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Groundwater & aquifers

Find USGS groundwater and aquifer publications. Search an aquifer name or place, compare source-supplied dates and open reports for hydrogeology, recharge and water-level studies.

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At least 1,135 records · Page 63Linked to original sources

USGS2019

Delineation of spatial extent, depth, thickness, and potential volume of aquifers used for domestic and public water-supply in the Central Valley, California

Identification of the groundwater resources used for drinking-water supplies is essential for the design of strategies to manage those resources. In this study, the spatial extent, depths, thicknesses, and volumes of groundwater aquifers used for domestic and public drinking-water supply were estimated from locations and well-construction data from 11,725 domestic-supply wells and 2,376 public-supply wells in the Central Valley, California. The data were compiled as part of the U.S. Geological Survey National Water Quality Assessment Project and California State Water Resources Control Board Groundwater Ambient Monitoring and Assessment Program Priority Basin Project. The spatial distributions of the depth to top and bottom of well screens were interpolated using Empirical Bayesian Kriging across buffer areas surrounding domestic- and public-supply wells. These surfaces provide a measure of the likely maximum horizontal and vertical extent of the aquifer volume accessed for drinking water in the Central Valley during the past century. Well depth generally increased from north to south, and over time from 1905 to 2010. Well-construction depths were generally more consistent in the Sacramento Valley than in the San Joaquin Valley. The total potential aquifer volume accessed for public supply was calculated to be greater than domestic-supply access, even though the estimated spatial extent of domestic-supply wells was 1.5 times larger than the spatial extent of public-supply wells. Public-supply wells commonly have screen lengths greater than 51 meters, whereas domestic-supply wells typically have shorter screen lengths (overall median of 6 meters). Consequently, the accessed thickness and volume of the aquifer is on average 1.8 and 1.4 times greater for public-supply wells than domestic-supply wells, respectively. Results are presented as maps of areal extent, depth, and thickness of zones in the Central Valley aquifer system used for domestic and public drinking-water supplies.

California↗

USGS2012

Effects of climate change and population growth on the transboundary Santa Cruz aquifer

The USA and Mexico have initiated comprehensive assessment of 4 of the 18 aquifers underlying their 3000 km border. Binational management of groundwater is not currently proposed. University and agency researchers plus USA and Mexican federal, state, and local agency staff have collaboratively identified key challenges facing the Santa Cruz River Valley Aquifer located between the states of Arizona and Sonora. The aquifer is subject to recharge variability, which is compounded by climate change, and is experiencing growing urban demand for groundwater. In this paper, we briefly review past, current, and projected pressures on Santa Cruz groundwater. We undertake first-order approximation of the relative magnitude of climate change and human demand drivers on the Santa Cruz water balance. Global circulation model output for emissions scenarios A1B, B1, and A2 present mixed trends, with annual precipitation projected to vary by ±20% over the 21st century. Results of our analysis indicate that urban water use will experience greater percentage change than climate-induced recharge (which remains the largest single component of the water balance). In the Mexican portion of the Santa Cruz, up to half of future total water demand will need to be met from non-aquifer sources. In the absence of water importation and with agricultural water use and rights increasingly appropriated for urban demand, wastewater is increasingly seen as a resource to meet urban demand. We consider decision making on both sides of the border and conclude by identifying short- and longer-term opportunities for further binational collaboration on transboundary aquifer assessment.

Santa Cruz Aquifer↗

USGS2008

Canadian groundwater inventory: Regional hydrogeological characterization of the south-central part of the maritimes basin

The Maritimes Groundwater Initiative (MGWI) is a large, integrated, regional hydrogeological study focusing on a representative area of the Maritimes Basin in eastern Canada. The study area covers a land surface of 10 500 km 2 , of which 9 400 km 2 are underlain by sedimentary rocks. This sedimentary bedrock is composed of a sequence of discontinuous strata of highly variable hydraulic properties, and is generally overlain by a thin layer of glacial till(mostly 4-8 m thick, but can reach 20 m). Depending on the area, 46 to 100% of the population relieson groundwater for water supply, either from municipal wells or from private residential wells. The main objectives of this project were to improve the general understanding of groundwater-flow dynamics and to provide baseline information and tools for a regional groundwater-resource assessment. This bulletin presents the current state of understanding of this hydrogeological system, along with the methodology used to characterize and analyze its distinct behaviour at three different scales. This regional bedrock aquifer system contains confined and unconfined zones, and each of its lenticular permeable strata extends only a few kilometres. Preferential groundwater recharge occurs where sandy till is present. The mean annual recharge rate to the bedrock is estimated to range between 130 and 165 mm/a. Several geological formations of this basin provide good aquifers, with hydraulic conductivity in the range 5x10 -6 to 10 -4 m/s. Based on results of numerical flow modelling, faults were interpreted to have a key role in the regional flow. Pumping-test results revealed that the fractured aquifers can locally be very heterogeneous and anisotropic, but behave similarly to porous media. Work performed at the local scale indicated that most water-producing fractures seem to be subhorizontal and generally oriented in a northeasterly direction, in agreement with regional structures and pumping-test results. Almost all residential wells are shallow (about 20 m) open holes that are cased only through the surficial sediments.

