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Redox Conditions in Selected Principal Aquifers of the United States

Reduction/oxidation (redox) processes affect the quality of groundwater in all aquifer systems. Redox processes can alternately mobilize or immobilize potentially toxic metals associated with naturally occurring aquifer materials, contribute to the degradation or preservation of anthropogenic contami-nants, and generate undesirable byproducts, such as dissolved manganese (Mn2+), ferrous iron (Fe2+), hydrogen sulfide (H2S), and methane (CH4). Determining the kinds of redox processes that occur in an aquifer system, documenting their spatial distribution, and understanding how they affect concentrations of natural or anthropogenic contaminants are central to assessing and predicting the chemical quality of groundwater. This Fact Sheet extends the analysis of U.S. Geological Survey authors to additional principal aquifer systems by applying a framework developed by the USGS to a larger set of water-quality data from the USGS national water databases. For a detailed explanation, see the 'Introduction' in the Fact Sheet.

Fact Sheet↗

Hydrologic characteristics of soils in the High Plains, northern Great Plains, and Central Texas Carbonates Regional Aquifer Systems

Certain physical characteristics of soils, including permeability, available water capacity, thickness, and topographic position, have a measurable effect on the hydrology of an area. These characteristics control the rate at which precipitation infiltrates or is transmitted through the soil, and thus they have an important role in determining the rates of actual evapotranspiration (consumptive water use), groundwater recharge, and surface runoff. In studies of groundwater hydrology, it is useful to differentiate soils spatially according to their physical characteristics and to assign values that indicate their hydrologic responses. The principal purpose of this report is to describe the relation between the hydrologic characteristics of the soils in the study area and those environmental factors that affect the development and distribution of the soils. This objective will be achieved by (1) defining both qualitatively and quantitatively those soil characteristics that affect hydrology, and (2) classifying and delineating the boundaries of the soils in the study area according to these hydrologic characteristics. The study area includes the High Plains, Northern Great Plains, the Central Texas Carbonates, and parts of the Central Midwest Regional Aquifer Systems as described by the U.S. Geological Survey Regional Aquifer-System Analysis (RASA) Program (Sun, 1986, p.5and Sun, personal commun., June 1985) and shown in figures 1 through 5. The spatial patterns of the soils classified according to their quantifiable hydrologic characteristics will subsequently serve as an integral component in the analysis of actual evapotranspiration (consumptive water use), consumptive irrigation requirements, and potential ground-water recharge of the study area. The classification system used to describe the soils in this report is compatible with that of Dugan (1986). Dugan described the same characteristics of soils that are immediately underlain by principal aquifers of Cretaceous or older age in adjacent parts of the Central Midwest Regional Aquifer System. However, map scales and mapping detail are different between this report and the report by Dugan (1986) because of the size of the study area.

Hydrologic Atlas↗

Revised geologic cross sections of parts of the Colorado, White River, and Death Valley regional groundwater flow systems, Nevada, Utah, and Arizona

This report presents revisions to parts of seven of the ten cross sections originally published in U.S. Geological Survey Open-File Report 2006-1040. The revisions were necessary to correct errors in some of the original cross sections, and to show new parts of several sections that were extended and (or) appended to the original section profiles. Revisions were made to cross sections C-C', D-D', E-E', F-F', G-G', I-I', and J-J', and the parts of the sections revised or extended are highlighted below the sections on plate 1 by red brackets and the word "revised," or "extended." Sections not listed above, as well as the interpretive text and figures, are generally unchanged from the original report. Cross section C-C' includes revisions in the east Mormon Mountains in the east part of the section; D-D' includes revisions in the Mormon Mesa area in the east part of the section; E-E' includes revisions in the Muddy Mountains in the east part of the section; F-F' includes revisions from the Muddy Mountains to the south Virgin Mountains in the east part of the section; and J-J' includes some revisions from the east Mormon Mountains to the Virgin Mountains. The east end of G-G' was extended about 16 km from the Black Mountains to the southern Virgin Mountains, and the northern end of I-I' was extended about 45 km from the Muddy Mountains to the Mormon Mountains, and revisions were made in the Muddy Mountains part of the original section. This report contains 10 interpretive cross sections and an integrated text describing the geology of parts of the Colorado, White River, and Death Valley regional groundwater flow systems in Nevada, Utah, and Arizona. The primary purpose of the report is to provide geologic framework data for input into a numerical groundwater model. Therefore, the stratigraphic and structural summaries are written in a hydrogeologic context. The oldest rocks (basement) are Early Proterozoic metamorphic and intrusive crystalline rocks that are considered confining units because of their low permeability. Late Proterozoic to Lower Cambrian clastic units overlie the crystalline rocks and are also considered confining units within the regional flow systems. Above the clastic units are Middle Cambrian to Lower Permian carbonate rocks that are the primary aquifers in the flow systems. The Middle Cambrian to Lower Permian carbonate rocks are overlain by a sequence of mainly clastic rocks of late Paleozoic to Mesozoic age that are mostly considered confining units, but they may be permeable where faulted. Tertiary volcanic and plutonic rocks are exposed in the northern and southern parts of the study area. In the Clover and Delamar Mountains, these rocks are highly deformed by north- and northwest-striking normal and strike-slip faults that are probably important conduits in transmitting groundwater from the basins in the northern Colorado and White River flow systems to basins in the southern part of the flow systems. The youngest rocks in the region are Tertiary to Quaternary basin-fill deposits. These rocks consist of middle to late Tertiary sediments consisting of limestone, conglomerate, sandstone, tuff, and gypsum, and younger Quaternary surficial units consisting of alluvium, colluvium, playa deposits, and eolian deposits. Basin-fill deposits are both aquifers and aquitards. The rocks in the study area were complexly deformed by episodes of Mesozoic compression and Cenozoic extensional tectonism. Some Cretaceous thrust faults and folds of the Sevier orogenic belt form duplex zones and define areas of maximum thickness for the Paleozoic carbonate rocks. Cenozoic faults are important because they are the primary structures that control groundwater flow in the regional flow systems.

