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Groundwater & aquifers

Find USGS groundwater and aquifer publications. Search an aquifer name or place, compare source-supplied dates and open reports for hydrogeology, recharge and water-level studies.

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USGS2019

Characterizing groundwater/surface-water interaction using hydrograph-separation techniques and groundwater-level data throughout the Mississippi Delta, USA

The Mississippi Delta, located in northwest Mississippi, is an area dense with industrial-level agriculture sustained by groundwater-dependent irrigation supplied by the Mississippi River Valley Alluvial aquifer (alluvial aquifer). The Delta provides agricultural commodities across the United States and around the world. Observed declines in groundwater altitudes and streamflow contemporaneous with increases in irrigation have raised concerns about future groundwater availability and the effects of groundwater withdrawals on streamflow. To quantify the impacts of groundwater withdrawals on streamflow and increase understanding of groundwater and surface-water interaction, hydrograph-separation techniques were used to estimate baseflow and identify statistical streamflow trends. The analysis was conducted using the U.S. Geological Survey Groundwater Toolbox open-source software and daily hydrologic data provided by a spatially-distributed network of paired groundwater wells and streamgaging sites. This study found that effects of groundwater withdrawals on streamflow were observed as statistically significant reductions in baseflow in areas with substantial groundwater-altitude declines. Hydrograph-separation and trend analyses may be applicable to assess the impacts of groundwater withdrawals in altered environments and streamflow may be used as a proxy for changes in groundwater availability. Characterizing and defining hydrologic relations between groundwater and surface water will help scientists and water-resource managers refine a regional groundwater-flow model that includes the Mississippi Delta that will be used to aid water-resource managers in future decisions concerning the alluvial aquifer.

Arkansas, Illinois, Kentucky, Louisiana, Mississip↗

USGS2014

Assessing the solubility controls on vanadium in groundwater, northeastern San Joaquin Valley, CA

The solubility controls on vanadium (V) in groundwater were studied due to concerns over possible harmful health effects of ingesting V in drinking water. Vanadium concentrations in the northeastern San Joaquin Valley ranged from <3 μg/L to 70 μg/L with a median of 21 μg/L. Concentrations of V were highest in samples collected from oxic groundwater (49% > 25 μg/L) and lowest in samples collected from anoxic groundwater (70% < 0.8 μg/L). In oxic groundwater, speciation modeling (SM) using PHREEQC predicted that V exists primarily as the oxyanion H 2 VO 4 − . Adsorption/desorption reactions with mineral surfaces and associated oxide coatings were indicated as the primary solubility control of V 5+ oxyanions in groundwater. Environmental data showed that V concentrations in oxic groundwater generally increased with increasing groundwater pH. However, data from adsorption isotherm experiments indicated that small variations in pH (7.4–8.2) were not likely as an important a factor as the inherent adsorption capacity of oxide assemblages coating the surface of mineral grains. In suboxic groundwater, accurate SM modeling was difficult since Eh measurements of source water were not measured in this study. Vanadium concentrations in suboxic groundwater decreased with increasing pH indicating that V may exist as an oxycationic species [e.g. V(OH) 3 + ]. Vanadium may complex with dissolved inorganic and organic ligands under suboxic conditions, which could alter the adsorption behavior of V in groundwater. Speciation modeling did not predict the existence of V-inorganic ligand complexes and organic ligands were not collected as part of this study. More work is needed to determine processes governing V solubility under suboxic groundwater conditions. Under anoxic groundwater conditions, SM predicts that aqueous V exists as the uncharged V(OH) 3 molecule. However, exceedingly low V concentrations show that V is sparingly soluble in anoxic conditions. Results indicated that V may be precipitating as V 3+ - or mixed V 3+ /Fe 3+ -oxides in anoxic groundwater, which is consistent with results of a previous study. The fact that V appears insoluble in anoxic (Fe reducing) redox conditions indicates that the behavior of V is different than arsenic (As) in aquifer systems where the reductive dissolution of Fe-oxides with As adsorbed to the surface is a well-documented mechanism for increasing As concentrations in groundwater. This hypothesis is supported by the relation of V to As concentrations in oxic versus anoxic redox conditions. Sequential extraction procedures (SEP) applied to aquifer material showed that the greatest amount of V was recovered by the nitric acid (HNO 3 ) extract (37–71%), followed by the oxalate-ascorbic acid extract (19–60%) and the oxalate extract (3–14%). These results indicate that V was not associated with the solid phase as an easily exchangeable fraction. Although the total amount of V recovered was greatest for the HNO 3 extract that targets V adsorbed to sorption sites of crystalline Al, Fe and Mn oxides, the greatest V saturation of sorption sites appeared to occur on the amorphous and poorly crystalline oxide solid phases targeted by the oxalate and oxalate-ascorbic acid extracts respectively. Adsorption isotherm experiments showed no correlation between V sorption and any of the fractions identified by the SEP. This lack of correlation indicates the application of an SEP alone is not adequate to estimate the sorption characteristics of V in an aquifer system.

