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Groundwater & aquifers

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USGS2015

Hydrogeologic and geochemical characterization of groundwater resources in Deep Creek Valley and adjacent areas, Juab and Tooele Counties, Utah, and Elko and White Pine Counties, Nevada

The water resources of Deep Creek Valley were assessed during 2012–13 with an emphasis on better understanding the groundwater flow system and groundwater budget. Surface-water resources are limited in Deep Creek Valley and are generally used for agriculture. Groundwater is the predominant water source for most other uses and to supplement irrigation. Most groundwater withdrawal in Deep Creek Valley occurs from the unconsolidated basin-fill deposits, in which conditions are generally unconfined near the mountain front and confined in the lower-altitude parts of the valley. Productive aquifers are also present in fractured bedrock that occurs along the valley margins and beneath the basin-fill deposits. The consolidated-rock and basin-fill aquifers are hydraulically connected in many areas with much of the recharge occurring in the consolidated-rock mountain blocks and most of the discharge occurring from the lower-altitude basin-fill deposits. Average annual recharge to the Deep Creek Valley hydrographic area was estimated to be between 19,000 and 29,000 acre-feet. Groundwater recharge occurs mostly from the infiltration of precipitation and snowmelt at high altitudes. Additional, but limited recharge occurs from the infiltration of runoff from precipitation near the mountain front, infiltration along stream channels, and possible subsurface inflow from adjacent hydrographic areas. Groundwater moves from areas of recharge to springs and streams in the mountains, and to evapotranspiration areas, springs, streams, and wells in the basins. Discharge may also occur as subsurface groundwater outflow to adjacent hydrographic areas. Average annual discharge from the Deep Creek Valley hydrographic area was estimated to be between 21,000 and 22,000 acre-feet, with the largest portion of discharge occurring as evapotranspiration. Groundwater samples were collected from 10 sites for geochemical analysis. Dissolved-solids concentrations ranged from 126 to 475 milligrams per liter, and none of the sites sampled during this study had dissolved-solids concentrations that exceeded the Environmental Protection Agency secondary standard for drinking water of 500 milligrams per liter. Tritium concentrations from 1.6 to 10.1 tritium units at 3 of the 10 sample sites indicate the presence of modern (less than 60 years old) groundwater, and apparent tritium/helium-3 ages calculated for these sites ranged from 7 to 29 years. The other seven sample sites had tritium concentrations less than or equal to 0.4 tritium units and are assumed to be pre-modern. Adjusted minimum radiocarbon ages of these seven pre-modern water samples ranged from 1,000 to 8,000 years with the ages of at least four of the samples being more than 3,000 years. Noble-gas recharge temperatures indicate that groundwater sampled along the valley axis recharged at both mountain and valley altitudes, providing evidence for both mountain-block and mountain-front recharge. Water-level altitude contours and groundwater ages indicate the potential for a long flow path from southwest to northeast between northern Spring and Deep Creek Valleys through Tippett Valley. Although information gathered during this study is insufficient to conclude whether or not groundwater travels along this interbasin flow path, dissolved sulfate and chloride data indicate that a small fraction of the lower altitude, northern Deep Creek Valley discharge may be sourced from these areas. Despite the uncertainty due to limited data collection points, a hydraulic connection between northern Spring Valley, Tippett Valley, and Deep Creek Valley appears likely, and potential regional effects resulting from future groundwater withdrawals in northern Spring Valley warrant ongoing monitoring of groundwater levels across this area.

Nevada, Utah↗

USGS2016

Baseline assessment of groundwater quality in Wayne County, Pennsylvania, 2014

The Devonian-age Marcellus Shale and the Ordovician-age Utica Shale, geologic formations which have potential for natural gas development, underlie Wayne County and neighboring counties in northeastern Pennsylvania. In 2014, the U.S. Geological Survey, in cooperation with the Wayne Conservation District, conducted a study to assess baseline shallow groundwater quality in bedrock aquifers in Wayne County prior to potential extensive shale-gas development. The 2014 study expanded on previous, more limited studies that included sampling of groundwater from 2 wells in 2011 and 32 wells in 2013 in Wayne County. Eighty-nine water wells were sampled in summer 2014 to provide data on the presence of methane and other aspects of existing groundwater quality throughout the county, including concentrations of inorganic constituents commonly present at low levels in shallow, fresh groundwater but elevated in brines associated with fluids extracted from geologic formations during shale-gas development. Depths of sampled wells ranged from 85 to 1,300 feet (ft) with a median of 291 ft. All of the groundwater samples collected in 2014 were analyzed for bacteria, major ions, nutrients, selected inorganic trace constituents (including metals and other elements), radon-222, gross alpha- and gross beta-particle activity, selected man-made organic compounds (including volatile organic compounds and glycols), dissolved gases (methane, ethane, and propane), and, if sufficient methane was present, the isotopic composition of methane. Results of the 2014 study show that groundwater quality generally met most drinking-water standards, but some well-water samples had one or more constituents or properties, including arsenic, iron, pH, bacteria, and radon-222, that exceeded primary or secondary maximum contaminant levels (MCLs). Arsenic concentrations were higher than the MCL of 10 micrograms per liter (µg/L) in 4 of 89 samples (4.5 percent) with concentrations as high as 20 µg/L; arsenic concentrations were higher than the Health Advisory level of 2 µg/L in 27 of 89 samples (30 percent). Total iron concentrations exceeded the secondary maximum contaminant level (SMCL) of 300 µg/L in 9 of 89 samples (10 percent). The pH ranged from 5.4 to 9.3 and did not meet the SMCL range of greater than 6.5 to less than 8.5 in 27 samples (30 percent); 22 samples had pH values less than 6.5, and 5 samples had pH values greater than 8.5. Total coliform bacteria were detected in 22 of 89 samples (25 percent); Escherichia coli were detected in only 2 of those 22 samples. Radon-222 activities ranged from 25 to 7,400 picocuries per liter (pCi/L), with a median of 2,120 pCi/L, and exceeded the proposed drinking-water standard of 300 pCi/L in 86 of 89 samples (97 percent); radon-222 activities were higher than the alternative proposed standard of 4,000 pCi/L in 12 of 89 samples (13.5 percent). Water from 8 of the 89 wells (9 percent) had concentrations of methane greater than the reporting level of 0.24 milligrams per liter (mg/L) with the detectable methane concentrations ranging from 0.74 to 9.6 mg/L. Of 16 replicate samples submitted to another laboratory with a lower reporting level of 0.0002 mg/L, 15 samples had detectable methane concentrations that ranged from 0.0011 to 9.7 mg/L. Of these 15 samples, low levels of ethane (0.00032 to 0.0017 mg/L) were detected in 6 of 7 samples with methane concentrations greater than 0.75 mg/L. The isotopic composition of methane in 6 of 8 samples with sufficient dissolved methane (about 1 mg/L) for isotopic analysis is consistent with a predominantly thermogenic methane source (sample carbon isotopic ratio δ13C CH4 values ranging from -56.36 to -45.97 parts per thousand (‰) and hydrogen isotopic ratio δD CH4 values ranging from -233.1 to -141.1 ‰). However, the low levels of ethane relative to methane indicate that the methane may be of microbial origin and subsequently underwent oxidation. Isotopic compositions indicated a possibly mixed thermogenic and microbial source (carbon dioxide reduction process) for the methane in 1 of the 8 samples (δ 13 C CH4 of -63.72 and δD CH4 of -192.3 ‰) and potential oxidation of microbial and (or) thermogenic methane in the remaining sample (δ 13 C CH4 of -46.56 and δD CH4 of -79.7 ‰). Groundwater samples with relatively elevated methane concentrations (near or greater than 1 mg/L) had a chemical composition that differed in some respects (pH, selected major ions, and inorganic trace constituents) from groundwater with relatively low methane concentrations (less than 0.75 mg/L). The seven well-water samples with the highest methane concentrations (from about 1 to 9.6 mg/L) also had among the highest pH values (8.1 to 9.3, respectively) and the highest concentrations of sodium, lithium, boron, fluoride, arsenic, and bromide. Relatively elevated concentrations of some other constituents, such as barium, strontium, and chloride, commonly were present in, but not limited to, those well-water samples with elevated methane. Groundwater samples with the highest methane concentrations had chloride/bromide ratios that indicate mixing with a small amount of brine (0.02 percent or less, by volume) similar in composition to that reported for gas and oil well brines in Pennsylvania. Most other samples with low methane concentrations (less than about 1 mg/L) had chloride/bromide ratios that indicate predominantly man-made sources of chloride, such as road salt, septic systems, and (or) animal waste. Although naturally occurring brines may originate from deeper parts of the aquifer system, the man-made sources are likely to affect shallow groundwater. Geochemical modeling showed that the water chemistry of samples with elevated pH, sodium, lithium, bromide, and alkalinity could result from dissolution of calcite (calcium carbonate) combined with cation exchange and mixing with a small amount of brine. Through cation exchange reactions (which are equivalent to processes in a water softener) calcium ions released by calcite dissolution are exchanged for sodium ions on clay minerals. The spatial distribution of groundwater compositions generally shows that (1) relatively dilute, slightly acidic, oxygenated, calcium-carbonate type waters tend to occur in the uplands along the western border of Wayne County; (2) waters of near neutral pH with the highest amounts of hardness (calcium and magnesium) generally occur in areas of intermediate altitudes; and (3) waters with pH values greater than 8, low oxygen concentrations, and the highest arsenic, sodium, lithium, bromide, and methane concentrations can occur in deep wells in uplands but most frequently occur in stream valleys, especially at low elevations (less than about 1,200 ft above North American Vertical Datum of 1988) where groundwater may be discharging regionally, such as to the Delaware River. Thus, the baseline assessment of groundwater quality in Wayne County prior to gas-well development shows that shallow (less than about 1,000 ft deep) groundwater is generally of good quality, but methane and some constituents present in high concentrations in brine (and produced waters from gas and oil wells) may be present at low to moderate concentrations in some parts of Wayne County.