Arizona, Nevada, Utah↗

Summary of available hydrogeologic data for the northeast portion of the alluvial aquifer at Louisville, Kentucky

The hydrogeologic characteristics of the unconsolidated glacial outwash sand and gravel deposits that compose the northeast portion of the alluvial aquifer at Louisville, Kentucky, indicate a prolific water-bearing formation with approximately 7 billion gallons of ground-water storage and an estimated sustainable yield of over 280 million gallons per day. This abundance of ground water and the need to properly develop and manage this resource has prompted many past investigations (since 1956), which have produced reports, maps, and data files covering a variety of topics relative to the movement, availability, and use of ground water in this area. These data have been compiled into a single report to assist in future development and use of the ground-water resources. Available ground-water data for the alluvial aquifer at Louisville, Kentucky, from Beargrass Creek to Harrods Creek, were compiled from the U.S. Geological Survey National Water Information System and the Kentucky Groundwater Data Repository. Data contained in these databases include ground-water well-construction details and historical ground-water levels, drillers' logs, and water-quality information. Additional data and information were gathered from project files at the U.S. Geological Survey--Kentucky Water Science Center and files at the Louisville Water Company. Information contained in these files included data from area pumping tests describing aquifer characteristics and ground-water flow. Data describing current conditions of the ground-water system in the northeast portion of the alluvial aquifer also are included. Ground-water levels from a network of observation wells show recent trends in the flow system, and information from the Kentucky Division of Water-Groundwater Branch lists current permitted ground-water withdrawals in the area.

Open-File Report↗

Megaporosity and permeability of Thalassinoides-dominated ichnofabrics in the Cretaceous karst-carbonate Edwards-Trinity aquifer system, Texas

Current research has demonstrated that trace fossils and their related ichnofabrics can have a critical impact on the fluid-flow properties of hydrocarbon reservoirs and groundwater aquifers. Most petroleum-associated research has used ichnofabrics to support the definition of depositional environments and reservoir quality, and has concentrated on siliciclastic reservoir characterization and, to a lesser degree, carbonate reservoir characterization (for example, Gerard and Bromley, 2008; Knaust, 2009). The use of ichnology in aquifer characterization has almost entirely been overlooked by the hydrologic community because the dynamic reservoir-characterization approach has not caught on with hydrologists and so hydrology is lagging behind reservoir engineering in this area (de Marsily and others, 2005). The objective of this research is to show that (1) ichnofabric analysis can offer a productive methodology for purposes of carbonate aquifer characterization, and (2) a clear relation can exist between ichnofabrics and groundwater flow in carbonate aquifers.

Texas↗

Baseline groundwater quality from 34 wells in Wayne County, Pennsylvania, 2011 and 2013

