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Groundwater & aquifers

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USGS2011

Water availability and use pilot: Methods development for a regional assessment of groundwater availability, southwest alluvial basins, Arizona

Executive Summary: Arizona is located in an arid to semiarid region in the southwestern United States and is one of the fastest growing States in the country. Population in Arizona surpassed 6.5 million people in 2008, an increase of 140 percent since 1980, when the last regional U.S. Geological Survey (USGS) groundwater study was done as part of the Regional Aquifer System Analysis (RASA) program. The alluvial basins of Arizona are part of the Basin and Range Physiographic Province and cover more than 73,000 mi 2 , 65 percent of the State's total land area. More than 85 percent of the State's population resides within this area, accounting for more than 95 percent of the State's groundwater use. Groundwater supplies in the area are expected to undergo further stress as an increasing population vies with the State's important agricultural sector for access to these limited resources. To provide updated information to stakeholders addressing issues surrounding limited groundwater supplies and projected increases in groundwater use, the USGS Groundwater Resources Program instituted the Southwest Alluvial Basins Groundwater Availability and Use Pilot Program to evaluate the availability of groundwater resources in the alluvial basins of Arizona. The principal products of this evaluation of groundwater resources are updated groundwater budget information for the study area and a proof-of-concept groundwater-flow model incorporating several interconnected groundwater basins. This effort builds on previous research on the assessment and mapping of groundwater conditions in the alluvial basins of Arizona, also supported by the USGS Groundwater Resources Program. Regional Groundwater Budget: The Southwest Alluvial Basins-Regional Aquifer System Analysis (SWAB-RASA) study produced semiquantitative groundwater budgets for each of the alluvial basins in the SWAB-RASA study area. The pilot program documented in this report developed new quantitative estimates of groundwater budget components using recent (2000-2007) data and methods of data analysis. Estimates of inflow components, including mountain-front recharge, incidental recharge from irrigation of agriculture, managed recharge from recharge facilities, interbasin underflow from upgradient basins, and streamflow losses, are quantified for recent time periods. Mountain-front recharge is the greatest inflow component to the groundwater system and was estimated using two methods: a basin characteristic model and new precipitation information used in a previously developed regression equation. Annual mountain-front recharge for the study area for 1940-2007 estimated by the two methods is 730,000 acre-ft for the basin characteristic model and 643,000 acre-ft for the regression equation, representing 1.5 percent and 1.3 percent of precipitation, respectively. Outflow components, including groundwater withdrawals, evapotranspiration, and interbasin flow to downgradient basins, are also presented for recent time periods. Groundwater withdrawals accounted for the largest share of the water budget, with nearly 2.4 million acre-ft per year withdrawn from the study area in recent years. Evapotranspiration from groundwater was estimated at nearly 1.3 million acre-ft per year for the study area using a newly developed method incorporating vegetation indices from satellite images and land cover information. For water-budget components with temporal variation that could be assessed from available data, estimates for intervening time periods since before development were also developed. An estimate of aquifer storage change, representing both gains to and losses from the groundwater system since before development, was derived for the most developed basins in the study area using available estimates of groundwater-level changes and storage coefficients. An overall storage loss of 74.5 million acre-ft was estimated for these basins within the study area. Demonstration

Arizona↗

USGS2020

Conjoint use of hydraulic head and groundwater age data to detect hydrogeologic barriers

Hydraulic head and groundwater age data are effective in building understanding of groundwater systems. Yet their joint role in detecting and characterising low-permeability geological structures, i.e. hydrogeologic barriers such as faults and dykes, has not been widely studied. Here, numerical flow and transport models, using MODFLOW-NWT and MT3D-USGS, were developed with different hydrogeologic barrier configurations in a hypothetical aquifer. Computed hydraulic head and groundwater age distributions were compared to those without a barrier. The conjoint use of these datasets helps in detecting vertically-oriented barriers. Two forms of recharge were compared: (1) applied across the entire aquifer surface (uniform), and (2) applied to the upstream part of the aquifer (upgradient). The hydraulic head distribution is significantly impacted by a barrier that penetrates the aquifer’s full vertical thickness. This barrier also perturbs the groundwater age distribution when upgradient recharge prevails; however, with uniform recharge, groundwater age is not successful in detecting the barrier. When a barrier is buried, such as by younger sediment, hydraulic head data also do not clearly identify the barrier. Groundwater age data could, on the other hand, prove to be useful if sampled at depth-specific intervals. These results are important for the detection and characterisation of hydrogeologic barriers, which may play a significant role in the compartmentalisation of groundwater flow, spring dynamics, and drawdown and recovery associated with groundwater extraction.