Pennsylvania↗

USGS2017

Sequence stratigraphy, seismic stratigraphy, and seismic structures of the lower intermediate confining unit and most of the Floridan aquifer system, Broward County, Florida

Deep well injection and disposal of treated wastewater into the highly transmissive saline Boulder Zone in the lower part of the Floridan aquifer system began in 1971. The zone of injection is a highly transmissive hydrogeologic unit, the Boulder Zone, in the lower part of the Floridan aquifer system. Since the 1990s, however, treated wastewater injection into the Boulder Zone in southeastern Florida has been detected at three treated wastewater injection utilities in the brackish upper part of the Floridan aquifer system designated for potential use as drinking water. At a time when usage of the Boulder Zone for treated wastewater disposal is increasing and the utilization of the upper part of the Floridan aquifer system for drinking water is intensifying, there is an urgency to understand the nature of cross-formational fluid flow and identify possible fluid pathways from the lower to upper zones of the Floridan aquifer system. To better understand the hydrogeologic controls on groundwater movement through the Floridan aquifer system in southeastern Florida, the U.S. Geological Survey and the Broward County Environmental Planning and Community Resilience Division conducted a 3.5-year cooperative study from July 2012 to December 2015. The study characterizes the sequence stratigraphy, seismic stratigraphy, and seismic structures of the lower part of the intermediate confining unit aquifer and most of the Floridan aquifer system. Data obtained to meet the study objective include 80 miles of high-resolution, two-dimensional (2D), seismic-reflection profiles acquired from canals in eastern Broward County. These profiles have been used to characterize the sequence stratigraphy, seismic stratigraphy, and seismic structures in a 425-square-mile study area. Horizon mapping of the seismic-reflection profiles and additional data collection from well logs and cores or cuttings from 44 wells were focused on construction of three-dimensional (3D) visualizations of eight sequence stratigraphic cycles that compose the Eocene to Miocene Oldsmar, Avon Park, and Arcadia Formations. The mapping of these seismic-reflection and well data has produced a refined Cenozoic sequence stratigraphic, seismic stratigraphic, and hydrogeologic framework of southeastern Florida. The upward transition from the Oldsmar Formation to the Avon Park Formation and the Arcadia Formation embodies the evolution from (1) a tropical to subtropical, shallow-marine, carbonate platform, represented by the Oldsmar and Avon Park Formations, to (2) a broad, temperate, mixed carbonate-siliciclastic shallow marine shelf, represented by the lower part of the Arcadia Formation, and to (3) a temperate, distally steepened carbonate ramp represented by the upper part of the Arcadia Formation. In the study area, the depositional sequences and seismic sequences have a direct correlation with hydrogeologic units. The approximate upper boundary of four principal permeable units of the Floridan aquifer system (Upper Floridan aquifer, Avon Park permeable zone, uppermost major permeable zone of the Lower Floridan aquifer, and Boulder Zone) have sequence stratigraphic and seismic-reflection signatures that were identified on cross sections, mapped, or both, and therefore the sequence stratigraphy and seismic stratigraphy were used to guide the development of a refined spatial representation of these hydrogeologic units. In all cases, the permeability of the four permeable units is related to stratiform megaporosity generated by ancient dissolution of carbonate rock associated with subaerial exposure and unconformities at the upper surfaces of carbonate depositional cycles of several hierarchical scales ranging from high-frequency cycles to depositional sequences. Additionally, interparticle porosity also contributes substantially to the stratiform permeability in much of the Upper Floridan aquifer. Information from seismic stratigraphy allowed 3D geomodeling of hydrogeologic units—an approach never before applied to this area. Notably, the 3D geomodeling provided 3D visualizations and geocellular models of the depositional sequences, hydrostratigraphy, and structural features. The geocellular data could be used to update the hydrogeologic structure inherent to groundwater flow simulations that are designed to address the sustainability of the water resources of the Floridan aquifer system. Two kinds of pathways that could enable upward cross-formational flow of injected treated wastewater from the Boulder Zone have been identified in the 80 miles of high-resolution seismic data collected for this study: a near-vertical reverse fault and karst collapse structures. The single reverse fault, inferred to be of tectonic origin, is in extreme northeastern Broward County and has an offset of about 19 feet at the level of the Arcadia Formation. Most of the 17 karst collapse structures identified manifest as columniform, vertically stacked sagging seismic reflections that span early Eocene to Miocene age rocks equivalent to much of the Floridan aquifer system and the lower part of the overlying intermediate confining unit. In some cases, the seismic-sag structures extend upward into strata of Pliocene age. The seismic-sag structures are interpreted to have a semicircular shape in plan view on the basis of comparison to (1) other seismic-sag structures in southeastern Florida mapped with two 2D seismic cross lines or 3D data, (2) comparison to these structures located in other carbonate provinces, and (3) plausible extensional ring faults detected with multi-attribute analysis. The seismic-sag structures in the study area have heights as great as 2,500 vertical feet, though importantly, one spans about 7,800 feet. Both multi-attribute analysis and visual detection of offset of seismic reflections within the seismic-sag structures indicate faults and fractures are associated with many of the structures. Multi-attribute analysis highlighting chimney fluid pathways also indicates that the seismic-sag structures have a high probability for potential vertical cross-formational fluid flow along the faulted and fractured structures. A collapse of the seismic-sag structures within a deep burial setting evokes an origin related to hypogenic karst processes by ascending flow of subsurface fluids. In addition, paleo-epigenic karst related to major regional subaerial unconformities within the Florida Platform generated collapse structures (paleo-sinkholes) that are much smaller in scale than the cross-formational seismic-sag structures.