Wayne County, Pennsylvania, is underlain by the Marcellus Shale, which currently (2014) is being developed elsewhere in Pennsylvania for natural gas. All residents of largely rural Wayne County rely on groundwater for water supply, primarily from bedrock aquifers (shales and sandstones). This study, conducted by the U.S. Geological Survey in cooperation with the Pennsylvania Department of Conservation and Natural Resources, Bureau of Topographic and Geologic Survey (Pennsylvania Geological Survey), provides a groundwater-quality baseline for Wayne County prior to development of the natural gas resource in the Marcellus Shale. Selected wells completed in the Devonian-age Catskill Formation, undifferentiated; the Poplar Gap and Packerton Members of the Catskill Formation, undivided; and the Long Run and Walcksville Members of the Catskill Formation, undivided, were sampled. Water samples were collected once from 34 domestic wells during August 2011 and August and September 2013 and analyzed to characterize their physical and chemical quality. Samples were analyzed for 45 constituents and properties, including nutrients, major ions, metals and trace elements, radioactivity, and dissolved gases, including methane and radon-222. The quality of the sampled groundwater was generally within U.S. Environmental Protection Agency (USEPA) drinking-water standards, although in some samples, the concentrations of a few constituents exceeded USEPA drinking-water standards and health advisories. The pH of water samples ranged from 5.5 to 9.3 with a median of 7.0. The pH was outside the USEPA secondary maximum contaminant level (SMCL) range of 6.5 to 8.5 in water samples from 14 of the 34 wells (41 percent). Eleven samples had a pH less than 6.5, and three samples had a pH greater than 8.5. Dissolved oxygen concentrations ranged from 0.2 to 11.5 milligrams per liter (mg/L) with a median of 4.7 mg/L. The dissolved oxygen concentration was less than 1 mg/L in water samples from 6 wells; 5 of these 6 water samples had a pH greater than 7.7. Concentrations of dissolved methane ranged from less than 0.00006 to 3.3 mg/L. Methane was detectable in 22 of the 34 wells sampled (65 percent). Methane concentrations were greatest in the 5 samples with pH of 7.8 or higher, ranging from 0.040 to 3.3 mg/L. These samples also had among the lowest concentrations of dissolved oxygen. Three water samples, which had sufficient dissolved methane concentrations (greater than 0.9 mg/L), were analyzed for isotopes of carbon and hydrogen in the methane. The isotopic ratio values fell within (two samples) or close to (one sample) the range for a thermogenic natural gas source. The total dissolved solids concentration ranged from 33 to 346 mg/L; the median concentration was 126 mg/L. Sodium concentrations ranged from 1.07 to 116 mg/L; the median concentration was 9.42 mg/L. The sodium concentration exceeded the USEPA health advisory for sodium of 20 mg/L in water samples from 7 of the 34 wells (21 percent). Concentrations of dissolved arsenic ranged from less than 0.06 to 21.8 micrograms per liter (µg/L); the median concentration was 0.59 µg/L. Water samples from 2 of the 34 wells (6 percent) exceeded the USEPA maximum contaminant level (MCL) of 10 µg/L for arsenic. Concentrations of dissolved manganese ranged from less than 0.15 to 61.5 µg/L; the median concentration was 0.42 µg/L. A water sample from 1 of the 34 wells (3 percent) exceeded the USEPA SMCL of 50 µg/L for manganese; the concentration was less than the USEPA lifetime health advisory of 300 µg/L for manganese. Activities of radon-222 in water from the 34 sampled wells ranged from 110 to 7,180 picocuries per liter (pCi/L); the median activity was 2,105 pCi/L. Water samples from 33 of the 34 wells (97 percent) exceeded the proposed USEPA MCL of 300 pCi/L, and 4 water samples (12 percent) exceeded the USEPA proposed alternative MCL of 4,000 pCi/L for radon-222. Differences in groundwater chemistry were related to pH. Water with a pH greater than 7.6 generally had low dissolved oxygen concentrations, indicating reducing conditions in the aquifer. These high pH waters also had relatively elevated concentrations of methane, arsenic, boron, bromide, fluoride, lithium, and sodium but low concentrations of copper, nickel, and zinc. Water samples with a pH greater than 7.8 had methane concentrations equal to or greater than 0.04 mg/L.

Pennsylvania↗

Digital modeling of radioactive and chemical waste transport in the Snake River plain aquifer at the National Reactor Testing Station, Idaho