California↗

USGS2020

Regional hydrostratigraphic framework of Joint Base McGuire-Dix-Lakehurst and vicinity, New Jersey, in the context of perfluoroalkyl substances contamination of groundwater and surface water

A study was conducted by the U.S. Geological Survey, in cooperation with the U.S. Air Force, to describe the regional hydrostratigraphy of shallow aquifers and confining units underlying Joint Base McGuire-Dix-Lakehurst (JBMDL) and vicinity, New Jersey, in the context of contamination of groundwater and surface water by per- and polyfluoroalkyl substances (PFAS) potentially originating from JBMDL sources. The aquifers studied are two that crop out within JBMDL boundaries—the Kirkwood-Cohansey aquifer system and the Vincentown aquifer—and another aquifer near JBMDL that does not crop out at land surface—the Piney Point aquifer. The unconfined portion of the Vincentown aquifer and portions of the Kirkwood-Cohansey aquifer system that overlie the unconfined portion of the Vincentown aquifer are consolidated into, and described as, a single, separate unconfined aquifer system. Regionally extensive clay subunits that potentially create semiconfined hydrologic conditions within the mostly unconfined Kirkwood-Cohansey aquifer system also are identified. Two confining units were studied—the Manasquan-Shark River confining unit underlying the Kirkwood-Cohansey aquifer system, which includes the basal confining sediment in the Kirkwood Formation, and the Navesink-Hornerstown confining unit underlying the Vincentown aquifer. The hydrostratigraphic units are defined using available borehole geophysical logs, lithologic logs, and (or) drillers’ logs from 131 wells and are presented in a series of 8 aquifer structure maps and 12 cross sections. The framework positions JBMDL into a regional hydrostratigraphic structure for which higher-resolution delineation of the shallow aquifers can be constructed to determine potential pathways of PFAS contamination in groundwater to off-site drinking water wells in areas adjacent to JBMDL.

New Jersey↗

USGS2018

Groundwater conditions in Georgia, 2015–16

The U.S. Geological Survey collects groundwater data and conducts studies to monitor hydrologic conditions, define groundwater resources, and address problems related to water supply, water use, and water quality. In Georgia, water levels were monitored continuously at 157 wells during calendar years 2015 and 2016. Because of missing data or short periods of record (less than 5 years) for several of these wells, data for 147 wells are presented in this report. These wells include 15 in the surficial aquifer system, 18 in the Brunswick aquifer system and equivalent sediments, 59 in the Upper Floridan aquifer, 13 in the Lower Floridan aquifer and underlying units, 9 in the Claiborne aquifer, 1 in the Gordon aquifer, 8 in the Clayton aquifer, 16 in the Cretaceous aquifer system, 2 in Paleozoic-rock aquifers, and 6 in crystalline-rock aquifers. Data from the well network indicate that water levels generally rose during the 10-year period from 2007 through 2016, with water levels rising in 105 wells and declining in 31 wells; insufficient data prevented determination of a 10-year trend in 11 wells. Water levels declined over the long-term period of record at 80 wells, increased at 62 wells, and remained relatively constant at 5 wells. In addition to continuous water-level data, periodic water-level data were collected and used to construct potentiometric-surface maps for the Upper Floridan aquifer in the Brunswick–Glynn County area during October 2015 and October 2016 and in the Albany–Dougherty County area during December 2015 and November and December 2016. Periodic water-level measurements were also collected and used to construct potentiometric-surface maps for the Cretaceous aquifer system in the Augusta–Richmond County area during July 2015 and June 2016. In general, water levels in the Upper Floridan aquifer were higher during 2015 than during 2016 in the Brunswick–Glynn County and Albany–Dougherty County areas due to higher precipitation during 2015. Water levels were lower, however, during 2015 than during 2016 in the Cretaceous aquifer system in the Augusta–Richmond County area. In the Brunswick area, maps showing the chloride concentration of water in the Upper Floridan aquifer constructed using data collected from 33 wells during October 2015 and from 30 wells during October 2016 indicate that chloride concentrations remained above the U.S. Environmental Protection Agency’s secondary drinking-water standard in an approximately 2-square-mile area. During calendar years 2015–16, chloride concentrations generally were similar to those measured during 2012–14; however, some wells did show an increase in chloride concentration, likely due to increases in pumping.

Georgia↗

USGS2021

The triple argon isotope composition of groundwater on ten-thousand-year timescales