Florida↗

USGS2022

Drainage infrastructure and groundwater system response to changes in sea level and precipitation, Broward County, Florida

Executive Summary Southeast Florida is highly susceptible to flooding because of its low topography and porous, highly permeable Biscayne aquifer. Rising seas will likely result in increased groundwater levels in parts of Broward County, Florida, that will reduce available soil storage and therefore increase the likelihood of inundation and flooding from precipitation events. Moreover, rising seas may also reduce the capacity of the coastal water-control structures to discharge inland waters to tidal areas, thereby increasing surface-water stage and nearby groundwater levels. Increased rainfall intensity will likely further increase peak surface-water stages and groundwater levels, more quickly fill the reduced soil storage capacity, and increase the likelihood for inundation. Managers and planners in Broward County, Florida, face the challenge of understanding and preparing for the consequent risk to residents, businesses, and critical infrastructure posed by increased sea level and precipitation. The U.S. Geological Survey, in cooperation with the Broward County Environmental Planning and Resilience Division, has developed a groundwater/surface-water model to evaluate the response of the drainage infrastructure and groundwater system in Broward County to projected increases in sea level and potential changes in precipitation. The model was constructed using Modular Finite-Difference Groundwater Flow Model Newton formulation, with the surface-water system represented using the Surface-Water Routing process and the Urban Runoff process. The aquifer layering and flow parameters rely heavily on existing hydrologic flow models developed by the U.S. Geological Survey for the same model area. The surface-water drainage system within this newly developed model actively simulates the extensive canal network using level-pool routing and active structures representing gates, weirs, culverts, and pumps. Steady-state and transient simulation results represented historical conditions (2013–17). The simulated historical groundwater levels and upstream stage and flow at the primary structures generally captured the behavior of the actual hydrologic system. Simulation results incorporating increased sea level and precipitation were used to evaluate the effects of these projected changes on the surface-water drainage system and wet season groundwater levels. Four future sea-level scenarios were simulated by modifying the historical inputs for both steady-state and the transient versions of the model to represent mean sea levels of 0.5, 2.0, 2.5, and 3.0 feet (ft) above the North American Vertical Datum of 1988. These mean sea levels correspond to sea-level rises of 1.05, 2.55, 3.05, and 3.55 ft, respectively, above the 2013–17 mean measured tidal stage. Additional simulations represented a 15-percent increase in rainfall rates using the transient model and a 15-percent increase in rainfall recharge using the steady-state model. The simulated results indicated that (1) the effects of increased sea level were more evident in the easternmost, coastal areas of the county where increases in groundwater levels are nearly equivalent to sea-level rise; (2) groundwater levels west of the coastal water-control structures only changed slightly in response to increased sea level for most scenarios; (3) when the control elevations of the gravity-controlled coastal water-control structures were surpassed by sea-level rise, the resulting increases in upstream stage in the connected primary canal resulted in increased groundwater levels that can propagate into the western parts of the county; (4) the historical west-to-east downward gradient in groundwater levels decreased with increased sea level, and groundwater levels were lower in central parts of the county than areas west and east for the higher sea-level scenarios; (5) simulated upstream stage for most of the primary coastal water-control structures increased with increased sea level, with the largest increases occurring at gravity-controlled structures having the lowest control elevations; (6) total flow through the primary structures increased as sea level increased because of additional groundwater leakage into the surface-water network; (7) the 3.0-ft mean sea-level rise scenario resulted in an increase of 37.10 square miles in area having a wet season average depth to groundwater of less than 2 ft, and an increase of 22.84 square miles in newly inundated areas compared to historical simulation results; and (8) a 15-percent increase in rainfall rate for the entire simulation period produced little increase in upstream stages at the primary structures and an increase in total flow through the primary structures proportional to the increase in rainfall.

Florida↗

USGS1987

Geohydrology and susceptibility of major aquifers to surface contamination in Alabama; area 1

This report delineates and describes the geohydrology and susceptibility of the major aquifers to contamination in Area 1 - Colbert, Franklin, Lauderdale, Lawrence, Limeston, Madison, and Morgan Counties. Most of the area is underlain by a Mississippian carbonate sequence that includes two major aquifers, the Tuscumbia-Fort Payne aquifer and the Bangor aquifer. A third major aquifer, the Tuscaloosa aquifer of Cretaceous age, occurs in the southwest part of the area. The Mississippi carbonate aquifers are the Tuscumbia-Fort Payne aquifer which includes most Tuscumbia Limestone and the Fort Payne Chert, and a small area of the Monteagle Limestone, and the Bangor aquifer which includes the Bangor Limestone and Hartselle Sandstone. Both of these aquifers possess highly-variable secondary porosity and permeability related to fractures that have been enlarged, sometimes to cavernous proportions, due to solution processes. The Tuscaloosa aquifer consists of the Tuscaloosa Group, an unconsolidated clastic deposit that has relatively uniform primary porosity and permeability. Significant quantities of groundwater are available from each of the aquifers. Water levels at nearly 2 ,000 wells indicate that, for each aquifer, general groundwater movement is from topographically high to low areas. Each of the aquifers is recharged throughout its outcrop in the study area and is susceptible to contamination within the outcrop. Generalized topographic settings such as closed-contour depressions are identified as areas that are highly susceptible to contamination. Specific features such as sinkholes also are identified as extremely susceptible to contamination.