Bulletin of the Geological Survey of Canada↗

USGS2013

Characterization and conceptualization of groundwater flow systems

This chapter discusses some of the fundamental concepts, data needs and approaches that aid in developing a general understanding of a groundwater system. Principles of the hydrological cycle are reviewed; the processes of recharge and discharge in aquifer systems; types of geological, hydrological and hydraulic data needed to describe the hydrogeological framework of an aquifer system; factors affecting the distribution of recharge to aquifers; and uses of groundwater chemistry, geochemical modelling, environmental tracers and age interpretations in groundwater studies. Together, these concepts and observations aid in developing a conceptualization of groundwater flow systems and provide input to the development of numerical models of a flow system. Conceptualization of the geology, hydrology, geochemistry, and hydrogeological and hydrochemical framework can be quite useful in planning, study design, guiding sampling campaigns, acquisition of new data and, ultimately, developing numerical models capable of assessing a wide variety of societal issues — for example, sustainability of groundwater resources in response to real or planned withdrawals from the system, CO 2 sequestration or other waste isolation issues (such as nuclear waste disposal).

Book chapter↗

USGS1990

Development of an aquifer management model AQMAN3D

A computer code that enables the use of the USGS Modular groundwater flow model for aquifer management modeling has been developed. Aquifer management techniques integrate groundwater flow modeling with linear quadratic optimization methods for the solution of various aquifer management problems. The model AQMAN3D , is a modified version of a previously developed two-dimensional AQMAN model . The idea of coupling the AQMAN model with the MODULAR model arose because actual groundwater flow systems behave in a three dimensional manner, therefore requiring treatment as such, and due to the widespread use of MODULAR. The use of the AQMAN3D model permits the implementation of the technique known as aquifer management modeling. A generalized approach to obtain an optimal solution to an aquifer management problem is proposed, and a sample test problem is presented to illustrate the use of the model . Even though the model provides the hydrologist with a new and powerful investigative tool, its applicability is limited to confined or quasiconfined systems.

Conference Paper↗

USGS2021

Simulation of groundwater budgets and travel times for watersheds on the north shore of Long Island Sound, with implications for nitrogen-transport studies

Aquatic systems in and around the Long Island Sound (LIS) provide a variety of ecological and economic benefits, but in some areas of the LIS, aquatic ecosystems have become degraded by excess nitrogen. A substantial fraction of the nitrogen inputs to the LIS are transported through the groundwater-flow system. Because groundwater travel times in surficial aquifers can exceed 100 years, multiyear lags are introduced between inputs at the water table in recharge areas and discharge to inland or coastal receiving waters. The U.S. Geological Survey, in cooperation with the Connecticut Department of Energy and Environmental Protection and the U.S. Environmental Protection Agency’s Long Island Sound Study, developed a steady-state groundwater model of the watersheds draining from the northern shore of the LIS for the purpose of calculating groundwater budgets and travel times to coastal waters. The model was developed by using the MODFLOW–NWT software and existing spatial data on aquifers, river networks, land-surface altitudes, land cover, groundwater recharge, and water use. Coastal waters were delineated on the basis of the National Wetland Inventory; all non-coastal waters were collectively termed “inland waters.” A coarse-resolution model was calibrated by using the PEST++ software, long-term records of water levels in 65 wells, stream altitudes from 477 streams, base-flow records for 14 streamgages that are relatively unaffected by withdrawals, and error metrics based on incorrectly simulated flooding and incorrectly simulated dry streams. The calibrated values were used in a fine-resolution model in which the mean absolute residuals were 4.5 meters for groundwater levels, 1.3 meters for stream altitudes, and 7,200 cubic meters per day (2.9 cubic feet per second) for base flow. About 89 percent of the terrestrial cells were correctly simulated with the water table below land surface, and nearly 90 percent of the cells representing streams were correctly simulated as having the water table above the stream bottom. Together, these metrics suggest that this model is robust for simulating regional-scale groundwater patterns. Simulated groundwater budgets were compiled for the entire study area, for each HUC12 (Hydrologic Unit Code no. 12) watershed and its adjacent coastal waters, if applicable, within the study area, and for 14 coastal-embayment watersheds. Most groundwater (90.6 percent of inflows) discharged to inland waters, with smaller fractions to coastal waters (7.0 percent) and well withdrawals (2.4 percent). When computed for HUC12 watersheds with coastal discharge, the portions of groundwater discharging to coastal waters ranged from 0.02 to 66 percent of groundwater outflows, with a median of 13 percent. Within priority-embayment watersheds, the portions of groundwater discharging to coastal waters ranged from 2 to 56 percent, with a median of 15 percent. Groundwater travel times also were simulated for the entire study area, for each HUC12 watershed and its adjacent coastal waters, if applicable, within the study area and for 14 priority coastal embayments. Within the entire study area, the median groundwater travel time was 1.9 years, with an interquartile range of 0.1 to 5.9 years. Sensitivity analysis of groundwater travel times within a subbasin in the study area indicates that the travel times are a function of the grid resolution, with coarser grids resulting in shorter median travel times. Travel times for groundwater discharging to coastal waters were similar to travel times for groundwater discharging to inland waters, with a median of 1.9 years. Median travel times for the HUC12 watersheds ranged from 0.9 to 53.5 years, with a median of 1.8 years. Among HUC12 watersheds that include coastal areas, travel times for groundwater discharging to coastal waters ranged from less than 1 to 61.6 years, with a median of 2.8 years. The HUC12 watersheds with the longest simulated travel times were in the urban area near New York City where the model performance is less accurate. Median travel times for groundwater discharging to coastal waters within the priority-embayment watersheds ranged from less than 1 to 18.6 years, with a median of 2.3 years. A more focused analysis was conducted for the Niantic River watershed to demonstrate the applicability of the regional model to local-scale nitrogen-transport analyses by using nitrogen-input and -attenuation rates from literature sources. Nitrogen inputs were estimated by using land-cover-based loading factors, and attenuation was estimated by using attenuation factors based on geologic zones and soil properties. Based on this analysis, groundwater transports an estimated 22,000 kilograms of nitrogen per year (2.9 kilograms of nitrogen per hectare per year) to streams, rivers, and coastal waters within the Niantic River watershed. Approximately 36 percent of discharging nitrogen is from atmospheric-deposition sources, 38 percent is from fertilizers, and 26 percent is from septic systems. Most of the groundwater-transported nitrogen (88 percent) discharges first to streams and rivers, with only 12 percent discharging directly to coastal waters. Travel times for groundwater-transported nitrogen ranged from less than 1 day to more than 100 years, with a median of 1.6 years.