Understanding the age and movement of groundwater is important for predicting the vulnerability of wells to contamination, constraining flow models that inform sustainable groundwater management, and interpreting geochemical signals that reflect past climate. Due to both the ubiquity of groundwater with order ten-thousand-year residence times and its importance for climate reconstruction of the last glacial period, there is a strong need for improving geochemical dating tools on this timescale. Whereas 14 C of dissolved inorganic carbon and dissolved 4 He are common age tracers for Late Pleistocene groundwater, each is limited by systematic uncertainties related to aquifer composition and lithology, and the extent of water-rock interaction. In principle, radiogenic 40 Ar in groundwater acquired from decay of 40 K in aquifer minerals should be insensitive to some processes that impact 14 C and 4 He and thus represent a useful, complementary age tracer. In practice, however, detection of significant radiogenic 40 Ar signals in groundwater has been limited to a small number of studies of extremely old groundwater (>100 ka). Here we present the first high-precision (<1‰) measurements of triple Ar isotopes ( 40 Ar, 38 Ar, 36 Ar) in groundwater. We introduce a model that distinguishes radiogenic 40 Ar from atmospheric 40 Ar by using the non-radiogenic Ar isotopes ( 36 Ar, 38 Ar) to correct for mass-dependent fractionation. Using this model, we investigate variability in radiogenic 40 Ar excess (Δ 40 Ar) across 58 groundwater samples collected from 36 wells throughout California (USA). We find that Δ 40 Ar ranges from ~0‰ (the expected minimum value) to +4.2‰ across three study areas near Fresno, San Diego, and the western Mojave Desert. Based on measurements from a network of 23 scientific monitoring wells in San Diego, we find evidence for a strong dependence of Δ 40 Ar on aquifer lithology. We suggest that Δ 40 Ar is fundamentally controlled by the weathering of old K-bearing minerals and thus reflects both the degree of groundwater-rock interaction, which is related to groundwater age, and the integrated flow through different geological formations. Future studies of Late Pleistocene groundwater may benefit from high-precision triple Ar isotope measurements as a new tool to better interpret 14 C- and 4 He-based constraints on groundwater age and flow.

Chemical Geology↗

USGS2012

Aquifer test at well SMW-1 near Moenkopi, Arizona

The Hopi villages of Lower Moencopi and Upper Moenkopi are on the Hopi Indian Reservation south of Tuba City in northern Arizona. These adjacent Hopi villages, located west and north of the confluence of Pasture Canyon Wash and Moenkopi Wash, are dependent on groundwater withdrawals from three wells that penetrate the N aquifer and from two springs that discharge from the N aquifer. The N aquifer is the principal aquifer in this region of northern Arizona and is composed of thick beds of sandstone between less permeable layers of siltstone and mudstone. The fine-grained character of the N aquifer inhibits rapid movement of water and large yields to wells; however, the aquifer is moderately productive at yields generally less than 25 gallons per minute in the study area. In recent years, the water level has declined in the three public-supply wells and the flow from the springs has decreased, causing concern that the current water supply will not be able to accommodate peak demand and allow for residential and economic growth. In addition to the challenge imposed by declining groundwater levels, the water-supply wells and springs are located about 2 miles downgradient from the Tuba City Landfill site where studies are ongoing to determine if uranium and other metals in groundwater beneath the landfill are higher than regional concentrations in the N aquifer. In August 2008, the U.S. Geological Survey, in cooperation with the Hopi Tribe, conducted an aquifer test on well SMW-1, designed to help the Hopi Tribe determine the potential yield and water quality of the N aquifer south of Moenkopi Wash as a possible source of additional water supply. Well SMW-1 was drilled south of Moenkopi Wash to a depth of 760 feet below land surface before being backfilled and cased to about 300 feet. The well penetrates, in descending order, the Navajo Sandstone and the Kayenta Formation, both units of the N aquifer. The pre-test water level in the well was 99.15 feet below land surface. A 9.25-hour step-drawdown test and a 72-hour constant-rate test followed by recovery tests were used to investigate the performance of the test well and to estimate the transmissivity and potential yield of the N aquifer south of Moenkopi Wash. The test data were analyzed using the Cooper-Jacob method adjusted for confined conditions, the Papadopulos-Cooper method that accounts for wellbore storage, and the Theis method on the recovery data. Results of the tests indicate that in the vicinity of the well, the N aquifer has a transmissivity of about 50 feet squared per day. The test well, as completed, should yield about 15 gallons per minute with about 75 feet of drawdown (less than half of the available saturated thickness of the aquifer at the well).

Arizona↗

USGS2021

Development of a groundwater-simulation model in the Los Angeles Coastal Plain, Los Angeles County, California