Industrial and low-level radioactive liquid wastes at the National Reactor Testing Station (NRTS) in Idaho have been disposed to the Snake River Plain aquifer since 1952. Monitoring studies have indicated that tritium and chloride have dispersed over a 15-square mile (39-square kilometer) area of the aquifer in low but detectable concentrations and have only migrated as far as 5 miles (8 kilometers) downgradient from discharge points. The movement of cationic waste solutes, particularly 90 Sr and 137 Cs, has been significantly retarded due to sorption phenomena, principally ion exchange. 137 Cs has shown no detectable migration in the aquifer and 90 Sr has migrated only about 1.5 miles (2 kilometers) from the Idaho Chemical Processing Plant (ICPP) discharge well, and is detectable over an area of only 1.5 square miles ( 4 square kilometers) of the aquifer. Digital modeling techniques have been applied successfully to the analysis of the complex waste-transport system by utilizing numerical solution of the coupled equations of groundwater motion and mass transport. The model includes the effects of convective transport, flow divergence, two-dimensional hydraulic dispersion, radioactive decay, and reversible linear sorption. The hydraulic phase of the model uses the iterative, alternating direction, implicit finite-difference scheme to solve the groundwater flow equations, while the waste-transport phase uses a modified method of characteristics to solve the solute transport equations simulated by the model. The modeling results indicate that hydraulic dispersion (especially transverse) is a much more significant influence than previously suggested by earlier studies. The model has been used to estimate future waste migration patterns for varied assumed hydrological and waste conditions up through the year 2000. The hydraulic effects of recharge from the Big Lost River have an important (but not predominant) influence on the simulated future migration patterns. For the assumed conditions, the model indicates that detectable concentrations of waste chloride and tritium could move as much as 15 miles (24 kilometers) downgradient from the original discharge points by the year 2000. However, the model shows 90 Sr moving only 2 to 3 miles (3 to 5 kilometers) downgradient in the same time. The model may also be used to estimate the effects of the various future waste disposal practices and hydrologic conditions on subsequent migration of waste products.

Idaho↗

Digital model of the Bayou Bartholomew alluvial aquifer stream system, Arkansas

A digital model of the Bayou Bartholomew aquifer-stream system in Arkansas was calibrated for the purpose of predicting hydrologic responses to stresses of water development. The simulated-time span for model calibration was from 1953 to 1970, during which time the system was stressed largely by ground- and surface-water diversions for rice irrigation. The model was calibrated by comparing groundwater-level and streamflow data with model-derived groundwater levels and streamflow. In the calibrated model, the ratio of model-derived to observed streamflows for 17 subbasins averaged 1.1; the ratios among the subbasins ranged from 0.8 to 1.6. The average deviation of the differences between model-derived and observed groundwater levels at 47 nodes was 0.2; the average among the nodes ranged from -2.3 to 10.4. The average standard deviation of the differences between the model-derived and observed groundwater levels was 3.5; the average among the nodes ranged from 0.4 to 10.5. The model will provide projections of changes in the potentiometric surface resulting from (1) changes in the rate or distribution of groundwater pumpage or (2) changes in the stage of streams and reservoirs. The model will provide only approximate projections of the streamflow.

Arkansas↗

Groundwater budgets for Detrital, Hualapai, and Sacramento Valleys, Mohave County, Arizona, 2007-08

The United States Geological Survey, in cooperation with the Arizona Department of Water Resources, initiated an investigation of the hydrogeology and water resources of Detrital, Hualapai, and Sacramento Valleys in northwestern Arizona in 2005, and this report is part of that investigation. Water budgets were developed for Detrital, Hualapai, and Sacramento Valleys to provide a generalized understanding of the groundwater systems in this rural area that has shown some evidence of human-induced water-level declines. The valleys are within the Basin and Range physiographic province and consist of thick sequences of permeable alluvial sediment deposited into basins bounded by relatively less permeable igneous and metamorphic rocks. Long-term natural recharge rates (1940-2008) for the alluvial aquifers were estimated to be 1,400 acre-feet per year (acre-ft/yr) for Detrital Valley, 5,700 acre-ft/yr for Hualapai Valley, and 6,000 acre-ft/yr for Sacramento Valley. Natural discharge rates were assumed to be equal to natural recharge rates, on the basis of the assumption that all groundwater withdrawals to date have obtained water from groundwater storage. Groundwater withdrawals (2007-08) for the alluvial aquifers were less than 300 acre-ft/yr for Detrital Valley, about 9,800 acre-ft/yr for Hualapai Valley, and about 4,500 acre-ft/yr for Sacramento Valley. Incidental recharge from leaking water-supply pipes, septic systems, and wastewater-treatment plants accounted for about 35 percent of total recharge (2007-08) across the study area. Natural recharge and discharge values in this study were 24-50 percent higher than values in most previously published studies. Water budgets present a spatially and temporally "lumped" view of water resources and incorporate many sources of uncertainty in this study area where only limited data presently are available. Figures 9, 10, and 11 from this report present water budgets for Detritial, Hualapai, and Sacramento Valleys in Northwestern Arizona. These figures show average values for each water-budget component. Uncertainty is discussed but not shown on these report figures. As an aid to readers, these figures have been implemented as interactive, web-based figures here. Water-budget parameters can be varied within reasonable bounds of uncertainty and the effects those changes have on the water budget will be shown as they are varied. This can aid in understanding sensitivity-which parameters most or least affect the water budgets-and also could provide a generally improved sense of the hydrologic cycle represented in these water budgets.