Connecticut, New York, Rhode Island↗

USGS2015

Assessment of aquifer properties, evapotranspiration, and the effects of ditching in the Stoney Brook watershed, Fond du Lac Reservation, Minnesota, 2006-9

The U.S. Geological Survey, in cooperation with the Fond du Lac Band of Lake Superior Chippewa, assessed hydraulic properties of geologic material, recharge, and evapotranspiration, and the effects of ditching on the groundwater resources in the Stoney Brook watershed in the Fond du Lac Reservation. Geologic, groundwater, and surface-water data were collected during 2006–9 to estimate hydrologic properties in the watershed. Streamflow and groundwater levels in the shallow glacial deposits in the Stoney Brook watershed were analyzed to estimate groundwater-flow directions, groundwater recharge, and evapotranspiration within the watershed and to assess the effect of ditches on surrounding groundwater resources. Groundwater, streamflow, and precipitation data collected during the study (2006–9) can be used to update the U.S. Department of Agriculture’s Natural Resource Conservation Service and Fond du Lac Resource Management Division surface-water models, which are used to evaluate the effect of proposed adjustments to the ditching system on streamflow on wild rice production and aquatic habitats. Specific yields calculated from the well water levels ranged from 0.11 to 0.40, and hydraulic conductivities determined from water levels measured during well slug tests ranged from 1 to 7 feet per day. The values for specific yields were similar to values obtained in other studies done in glacial materials of similar composition in Minnesota. The higher hydraulic conductivity estimate (7 feet per day) was similar to lower hydraulic conductivities estimated in another hydrologic study conducted in Carlton County, Minnesota. The installation of drainage ditches in the Stoney Brook watershed has reduced water levels in lakes connected to the ditch system, and has locally reduced groundwater levels in shallow groundwater adjacent to the ditches and lakes. Differences in near-ditch groundwater hydrographs relative to far-ditch groundwater hydrographs indicate that the effect of the ditches on groundwater is only localized to near-ditch areas. These hydrograph differences resulted in large differences between recharge estimated at wells near and far from ditches. In this study, recharge estimated at wells within 50 feet of a ditch was influenced by ditch-water levels. Annual groundwater recharge estimates from water levels and streamflows during 2006–9 ranged from 0.36 to 34.8 inches, and varied with climate, geology, and well location relative to ditches. The higher recharge estimates were determined from analysis of groundwater levels in wells near the ditches because the shallow groundwater in these wells received both infiltration from ditches and areal groundwater recharge from precipitation. The water-table fluctuation method using a manual groundwater recession approach for wells far from ditches provided the best estimates of areal groundwater recharge to the shallow glacial aquifer because water levels in these wells were not affected by water infiltrating from ditches (bank storage). For wells more than 400 feet from ditches, mean annual areal groundwater recharge estimates using the manual groundwater recession approach for wells screened mostly in outwash sands during 2007, 2008, and 2009 ranged from 4.47 to 18.6 inches (wells 5, 7, 13, 14 and 15), and ranged from 0.43 to 2.85 inches for wells screened mostly in clayey sand or sandy clay (wells 9 and 16). Recharge estimates at wells far from ditches were similar to basinwide recharge estimates from streamflow. Daily fluctuations in water levels in two wells indicated that the evapotranspiration extinction depth in the Stoney Brook watershed is approximately 4.6 to 6 feet below the land surface. A polynomial regression fit of the daily evapotranspiration rates during 2006–9 for well 1 produced a total evapotranspiration estimate of 16.1 inches from June 26 to October 6 for every year. Evapotranspiration estimated from daily water-level fluctuations in wells near ditches is relatively high. The ditch-water surface allowed for relatively high evaporation compared to the land surface, which, with a good hydraulic connection to surrounding groundwater, resulted in relatively high fluctuations in daily groundwater levels near ditches, resulting in high evapotranspiration estimates.