Executive Summary The Los Angeles Coastal Plain (LACP) covers about 580 square miles and is the largest coastal plain of semiarid southern California. The LACP is heavily developed with mostly residential, commercial, and industrial land uses that rely heavily on groundwater for water supply. In 2010, the LACP was home to about 14 percent of California’s population, or about 5.4 million residents. The LACP is also a major commercial and industrial hub with industries including manufacturing, aerospace, entertainment, and tourism. There has been a heavy reliance on groundwater from the LACP for many years. An average of 305,000 acre-feet per year (acre-ft/yr) of groundwater was used annually from the LACP from 1971 to 2015. The need to replenish the groundwater basins within the LACP was recognized as far back as the 1930s, when spreading grounds were first used to replenish groundwater basins and store water underground during times of water surplus to meet demands in times of shortage. Seawater intrusion resulting from freshwater pumping was first observed in the 1940s. As a result, injection of imported water through wells at what is now the West Coast Basin Barrier Project began on an experimental basis in 1951. Managed aquifer recharge from the spreading grounds and barrier wells is now a substantial component of the LACP’s groundwater supply. The average annual recharge from water spreading from 1971 to 2015 was about 120,000 acre-ft/yr, and the average annual injection into the barrier wells was about 33,000 acre-ft/yr. Other inflows include areal recharge, underflow from San Gabriel and San Fernando Valleys, and onshore flow from the ocean. The average annual recharge from these sources was 100,000 acre-feet (acre-ft) from 1971 to 2015. Additionally, cross-boundary flow from Orange County into the western Orange County subareas of the LACP was simulated as 48,000 acre-ft from 1971 to 2015. This study, conducted in cooperation with the Water Replenishment District of Southern California (WRD), involved an assessment of the historical and present status of groundwater resources in the LACP and the development of tools to better understand the groundwater system. These efforts were built upon results from previous studies and incorporate new information and developments in modeling capabilities to provide a more detailed analysis of the aquifer systems. This study includes a comprehensive compilation of geologic and hydrologic data (Chapter A), development of a chronostratigraphic model that provides a detailed description of the LACP aquifer systems (Chapter B), characterization of the groundwater hydrology of the LACP, including a down-hole analysis of grain size using lithologic and geophysical logs (Chapter C), and development and application of the Los Angeles Coastal Plain Groundwater-flow Model (LACPGM) to simulate past groundwater conditions, estimate groundwater-budget components and flow paths, and approximate future groundwater conditions under different scenarios (Chapter D).

California↗

USGS2019

Timescales of water-quality change in a karst aquifer, south-central Texas

Understanding the drivers and timescales over which groundwater quality changes informs groundwater management, use, and protection. To better understand timescales of water-quality change over short (daily to monthly) and long (seasonal to decadal) timescales, the U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Enhanced Trends Network (ETN) program instrumented and sampled three wells in the Edwards aquifer in south-central Texas. The wells were instrumented to provide high-frequency continuous (subhourly) water-quality data (temperature, pH, specific conductance, and dissolved oxygen), which were augmented by the collection of discrete samples (about 6 per year) for a range of geochemical constituents (including selected isotopes and age tracers). ETN data (2013–2017) are considered with data from additional sites for the same time period, and also historical records (over more than 80 years) of climatic and hydrologic conditions. During the four-year study, hydrologic conditions transitioned from very dry to very wet. Sites in the updip/unconfined part of the aquifer showed notable changes in water level and geochemistry (1) in response to rainfall/recharge events, and (2) over the multiyear dry/wet cycle. Sites in the downdip/confined part of the aquifer showed changes in water level/spring discharge over similar timescales, although the response is more muted. Geochemistry at the downdip/confined sites, however, varied slowly and minimally, indicating that the geochemical response of the deeper aquifer is decoupled from recent hydrologic responses. Changes at the updip/unconfined sites reflect mixing with recent recharge, whereas the downdip/confined sites were dominated by mineral-solution reactions resulting from longer (decadal) residence times. Mean groundwater ages interpreted from measured age tracers and lumped parameter models range from 7 to >700 years (where mixed with premodern downdip water) but were mostly modern. The aquifer is characterized by updip-to-downdip trends in geochemistry with respect to water-rock interaction and groundwater age. Fourier spectral analysis of historical records indicate hydrologic variability has occurred at dominant periods of 30 and 15 years; in conjunction with age tracers, these results provide insight into timescales at which the aquifer’s public supply is vulnerable to changes in the water quality of recharge.

Texas↗

USGS2012

Principal aquifers can contribute radium to sources of drinking water under certain geochemical conditions

What are the most important factors affecting dissolved radium concentrations in principal aquifers used for drinking water in the United States? Study results reveal where radium was detected and how rock type and chemical processes control radium occurrence. Knowledge of the geochemical conditions may help water-resource managers anticipate where radium may be elevated in groundwater and minimize exposure to radium, which contributes to cancer risk. Summary of Major Findings: * Concentrations of radium in principal aquifers used for drinking water throughout the United States generally were below 5 picocuries per liter (pCi/L), the U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL) for combined radium - radium-226 (Ra-226) plus radium-228 (Ra-228) - in public water supplies. About 3 percent of sampled wells had combined radium concentrations greater than the MCL. * Elevated concentrations of combined radium were more common in groundwater in the eastern and central United States than in other regions of the Nation. About 98 percent of the wells that contained combined radium at concentrations greater than the MCL were east of the High Plains. * The highest concentrations of combined radium were in the Mid-Continent and Ozark Plateau Cambro-Ordovician aquifer system and the Northern Atlantic Coastal Plain aquifer system. More than 20 percent of sampled wells in these aquifers had combined radium concentrations that were greater than or equal to the MCL. * Concentrations of Ra-226 correlated with those of Ra-228. Radium-226 and Ra-228 occur most frequently together in unconsolidated sand aquifers, and their presence is strongly linked to groundwater chemistry. * Three common geochemical factors are associated with the highest radium concentrations in groundwater: (1) oxygen-poor water, (2) acidic conditions (low pH), and (3) high concentrations of dissolved solids.