Hydrogeology Journal↗

USGS2012

Changes in sources and storage in a karst aquifer during a transition from drought to wet conditions

Understanding the sources and processes that control groundwater compositions and the timing and magnitude of groundwater vulnerability to potential surface-water contamination under varying meteorologic conditions is critical to informing groundwater protection policies and practices. This is especially true in karst terrains, where infiltrating surface water can rapidly affect groundwater quality. We analyzed the evolution of groundwater compositions (major ions and Sr isotopes) during the transition from extreme drought to wetconditions, and used inverse geochemical modeling (PHREEQC) to constrain controls on groundwater compositions during this evolution. Spring water and groundwater from two wells dominantly receiving diffuse and conduit flow (termed diffuse site and conduit site, respectively) in the Barton Springs segment of the Edwards aquifer (central Texas, USA) and surface water from losing streams that recharge the aquifer were sampled every 3–4 weeks during November 2008–March 2010. During this period, water compositions at the spring and conduit sites changed rapidly but there was no change at the diffuse site, illustrating the dual nature (i.e., diffuse vs. conduit) of flow in this karst system. Geochemical modeling demonstrated that, within a month of the onset of wetconditions, the majority of spring water and groundwater at the conduit site was composed of surface water, providing quantitative information on the timing and magnitude of the vulnerability of groundwater to potential surface-water contamination. The temporal pattern of increasing spring discharge and changing pattern of covariation between spring discharge and surface-water (steam) recharge indicates that that there were two modes of aquifer response—one with a small amount of storage and a second that accommodates more storage.

Texas↗

USGS1987

Simulation of flow in the Edwards Aquifer, San Antonio region, Texas, and refinement of storage and flow concepts

The Edwards aquifer is a complexly faulted, carbonate aquifer lying within the Balcones fault zone of south-central Texas. The aquifer is recharged mainly by streamflow losses in the outcrop area of the Edwards aquifer and is discharged by major springs located at considerable distances, as much as 150 mi, from the areas of recharge, and by wells. Groundwater flow within the Edwards aquifer of the San Antonio region was simulated to investigate concepts relating to the storage and flow characteristics. A general purpose, finite difference model, modified to provide the capability of representing barrier faults, was used to simulate groundwater flow and storage in the aquifer. The simulations investigated the effects of complex geologic structures and significant changes in transmissivity, anisotropy, and storage coefficient, with initial values based on concepts developed in previous studies. Results of the simulations confirmed the original estimates of transmissivity values (> 100 sq ft/sec) in the confined zone of the aquifer between San Antonio and Comal Springs. A storage coefficient of 0.05 in the unconfined zone of the aquifer produced the best simulation of water levels and springflow. A major interpretation resulting from the simulations is that two essentially independent areas of regional flow were identified in the west and central part of the study area. Flow from the two areas converges at Comal Springs. The directions of computed flux vectors reflected the presence of major barrier faults which locally deflect patterns of groundwater movement. The most noticeable deflection is the convergence of flow through the geologic structural opening, the Knippa gap, in eastern Uvalde County. A second significant interpretation is that groundwater flow in northeastern Bexar, Comal, and Hays Counties is diverted by barrier faults toward San Marcos Springs, a regional discharge point. (Lantz-PTT)