Minnesota↗

USGS2020

Groundwater levels and generalized potentiometric surfaces, former Naval Air Warfare Center, West Trenton, New Jersey, 2018

Groundwater-level conditions, generalized groundwater potentiometric surfaces, and generalized flow directions at the decommissioned Naval Air Warfare Center in West Trenton, New Jersey, were evaluated for calendar year 2018. Groundwater levels measured continuously in five on-site wells and one nearby off-site well were plotted as hydrographs for January 1, 2018, through December 31, 2018. Groundwater levels measured in 110 wells on June 18, 2018, were contoured as generalized potentiometric surfaces on maps and sections. Generalized groundwater-flow directions inferred from the June 2018 data are shown in the maps and sections. Groundwater levels in six monitoring wells fluctuated in response to seasonal changes, precipitation, and pumping from “pump-and-treat” (P&T) wells. Record high precipitation totals in November, combined with a shutdown of three P&T wells in November, resulted in annual high water levels in late November for five of the six wells monitored. Annual high groundwater levels that occur during the fall are uncharacteristic of the typical timing of annual high water levels, which usually occur in the spring following low evapotranspiration during the winter months, compared to annual low water levels, which usually occur in fall because of high evapotranspiration during the summer months. The annual high water levels occurred following a 3-day precipitation event totaling 3.50 inches from November 24-26, which also caused the largest 1-day water-level increase for five of the six wells in 2018. The groundwater-level contour maps and sections include generalized flow directions. Given the heterogeneity of the site’s fractured rock aquifers, contours and associated groundwater-flow directions shown on the maps and sections should be considered as broad conceptualizations. A nearly vertical fault striking southwest to northeast separates the northwestern part of the site underlain by the Lockatong Formation from the southeastern part, which is underlain by the Stockton Formation. In the Lockatong Formation, general groundwater-flow directions were toward P&T wells. The P&T wells limited the flow of groundwater in the Lockatong Formation from the site into the adjacent areas and contained most groundwater contamination within the site. A groundwater divide bisected the site; groundwater in the western part generally flowed to P&T wells 8BR, 15BR, 20BR, 29BR, 56BR, 91BR, and BRP-2, and groundwater in the eastern part generally flowed to P&T well 48BR. A groundwater divide also was present in the Stockton Formation. Groundwater west of the divide in the Stockton Formation generally flowed toward P&T well 22BR, and groundwater east of the divide generally flowed south and southeast, away from the site. Saprolite and fill from land surface to depths of 25 feet below land surface exhibit similar properties to those of porous media, and water levels in surficial wells were contoured using a porous media aquifer approach. Water levels in these surficial wells indicate that groundwater in the saprolite and fill flowed predominantly toward Gold Run and, to a lesser extent, the West Ditch spring that drains to Gold Run. In addition, some shallow groundwater was captured by the cone of depression in the fractured bedrock and was attributed to P&T well 48BR.

New Jersey↗

USGS2016

Regional chloride distribution in the Northern Atlantic Coastal Plain aquifer system from Long Island, New York, to North Carolina