Fact Sheet↗

USGS1994

Potentiometric surface of the upper Floridan aquifer system, west-central Florida, May 1993

The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by a middle confining unit. The potentiometric surface of the Upper Floridan aquifer was mapped by determining the altitude of water levels in a network of wells and represented on a map by contours that connect points of equal altitude. This map represents water-level conditions near the end of the spring dry season when groundwater withdrawals for agricultural use were high. The cumulative rainfall for the study area was 4.84 inches above normal for the period from June 1992 to May 1993. Hydrographs of selected wells generally indicated that water levels in wells north of the Hillsborough/Pasco County line (northern area), where the aquifer generally is unconfined and groundwater withdrawals are relatively small, remained fairly uniform from year to year and season to season, whereas water levels south of the county line (southern area), where the aquifer is confined and withdrawals are relatively large, showed large year-to-year and seasonal fluctuations. Maximum daily water levels for selected wells from May 1992 through May 1993 showed that water levels were relatively stable during May 1993 in the northern part of the study area, but were declining rapidly in the southern part. Water levels in most wells measured in May 1993 were lower than those measured in September 1992. The greatest decline in water levels occurred in southern Hillsborough, central Manatee, and northern Sarasota Counties as a result of heavy seasonal groundwater withdrawals for irrigation. Water levels measured in May 1993 were generally higher than those reported for May 1992. The general increase in water levels during this period was largely the result of above-normal rainfall that resulted in below-average seasonal groundwater withdrawals from the aquifer.

Open-File Report↗

USGS2011

River-aquifer exchanges in the Yakima River basin, Washington

Five categories of data are analyzed to enhance understanding of river-aquifer exchanges-the processes by which water moves between stream channels and the adjacent groundwater system-in the Yakima River basin. The five datasets include (1) results of chemical analyses of water for tritium (3H, a radioactive isotope of hydrogen) and the ratios of the stable isotopes of hydrogen (2H/1H) and oxygen (18O/16O), (2) series of stream discharge measurements within specified reaches (seepage investigations or 'runs'), (3) vertical hydraulic gradients (between stream stage and hydraulic heads the underlying aquifer) measured using mini-piezometers, (4) groundwater levels and water temperature in shallow wells near stream channels, and (5) thermal profiles (continuous records of water temperature along river reaches). Exchanges are described in terms of streamflow, vertical hydraulic gradients, groundwater temperature and levels, and streamflow temperature, and where appropriate, the exchanges are discussed in terms of their relevance to and influence on salmonid habitat. The isotope data shows that the ultimate source of surface and groundwater is meteoric water derived from atmospheric precipitation. Water from deep wells has a different isotopic composition than either shallow groundwater or surface water, indicating that the deep groundwater system contributes, at most, only a small component of the surface-water discharge. The isotope data confirms that river-aquifer exchanges involve primarily modern streamflow and modern, shallow groundwater. Net exchanges of water for 46 stream sections investigated with seepage runs ranged from nearly zero to 1,071 ft3/s for 28 gaining sections, and -3 to -242 ft3/s for 18 losing sections. The magnitude of the upper 50 percent of the net gains is an order of magnitude larger than those for net losses. The sections have a normalized net exchange (as absolute value) that fully ranged from near 0 to 65.6 (ft3/s)/mi. Gaining-section values ranged from about 0.1 to 65.6 (ft3/s)/mi, and losing section values ranged from about -0.1 to -35.4 (ft3/s)/mi. Gains are much more vigorous than the losses with 55 percent being larger than 3.0 (ft3/s)/ mi, whereas, only 6 percent of the negative net exchanges were larger than 3.0 (ft3/s)/mi. Gains and losses for 167 measured reaches within the 46 sections ranged from about 70 to -75 (ft3/s)/mi, and ranged more than 5 orders of magnitude. The median values for the gains and losses were 5.1 and -4.4 (ft3/s)/mi, respectively. The magnitude of the gains was larger than the losses; more than 40 percent of the gains were greater than 10 (ft3/s)/mi, and only about 25 percent of the losses were greater than 10 (ft3/s)/mi. Reaches with large gains are identified and these reaches represent potentially important areas for various life stages of salmonids and possibly for preservation or restoration of that habitat. Ninety-nine measurements of vertical hydraulic gradients (VHGs) were made using mini-piezometers. The median for the measurements was -0.35 ft/ft (negative values indicate downward flow), and in terms of absolute values, the median was 0.05 ft/ft. The VHGs tended to be small. Seventy VHG values were negative (indicating streamflow losses), and 29 were positive (indicating streamflow gains). VHGs vary more than 4 orders of magnitude, and in terms of magnitudes, 65 percent were less than 0.1 ft/ft. The negative VHG values are not only more prevalent but are larger than the positive values. The magnitudes of almost 50 percent of the negative VHGs are greater than 0.05 ft/ft and only 33 percent of the positive VHGs are greater than 0.05 ft/ft. The percentile distribution of the VHG data, which is similar to the shape of the seepage data distribution, shows that beyond the 80th percentile, the positive values become much larger, indicating that the largest VHGs have a different controlling mechanism. The VHGs were formulated in terms of fluxes per unit are