Alabama↗

USGS1986

Hydrology of carbonate aquifers in southwestern Linn County and adjacent parts of Benton, Iowa, and Johnson Counties, Iowa

Groundwater is the major source of water in Linn County and the surrounding area. Approximately 90 percent of the groundwater production is from Silurian, Devonian, and Quaternary aquifers. The Silurian and Devonian aquifers consist of limestone and dolomite with minor shale beds, which have a regional dip to the southwest of approximately 20 feet per mile. The Silurian aquifer in east-central Iowa is confined from below by Upper Ordovician, Maquoketa Formation shales, and from above by the Kenwood Member of the Wapsipinicon Formation and the Otis and Bertram formations. The Quaternary aquifer consists of unconsolidated sand and gravel beds in the glacial drift, and in the alluvium which is associated with modern streams. The alluvium consists of lenticular beds of poorly-to well-sorted silt, sand, and gravel. The sand and gravel beds are interlayered with relatively-impermeable beds of till, silt, and clay. Water moves through the Silurian aquifer in part due to a complex distribution of porous and dense carbonate facies. Horizons containing skeletal molds in the Silurian dolomite have porosities as much as 39 percent, and are laterally equivalent to dolomites with porosities as little as less than one percent. Because of subsequent fracturing and solutional enlargement of these porous horizons, hydrologic correlation of the primary water-yielding zones is not always possible. One horizon, however, does occur approximately 70 to 105 feet above the base of the Silurian, and is the most consistently productive water-yielding unit in the area. This horizon is Informally referred to as the Farmers Creek aquifer. The potentiometric surface of the Silurian aquifer has a gradient towards the Cedar River, indicating discharge from the aquifer through the alluvium into the river. By comparison, the potentiometric surface of the overlying Devonian aquifer is equal to that of the Silurian and may range to more than 40 feet higher. Yields to individual wells completed in the Silurian and Devonian carbonate aquifers vary from less than 10 to about 500 gallons per minute. Individual wells completed in the Quaternary aquifer yield as much as 2,000 gallons per minute. Water analyses from the Devonian and Silurian aquifers indicate that they are of similar chemical quality at most locations in the study area. However, they may commonly contain concentrations of sulfate that exceed 1,000 mil grams per liter. Dissolved-solids concentrations as much as 2,350 milligrams per liter occur in the Silurian aquifer in the western and southwestern part of the study area. Water from the Quaternary aquifer generally is suitable for most uses and dissolved-solids concentrations generally are less than 750 milligrams per liter.

Iowa↗

USGS2019

A parametric numerical analysis of factors controlling ground ruptures caused by groundwater pumping

A modeling analysis is used to investigate the relative susceptibility of various hydrogeologic configurations to aseismic rupture generation due to deformation of aquifer systems accompanying groundwater pumping. An advanced numerical model (GEPS3D) is used to simulate rupture generation and propagation for three typical processes: (i) reactivation of a preexisting fault, (ii) differential compaction due to variations in thickness of aquifer/aquitard layers constituting the aquifer system, and (iii) tensile fracturing above a bedrock ridge that forms the base of the aquifer system. A sensitivity analysis is developed to address the relative importance of various factors, including aquifer depletion, aquifer thickness, the possible uneven distribution and depth below land surface of the aquifer/aquitard layers susceptible to aquifer-system compaction, and the height of bedrock ridges beneath the aquifer system which contributes to thinning of the aquifer system. The rupture evolution is classified in two occurrences. In one, the rupture develops at the top of the aquifer or at land surface and does not propagate. In the other, the developed rupture propagates from the aquifer top toward the land surface and/or from the land surface downward. The aquifer depth is the most important factor controlling rupture evolution. Specifically, the probability of a significant rupture propagation is higher when the aquifer top is near land surface. The numerical results are processed by a statistical regression analysis to provide a general methodology for a preliminary evaluation of possible ruptures development in exploited aquifer systems susceptible to aquifer-system compaction and accompanying land subsidence. A comparison with a few representative case studies in Arizona, USA, China, and Mexico supports the study outcomes.

Arizona↗

USGS2014

Factors affecting public-supply well vulnerability in two karst aquifers

Karst aquifers occur in a range of climatic and geologic settings. Nonetheless, they are commonly characterized by their vulnerability to water-quality impairment. Two karst aquifers, the Edwards aquifer in south-central Texas and the Upper Floridan aquifer in western Florida, were investigated to assess factors that control the movement of contaminants to public-supply wells (PSWs). The geochemistry of samples from a selected PSW or wellfield in each aquifer was compared with that from nearby monitoring wells and regional PSWs. Geochemistry results were integrated with age tracers, flow modeling, and depth-dependent data to refine aquifer conceptual models and to identify factors that affect contaminant movement to PSWs. The oxic Edwards aquifer is vertically well mixed at the selected PSW/wellfield, although regionally the aquifer is geochemically variable downdip. The mostly anoxic Upper Floridan aquifer is affected by denitrification and also is geochemically variable with depth. In spite of considerable differences in geology and hydrogeology, the two aquifers are similarly vulnerable to anthropogenic contamination. Vulnerability in studied PSWs in both aquifers is strongly influenced by rapid karst flowpaths and the dominance of young (<10 years) groundwater. Vulnerability was demonstrated by the frequent detection of similar constituents of concern in both aquifers (nitrate, atrazine, deethylatrazine, tetrachloroethene, and chloroform). Specific consideration of water-quality protection efforts, well construction and placement, and aquifer response times to land-use changes and contaminant loading are discussed, with implications for karst groundwater management.

Ground Water↗

USGS2024

Quality of groundwater used for domestic supply in the eastern Sacramento Valley and adjacent foothills, California

Summary More than 2 million Californians rely on groundwater from privately owned domestic wells for drinking-water supply. This report summarizes a water-quality survey of domestic and small-system drinking-water supply wells in the eastern Sacramento Valley and adjacent foothills where more than 25,000 residents are estimated to use privately owned domestic wells. Study results show that inorganic and organic constituents in groundwater were present above regulatory (maximum contaminant level, MCL) benchmarks for public drinking-water quality in 8 and 3 percent, respectively, of the aquifer area used for domestic drinking-water supply (herein, “domestic groundwater resources”; fig. 1). The only inorganic constituent detected above regulatory benchmarks was arsenic. The only organic constituent exceeding regulatory benchmarks was the fumigant 1,2,3-trichloropropane (1,2,3-TCP). Three additional organic constituents—the disinfection by-product chloroform, the gasoline oxygenate methyl tert -butyl ether (MTBE), and the solvent tetrachloroethene (PCE)—were detected at low concentrations below one-tenth of regulatory benchmarks in 34, 10, and 10 percent of domestic groundwater resources, respectively. Total dissolved solids (TDS), iron, and manganese exceeded non-regulatory aesthetic guidelines for drinking water in 5, 10, and 26 percent of domestic groundwater resources, respectively. Per- and polyfluoroalkyl substances (PFASs) were detected in 29 percent of domestic groundwater resources,with 5 percent exceeding the recently enacted (April 2024) U.S. Environmental Protection Agency MCLs. Total coliform and enterococci bacteria were detected in 13 and 8 percent of domestic groundwater resources, respectively. Redox sensitive constituents in this study included arsenic, manganese, nitrate, and iron. In the lower elevation portions of the eastern Sacramento Valley study area, reducing conditions in groundwater aquifers promote elevated arsenic, iron, and manganese, and conversely lower concentrations of nitrate. The presence of the volatile organic compound (VOC) 1,2,3-TCP was related to its past history in select agricultural land uses (on orchards or vineyards) in the Sacramento Valley; however, unlike in the San Joaquin Valley where orchards and vineyards are more common, its detection frequency was low (only detected in one well in this study). Chloroform was frequently detected in this study at low levels. Chloroform is a disinfection byproduct commonly found in domestic wells treated by shock chlorination. The solvent PCE is among the most frequently detected VOCs in groundwater, which is primarily related to its long history of use and its persistence in groundwater in oxic conditions. The gasoline oxygenate MTBE was a contaminant introduced to groundwater through atmospheric exchange when it was used as a fuel additive to decrease smog inducing emissions from vehicles. Its occurrence in groundwater at low levels is expected and makes it a potentially useful tracer of relatively recent recharge water being withdrawn from wells. The PFASs are anthropogenic chemicals with hundreds of uses, and they have been incorporated into many different products, processes, and applications worldwide. Like MTBE, the occurrence of PFASs in groundwater may be in part due to atmospheric exchange, but there are several other pathways that contribute PFASs to the environment.