The aquifers of the Northern Atlantic Coastal Plain are the principal source of water supply for the region’s nearly 20 million residents. Water quality and water levels in the aquifers, and maintenance of streamflow, are of concern because of the use of this natural resource for water supply and because of the possible effects of climate change and changes in land use on groundwater. The long-term sustainability of this natural resource is a concern at the local community scale, as well as at a regional scale, across state boundaries. In 2010, the U.S. Geological Survey (USGS) began a regional assessment of the Northern Atlantic Coastal Plain aquifers. An important part of this assessment is a regional interpretation of the extent of saltwater and the proximity of saltwater to fresh-groundwater resources and includes samples and published interpretations of chloride concentrations newly available since the last regional chloride assessment in 1989. This updated assessment also includes consideration of chloride samples and refined interpretations that stem from the 1994 discovery of the buried 35 million year old Chesapeake Bay impact structure that has substantially altered the understanding of the hydrogeologic framework and saltwater distribution in eastern Virginia. In this study, the regional area of concern for the chloride samples and interpretations extends from the Fall Line in the west to the outer edge of the Continental Shelf in the east and from the eastern tip of Long Island in the north to about halfway down the North Carolina coast in the south. Discussions of chloride distribution are presented for each of the 10 regional aquifer layers of the Northern Atlantic Coastal Plain, including the offshore extents. Maps of interpreted lines of equal concentration or isochlors were manually prepared for nine of the regional aquifers; a map was not prepared for the surficial regional aquifer. The isochlor interpretations include the offshore extent of the nine regional aquifers and are presented on a 1:2,000,000 scale base map. Vertically, the chloride samples and interpretations range from deepest (oldest) to shallowest (youngest)—Potomac-Patuxent, Potomac-Patapsco, Magothy, Matawan, Monmouth-Mount Laurel, Aquia, Piney Point, Lower Chesapeake, and Upper Chesapeake regional aquifers. The approach of this study maximizes the overall density of chloride information and data by assessing relevant published interpretations, all USGS chloride samples, and all relevant offshore samples in one comprehensive interpretation. Published isochlors, where they were interpreted by regional aquifer, were used as much as possible for this regional isochlor assessment. Publication dates for the isochlors used range from 1982 to 2015, and the scales for the isochlors range from local (county or municipality) to state (sub-regional) to regional. The USGS National Water Information System database provided well sample data for the parts of aquifers that are mainly beneath the land areas and yielded 37,517 water-quality records for 1903 through 2011. Published data reports from four phases of research-related offshore coring (1976, 1993, 1997, 2009) were the main source of water-quality data for the parts of aquifers from the shoreline to the outer edge of the Continental Shelf and yielded samples from multiple depths of each of 13 cores. This study also used interpretations and offshore core data from the last regional chloride assessment (1989) which, in addition to 7 offshore cores, included water-quality data from about 500 wells, and borehole geophysics interpretations from a subset of 11 wells. All published information and data that were used in this study were considered time independent and did not assess the published interpretations or data for temporal trends. The approach used here examined only published interpretations and available chloride data, and did not directly use supplemental techniques that can provide insight into the distribution of saltwater, such as geochemical characterization, borehole geophysical information, and geochronology. Isochlor maps for this study are limited to manual interpretations of the 250-milligram per liter (mg/L) and 10,000-mg/L boundaries developed for 9 of the 10 regional aquifers that constitute the regional hydrogeologic framework of the Northern Atlantic Coastal Plain. For a given aquifer, the approach was to initially consider published isochlor interpretations, where available, then to modify the published interpretations, if necessary, to the extent indicated by the well and core samples. The final step was to interpolate isochlors to the full extent of each aquifer layer in areas with sufficient samples or cited interpretations, or to extrapolate isochlors in areas with no samples or where samples were sparse. The principal limitation of this study is that, because of its regional extent, data and information density can vary greatly, and thus confidence in interpretations can vary widely for onshore and offshore areas across the study area. In areas of sparse data, some samples of elevated chloride could be misinterpreted as being part of a regional elevated chloride trend, and in other cases, an elevated concentration could be misinterpreted as being of only local importance. The interpretive work of this study was applied to a 1:2,000,000 scale base map. Locations of isochlors, wells, cores, political boundaries, and shorelines are meant to be considered approximate. The isochlors presented in this study were manually interpreted for each aquifer unit as a conceptual representation of an equal concentration line approximately in the middle of an aquifer’s thickness. Differences in chloride concentration lines between the top and bottom of an aquifer could be substantial, especially for the thick parts of aquifers, but that information is not presented in this regional assessment. Although additional offshore chloride data are available compared to 27 years ago (1989), the offshore information remains sparse, resulting in less confidence in the offshore interpretations than in the onshore interpretations. Regionally, the 250- and 10,000-mg/L isochlors tend to map progressively eastward from the deepest to the shallowest aquifers across the Northern Atlantic Coastal Plain aquifer system but with some exceptions. The additional data, conceptual understanding, and interpretations in the vicinity of the buried Chesapeake Bay impact structure in eastern Virginia resulted in substantial refinement of isochlors in that area. Overall, the interpretations in this study are updates of the previous regional study from 1989 but do not comprise major differences in interpretation and do not indicate regional movement of the freshwater-saltwater interface since then.

Delaware, Maryland, New Jersey, New York, North Ca↗

USGS2021

Hydrologic and water-quality conditions in the Cedar River alluvial aquifer, Linn County, Iowa, 1990–2019

Alluvial aquifers in Iowa have more wells with nitrate exceeding drinking-water standards than other aquifers; are susceptible to contamination by organic contaminants; and have high concentrations of naturally occurring iron and manganese in depositional areas that contain abundant organic matter. The U.S. Geological Survey, in cooperation with the City of Cedar Rapids, Iowa, studied the Cedar River alluvial aquifer in Linn County, Iowa, from 1990 to 2019 to understand the effect of municipal pumping on spatial and temporal hydrologic and water-quality variability. The Cedar River alluvial aquifer is the source of water for the city of Cedar Rapids, Iowa. Withdrawal of large quantities of water for municipal and industrial supply has altered the normal flow of water in the alluvial aquifer. Pumping induces flow from the Cedar River and the underlying bedrock aquifer into the alluvial aquifer. Water quality in the alluvial aquifer varies along the Cedar River. Changes in nitrate, ammonia, manganese, and iron in the alluvial aquifer are seen as the upstream free-flowing reach of the Cedar River transitions to a partially regulated downstream reach, likely because of differences in reduction-oxidation conditions in the aquifer, which are controlled by infiltration from the Cedar River under normal conditions and when wells are being pumped. Nitrate, normally found in oxygenated environments, had the highest concentrations in the most upstream wells in the Seminole well field and the lowest concentrations in the most downstream wells in the East well field. In contrast, ammonia, manganese, and iron, normally found in greatest abundance in anoxic (reducing) conditions, had the greatest concentrations in the most downstream wells. Additionally, dissolved nitrate plus nitrite nitrogen concentrations in wells were substantially less and manganese concentrations were greater in production wells near backwater wetlands in contrast to wells near the Cedar River. Temporal variability in water quality in the alluvial aquifer was driven by pumping that increased flow from the Cedar River into the alluvial aquifer and ultimately led to changes in reduction-oxidation conditions of the aquifer. Increasing dissolved nitrate plus nitrite nitrogen concentrations in the Cedar River from 1990 to 2019 were mirrored in the alluvial aquifer. Anoxic conditions are prevalent in the alluvial aquifer next to the Cedar River when the aquifer is not under pumping stress. However, production well pumping caused induced infiltration of oxygenated river water into the aquifer resulting in increased dissolved nitrate plus nitrite nitrogen concentrations and pesticides and decreased naturally occurring dissolved iron and manganese. Hydrologic and water-quality conditions in the Cedar River alluvial aquifer from 1990 to 2019 provide baseline conditions needed to evaluate the effects of current and future nutrient reduction efforts and land-use changes in the Cedar River Basin on water quality of the Cedar River alluvial aquifer and its source water, the Cedar River. This summary and analysis provide information that can assist the City of Cedar Rapids Utilities Water Department in managing groundwater resources, and provides information that could be used develop a groundwater-quality model to characterize variability over larger areas of the alluvial aquifer, allowing water providers to plan for future water needs of their users.