Scientific Investigations Report↗

Groundwater-level change and evaluation of simulated water levels for irrigated areas in Lahontan Valley, Churchill County, west-central Nevada, 1992 to 2012

The acquisition and transfer of water rights to wetland areas of Lahontan Valley, Nevada, has caused concern over the potential effects on shallow aquifer water levels. In 1992, water levels in Lahontan Valley were measured to construct a water-table map of the shallow aquifer prior to the effects of water-right transfers mandated by the Fallon Paiute-Shoshone Tribal Settlement Act of 1990 (Public Law 101-618, 104 Stat. 3289). From 1992 to 2012, approximately 11,810 water-righted acres, or 34,356 acre-feet of water, were acquired and transferred to wetland areas of Lahontan Valley. This report documents changes in water levels measured during the period of water-right transfers and presents an evaluation of five groundwater-flow model scenarios that simulated water-level changes in Lahontan Valley in response to water-right transfers and a reduction in irrigation season length by 50 percent. Water levels measured in 98 wells from 2012 to 2013 were used to construct a water-table map. Water levels in 73 of the 98 wells were compared with water levels measured in 1992 and used to construct a water-level change map. Water-level changes in the 73 wells ranged from -16.2 to 4.1 feet over the 20-year period. Rises in water levels in Lahontan Valley may correspond to annual changes in available irrigation water, increased canal flows after the exceptionally dry and shortened irrigation season of 1992, and the increased conveyance of water rights transferred to Stillwater National Wildlife Refuge. Water-level declines generally occurred near the boundary of irrigated areas and may be associated with groundwater pumping, water-right transfers, and inactive surface-water storage reservoirs. The largest water-level declines were in the area near Carson Lake. Groundwater-level response to water-right transfers was evaluated by comparing simulated and observed water-level changes for periods representing water-right transfers and a shortened irrigation season in areas near Fallon and Stillwater, Nevada. In the Stillwater modeled area, water rights associated with nearly 50 percent of the irrigated land were transferred from 1992 to 1998, represented by the model scenario reduction in groundwater recharge by 50 percent. The scenario resulted in a simulated average decline of 0.6 foot; average observed water-level change for the modeled area was estimated to be 0.0 foot, or no change. In the Fallon modeled area, transfers of water rights associated with 180 acres of land occurred from 1994 to 2008. The transfer is most similar to the scenario for removal of 320 acres of irrigated land. The model scenario resulted in simulated water-level declines of 0.1; water levels measured from 1994 to 2012 indicate no significant trends in water levels, or approximately zero change in water levels, for the Fallon modeled area. The model scenarios included the simulation of a irrigation season shortened by 50 percent, which was determined to have occurred in the 1992 irrigation season in both modeled areas. The shortening of the irrigation season in the Fallon modeled area resulted in simulated water-level declines of 1.1 feet; observed declines were estimated to be 1.3 feet. The Stillwater model simulations resulted in a simulated decline of 1.4 feet, and observed water levels declined an estimated 2.3 feet for the area. The estimated difference between simulated and observed water levels are 0.2 and 0.9 foot for the Fallon and Stillwater modeled areas, respectively. Observed water-level changes were generally within one standard deviation of changes from model simulations, based on the selected periods of comparison. Simulated and observed water-level changes agree well, generally within 1 foot; however, the model scenarios were only approximately similar to the observed conditions, and periods of comparison were generally shorter for the observed periods and included additional cumulative effects of water-right transfers. Climate variability was not considered in the model scenarios.

Nevada↗

Water quality in the surficial aquifer near agricultural areas in the Delaware Coastal Plain, 2014

The U.S. Geological Survey, in cooperation with the Delaware Department of Agriculture, developed a network of wells to monitor groundwater quality in the surficial aquifer of the Delaware Coastal Plain. Well-drained soils, a flat landscape, and accessible water in the Delaware Coastal Plain make for a productive agricultural setting. As such, agriculture is one of the largest industries in the State of Delaware. This setting enables the transport of chemicals from agriculture and other land uses to shallow groundwater. Efforts to mitigate nutrient transport to groundwater by the implementation of agricultural best management practices (BMPs) have been ongoing for several decades. To measure the effectiveness of BMPs on a regional scale, a network of 48 wells was designed to measure shallow groundwater quality (particularly nitrate) over time near agricultural land in the Delaware Coastal Plain. Water characteristics, major ions, nutrients, and dissolved gases were measured in groundwater samples collected from network wells during fall 2014. Wells were organized into three groups based on their geochemical similarity and these groups were used to describe nitrate and chloride concentrations and factors that affect the variability among the groups. The results from this study are intended to establish waterquality conditions in 2014 to enable comparison of future conditions and evaluate the effectiveness of agricultural BMPs on a regional scale.