Texas↗

USGS2009

Hydrogeologic Framework of the Yakima River Basin Aquifer System, Washington

The Yakima River basin aquifer system underlies about 6,200 square miles in south-central Washington. The aquifer system consists of basin-fill deposits occurring in six structural-sedimentary basins, the Columbia River Basalt Group (CRBG), and generally older bedrock. The basin-fill deposits were divided into 19 hydrogeologic units, the CRBG was divided into three units separated by two interbed units, and the bedrock was divided into four units (the Paleozoic, the Mesozoic, the Tertiary, and the Quaternary bedrock units). The thickness of the basin-fill units and the depth to the top of each unit and interbed of the CRBG were mapped. Only the surficial extent of the bedrock units was mapped due to insufficient data. Average mapped thickness of the different units ranged from 10 to 600 feet. Lateral hydraulic conductivity (Kh) of the units varies widely indicating the heterogeneity of the aquifer system. Average or effective Kh values of the water-producing zones of the basin-fill units are on the order of 1 to 800 ft/d and are about 1 to 10 ft/d for the CRBG units as a whole. Effective or average Kh values for the different rock types of the Paleozoic, Mesozoic, and Tertiary units appear to be about 0.0001 to 3 ft/d. The more permeable Quaternary bedrock unit may have Kh values that range from 1 to 7,000 ft/d. Vertical hydraulic conductivity (Kv) of the units is largely unknown. Kv values have been estimated to range from about 0.009 to 2 ft/d for the basin-fill units and Kv values for the clay-to-shale parts of the units may be as small as 10-10 to 10-7 ft/d. Reported Kv values for the CRBG units ranged from 4x10-7 to 4 ft/d. Variations in the concentrations of geochemical solutes and the concentrations and ratios of the isotopes of hydrogen, oxygen, and carbon in groundwater provided information on the hydrogeologic framework and groundwater movement. Stable isotope ratios of water (deuterium and oxygen-18) indicated dispersed sources of groundwater recharge to the CRBG and basin-fill units and that the source of surface and groundwater is derived from atmospheric precipitation. The concentrations of dissolved methane were larger than could be attributable to atmospheric sources in more than 80 percent of wells with measured methane concentrations. The concentrations of the stable isotope of carbon-13 of methane were indicative of a thermogenic source of methane. Most of the occurrences of methane were at locations several miles distant from mapped structural fault features, suggesting the upward vertical movement of thermogenic methane from the underlying bedrock may be more widespread than previously assumed or there may be a more general occurrence of unmapped (buried) fault structures. Carbon and tritium isotope data and the concentrations of dissolved constituents indicate a complex groundwater flow system with multiple contributing zones to groundwater wells and relative groundwater residence time on the order of a few tens to many thousands of years. Potential mean annual recharge for water years 1950-2003 was estimated to be about 15.6 in. or 7,149 ft3/s (5.2 million acre-ft) and includes affects of human activities such as irrigation of croplands. If there had been no human activities (predevelopment conditions) during that time period, estimated recharge would have been about 11.9 in. or 5,450 ft3/s (3.9 million acre-ft). Estimated mean annual recharge ranges from virtually zero in the dry parts of the lower basin to more than 100 in. in the humid uplands, where annual precipitation is more than 120 in. Groundwater in the different hydrogeologic units occurs under perched, unconfined, semiconfined, and confined conditions. Groundwater moves from topographic highs in the uplands to topographic low areas along the streams. The flow system in the basin-fill units is compartmentalized due to topography and geologic structure. The flow system also is compartmentalized for the CRBG units but not to as large

Scientific Investigations Report↗

USGS2012

Potentiometric surface and water-level difference maps of selected confined aquifers of Southern Maryland and Maryland's Eastern Shore, 1975-2011

Groundwater is the principal source of freshwater supply in most of Southern Maryland and Maryland's Eastern Shore. It is also the source of freshwater supply used in the operation of the Calvert Cliffs, Chalk Point, and Morgantown power plants. Increased groundwater withdrawals over the last several decades have caused groundwater levels to decline. This report presents potentiometric surface maps of the Aquia, Magothy, upper Patapsco, lower Patapsco, and Patuxent aquifers using water levels measured during September 2011. Water-level difference maps also are presented for the first four of these aquifers. The water-level differences in the Aquia aquifer are shown using groundwater-level data from 1982 and 2011, whereas the water-level differences in the Magothy aquifer are presented using data from 1975 and 2011. Water-level difference maps in both the upper Patapsco and lower Patapsco aquifers are presented using data from 1990 and 2011. These maps show cones of depression ranging from 25 to 198 feet (ft) below sea level centered on areas of major withdrawals. Water levels have declined by as much as 112 ft in the Aquia aquifer since 1982, 85 ft in the Magothy aquifer since 1975, and 47 and 71 ft in the upper Patapsco and lower Patapsco aquifers, respectively, since 1990.

Maryl↗

USGS2014

Hydrogeology and water quality of the Nanticoke Creek stratified-drift aquifer, near Endicott, New York

The Village of Endicott, New York, is seeking an alternate source of public drinking water with the potential to supplement their current supply, which requires treatment due to legacy contamination. The southerly-draining Nanticoke Creek valley, located north of the village, was identified as a potential water source and the local stratified-drift (valley fill) aquifer was investigated to determine its hydrogeologic and water-quality characteristics. Nanticoke Creek and its aquifer extend from the hamlet of Glen Aubrey, N.Y., to the village of Endicott, a distance of about 15 miles, where it joins the Susquehanna River and its aquifer. The glacial sediments that comprise the stratified-drift aquifer vary in thickness and are generally underlain by glacial till over Devonian-aged shale and siltstone. Groundwater is more plentiful in the northern part of the aquifer where sand and gravel deposits are generally more permeable than in the southern part of the aquifer where less-permeable unconsolidated deposits are found. Generally there is enough groundwater to supply most homeowner wells and in some cases, supply small public-water systems such as schools, mobile-home parks, and small commercial/industrial facilities. The aquifer is recharged by precipitation, runoff, and tributary streams. Most tributary streams flowing across alluvial deposits lose water to the aquifer as they flow off of their bedrock-lined channels and into the more permeable alluvial deposits at the edges of the valley. The quality of both surface water and groundwater is generally good. Some water wells do have water-quality issues related to natural constituents (manganese and iron) and several homeowners noted either the smell and (or) taste of hydrogen sulfide in their drinking water. Dissolved methane concentrations from five drinking-water wells were well below the potentially explosive value of 28 milligrams per liter. Samples from surface and groundwater met nearly all State and Federal water-quality standards for common ion and nutrient concentrations with the exception of manganese, which is common in central New York where water sourced from shale rock or glacial sediments derived from shale bedrock naturally develops higher manganese concentrations. One shallow dug well also had elevated sodium and chloride concentrations that are likely sourced from road salt runoff from two nearby roads.