California↗

USGS2023

Potentiometric surface map of the Southern High Plains aquifer in the Cannon Air Force Base area, Curry County, New Mexico, 2020

Declining water levels and the potential impact on water resources on and around Cannon Air Force Base (AFB), New Mexico, has necessitated an up-to-date review of the potentiometric surface to evaluate the availability of water resources for future use. Analysis of groundwater-flow directions and hydraulic gradients can provide an understanding of depletion by heavy groundwater pumping and recharge through playa lakes, as well as the relationship between the groundwater levels and underlying geology. The objectives of this study, conducted by the U.S. Geological Survey in cooperation with the U.S. Air Force Civil Engineer Center, are to assist Cannon AFB in understanding and interpreting current and local hydrologic conditions and to evaluate groundwater-level change from 2015 to 2020 using new and historical data. A groundwater potentiometric surface contour map was constructed to better understand the Southern High Plains aquifer around Cannon AFB and to show the altitude of the water-table surface and groundwater-flow patterns. Four hydrographs were created from periodic measurements of groundwater levels in wells on and around Cannon AFB to provide information about historical groundwater-level changes and visualize trends from the water-level records. The long-term trend present in all four hydrographs is a steady decline in groundwater levels, with some areas declining faster than others. The groundwater-level change map presented in this study provides a visual representation of the change in groundwater level from the winter 2015 to winter 2020 measuring events. Results show that among corresponding wells measured in 2015 and 2020, 50.7 percent indicated a decline in water levels, 29.9 percent indicated neutral water levels, and 19.4 percent indicated a rise in water levels. The region to the north of the groundwater trough on Cannon AFB contained most of the groundwater-level rises, whereas the regions located near the trough and just west of Clovis, N. Mex., contained most of the declines. These results suggest that continued monitoring of declining groundwater levels in the area would provide valuable decision-support information for assessing the sustainability of this water resource.

New Mexico↗

USGS2012

Biodegradation of chloroethene compounds in groundwater at Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington, 1999-2010

The U.S. Geological Survey evaluated the biodegradation of chloroethene compounds in groundwater beneath the former landfill at Operable Unit 1 (OU 1) of the U.S. Naval Undersea Warfare Center (NUWC), Division Keyport. The predominant contaminants in groundwater are the chloroethene compounds trichloroethene, cis -1,2-dichloroethene, and vinyl chloride. The remedy selected for groundwater contamination at OU 1 includes phytoremediation and natural attenuation. In 1999, the U.S. Navy planted two hybrid poplar plantations, referred to as the northern and southern plantations, over the most contaminated parts of the landfill. The U.S. Navy monitors tree health, groundwater levels, and contaminant concentrations to assess the effectiveness of phytoremediation. The U.S. Geological Survey began a cooperative effort with the U.S. Navy in 1995 to monitor the effectiveness of natural attenuation processes for removing and controlling the migration of chloroethenes and chloroethanes. Field and laboratory studies from 1996 through 2000 demonstrated that biodegradation of chloroethenes and chloroethanes in shallow groundwater at OU 1 was substantial. The U.S. Geological Survey monitored geochemical and contaminant concentrations in groundwater annually from 2001 through 2010. This report presents groundwater geochemical and contaminant data collected by the U.S. Geological Survey during June 2010 and evaluates evidence for continued biodegradation of chloroethenes in groundwater. Geochemical and contaminant concentration data through 2010 indicate that biodegradation of chloroethenes in groundwater continued beneath the landfill at OU 1. Contaminant concentrations in groundwater decreased beneath most of the 9-acre landfill between 1999 and 2010. The evidence indicating that biodegradation was a primary cause for the decreased concentrations included decreasing ratios of more highly chlorinated compounds to less chlorinated compounds over time, and widespread detections of non-chlorinated biodegradation end-products ethane and ethene. No widespread changes in groundwater reduction-oxidation (redox) conditions were observed that could result in either more or less efficient biodegradation. Even with continued biodegradation, dissolved-phase contaminant concentrations in the tens of milligrams per liter have persisted beneath part of the 0.7-acre southern plantation. The magnitude and persistence of those concentrations indicate that non-aqueous phase liquid chloroethenes likely are present beneath the southern plantation and are not substantially affected by biodegradation. During 2010, chloroethenes continued to be measured in shallow groundwater samples from the southern part of the adjacent marsh, although at the lowest concentrations ever measured. Flux calculations based on 2010 data indicate that 95 percent of dissolved-phase chloroethenes in the upper aquifer beneath the southern landfill were degraded before discharging to surface water. Overall, biodegradation of chloroethenes in groundwater throughout OU 1 continued through 2010, and it prevented most of the mass of dissolved-phase chloroethenes in the upper aquifer beneath the landfill from discharging to surface water.

Washington↗

USGS2013

Potential effects of deepening the St. Johns River navigation channel on saltwater intrusion in the surficial aquifer system, Jacksonville, Florida

