water quality and water-level data were collected from the monitoring wells, and precipitation and salt-application data were compiled from 1994 through 1997. The water-quality data indicated that chloride was the most easily traced indicator of highway deicers in ground water. Concentration ratios of chloride to iodide and chloride to bromide and Stiff diagrams of major element concentrations indicated that the principal source of chloride and sodium in ground water from the uppermost one-third to one-half of the Calumet aquifer and downgradient from US–12 was from a halite highway-deicer source. Borehole logs of relative electromagnetic conductivity defined a distinct plume of deicer-affected water in the uppermost 8 feet of aquifer at about 9 feet horizontally from the paved roadway edge and a zone of higher conductivity than background in the lower one-third of the aquifer. Chloride and sodium in the deep parts of the aquifer originated from natural sources. Chloride and sodium from highway deicers were present in the aquifer throughout the year. The highest concentrations of chloride and sodium in ground water were determined in samples collected during the spring and summer from wells open to the water table within about 9 feet of the highway. Chloride concentrations in ground water that were attributable to highway deicers also were found in tested wells about 400 feet downgradient from US–12 during the fall and winter and at greater depths than in wells closer to US–12. Chloride concentrations exceeded the U.S. Environmental Protection Agency’s (USEPA) secondary maximum contaminant level of 250 milligrams per liter for drinking water at seven wells downgradient from the highway during late winter, spring, and summer samplings. The chloride standard was exceeded only in water from wells with total depths that are less than about 10 feet below land surface. Sodium concentrations in water periodically exceeded the USEPA drinking-water equivalency level of 20 milligrams per liter in both the uppermost (deicer 2 Effects of Highway-Deicer Application on Ground-Water Quality in a Part of the Calumet Aquifer, Northwestern Indiana affected) and lower one-thirds of the aquifer. Sodium concentrations in ground water downgradient from US–12 and in the upper 5 feet of the aquifer also occasionally exceeded drinking-water standards for sodium (160 milligrams per liter) as set by the State of Florida and a standard for taste (200 milligrams per liter) as set by the World Health Organization. Dispersion was identified by analysis of aquifer-test data, isotopic dating of ground water, and water-quality data to be the process most responsible for reducing concentrations of highway deicers in the aquifer. Chemical analyses of the sand composing the aquifer indicated that cation exchange decreased the mass of deicerrelated sodium in ground water, although the sand has a limited capacity to sustain the process. Automated daily measurements of specific conductance, correlated to chloride concentrations, indicated that some deicer is retained in the aquifer near the highway throughout the entire year and acts as a continuous chloride source for ground water. Peak concentrations of deicerrelated constituents occasionally were detected by the daily, automated measurements of specific conductance that were made between the monthly samplings of ground water. Data analysis indicated that more frequent sampling than monthly intervals would be necessary if maximum chloride concentrations were to be measured. Some deicer may be retained in the aquifer and unsaturated zone between annual salt-application periods. Chloride concentrations at wells 1-DG-WT and 2-DG-WT remained greater than background through much or all of the year. The estimated masses of chloride transported in ground water past 2-DG in 1995 and 1996 were either slightly greater than (1995) or less than (1996) the masses of chloride applied to US–12 during the study.

Indiana↗