Delaware↗

Statewide assessment of karst aquifers in New York with an inventory of closed-depression and focused-recharge features

Karst is a landscape formed from the dissolution of soluble rock or rock containing minerals that are easily dissolved from within the rock. The landscape is characterized by sinkholes, caves, losing streams, springs, and underground drainage systems, which rapidly move water through the karst. The two forms of karst in New York State include carbonate karst, which forms in carbonate rock (limestone, marble, and dolostone), and evaporite karst, which forms in rock that contains the evaporite minerals gypsum and halite. Past and recent studies of karst across the State have shown that areas of focused recharge in karstic carbonate rock allow contaminants to enter aquifer systems with little attenuation. Focused areas of recharge need to be identified to help prevent such contamination from sources on or adjacent to the karst. The New York State Departments of Environmental Conservation and Health are collaborating with the agricultural community to make farmers and farm-planning advisors more aware of karst and how to manage daily farming activities to reduce their impact on surface water and groundwater resources, especially in karst areas. There is also a need to make regulators, planners, and the general public aware of New York’s karst resources and to properly protect and manage these resources to protect the quality of groundwater and surface water that can flow into, through, and from karst bedrock. Using publicly available geospatial data, karst bedrock and closed depressions over or near karst rock were identified across New York. Carbonate, evaporite, and marble geologic units were selected from a statewide 1:250,000-scale bedrock geology dataset. The selected geologic units were intersected with 7.5-minute quadrangle maps to define the study area. The U.S. Geological Survey has compiled an inventory of closed depressions from statewide digital contour data, scanned 7.5-minute topographic maps known as a digital raster graphics, and light detection and ranging (lidar) digital elevation models. Analysis of the data resulted in the identification of 5,023 closed depressions statewide. The inventory was conducted to eliminate duplication of results from analysis of the three data sources. A series of overlay analyses was conducted using the closed depressions and thematic data known to be key factors in determining the probability of a closed depression contributing to focused groundwater recharge; the thematic data include bedrock geology, soil type, soil infiltration rate, and land cover. Though the extent of karst development is important in understanding the interaction between surface water and groundwater in karst terrains, some of the worst cases of groundwater contamination in karst can occur where only minor karst features might be present. The presence of karst—be it a short section of a solutioned fracture or an extensive cave system—requires careful consideration, forward-looking environmental planning, and consistent water-quality protection to preserve New York State’s water resources.

New York↗

Surface infiltration and unsaturated zone characterization in support of managed aquifer recharge in Bedell Flat, Washoe County, Nevada

Aquifer storage and recovery (ASR) expands the portfolio of public water supply and improves resiliency to drought and future water demand. This study investigated the feasibility of ASR in the Bedell Flat Hydrographic Area using land-based methods including in-channel managed aquifer recharge (MAR) and rapid infiltration basins (RIB). Bedell Flat, one of two flow-through groundwater basins near Reno, Nevada, was a likely candidate for ASR because of its deep basin fill, proximity to supplemental water sources and infrastructure, and lack of development. In-channel MAR feasibility was determined from seepage losses along the Bird Springs ephemeral channel measured using Parshall flumes and heat-as-a-tracer inverse modeling. The feasibility of RIB was evaluated by characterizing vadose zone boreholes installed with roto-sonic drilling to water table. Field characterization of sediment and lithologic descriptions was accomplished at 1-foot (ft) increments. Bulk sediment samples were collected every 5 ft and cores from a split spoon were sampled at 10, 20, 30, 40, 60 and 100 ft below land surface (bls). Collected samples were analyzed for texture, moisture content, and geochemistry. Infiltration rates in Bird Springs channel increased downgradient with the hydraulic conductivity of the upper reaches ranging from 0.002 to 0.14 meter per hour (m/h) and the lower reaches from 0.5 to 1.5 m/h. Differences in discharge measurements indicate that seepage losses also increase down channel. When normalized to 1 ft of channel stage, modeled seepage loss rates ranged from 0.02 to 5.34 cubic feet per second (ft 3 /s) per mile (mi). Perched zones of soil moisture residing on top of dry fine-textured, clay-rich layers were prevalent in the Bird Springs drainage, indicating complicated flow paths for any supplement recharge water. Characterization of boreholes in Bird Springs drainage indicates low permeability clay layers 1–10 ft thick interbedded within extensive, grussy sands of high permeability. The presence of low permeability clay layers (1–10 ft thick) prompted a shift in analysis to the adjacent Sand Hills drainage where four additional boreholes indicated fewer perched water zones and at greater depths. Nitrates in the sediment pore-water (a condition that would discourage ASR) were integrated with depth to the aquifer 180 ft bls. Wells BF-MW-04 (Bird Springs) and BF-MW-07 (Sand Hills) contained 4,270 and 2,436 kilograms per hectare of nitrogen, respectively, which could potentially load excessive nitrogen to a receiving aquifer. An economically viable ASR project requires a minimum input of 2 million gallons per day (approximately 3 ft 3 /s), which either channel appears to have the sufficient capacity to infiltrate such a volume before reaching the valley bottom of Bedell Flat. However, the trajectory of the infiltrated water is complicated by the lithology and lateral transmissivity of the underlying sediments. There is also concern that this volume of infiltrated water may cause undesirable groundwater levels at the outflow in less than 5 years.