The U.S. Army Corps of Engineers (USACE) has proposed dredging a 13-mile reach of the St. Johns River navigation channel in Jacksonville, Florida, deepening it to depths between 50 and 54 feet below North American Vertical Datum of 1988. The dredging operation will remove about 10 feet of sediments from the surficial aquifer system, including limestone in some locations. The limestone unit, which is in the lowermost part of the surficial aquifer system, supplies water to domestic wells in the Jacksonville area. Because of density-driven hydrodynamics of the St. Johns River, saline water from the Atlantic Ocean travels upstream as a saltwater “wedge” along the bottom of the channel, where the limestone is most likely to be exposed by the proposed dredging. A study was conducted to determine the potential effects of navigation channel deepening in the St. Johns River on salinity in the adjacent surficial aquifer system. Simulations were performed with each of four cross-sectional, variable-density groundwater-flow models, developed using SEAWAT, to simulate hypothetical changes in salinity in the surficial aquifer system as a result of dredging. The cross-sectional models were designed to incorporate a range of hydrogeologic conceptualizations to estimate the effect of uncertainty in hydrogeologic properties. The cross-sectional models developed in this study do not necessarily simulate actual projected conditions; instead, the models were used to examine the potential effects of deepening the navigation channel on saltwater intrusion in the surficial aquifer system under a range of plausible hypothetical conditions. Simulated results for modeled conditions indicate that dredging will have little to no effect on salinity variations in areas upstream of currently proposed dredging activities. Results also indicate little to no effect in any part of the surficial aquifer system along the cross section near River Mile 11 or in the water-table unit along the cross section near River Mile 8. Salinity increases of up to 4.0 parts per thousand (ppt) were indicated by the model incorporating hydrogeologic conceptualizations with both a semiconfining bed over the limestone unit and a preferential flow layer within the limestone along the cross section near River Mile 8. Simulated increases in salinity greater than 0.2 ppt in this area were generally limited to portions of the limestone unit within about 75 feet of the channel on the north side of the river. The potential for saltwater to move from the river channel to the surficial aquifer system is limited, but may be present in areas where the head gradient from the aquifer to the river is small or negative and the salinity of the river is sufficient to induce density-driven advective flow into the aquifer. In some areas, simulated increases in salinity were exacerbated by the presence of laterally extensive semiconfining beds in combination with a high-conductivity preferential flow zone in the limestone unit of the surficial aquifer system and an upgradient source of saline water, such as beneath the salt marshes near Fanning Island. The volume of groundwater pumped in these areas is estimated to be low; therefore, saltwater intrusion will not substantially affect regional water supply, although users of the surficial aquifer system east of Dames Point along the northern shore of the river could be affected. Proposed dredging operations pose no risk to salinization of the Floridan aquifer system; in the study area, the intermediate confining unit ranges in thickness from more than 300 to about 500 feet and provides sufficient hydraulic separation between the surficial and Floridan aquifer systems.

Florida↗

USGS2018

Hydrogeologic framework and groundwater conditions of the Ararat Basin in Armenia

Armenia is a landlocked country located in the mountainous Caucasus region between Asia and Europe. It shares borders with the countries of Georgia on the north, Azerbaijan on the east, Iran on the south, and Turkey and Azerbaijan on the west. The Ararat Basin is a transboundary basin in Armenia and Turkey. The Ararat Basin (or Ararat Valley) is an intermountain depression that contains the Aras River and its tributaries, which also form the border between Armenia and Turkey and divide the basin into northern and southern regions. The Ararat Basin also contains Armenia’s largest agricultural and fish farming zone that is supplied by high-quality water from wells completed in the artesian aquifers that underlie the basin. Groundwater constitutes about 40 percent of all water use, and groundwater provides 96 percent of the water used for drinking purposes in Armenia. Since 2000, groundwater withdrawals and consumption in the Ararat Basin of Armenia have increased because of the growth of aquaculture and other uses. Increased groundwater withdrawals caused decreased springflow, reduced well discharges, falling water levels, and a reduction of the number of flowing artesian wells in the southern part of Ararat Basin in Armenia. In 2016, the U.S. Geological Survey and the U.S. Agency for International Development (USAID) began a cooperative study in Armenia to share science and field techniques to increase the country’s capabilities for groundwater study and modeling. The purpose of this report is to describe the hydrogeologic framework and groundwater conditions of the Ararat Basin in Armenia based on data collected in 2016 and previous hydrogeologic studies. The study area includes the Ararat Basin in Armenia. This report was completed through a partnership with USAID/Armenia in the implementation of its Science, Technology, Innovation, and Partnerships effort through the Advanced Science and Partnerships for Integrated Resource Development program and associated partners, including the Government of Armenia, Armenia’s Hydrogeological Monitoring Center, and the USAID Global Development Lab and its GeoCenter. The hydrogeologic framework of the Ararat Basin includes several basin-fill stratigraphic units consisting of interbedded dense clays, gravels, sands, volcanic basalts, and andesite deposits. Previously published cross sections and well lithologic logs were used to map nine general hydrogeologic units. Hydrogeologic units were mapped based on lithology and water-bearing potential. Water-level data measured in the water-bearing hydrogeologic units 2, 4, 6, and 8 in 2016 were used to create potentiometric surface maps. In hydrogeologic unit 2, the estimated direction of groundwater flow is from the west to north in the western part of the basin (away from the Aras River) and from north to south (toward the Aras River) in the eastern part of the basin. In hydrogeologic unit 4, the direction of groundwater flow is generally from west to east and north to south (toward the Aras River) except in the western part of the basin where groundwater flow is toward the north or northwest. Hydrogeologic unit 6 has the same general pattern of groundwater flow as unit 4. Hydrogeologic unit 8 is the deepest of the water-bearing units and is confined in the basin. Groundwater flow generally is from the south to north (away from the Aras River) in the western part of the basin and from west to east and north to south (toward the Aras River) elsewhere in the basin. In addition to water levels, personnel from Armenia’s Hydrogeological Monitoring Center also measured specific conductance at 540 wells and temperature at 2,470 wells in the Ararat Basin using U.S. Geological Survey protocols in 2016. The minimum specific conductance was 377 microsiemens per centimeter (μS/cm), the maximum value was 4,000 μS/cm, and the mean was 998 μS/cm. The maximum water temperature was 24.2 degrees Celsius. An analysis between water temperature and well depth indicated no relation; however, spatially, most wells with cooler water temperatures were within the 2016 pressure boundary or in the western part of the basin. Wells with generally warmer water temperatures were in the eastern part of the basin. Samples were collected from four groundwater sites and one surface-water site by the U.S. Geological Survey in 2016. The stable-isotope values were similar for all five sites, indicating similar recharge sources for the sampled wells. The Hrazdan River sample was consistent with the groundwater samples, indicating the river could serve as a source of recharge to the Ararat artesian aquifer.

Ararat Basin↗

USGS2020

Hydrology of Haskell Lake and investigation of a groundwater contamination plume, Lac du Flambeau Reservation, Wisconsin