New York↗

USGS2018

Geochemistry and microbiology of groundwater and solids from extraction and monitoring wells and their relation to well efficiency at a Federally operated confined disposal facility, East Chicago, Indiana

In cooperation with the U.S. Army Corps of Engineers, Chicago District, the U.S. Geological Survey investigated the processes affecting water quality, geochemistry, and microbiology in representative extraction and monitoring wells at a confined disposal facility (CDF) in East Chicago, Indiana. The CDF is a 140-acre Federally-managed facility that was the former location of an oil refinery and is now used for the long-term disposal and storage of dredge material from the Indiana Harbor and Indiana Harbor Canal. Residual petroleum hydrocarbons and leachate from the CDF are contained within the facility by use of a groundwater cutoff wall. The wall consists of a soil-bentonite slurry and a gradient control system made up of an automated network of 96 extraction wells, 42 monitoring wells, and 2 ultrasonic sensors that maintain an inward hydraulic gradient at the site. The pumps in the extraction wells require vigilant maintenance and must be replaced when unable to withdraw water at a rate sufficient to maintain the required inward gradient. The wells are screened in the Calumet aquifer, a coarse-grained sand and gravel unit that extends approximately 35 feet below the land surface and is not utilized for drinking-water supply at the CDF or in the surrounding area. This study was initiated to identify the cause of decreased pump discharges and to identify potential mitigation strategies. For this study, the U.S. Geological Survey collected groundwater and solids from monitoring and extraction wells. Groundwater samples were collected during June 2014 for precautionary health screening and on four occasions during September 2014 through November 2014. Groundwater samples collected from two extraction wells during June 2014 were analyzed for concentrations of anthropogenic organic constituents. During September through November 2014, groundwater samples were collected from one additional extraction well, and samples from three monitoring wells were analyzed for concentrations of inorganic and organic constituents, dissolved gases, and bacterial abundance and diversity. Solid samples were collected during April 2014, during September 2014 through November 2014, and during November 2016. Solid samples were collected from the exterior of extraction-well pumps and as flocculent from water samples. Solid samples were collected from 10 wells, including 1 extraction well and 3 monitoring wells sampled for water quality. Solid samples were analyzed for mineralogy, solid-phase habit, geochemistry, and organic composition. The following is a list of observations that were made during this study: (1) the water quality is substantially variable among the six well locations sampled as part of this study—lower (more negative) redox values and higher concentrations of many constituents (including calcium, magnesium, sodium, and sulfate) and properties (including dissolved solids, hardness, and turbidity) were detected in sampled wells located near the extraction wells with the highest frequency of failure; (2) water-level drawdown is variable between extraction wells—wells with the greatest drawdown may pull deeper groundwater into the borehole; (3) dissolved gas results indicate reducing oxidation-reduction processes in the aquifer material that can feasibly contribute iron, carbon dioxide, and other byproducts from hydrocarbon degradation to precipitates and solids that accumulate on and impair pump operation; (4) crystalline and amorphous solid-phase minerals are precipitating in the borehole; (5) several types of bacteria are present in water pumped from extraction wells and are likely responsible for bonding mineral and microbiologic matter to the pump (and other well components); and (6) bacteria may create microenvironments that facilitate precipitation of solids or inhibit dissolution of unstable minerals once the bacteria adhere to biofilm attached to the pump. Results of the study indicate that bacteria may be accumulating and entrapping solid material on the exterior of pumps. This accumulation reduces heat transfer and water discharge from the pump and may lead to decreased efficiency or mechanical failure. Observations could not be made on the well screen, gravel pack, or surrounding geologic formation; therefore, mitigating measures in the borehole may not solve well-productivity issues. Remedies for the pump fouling problems were derived from the review and interpretation of data collected during this study and from information documented in other sources about groundwater well fouling. Potential remedies to problems associated with pump fouling at the CDF may include the following: (1) reducing attractiveness of the extraction wells for microbiological growth by modifying the chemical or physical environment of the well, (2) modifying the pump exterior to decrease microbiological adherence, (3) changing the pumping regime to control the chemistry of water entering the well from the surrounding aquifer material, (4) modifying the pumps to be less physically and thermally attractive, and (5) removing hydrocarbons from groundwater and the aquifer material surrounding the wells or adding surfactants to make them more mobile. Pilot scale testing may be necessary to identify the most effective treatment or combination of treatments.