Scientific Investigations Report↗

USGS2017

Hydrogeologic and geochemical characterization and evaluation of two arroyos for managed aquifer recharge by surface infiltration in the Pojoaque River Basin, Santa Fe County, New Mexico, 2014–15

In order to provide long-term storage of diverted surface water from the Rio Grande as part of the Aamodt water rights settlement, managed aquifer recharge by surface infiltration in Pojoaque River Basin arroyos was proposed as an option. The initial hydrogeologic and geochemical characterization of two arroyos located within the Pojoaque River Basin was performed in 2014 and 2015 in cooperation with the Bureau of Reclamation to evaluate the potential suitability of these two arroyos as sites for managed aquifer recharge through surface infiltration. The selected reaches were high-gradient (average 3.0–3.5 percent) braided channels filled with unconsolidated sand and gravel-sized deposits that were generally 30–50 feet thick. Saturation was not observed in the unconsolidated channel sands in four subsurface borings but was found at 7–60 feet below the contact between the unconsolidated channel sands and the bedrock. The poorly to well-cemented alluvial deposits that make up the bedrock underlying the unconsolidated channel material is the Tesuque Formation. The individual beds of the Tesuque Formation are reported to be highly heterogeneous and anisotropic, and the bedrock at the site was observed to have variable moisture and large changes in lithology. Surface electrical-resistivity geophysical survey methods showed a sharp contrast between the electrically resistive unconsolidated channel sands and the highly conductive bedrock; however, because of the high conductivity, the resistivity methods were not able to image the water table or preferential flow paths (if they existed) in the bedrock. Infiltration rates measured by double-ring and bulk infiltration tests on a variety of channel morphologies in the study reaches were extremely large (9.7–94.5 feet per day), indicating that the channels could potentially accommodate as much as 6.6 cubic feet per second of applied water without generating surface runoff out of the reach; however, the small volume available for storage in the unconsolidated channel sands (about 410 acre-feet in the east arroyo and about 190 acre-feet in the west arroyo) and the potential for the infiltrating water to preferentially flow over the bedrock contact and out of the reach present a challenge for storing water. Although a detailed assessment of the infiltration rate of the Tesuque Formation is beyond the scope of this investigation, one double-ring infiltrometer test was conducted on an outcrop, resulting in an estimated infiltration rate of about 4 feet per day. The shallow groundwater observed in this investigation was determined to be recharged locally on the basis of groundwater elevations and geochemical and isotopic signatures. The channel sands and shallow bedrock were observed to be weathered, indicating contact with oxic groundwater following deposition. This observation was supported by whole-rock elemental analysis and mineralogy of several core samples. The downward groundwater gradient between the shallow wells and those wells screened at greater depths suggests that the shallow groundwater is recharged by local precipitation and has the potential to migrate to the deeper aquifer units. The two age-dating tracers measured in this investigation, however, demonstrate that the shallow groundwater flow paths are very slow and that the deeper flow paths are likely part of a larger regional system. The composition of the shallow, native groundwater suggests that storing water diverted from the Rio Grande is not likely to leach constituents of concern that would cause the stored water to exceed health-based U.S. Environmental Protection Agency Maximum Contaminant Levels.

New Mexico↗

USGS2017

Hydrogeology and water quality of sand and gravel aquifers in McHenry County, Illinois, 2009–14, and comparison to conditions in 1979