Nevada↗

Delineation of groundwater recharge areas, western Cape Cod, Massachusetts

The unconfined sand-and-gravel aquifer in western Cape Cod, Massachusetts, which is the sole source of water supply for the communities in the area, is recharged primarily from precipitation. The rate of recharge from precipitation is estimated to be about 26 inches per year (in/yr), or about 60 percent of the precipitation rate. This recharge rate yields a flow through the aquifer of about 180 million gallons per day (Mgal/d). Groundwater flows radially outward from the top of the water-table mound in the north-central part of the flow system toward the coast, as indicated by the water-table contours on the large map on this sheet. Recharge that reaches the water table near the top of the mound travels deeper through the aquifer than recharge that reaches the water table closer to the coast. All recharge to the aquifer ultimately discharges to pumping wells, streams, or coastal areas; however, some of this recharge may flow first through kettle ponds before eventually reaching these discharge points. Continued land development and population growth on western Cape Cod, and activities related to the operation of the Massachusetts Military Reservation (MMR), have created concerns regarding the supply of potable water in western Cape Cod and the quality and quantity of water discharging to ponds, streams, and coastal areas. Recent investigations estimated the future demand for drinking water in western Cape Cod, as well as the areas that contribute water to existing and proposed public-supply wells. Determining the source of freshwater that discharges to ponds, streams, and coastal areas is of critical importance in the protection of these natural resources for the communities of western Cape Cod. The purpose of this report is to illustrate concepts of ground-water recharge areas under average pumping and recharge conditions. This report presents results of an investigation conducted by the U.S. Geological Survey (USGS), in cooperation with the Air Force Center for Environmental Excellence (AFCEE), to delineate the areas that contribute recharge to public-supply wells, ponds, streams, and coastal areas on western Cape Cod for average annual pumping and recharge rates for the period of 1994–1996. The time period of 1994–1996 was selected for this analysis because it represents the average stress conditions prior to large-scale pumping, treatment, and reinjection of water from the MMR Installation Restoration Program's ground-water remediation systems. The pumping and reinjection of large amounts of water from these remediation systems would complicate greatly the delineation of ground-water recharge areas and therefore is beyond the scope of this analysis. The Chemical Spill-4 plume-containment system, however, is included in the simulation since it has been operating since 1993 and has been pumping, treating, and reinjecting only about 0.2 Mgal/d of water. Since 1996, however, AFCEE has constructed remediation systems for seven additional contaminant plumes that are not included in this analysis. Currently (1999), these systems are pumping, treating, and reinjecting about 9.7 Mgal/d. By 2002, when all of these systems, including those being designed, are expected to be operating, it is estimated that they will be pumping, treating, and reinjecting as much as 15.6 Mgal/d of water in the western Cape Cod aquifer. For additional information on the hydrology and geology of western Cape Cod, the reader is referred to the following reports: LeBlanc and others (1986), Barlow and Hess (1993), Masterson and others (1997a), Masterson and others (1997b), Masterson and others (1998), Ogden Environmental and Energy Services, Inc. (1998) and Jacobs Engineering Group, Inc. (1999).

Massachusetts↗

The ground-water system in the LaGrange Aquifer near LaGrange, southeastern Wyoming

Groundwater is being developed from the La Grange aquifer in southeastern Wyoming. It consists of saturated permeable alluvium that is hydraulically connected with most of the underlying White River Group. In the area of principal interest east of Horse Creek, Hawk Springs Reservoir and 14 adjacent wells used to supplement surface-water supply in the reservoir are in a natural discharge area. Upgradient of the reservoir there are 28 irrigation wells in about a 6-square-mile area. In this area, water levels declined between 3 and 12 feet from 1973 to 1978 causing concern about the effects of well pumpage on the hydrologic system. A digital model was developed and used to simulate the two-dimensional groundwater flow system in the unconfined La Grange aquifer. Transient simulations were made for 1973-78 using 12 time periods and for 1978-80 using 25 time periods. The calibrated digital model was used to simulate four 6-month pumping alternatives including three hypothetical alternatives for the area of principal interest east of Horse Creek. The reservoir altitude was held constant, approximating a reservoir volume 7,000 acre-feet. Pumping alternative 1 simulated historic conditions for 1973-78 including monthly recharge from precipitation which was included in the next three pumping alternatives. For pumping alternative 1, the calculated rate of discharge at the end of the 6-month simulation was 5.2 cubic feet per second from the aquifer to the reservoir. At the end of the 6-month simulations for pumping alternatives 2 and 3, the calculated rate of discharge to the reservoir was decreased to 0.4 cubic feet per second by pumpage from the 14 wells and to 3.8 cubic feet per second by pumpage from the 28 irrigation wells. For pumping alternative 4, pumpage from the total 42 wells resulted in a 1.0 cubic feet per second loss from the reservoir to the aquifer. (USGS)