Iowa↗

USGS2012

Threshold amounts of organic carbon needed to initiate reductive dechlorination in groundwater systems

Aquifer sediment and groundwater chemistry data from 15 Department of Defense facilities located throughout the United States were collected and analyzed with the goal of estimating the amount of natural organic carbon needed to initiate reductive dechlorination in groundwater systems. Aquifer sediments were analyzed for hydroxylamine and NaOH-extractable organic carbon, yielding a probable underestimate of potentially bioavailable organic carbon (PBOC). Aquifer sediments were also analyzed for total organic carbon (TOC) using an elemental combustion analyzer, yielding a probable overestimate of bioavailable carbon. Concentrations of PBOC correlated linearly with TOC with a slope near one. However, concentrations of PBOC were consistently five to ten times lower than TOC. When mean concentrations of dissolved oxygen observed at each site were plotted versus PBOC, it showed that anoxic conditions were initiated at approximately 200 mg/kg of PBOC. Similarly, the accumulation of reductive dechlorination daughter products relative to parent compounds increased at a PBOC concentration of approximately 200 mg/kg. Concentrations of total hydrolysable amino acids (THAA) in sediments also increased at approximately 200 mg/kg, and bioassays showed that sediment CO 2 production correlated positively with THAA. The results of this study provide an estimate for threshold amounts of bioavailable carbon present in aquifer sediments (approximately 200 mg/kg of PBOC; approximately 1,000 to 2,000 mg/kg of TOC) needed to support reductive dechlorination in groundwater systems.

Remediation Journal↗

USGS2004

Hydrochemical tracers in the middle Rio Grande Basin, USA: 1. Conceptualization of groundwater flow

Chemical and isotopic data for groundwater from throughout the Middle Rio Grande Basin, central New Mexico, USA, were used to identify and map groundwater flow from 12 sources of water to the basin, evaluate radiocarbon ages, and refine the conceptual model of the Santa Fe Group aquifer system. Hydrochemical zones, representing groundwater flow over thousands to tens of thousands of years, can be traced over large distances through the primarily siliciclastic aquifer system. The locations of the hydrochemical zones mostly reflect the “modern” predevelopment hydraulic-head distribution, but are inconsistent with a trough in predevelopment water levels in the west-central part of the basin, indicating that this trough is a transient rather than a long-term feature of the aquifer system. Radiocarbon ages adjusted for geochemical reactions, mixing, and evapotranspiration/dilution processes in the aquifer system were nearly identical to the unadjusted radiocarbon ages, and ranged from modern to more than 30 ka. Age gradients from piezometer nests ranged from 0.1 to 2 year cm –1 and indicate a recharge rate of about 3 cm year –1 for recharge along the eastern mountain front and infiltration from the Rio Grande near Albuquerque. There has been appreciably less recharge along the eastern mountain front north and south of Albuquerque.

Rio Grande Basin↗

USGS2006

Groundwater-supported evapotranspiration within glaciated watersheds under conditions of climate change

This paper analyzes the effects of geology and geomorphology on surface-water/-groundwater interactions, evapotranspiration, and recharge under conditions of long-term climatic change. Our analysis uses hydrologic data from the glaciated Crow Wing watershed in central Minnesota, USA, combined with a hydrologic model of transient coupled unsaturated/saturated flow (HYDRAT2D). Analysis of historical water-table (1970-1993) and lake-level (1924-2002) records indicates that larger amplitude and longer period fluctuations occur within the upland portions of watersheds due to the response of the aquifer system to relatively short-term climatic fluctuations. Under drought conditions, lake and water-table levels fell by as much as 2-4 m in the uplands but by 1 m in the lowlands. The same pattern can be seen on millennial time scales. Analysis of Holocene lake-core records indicates that Moody Lake, located near the outlet of the Crow Wing watershed, fell by as much as 4 m between about 4400 and 7000 yr BP. During the same time, water levels in Lake Mina, located near the upland watershed divide, fell by about 15 m. Reconstructed Holocene climate as represented by HYDRAT2D gives somewhat larger drops (6 and 24 m for Moody Lake and Lake Mina, respectively). The discrepancy is probably due to the effect of three-dimensional flow. A sensitivity analysis was also carried out to study how aquifer hydraulic conductivity and land-surface topography can influence water-table fluctuations, wetlands formation, and evapotranspiration. The models were run by recycling a wet year (1985, 87 cm annual precipitation) over a 10-year period followed by 20 years of drier and warmer climate (1976, 38 cm precipitation). Model results indicated that groundwater-supported evapotranspiration accounted for as much as 12% (10 cm) of evapotranspiration. The aquifers of highest hydraulic conductivity had the least amount of groundwater-supported evapotranspiration owing to a deep water table. Recharge was even more sensitive to aquifer hydraulic conductivity, especially in the lowland regions. These findings have important implications for paleoclimatic studies, because the hydrologic response of a surface-water body will vary across the watershed to a given climate signal. ?? 2005 Elsevier B.V. All rights reserved.