Baseline conditions for the sand and gravel aquifers (groundwater) in McHenry County, Illinois, were assessed using data from a countywide network of 44 monitoring wells collecting continuous water-level data from 2009–14. In 2010, water-quality data were collected from 41 of the monitoring wells, along with five additional monitoring wells available from the U.S. Geological Survey National Water Quality Assessment Program. Periodic water-quality data were collected from 2010–14 from selected monitoring wells. The continuous water-level data were used to identify the natural and anthropogenic factors that influenced the water levels at each well. The water-level responses to natural influences such as precipitation, seasonal and annual variations, barometric pressure, and geology, and to anthropogenic influences such as pumping were used to determine (1) likely hydrogeologic setting (degree of aquifer confinement and interconnections) that, in part, are related to lithostratigraphy; and (2) areas of recharge and discharge related to vertical flow directions. Water-level trends generally were determined from the 6 years of data collection (2009–14) to infer effects of weather variability (drought) on recharge. Precipitation adds an estimated 2.4 inches per year of recharge to the aquifer. Some of this recharge is subsequently discharged to streams and some is discharged to supply wells. A few areas in the eastern half of the county had higher average recharge rates, indicating a need for adequate protection of these recharge areas. Downward vertical flow gradients in upland areas indicate that recharge to the confined aquifer units occurs near upland areas. Upward vertical flow gradients in lowland areas indicate discharge at locations of surface water and groundwater interaction (wetlands, ponds, and streams). Monitoring wells were sampled for major and minor ions, metals, and nutrients and a subset of wells was sampled for trace elements, dissolved gases, pesticides, and volatile organic compounds. The results were compared to health ‑ based and aesthetically based standards, which include the U.S. Environmental Protection Agency Maximum Contaminant Level (EPA MCL), and EPA Secondary Maximum Contaminant Levels (SMCL), as well as EPA Health-based Standards Drinking Water Advisories. Health‑based standards were exceeded for arsenic in 22 percent, sodium in 20 percent, and nitrates in 2 percent of the monitoring wells sampled. Aesthetically based standards were exceeded for total dissolved solids in 33 percent, chloride in 11 percent, iron in 85 percent, and manganese in 30 percent of the wells sampled. Many of these same constituents, such as arsenic, iron, and manganese, are naturally occurring but become elevated in areas that have anoxic, mixed, and suboxic conditions. Some areas of potential vulnerability to anthropogenic-sourced constituents in the sand and gravel aquifers were evidenced by trace amounts of volatile organic compounds and pesticides detected in water-quality samples from shallow wells (total depth less of than 46 feet below land surface) near urban settings, and by the detection of elevated major ions (chloride, sodium, magnesium, and calcium) associated, in part, with road-salt applications. Source analysis for chloride indicates mixtures of road salt, water softeners, and sewage. Continuously measured specific conductance values were used as a surrogate for continuously measured chloride concentrations in the groundwater. The estimated chloride concentrations generally were highest in spring and lowest in summer, and occasionally peak during spring melt. Overall, the range of concentrations varied depending on the local thickness and hydraulic conductivity of the aquifer. Water levels and water quality from the countywide groundwater monitoring network were compared to water levels and water-quality results in 1979 from a previous U.S. Geological Survey study. Potentiometric surface maps show areas with inferred decreases of water levels near the southern and southeastern areas of McHenry County. Significant increases were noted for total dissolved solids and specific conductance. Chloride concentrations increased as much as 521 percent in three of six wells resampled in 2015 from the previous study.

Illinois↗

USGS2019

Tritium as an indicator of modern, mixed, and premodern groundwater age

Categorical classification of groundwater age is often used for the assessment and understanding of groundwater resources. This report presents a tritium-based age classification system for the conterminous United States based on tritium ( 3 H) thresholds that vary in space and time: modern (recharged in 1953 or later), if the measured value is larger than an upper threshold; premodern (recharged prior to 1953) if the measured value is smaller than a lower threshold; or mixed if the measured value is between the two thresholds. Inclusion of spatially varying thresholds, rather than a single threshold, accounts for the observed systematic variation in 3 H deposition across the United States. Inclusion of time-varying thresholds, rather than a single threshold, accounts for the date of sampling given the radioactive decay of 3 H. The efficacy of the tritium-based age classification system was evaluated at national and regional scales. The system was evaluated at a national scale by classifying samples from 1,788 public-supply wells distributed across 19 principal aquifers and comparing those results with expectations based on hydrogeologic principles. The regional-scale data are from five paired networks of shallow and deep wells (287 wells). As expected, modern groundwater is more prevalent in shallow wells than in deeper wells, in fractured-rock and carbonate aquifers as compared to clastic aquifers, in unconfined areas as compared to confined areas, and in humid climates as compared to arid climates. The results from a tritium-based age classification system compared favorably with the results of 14 previous studies of groundwater ages that used different age tracers and analytical methods. The wells and samples from the Cambrian-Ordovician aquifer that had been analyzed using a more complex multi-tracer analysis were also analyzed using the tritium-based age classification system, and there was a close match between the two methods. The results from these various studies suggest that the tritium-based age classification system may be informative as a screening tool prior to selecting more expensive and complex age-dating tracers and methods, or to provide an explanatory variable for other water-quality data where more complex methods or tracers are not available. This work improves on previous groundwater age classification using 3 H by developing methods that (1) determine 3 H thresholds for groundwater recharged in 1953 or later that minimize the misclassification of modern samples as mixed; (2) determine a pre-1953 threshold to estimate premodern background concentrations; and (3) add a mixed category to classify samples that are clearly neither entirely modern nor entirely premodern. As with any tritium-based approach, it can fail when the 3 H record in precipitation does not accurately reflect the record of 3 H in recharge

Conterminous United States↗

USGS2021

Utilizing multiple hydrogeologic and anthropogenic indicators to understand zones of groundwater contribution to water-supply wells near Kirtland Air Force Base Bulk Fuels Facility in southeast Albuquerque, New Mexico