Water-Resources Investigations Report↗

Chemical characteristics of water in the surficial aquifer system, Broward County, Florida

Water quality data was collected in 1981 and 1982 during the drilling of test holes at 27 sites throughout Broward County, Florida. Determinations were made for the following physical properties and chemical constituents: pH, alkalinity, specific conductance, major ions, selected nutrients and dissolved iron, aluminum, and manganese. Determinations for the trace elements-arsenic, barium, cadmium, chromium, lead, zinc, selenium, and mercury-were made at 14 wells. Water in the surficial aquifer system between the coastal ridge and the conservation areas is potable and usually is a calcium bicarbonate type for the first 140 ft or more below land surface. Between depths of 140 and 230 ft, groundwater generally grades into a mixed-ion water type. In some areas, diluted seawater occurs beneath the mixed water zone. Dissolved iron concentrations between the coastal ridge and the conservation areas are variable but generally exceed 1,000 micrograms/L. Beneath the conservation areas and the western edge of Broward County, groundwater in the first 100 ft below land surface generally is either a calcium bicarbonate type or a mixed-ion type. At depths between 100 and 200 ft, diluted residual seawater occurs, except along the far western edge of the county. Residual seawater is least diluted in the north. Dissolved iron concentrations generally are between 300 and 1 ,000 micrograms/L but increase to the east of the conservation areas. Other findings of the investigation include: (1) groundwater in some areas west of the coastal ridge probably would be suitable for most domestic, agricultural, and industrial uses if it were treated for carbonate hardness; (2) groundwater in much of Broward County is chemically altered by natural softening and magnesium enrichment (natural softening increases to the west and is very pronounced beneath the far western edge of the county); and (3) there is evidence of mineralized water from the conservation areas mixing with groundwater east of the levees. (Lantz-PTT)

Water-Resources Investigations Report↗

Louisiana ground-water map no. 1: Potentiometric surface, 1985, and water-level changes, 1983-85, of the Chicot aquifer in southwestern Louisiana

The Chicot aquifer is the principle source of groundwater in southwestern Louisiana and is the most extensively pumped (nearly 1 billion gallons per day) aquifer in the State. Withdrawals from the Chicot aquifer are used primarily for irrigation. Two maps show the generalized potentiometric surfaces of the upper sand unit ('200-ft ' sand in the Lake Charles area) and the ' 500-ft ' sand of the Chicot aquifer. General water level altitudes and flow directions may be inferred from these maps which were prepared in cooperation with the Louisiana Department of Transportation and Development, Office of Public Works. Previous studies of groundwater hydrology in southwestern Louisiana are included in selected references.

Louisiana↗

Denitrification and inference of nitrogen sources in the karstic Floridan Aquifer

Aquifer denitrification is among the most poorly constrained fluxes in global and regional nitrogen budgets. The few direct measurements of denitrification in groundwaters provide limited information about its spatial and temporal variability, particularly at the scale of whole aquifers. Uncertainty in estimates of denitrification may also lead to underestimates of its effect on isotopic signatures of inorganic N, and thereby confound the inference of N source from these data. In this study, our objectives are to quantify the magnitude and variability of denitrification in the Upper Floridan Aquifer (UFA) and evaluate its effect on N isotopic signatures at the regional scale. Using dual noble gas tracers (Ne, Ar) to generate physical predictions of N2 gas concentrations for 112 observations from 61 UFA springs, we show that excess (i.e. denitrification-derived) N 2 is highly variable in space and inversely correlated with dissolved oxygen (O 2 ). Negative relationships between O2 and δ 15 N NO3 across a larger dataset of 113 springs, well-constrained isotopic fractionation coefficients, and strong 15 N: 18 O covariation further support inferences of denitrification in this uniquely organic-matter-poor system. Despite relatively low average rates, denitrification accounted for 32 % of estimated aquifer N inputs across all sampled UFA springs. Back-calculations of source δ 15 N NO3 based on denitrification progression suggest that isotopically-enriched nitrate (NO − 3 ) in many springs of the UFA reflects groundwater denitrification rather than urban- or animal-derived inputs.

Florida↗