Indiana↗

USGS2023

Simulating groundwater flow in the Mississippi Alluvial Plain with a focus on the Mississippi Delta

The Mississippi Alluvial Plain has become one of the most important agricultural regions in the United States but relies heavily on groundwater for irrigation. On average, more than 12 billion gallons are withdrawn daily from the Mississippi River Valley alluvial aquifer. Declining groundwater levels, especially in the Delta region of northwest Mississippi and the Cache and Grand Prairie regions of eastern Arkansas, have led to concerns about future sustainability. The U.S. Geological Survey Mississippi Alluvial Plain Project is focused on quantifying the groundwater system in the alluvial plain and the response of groundwater resources to future development. A key objective of the project is to provide updated groundwater flow models supported by extensive data collection and analyses. MODFLOW 6, PEST++, and several open-source python packages were used to develop a simplified, faster running version of the Mississippi Embayment Regional Aquifer Study model that can provide boundary conditions for local inset models, including the Mississippi Delta model described in this report. An automated workflow was used for model construction, history matching, and development of baseline future climate scenarios. The models incorporate information from a Soil-Water-Balance code simulation of the terrestrial water balance, metering-based estimates of water use from thousands of wells, measured and estimated streamflow and stages, and the largest airborne electromagnetic survey flown to date in the United States. Baseline scenarios for the Mississippi Delta under potential future climates were constructed using recharge, surface runoff and irrigation pumping forcings from a future version of the Soil-Water-Balance model, driven by downscaled temperature and precipitation output from 10 general circulation model simulations, including high and moderate carbon emissions pathways. Results indicate a complex water balance that varies in time and space in terms of the terrestrial recharge, stream leakage, and regional groundwater flow components, which are affected by seasonal forcings, human activity, and alluvial geomorphology. The general circulation model outputs indicate a continued rise in average temperatures but no clear precipitation trend. Increased crop water demand is anticipated from the higher temperatures, resulting in increased irrigation withdrawals to sustain current levels of irrigated agriculture. Simulated drawdowns in groundwater levels at the mid-21st century vary greatly. Under moderate or wet climate scenarios, and in parts of the aquifer that are well connected to surface water, little to no additional drawdown is anticipated. Under dry or warm scenarios, drawdowns of as much as 10 meters or more are possible in parts of the aquifer that are relatively disconnected from surface water. Under dry or warm scenarios, the portion of the Delta with greater than 60 feet of saturated thickness could be reduced from near 100 percent currently (2018) to 80–90 percent by mid-century. Future simulations with the model could include alternative management scenarios to identify options for improving groundwater sustainability. The automated model construction workflows are designed to facilitate regular updating, making this a “living” framework that the Mississippi Department of Environmental Quality and other stakeholders can use for adaptive management going forward.

Arkansas, Louisiana, Mississippi↗

USGS2024

Analysis of factors affecting plume remediation in a sole-source aquifer system, southeastern Nassau County, New York

Several plumes of dissolved, chlorinated solvents, including trichloroethylene, have been identified in a sole-source aquifer near the former Northrop Grumman Bethpage Facility and Naval Weapons Industrial Reserve Plant sites in southeastern Nassau County, New York. Past investigations have documented that the groundwater contamination originated from this industrial area and now extends to the south, in the direction of groundwater flow. The intermixed plumes are commonly referred to as the “Navy Grumman groundwater plume.” Detailed groundwater-flow modeling was needed for the New York State Department of Environmental Conservation (NYSDEC) to evaluate design options necessary for the construction, operation, optimization, maintenance, and monitoring of a groundwater extraction and treatment cleanup plan selected in a December 2019 Amended Record of Decision by the NYSDEC to comprehensively address these plumes. Consequently, the NYSDEC began a cooperative study with the U.S. Geological Survey in 2020 to better understand the local hydrogeologic framework using two independent approaches to characterize aquifer heterogeneity and update an existing regional groundwater-flow model to provide transient boundary conditions for new inset groundwater-flow models of the plume area. We developed these detailed inset models for the two independent aquifer characterizations using history-matching techniques coupled with a novel approach to risk-based management optimization of the remedial design. We also used the updated regional model to assess this optimized groundwater extraction and treatment design for potential saltwater intrusion. The ensembles of parameters resulting from history matching provided a platform with which to evaluate capture by water-supply and remedial wells using particle-tracking techniques. Using the ensemble to select a risk stance, we performed multiobjective optimization to identify various configurations of remedial pumping that are consistent with external constraints and that favor potentially competing objectives. Multiple solutions provide tradeoffs that NYSDEC can consider. In general, pumping redistribution may help to prevent further contamination migration downgradient. These and other study results are intended to support decisions for the remedial design focused on the local area encompassing the full extent of the Navy Grumman groundwater plume.