In 1999, a jet-fuels release was discovered at the Bulk Fuels Facility on Kirtland Air Force Base, Albuquerque, New Mexico. Contaminants had reached the water table and migrated north-northeast toward water-supply wells. Monitoring wells were installed downgradient from the facility to determine the primary zones of groundwater production for water-supply wells and assess contaminant presence. The monitoring wells are screened within the Santa Fe Group aquifer system, which includes clay units, at depths as great as 445 meters below land surface, and were categorized as water table, shallow, middle, deep, and aquifer-test pumping wells. Water-supply wells are screened across multiple water-bearing units within the aquifer system. All wells were sampled for major ions, trace elements, nutrients, stable isotopes, dissolved gases, tritium, carbon isotopes, and chlorofluorocarbons. The deeper and water-supply wells have evidence of longer groundwater residence times, as much as thousands of years, and water from the shallower wells shows evidence of anthropogenic nutrient inputs. Aquifer recharge is derived from either the mountain front or seepage from the Rio Grande. Dissolved-gas data indicate that the middle, deep, and aquifer-test pumping, and water-supply wells have cooler recharge temperatures than the shallower wells. Inferred groundwater age varies by method but indicates that the deeper, aquifer-test pumping, and water-supply wells have older water, as much as 15,000 years before present. Results indicate that the water-supply wells draw primarily from the middle and deeper portions of the aquifer system below the clay units and have not been affected by the contaminant plume, although some data indicate a potential for modern water entering some of the deeper and water-supply wells.

New Mexico↗

USGS2022

Data sources and methods for digital mapping of eight valley-fill aquifer systems in upstate New York

Digital hydrogeologic maps were developed in eight study areas in upstate New York by the U.S. Geological Survey in cooperation with the New York State Department of Environmental Conservation. The digital maps define the hydrogeologic framework of the valley-fill aquifers and surrounding till-covered uplands in the vicinity of the villages of Ellenville and Wurtsboro and hamlets of Woodbourne and South Fallsburg in Sullivan and Ulster Counties, town of Greene in Chenango County, city of Cortland and town of Cincinnatus in Cortland County, city of Jamestown in Chautauqua County, city of Olean and village of Ellicottville in Cattaraugus County, and villages of Fishkill and Wappinger Falls in Dutchess County. The hydrogeologic framework provided the foundation for groundwater-flow models that were used in the delineation of areas contributing groundwater flow to production wells screened in four of the eight valley-fill aquifers considered in this study. The hydrogeologic framework for the other four study areas was developed for potential future use in groundwater contributing-area studies. Data used in the creation of all digital surfaces and thicknesses included published surficial geology; aquifer maps and hydrogeologic sections; light detection and ranging (lidar) datasets; the Soil Survey Geographic Database; and lithologic well logs from the National Water Information System, New York State Department of Environmental Conservation, New York State Department of Transportation, and Empire State Organized Geologic Information System databases. Digital maps of the surficial geology; thickness of the surficial sand and gravel aquifers; and tops of the confining lacustrine silt and clay units, confined sand and gravel aquifers, and bedrock surfaces were created by using ArcGIS (a geographic information system). All surfaces and thicknesses were generated by using one of the following ArcGIS interpolation tools: Topo to Raster, Natural Neighbors, Kriging, or Empirical Bayesian Kriging. The datasets developed in this study provide a greater understanding of the underlying hydrogeologic framework in glacial valley-fill aquifers and can be applied in the evaluation of groundwater-supply development and protection.

New York↗

USGS2011

Documentation for the State Variables Package for the Groundwater-Management Process of MODFLOW-2005 (GWM-2005)

Many groundwater-management problems are concerned with the control of one or more variables that reflect the state of a groundwater-flow system or a coupled groundwater/surface-water system. These system state variables include the distribution of heads within an aquifer, streamflow rates within a hydraulically connected stream, and flow rates into or out of aquifer storage. This report documents the new State Variables Package for the Groundwater-Management Process of MODFLOW-2005 (GWM-2005). The new package provides a means to explicitly represent heads, streamflows, and changes in aquifer storage as state variables in a GWM-2005 simulation. The availability of these state variables makes it possible to include system state in the objective function and enhances existing capabilities for constructing constraint sets for a groundwater-management formulation. The new package can be used to address groundwater-management problems such as the determination of withdrawal strategies that meet water-supply demands while simultaneously maximizing heads or streamflows, or minimizing changes in aquifer storage. Four sample problems are provided to demonstrate use of the new package for typical groundwater-management applications.

Techniques and Methods↗

USGS2023

Advances in transboundary aquifer assessment

This Special Issue is intended to highlight both recent work to advance the physical understanding of transboundary aquifers and factors relevant in successful collaboration on transboundary groundwater resource use. The collected papers address: (1) the identification and prioritization of the needs and strategies for sustainable groundwater development and use, along with the complexities introduced by working across borders with differing governance frameworks, institutions, cultures, and sometimes languages; (2) the characterization of the physical framework of the aquifer, stressors on the aquifer system, and how those stressors influence the availability of groundwater in terms of its quantity and quality; and (3) the incorporation of stakeholder input and prioritization directly into the process of aquifer assessment and model building. The papers provide insights into the state of knowledge regarding the physical characterization of important transboundary aquifers, primarily along the U.S.–Mexico border and the opportunities for greater stakeholder involvement in resource evaluation and prioritization. They point the way towards a future focus that combines both of these aspects of transboundary aquifer assessment for informing groundwater management discussions by policymakers.

Water↗