Haskell Lake is a shallow, 89-acre drainage lake in the headwaters of the Squirrel River, on the Lac du Flambeau Reservation in northern Wisconsin. The lake has long been valued by the Lac du Flambeau Band of Lake Superior Chippewa Indians (LDF Tribe) for abundant wild rice and game fish. In recent decades, however, wild rice has mostly disappeared from the lake and the fishery has declined. A petroleum contamination plume discovered in the 1990s in the shallow aquifer upgradient from the northern end of the lake poses a threat to the ecological health of the lake and the aquifer, which is the sole drinking water source for nearby residents and businesses. Understanding of the lake’s hydrology is important to the LDF Tribe as they seek to restore wild rice and maintain the ecological health of the Haskell Lake/Tower Creek watershed. An improved understanding of lithology in the area of the contamination plume, documentation of a contamination pathway from groundwater in the plume source area to Haskell Lake, and an understanding of the plume extent beneath the lake are needed to advance remediation efforts. Evaluation of the fraction of groundwater discharge that is contaminated relative to the overall lake water budget is desired as a first step towards determining the extent of ecological effects from the plume. A cooperative study between the U.S. Geological Survey and the LDF Tribe was initiated to quantify the lake water budget and the sources of water to the lake, to provide a rough estimate of the maximum quantity of groundwater discharge to the lake that may be contaminated, and to improve the conceptual understanding of the plume extent and subsurface materials in the area of contamination. The results of this study can help inform natural resource management of the Haskell Lake/Tower Creek watershed, including planned wild rice restoration and cleanup of the contaminant plume. During 2016–17, field data on lake and groundwater levels, gradients, fluxes, and subsurface lithology were collected using a variety of techniques that ranged from basic measurement of water levels and streamflows to distributed temperature sensing, vertical temperature profiling, and several shallow geophysical methods. The data were used to inform a MODFLOW–NWT model that simulated the contributing groundwatershed, including the water budget for Haskell Lake and Tower Creek using the Lake, Streamflow-Routing, and Unsaturated Zone-Flow Packages. Particle tracking with the MODFLOW solution (using MODPATH 6) was used to improve understanding of the downgradient extent of the contamination plume, estimate groundwater flux through the plume area, and delineate the groundwater contributing area (groundwatershed) for the lake/creek system. Linear uncertainty estimates for model results were computed during model parameter estimation using the software package PEST++. Results indicate groundwater discharge along the perimeter of Haskell Lake, with groundwater accounting for about 22 (± 11.5) percent of the lake water budget. Field data and particle tracking results indicate discharge of the entire contamination plume to Haskell Lake. Although the exact locations where contaminated groundwater enters the lake are unknown, the downgradient extent of the plume beneath Haskell Lake is likely limited to within about 700 feet from the shore. Groundwater flux through the plume accounts for at most about 1.4 percent of total groundwater discharge to Haskell Lake, or about 0.3 percent of the lake water budget. Most groundwater discharging to Haskell Lake and Tower Creek originates as terrestrial recharge. A lesser amount originates in or passes through neighboring lakes, including Buckskin, Crawling Stone, Broken Bow, Tippecanoe, and Jerms Lakes, as well as several unnamed kettles. The average age of simulated groundwater discharge to the lake is about 20 years.

Wisconsin↗

USGS2020

Use of real-time sensors to temporally characterize water quality in groundwater and surface water in Mason County, Illinois, 2017–19

The persistence of high nitrate concentrations in shallow groundwater has been well documented in the shallow glacial aquifer of Mason County, Illinois. Nitrates in groundwater can be a concern when concentrations exceed 10 milligrams per liter in drinking water. Additionally, nitrate in groundwater can contribute to surface water nitrogen loads that can cause increased algal growth. Algal growth increases oxygen consumption causing anoxic conditions as observed in the Gulf of Mexico Hypoxic Zone. From March 8, 2017, to March 31, 2019, groundwater level, continuous nitrate, dissolved oxygen, specific conductance, water temperature, and pH data were collected in a monitoring well to temporally assess changes in water quality using high frequency data. During this same period, instantaneous field measurements of water quality and groundwater levels were made in surface water and groundwater in and near Quiver Creek in the presumed groundwater flow path about 0.6 mile from the continuous monitoring well. Groundwater nitrate concentrations continuously measured in the aquifer during this time ranged from 14.7 to 23.2 milligrams per liter, whereas instantaneously measured nitrate concentrations in Quiver Creek ranged from 0.9 to 6.4 milligrams per liter. Nitrate concentrations measured by piezometer varied laterally and vertically in the Quiver Creek floodplain and beneath the stream. Irrigation and fertigation for agriculture is widely practiced in Mason County. This may seasonally affect the groundwater flow and movement as well as the persistence of nitrate in this area. Continuously and instantaneously measured nitrate concentrations and groundwater levels indicate that during the irrigation season, discharge to Quiver Creek from the shallow groundwater system may be limited. During and following periods when estimated irrigation use is highest, the low-nitrate deeper groundwater may be the dominant contributor to the Quiver Creek surface water, whereas during recharge events and when the system is not under the stress of irrigation, there is more contribution from the local and higher-nitrate shallow groundwater.

Illinois↗

USGS2022

Glacial geology and hydrogeology of valley-fill aquifers in the Oneonta area, Otsego and Delaware Counties, New York

The glacial geology and hydrogeology of valley-fill aquifers and their surrounding uplands are described within a 112-square-mile area in southern Otsego and northwestern Delaware Counties, New York, centered around the City of Oneonta. The major valleys include those of the Susquehanna River, Otego Creek, Charlotte Creek, and Schenevus Creek. A variety of data were analyzed to provide a broad picture of the glacial deposits, hydrogeologic framework, aquifer occurrence, and water-resource potential in the area. Both valley-fill and bedrock aquifers are used for water supply within the study area. The valley-fill aquifers consist of coarse-grained stratified drift, are mostly limited to the larger valleys, and have well yields that typically are much greater than those obtained from the bedrock aquifers. The bedrock aquifers generally have lower well yields, are the sole source of groundwater in upland areas, and are tapped in valley areas where sediments are very silty or are absent. Through and non-through valleys and their orientations relative to ice flow have resulted in a variety of deglacial environments and deposits, some of which depart from glacial stratigraphy typically observed elsewhere in central New York. In comparison to through valleys with low in-valley divides, the regional thinning of ice over the high bedrock divides of the non-through valleys resulted in the earlier and more widespread stagnation of glacial ice, development of dead-ice sinks, and earlier diversion of meltwater from ice north of the divides. As the main through valley in the study area, the Susquehanna River valley is characterized by multiple inferred ice-margin positions with associated outwash deposition or ice-contact deposits. Throughout the study area, valleys orientated parallel or subparallel to the ice flow facilitated the development of long ice tongues; valleys oriented perpendicular to the ice flow led to little ice-tongue development, but they did facilitate the deposition of the extensive kame moraines that now occupy several-mile-long valley reaches. Lacustrine sediments were deposited in proglacial lakes. These sediments underlie most valleys that were oriented parallel and subparallel to ice flow, but they are largely absent in the Charlotte Creek valley, which was oriented perpendicular to the ice flow and now contains an extensive kame moraine. Beneath these lacustrine deposits, sand and gravel were deposited as subaqueous fans, eskers, and the distal parts of delta (kame) terraces, each with variable silt content. The presence of coarse-grained stratified deposits, their saturated thicknesses, and their recharge potential are the primary controls on aquifer locations in the study area. The most widespread aquifers in the study area consist of sand and gravel and are confined mostly beneath lacustrine deposits. Confined aquifer yields are enhanced by hydraulic connections with unconfined ice-contact deposits along the valley walls, especially where tributary streams cross these deposits and provide additional recharge through streambed infiltration. The Susquehanna River and other large valley creeks provide a potentially large source of recharge to aquifers where groundwater withdrawals from nearby production wells induce infiltration of river water into aquifers. Unconfined aquifers are present where ice-contact deposits extend below the valley floor and are sufficiently saturated. Most surficial outwash deposits in the study area are thinly saturated; thus their water-resource potential is likely to be limited. The upland areas contain very little stratified drift; therefore, characterization was limited to delineating areas of thick till and thin, or absent, till. Recharge of bedrock aquifers is greatest in areas overlain by thin till or where bedrock is exposed at land surface.