New York↗

USGS1987

Geohydrology and simulated effects of withdrawals on the Miocene aquifer system in the Mississippi Gulf Coast area

Intense development of the Miocene aquifer system for water supplies along the Mississippi Gulf Coast has resulted in large water level declines that have altered the groundwater flow pattern in the area. Water levels in some Miocene aquifers have declined about 2 ft/year since 1940; declines exceed 100 ft (80 ft sea level) in large areas along the coast. Water levels in the surficial aquifer system, generally less than 20 ft below land surface, have not declined. The Miocene and younger interbedded and lenticular sands and clays crop out in southern Mississippi and dip to the south and southwest. These sediments have large vertical variations in head and locally respond to stresses as separate aquifers. Freshwater recharge to the Miocene aquifer system primarily is from rainfall on the surficial aquifers. The water generally moves to the south and southeast along the bedding planes toward the Mississippi Gulf Coast where the water is either withdrawn by wells, discharges to the ocean, or gradually percolates upward into overlying aquifers. Drawdowns caused by large groundwater withdrawals along the coast probably have resulted in the gradual movement of the saltwater toward the pumping centers. In parts of the Miocene aquifer system commonly used for water supplies, the water generally is a sodium bicarbonate type. Increasing chloride concentrations in a few wells indicate that saline water is migrating into parts of all layers in the Pascagoula area. A quasi three-dimensional numerical model of the groundwater flow system was constructed and calibrated on the basis of the both pre- and post-development conditions. The effects of an expected 1.5% annual increase in groundwater withdrawals during the period 1985-2005 were evaluated by the flow model. Additional water level declines expected by the year 2005 in response to estimated pumpage are as follows: Gulfport, 135 ft in layer 4; Biloxi-Gulfport area, 100 ft in layer 5 and 50 ft in layer 3; Pascagoula area, 40 ft in layer 6 and 30 ft in layer 4. The most serious threats of saltwater encroachment occur in layers 4, 5, and 6 (the 800-, 600- and 400-ft sands) in the Pascagoula area where contamination of the southern edges of the production areas is expected to occur in less than 10 years. (Author 's abstract)

Water-Resources Investigations Report↗

USGS2010

Groundwater flow systems at the Nevada Test Site, Nevada: A synthesis of potentiometric contours, hydrostratigraphy, and geologic structures

Contaminants introduced into the subsurface of the Nevada Test Site by underground nuclear testing are of concern to the U.S. Department of Energy and regulators responsible for protecting human health and safety. The potential for contaminant movement away from the underground test areas and into the accessible environment is greatest by groundwater transport. The primary hydrologic control on this transport is evaluated and examined through a series of contour maps developed to represent the hydraulic-head distribution within each of the major aquifers underlying the area. Aquifers were identified and their extents delineated by merging and analyzing multiple hydrostratigraphic framework models developed by other investigators from existing geologic information. A map of the hydraulic-head distribution in each major aquifer was developed from a detailed evaluation and assessment of available water-level measurements. Multiple spreadsheets that accompany this report provide pertinent water-level and geologic data by well or drill hole. Aquifers are mapped and discussed in general terms as being one of two types: alluvial–volcanic, or carbonate. Both aquifer types are subdivided and mapped as independent regional and local aquifers, based on the continuity of their component rock. Groundwater-flow directions, approximated from potentiometric contours that were developed from the hydraulic-head distribution, are indicated on the maps and discussed for each of the regional aquifers and for selected local aquifers. Hydraulic heads vary across the study area and are interpreted to range in altitude from greater than 5,000 feet in a regional alluvial–volcanic aquifer beneath a recharge area in the northern part of the study area to less than 2,300 feet in regional alluvial–volcanic and carbonate aquifers in the southwestern part of the study area. Flow directions throughout the study area are dominantly south-southwest with some local deviations. Vertical hydraulic gradients between aquifer types are downward throughout most of the study area; however, flow from the alluvial–volcanic aquifer into the underlying carbonate aquifer, where both aquifers are present, is believed to be minor because of an intervening confining unit. Limited exchange of water between aquifer types occurs by diffuse flow through the confining unit, by focused flow along fault planes, or by direct flow where the confining unit is locally absent. Interflow between regional aquifers is evaluated and mapped to define major flow paths. These flow paths delineate tributary flow systems, which converge to form intermediate and regional flow systems. The implications of these flow systems in controlling transport of radionuclides away from the underground test areas at the Nevada Test Site are briefly discussed. Additionally, uncertainties in the delineation of aquifers, the development of potentiometric contours, and the identification of flow systems are identified and evaluated. Eleven tributary flow systems and three larger flow systems are mapped in the Nevada Test Site area. Flow systems within the alluvial–volcanic aquifer dominate the western half of the study area, whereas flow systems within the carbonate aquifer are most prevalent in the southeastern half of the study area. Most of the flow in the regional alluvial–volcanic aquifer that moves through the underground testing area on Pahute Mesa is discharged to the land surface at springs and seeps in Oasis Valley. Flow in the regional carbonate aquifer is internally compartmentalized by major geologic structures, primarily thrust faults, which constrain flow into separate corridors. Contaminants that reach the regional carbonate aquifer from testing areas in Yucca and Frenchman Flats flow toward downgradient discharge areas through the Alkali Flat–Furnace Creek Ranch or Ash Meadows flow systems and their tributaries.