Conference Paper↗

USGS2003

Arsenic in groundwater in eastern New England: Occurrence, controls, and human health implications

In eastern New England, high concentrations (greater than 10 ??g/L) of arsenic occur in groundwater. Privately supplied drinking water from bedrock aquifers often has arsenic concentrations at levels of concern to human health, whereas drinking water from unconsolidated aquifers is least affected by arsenic contamination. Water from wells in metasedimentary bedrock units, primarily in Maine and New Hampshire, has the highest arsenic concentrations - nearly 30% of wells in these aquifers produce water with arsenic concentrations greater than 10 ??g/L. Arsenic was also found at concentrations of 3-40 mg/kg in whole rock samples in these formations, suggesting a possible geologic source. Arsenic is most common in groundwater with high pH. High pH is related to groundwater age and possibly the presence of calcite in bedrock. Ion exchange in areas formerly inundated by seawater also may increase pH. Wells sampled twice during periods of 1-10 months have similar arsenic concentrations (slope = 0.89; r-squared = 0.97). On the basis of water-use information for the aquifers studied, about 103 000 people with private wells could have water supplies with arsenic at levels of concern (greater than 10 ??g/L) for human health.

Environmental Science & Technology↗

USGS2006

Application of carbonate cyclostratigraphy and borehole geophysics to delineate porosity and preferential flow in the karst limestone of the Biscayne aquifer, SE Florida

Combined analyses of cores, borehole geophysical logs, and cyclostratigraphy produced a new conceptual hydrogeologic framework for the triple-porosity (matrix, touching-vug, and conduit porosity) karst limestone of the Biscayne aquifer in a 0.65 km 2 study area, SE Florida. Vertical lithofacies successions, which have recurrent stacking patterns, fit within high-frequency cycles. We define three ideal high-frequency cycles as: (1) upward-shallowing subtidal cycles, (2) upward-shallowing paralic cycles, and (3) aggradational subtidal cycles. Digital optical borehole images, tracers, and flow meters indicate that there is a predictable vertical pattern of porosity and permeability within the three ideal cycles, because the distribution of porosity and permeability is related to lithofacies. Stratiform zones of high permeability commonly occur just above flooding surfaces in the lower part of upward-shallowing subtidal and paralic cycles, forming preferential groundwater flow zones. Aggradational subtidal cycles are either mostly high-permeability zones or leaky, low-permeability units. In the study area, groundwater flow within stratiform high-permeability zones is through a secondary pore system of touching-vug porosity principally related to molds of burrows and pelecypods and to interburrow vugs. Movement of a dye-tracer pulse observed using a borehole fluid-temperature tool during a conservative tracer test indicates heterogeneous permeability. Advective movement of the tracer appears to be most concentrated within a thin stratiform flow zone contained within the lower part of a high-frequency cycle, indicating a distinctly high relative permeability for this zone. Borehole flow-meter measurements corroborate the relatively high permeability of the flow zone. Identification and mapping of such high-permeability flow zones is crucial to conceptualization of karst groundwater flow within a cyclostratigraphic framework. Many karst aquifers are included in cyclic platform carbonates. Clearly, a cyclostratigraphic approach that translates carbonate aquifer heterogeneity into a consistent framework of correlative units will improve simulation of karst groundwater flow. ?? 2006 Geological Society of America.

Southern Florida↗

USGS2022

Mapping aquifer salinity gradients and effects of oil field produced water disposal using geophysical logs: Elk Hills, Buena Vista and Coles Levee Oil Fields, San Joaquin Valley, California

The effects of oil and gas production on adjacent groundwater quality are becoming a concern in many areas of the United States. As a result, it has become increasingly important to identify which aquifers require monitoring and protection. In this study, we map the extent of groundwater with less than 10,000 mg/L TDS both laterally and vertically near the Elk Hills, Buena Vista and Coles Levee Oil Fields in the San Joaquin Valley, California and note evidence of effects of produced water disposal on salinity within the Tulare aquifer. Subsurface maps showing the depth at which groundwater salinity is less than 10,000 mg/L (or Base 10K) in the Tulare aquifer are generated using geophysical logs and verified by comparison to water sample analyses. The depth to Base 10K ranges from 240 m (800 ft) in Elk Hills to 800 m (2650 ft) in the adjacent Buena Vista syncline and is 670 m (2,200 ft) deep in the Coles Levee area to the east. Log-calculated salinities show a relatively smooth increase with depth prior to disposal activities whereas salinities calculated from logs collected near and after disposal activities show a more variable salinity profile with depth. The effect of produced water injection is represented by log resistivity profiles that change from low resistivity at the base of the sand to higher resistivity near the top due to density differences between the saline produced water and the brackish groundwater within each sand. Continued post-disposal logging in new wells in the 18G disposal area on the south flank of Elk Hills shows that injected water has migrated approximately 1,200 m (4,000 ft) downdip (south) over a period of 20 years since the inception of disposal activity.