New York↗

USGS2024

Nutrient chemistry in the Elizabeth Lake subwatershed—Effects of onsite wastewater treatment systems on groundwater and lake water quality, Los Angeles County, California

Nutrient (nitrogen [N] and phosphorus [P] chemistry) downgradient from onsite wastewater treatment system (OWTS) was evaluated with a groundwater study in the area surrounding Elizabeth Lake, the largest of three sag lakes within the Santa Clara River watershed of Los Angeles County, California. Elizabeth Lake is listed on the “303 (d) Impaired Waters List” for excess nutrients and is downgradient from more than 600 OWTS. The primary objective of this study was to develop a conceptual hydrogeological model to determine if discharge from OWTS is transported into shallow groundwater within the Elizabeth Lake subwatershed and contributes nutrients to Elizabeth Lake in excess of the total maximum daily load limit. An analysis of historical data and data collected for this study provided estimates of aquifer properties, such as hydraulic gradients and other parameters necessary to estimate boundary conditions. Electrical resistivity tomography (ERT) surveys were done to determine the best monitoring well locations and to estimate depth to groundwater. During 4 separate sampling events, 11 wells, 2 imported water tanks, 1 spring (sampled on March 17, 2019), and Elizabeth Lake were sampled, which occurred during February–September 2020. ERT transects and borehole geophysical measurements indicated that there were low to high resistivity materials in the subsurface and potential perched fresh water. Most of the aquifer material was characterized as sandy silt, occasionally with mixed clays and medium gravels, and was estimated to have a hydraulic conductivity from 3.28x10 −3 to 16.4 feet per day, a porosity from 0.34 to 0.42, and a hydraulic gradient from 0.01 to 0.03. Although bedrock was not obvious in ERT transects, all well depths were terminated at depths of an impassible confining layer observed to be a highly consolidated blue-gray clay. Depths to granitic bedrock, based on road outcrops and lithologic driller logs, varied throughout the study area. Depth to the bedrock was estimated to be shallow on the north side of Elizabeth Lake at approximately 30 feet below land surface (ft bls). Depth to bedrock is at 50 ft bls toward the east of the Elizabeth Lake subwatershed, which is at topographic ground surface to the north and south of the residential development. Groundwater levels ranged from approximately 0 to 12 ft bls during this study. Historical water levels ranged from 8 to 16 ft bls in the lower elevation of the study area and increased to depths of as much as 80 ft bls at higher elevations on the north and south boundaries of the Elizabeth Lake subwatershed. Water-quality samples were analyzed for major ions, nutrients, dissolved organic carbon, stable isotopes, and age-dating tracers. A principal component analysis was completed to determine organic matter sources. The proportion of recharge from imported waters, used for domestic consumption, was calculated using stable water isotopes, deuterium (δD) and oxygen (δ 18 O). Recharge from imported waters accounted for approximately 15–71 percent of the total recharge to groundwater within the study area. Total nitrogen concentrations ranged from 0.17 to 30.9 milligrams per liter (mg/L) as N, and phosphorus, measured in the soluble form as orthophosphate, ranged from 0.03 to 0.35 mg/L as P. Nitrate concentrations in groundwater samples ranged from less than the detection limit (0.01 mg/L as N) to approximately 24 mg/L as N. Nitrate was not detected in 3 of the 12 sites sampled during the study (2 wells and Elizabeth Lake). Dissolved organic carbon concentrations ranged from 0.4 to 27 mg/L in groundwater and from 9.9 to 100 mg/L in Elizabeth Lake. Ammonium and orthophosphate concentrations generally were low in groundwater. However, elevated concentrations of ammonium in Elizabeth Lake were assumed to be due to avian waste products or biological nitrogen fixation. Groundwater ages were mostly modern (recharged since 1952), with a median recharge temperature of 13 degrees Celsius. Redox conditions in groundwater indicated the likely occurrence of nitrate attenuation by denitrification downgradient from the wells to the south of Elizabeth Lake before groundwater discharges to the lake. Undetectable nitrate in Elizabeth Lake at the time of sampling was likely due to algal uptake. Most wells contained stable isotopes of nitrogen and oxygen in nitrate (δ 15 N-NO 3 and δ 18 O-NO 3 ) molecules with values consistent with denitrification. However, one monitoring well on the north of Elizabeth Lake (ELLA-8) had no evidence of denitrification, based on elevated concentrations of nitrate and a sufficient amount of dissolved oxygen such that the water was oxic and not favorable for the denitrification reaction. Consequently, this nitrate could be delivered to Elizabeth Lake through groundwater discharge if nitrate is not removed from the system by denitrifying bacteria downgradient from the well before the groundwater discharges into Elizabeth Lake. The principal component analysis demonstrated that dissolved organic matter optical properties track different sources of dissolved organic matter from decayed plants, animals, and animal-derived wastes. Two wells contained strong indicators of OWTS water presence, although geochemical evidence indicated other wells may also be affected by OWTS discharge.

California↗

USGS1986

Water levels in major artesian aquifers of the New Jersey Coastal Plain, 1983

Water levels and changes in water levels in the major aquifers of the New Jersey Coastal Plain are documented. Water levels in 1,071 wells were measured in 1983, and are compared with 827 water level measurements made in the same wells in 1978. Increased groundwater withdrawals from the major artesian aquifers that underlie the New Jersey Coastal Plain have caused large cones of depression in the artesian heads. These cones are delineated on detailed potentiometric surface maps based on water level data collected in the fall of 1983. Hydrographs from observation wells show trends of water levels for the 6-year period of 1978 through 1983. The Potomac-Raritan-Magothy aquifer system is divided into the lower, middle, and upper aquifers. The potentiometric surfaces in these aquifers form large cones of depression centered in the Camden and Middlesex-Monmouth County areas. Measured water levels declined as much as 23 ft in these areas for the period of study. The lowest levels are 96 ft below sea level in Camden County and 91 ft below sea level in the Middlesex-Monmouth County area. Deep cones of depression in coastal Monmouth and Ocean counties in both the Englishtown aquifer system and Wenonah-Mount Laurel aquifer are similar in location and shape. This is because of an effective hydraulic connection between these aquifers. Measured water levels declined as much as 29 ft in the Englishtown aquifer system and 21 ft in the Wenonah-Mount Laurel aquifer during the period of study. The lowest levels are 249 ft below sea level in the Englishtown aquifer system and 196 ft below sea level in the Wenonah-Mount Laurel aquifer. Water levels in the Piney Point aquifer are as low as 75 ft below sea level at Seaside Park, Ocean County and 35 ft below sea level in southern Cumberland County. Water levels in Cumberland County are affected by large withdrawals of groundwater in Kent County, Delaware. Water levels in the Atlantic City 800 ft sand of the Kirkwood Formation define an extensive elongated cone of depression. Water levels are as low as 76 ft below sea level near Margate and Ventnor, Atlantic County. Measured water levels declined as much as 9 ft in the coastal region between Cape May County and Ocean County for the period of study. (Author 's abstract)

Water-Resources Investigations Report↗