Nevada↗

USGS2007

U/Th series radionuclides as coastal groundwater tracers

The study of coastal groundwater has recently surfaced as an active interdisciplinary area of research, driven foremost by its importance as a poorly quantified pathway for subsurface material transport into coastal ecosystems. Key issue in coastal groundwater research include a complete geochemical characterization of the groundwater(s); quantification of the kinetics of subsurface transport, including rock-water interactions; determination of groundwater ages; tracing of groundwater discharge into coastal waters using radiochemical fingerprints; and an assessment of the potential ecological impact of such subsurface flow to a reviving water body. For such applications, the isotopic systemics of select naturally occurring radionucludes in the U/Th series has proven to be particularly useful. These radionuclides (e.g., U, Th, Ram and Rn) are ubiquitous in all groundwaters ad are represented by several isotopes with widely different half-lives and chemistries (Figure 1). As a result, varied biogeochemical processes occurring over a broad range of time scales can be studied. In source rock, most U/Th series isotopes in secular equilibrium; that is, the rate of decay of a daughter isotope is equal to that of it radiogenic parent, and so will have equal activities (in this context, the specific activity is simply a measure of the amount of radioactivity per unit amount). In contrast, these nuclides exhibit strong fractionations within the surrounding groundwaters because of their respective physiochemical differences. Disequilibria in U/Th series radionuclides can thus be used to identify distinct water masses, quantify release rates from source rocks, assess groundwater migration rates, and assess groundwater discharge rates in coastal waters., Large isotopic variations also have the potential for providing precise fingerprints for groundwaters from specific aquifers and have been explored as a means for calculating groundwater ages and estuarine water mass transit times. The highly fractionated nature of U/Th series nuclides in groundwater is illustrated by the range in some measured activities. highest activities are typically observed for 222 Rn, reflecting the inert nature of this noble gas. Groundwater 222 Rn (t 1/2 =3.8) activities are thus controlled only by rapid in situ decay (Table 1) and production within host rocks, without the added complications of reversible removal via absorption or precipitation. Uranium, which is soluble as U(VI) in oxidizing waters, is present in intermediate activities in groundwaters that are moderated by redox-initiated removal onto aquifer rocks. The alkaline earth Ra and, to a greater extent, the less soluble actinide Th are readily removed from groundwater by water -- rock interactions and so are strongly depleted. Both of these elements have very short-lived as well as longer-lived isotopes, and so isotopes compositions reflect processes over a range of time scales. Many studies have evaluated and behavior of select radionuclides in groundwater and surface water systems. Recent advances in high-=precision mass spectrometry have opted new possibilities for more subtle interpretations in select long-lived U/Th series isotopes, such as U, Ra, Pa, and Th. However, these techniques have yet to be fully developed, ahns as a consequence, such data remain largely scarce and underutilized. Although many different approaches have been developed to study radionucluide behavior in groundwater, all are based on principles of radioactive production and decay and knowledge of source terms from weathering and recoil processes, as well as removal terms from the interaction with aquifer host rock surface by sorption and precipitation. This review is structured to present first a brief description of the background, driving forces, scales, and ecological significance of submarine groundwater discharge. Following this, a description of the geochemistry and behavior of select radionuclides in groundwater will be presented, and their application to tracing submarine groundwater discharge will be discussed.