California↗

USGS2020

Analysis of aquifer framework and hydraulic properties of Lovelock Valley, Lovelock, Nevada

Multiple aquifer tests were conducted in Lovelock, Nevada, to determine hydraulic conductivity and storage properties to be used with the numerical groundwater flow model of the lower Humboldt River Basin while accounting for the influence of surface features with a modeling component. The numerical model will ultimately provide the Nevada Division of Water Resources (NDWR) with information regarding the impacts of groundwater pumping on the Humboldt River, allowing the Nevada State Engineer to make informed decisions in the conjunctive management of the State’s groundwater and surface water resources. Seven slug tests, one single-well pumping test, and two multi-well pumping tests were conducted to evaluate properties of shallow Lahontan clays and silts; shallow fluvial deposits; and coarser, water-bearing deposits of the younger alluvium. Aquifer tests were conducted between March 2017 and April 2018. Results indicate aquifers in the Lovelock Valley have transmissivity ranging between 0.0001 and 95,000 feet squared per day (ft 2 /day). The results of these tests provide constraints on hydraulic properties for a numerical groundwater flow model being developed for a capture study in the lower Humboldt River Basin.

Nevada↗

USGS2023

Chromium in minerals and selected aquifer materials

Between 1952 and 1964, hexavalent chromium, Cr(VI), was released into groundwater from a Pacific Gas and Electric Company (PG&E) compressor station in Hinkley, California, in the western Mojave Desert 80 miles northeast of Los Angeles, California. In 2015, the extent of anthropogenic Cr(VI) in groundwater in Hinkley and Water Valleys was uncertain, but some Cr(VI) in groundwater may be naturally occurring from rock and aquifer material. To evaluate potential sources of natural Cr(VI), chromium and other selected trace-element concentrations were measured by inductively coupled plasma-mass spectrometry (ICP-MS), with multi-acid digestion, on 34 samples of surficial alluvium and core material from Hinkley and Water Valleys, California, and on 2 samples of alluvium from the mafic Sheep Creek fan to the southwest. Chromium concentrations in Hinkley and Water Valleys ranged from 2 to 110 milligrams per kilogram (mg/kg), with a median concentration of 14 mg/kg; concentrations were highest in weathered mafic hornblende diorite associated with Iron Mountain. High chromium concentrations also were present within fine-textured materials and visually abundant iron- and manganese-oxide coatings on the surfaces of mineral grains. For comparison, chromium concentrations as high as 170 mg/kg were measured in mafic alluvium from the Sheep Creek fan. In contrast, chromium concentrations were lowest in Mojave-type deposits (Mojave River stream and lake margin deposits), with a median of 6 mg/kg. Chromium concentrations measured by ICP-MS compared favorably with concentrations measured by portable (handheld) X-ray fluorescence (pXRF; chapter B), on the basis of least-squares regression results and a coefficient of determination (R 2 ) of 0.97. Minerals in bulk samples and the heavy (dense) mineral fractions isolated from those samples were identified using optical techniques, X-ray diffraction (XRD), and scanning electron microscopy (SEM). Quartz and feldspar were the most abundant minerals, especially within recent and older Mojave River deposits. Chromium concentrations were as high as 1,250 mg/kg in the heavy-mineral fraction, with specific gravity greater than 3.32. Chromium was not commonly detected in the light-mineral fraction, with specific gravity less than 2.85. Most chromium within the heavy-mineral fraction was substituted within magnetite mineral grains less than 100 micrometers (μm) in diameter, and almost no chromite was present within the heavy-mineral fraction. Although magnetite is resistive to weathering, weathering of magnetite to hematite was identified (1) in Miocene materials underlying unconsolidated deposits in the western subarea of Hinkley Valley and (2) in alluvium within Water Valley that contains weathered minerals eroded from Miocene rock. Less-dense, more easily weathered chromium-containing amphiboles, such as actinolite in older Mojave River alluvium and hornblende in locally derived alluvium from Iron Mountain, were identified optically. Magnetite was not identified in weathered hornblende diorite and was less abundant in locally derived materials and in Miocene materials than in Mojave-type deposits. A comparison of ICP-MS data and sequential extraction data shows that approximately 90 percent of chromium in aquifer material within Hinkley and Water Valleys was not extractable and was interpreted to reside within unweathered mineral grains. Most extractable chromium was within the strong acid extractable fraction. Chromium within the weakly sorbed, and specifically sorbed extractable fractions in oxide accumulations within the regulatory Cr(VI) plume is potentially mobile into groundwater with changes in ionic strength or pH. Although Hinkley and Water Valleys are regionally low in chromium, natural geologic sources of chromium may be present in aquifer materials penetrated by wells completed in (1) weathered hornblende diorite bedrock underlying the western subarea; (2) Miocene deposits underlying the western subarea and unconsolidated material in the northern subarea and Water Valley containing basalt or weathered minerals eroded from Miocene deposits; (3) unconsolidated material containing visually abundant iron- and manganese-oxide coatings on the surfaces of mineral grains that are present near the water table and near lithologic or geologic contacts; and (4) brown clay and mudflat/playa deposits in the northern subarea. Brown clay and mudflat/playa deposits in the eastern subarea near Mount General have a low-chromium, felsic mineralogy similar to Mojave River deposits and do not contain high concentrations of chromium; however, manganese(IV) oxides within these materials may facilitate oxidation of trivalent chromium, Cr(III), to Cr(VI).

California↗