Chemical Reviews↗

USGS2010

Water Quality in the Equus Beds Aquifer and the Little Arkansas River Before Implementation of Large-Scale Artificial Recharge, South-Central Kansas, 1995-2005

Artificial recharge of the Equus Beds aquifer using runoff from the Little Arkansas River in south-central Kansas was first proposed in 1956 and was one of many options considered by the city of Wichita to preserve its water supply. Declining aquifer water levels of as much as 50 feet exacerbated concerns about future water availability and enhanced migration of saltwater into the aquifer from past oil and gas activities near Burrton and from the Arkansas River. Because Wichita changed water-management strategies and decreased pumping from the Equus Beds aquifer in 1992, water storage in the aquifer recovered by about 50 percent. This recovery is the result of increased reliance on Cheney Reservoir for Wichita water supply, decreased aquifer pumping, and larger than normal precipitation. Accompanying the water-level recovery, the average water-level gradient in the aquifer decreased from about 12 feet per mile in 1992 to about 8 feet per mile in January 2006. An important component of artificial recharge is the water quality of the receiving aquifer and the water being recharged (source water). Water quality within the Little Arkansas River was defined using data from two real-time surface-water-quality sites and discrete samples. Water quality in the Equus Beds aquifer was defined using sample analyses collected at 38 index sites, each with a well completed in the shallow and deep parts of the Equus Beds aquifer. In addition, data were collected at diversion well sites, recharge sites, background wells, and prototype wells for the aquifer storage and recovery project. Samples were analyzed for major ions, nutrients, trace metals, radionuclides, organic compounds, and bacterial and viral indicators. Water-quality constituents of concern for artificial recharge are those constituents that frequently (more than 5 percent of samples) may exceed Federal [U.S. Environmental Protection Agency (USEPA)] and State drinking-water criteria in water samples from the receiving aquifer or in samples from the source water. Constituents of concern include major ions (sulfate and chloride), nutrients (nitrite plus nitrate), trace elements (arsenic, iron, and manganese), organic compounds (atrazine), and fecal bacterial indicators. This report describes the water quality in the Equus Beds aquifer and the Little Arkansas River from 1995 through 2005 before implementation of large-scale recharge activities. Sulfate concentrations in water samples from the Little Arkansas River rarely exceeded Federal secondary drinking water regulation (SDWR) of 250 milligrams per liter (mg/L). Sulfate concentrations in groundwater were exceeded in about 18 percent of the wells in the shallow (less than or equal to 80 feet deep) parts of the aquifer and in about 13 percent of the wells in the deep parts the aquifer. Larger sulfate concentrations were associated with parts of the aquifer with the largest water-level declines. Water-quality changes in the Equus Beds aquifer likely were caused by dewatering and oxidation of aquifer material that subsequently resulted in increased sulfate concentrations as water levels recovered. The primary sources of chloride to the Equus Beds aquifer are from past oil and gas activities near Burrton and from the Arkansas River. Computed chloride concentrations in the Little Arkansas River near Halstead exceeded the Federal SDWR of 250 mg/L about 27 percent of the time (primarily during low-flow conditions). Chloride concentrations in groundwater exceeded 250 mg/L in about 8 percent or less of the study area, primarily near Burrton and along the Arkansas River. Chloride in groundwater near Burrton has migrated downgradient about 3 miles during the past 40 to 45 years. The downward and horizontal migration of the chloride is controlled by the hydraulic gradient in the aquifer, dispersion of chloride, and discontinuous clay layers that can inhibit further downward migration. Chloride in the shallow parts of the Equus Beds

Scientific Investigations Report↗

USGS2012

Conceptual and numerical models of the glacial aquifer system north of Aberdeen, South Dakota

This U.S. Geological Survey report documents a conceptual and numerical model of the glacial aquifer system north of Aberdeen, South Dakota, that can be used to evaluate and manage the city of Aberdeen's water resources. The glacial aquifer system in the model area includes the Elm, Middle James, and Deep James aquifers, with intervening confining units composed of glacial till. The Elm aquifer ranged in thickness from less than 1 to about 95 feet (ft), with an average thickness of about 24 ft; the Middle James aquifer ranged in thickness from less than 1 to 91 ft, with an average thickness of 13 ft; and the Deep James aquifer ranged in thickness from less than 1 to 165 ft, with an average thickness of 23 ft. The confining units between the aquifers consisted of glacial till and ranged in thickness from 0 to 280 ft. The general direction of groundwater flow in the Elm aquifer in the model area was from northwest to southeast following the topography. Groundwater flow in the Middle James aquifer was to the southeast. Sparse data indicated a fairly flat potentiometric surface for the Deep James aquifer. Horizontal hydraulic conductivity for the Elm aquifer determined from aquifer tests ranged from 97 to 418 feet per day (ft/d), and a confined storage coefficient was determined to be 2.4x10 -5 . Estimates of the vertical hydraulic conductivity of the sediments separating the Elm River from the Elm aquifer, determined from the analysis of temperature gradients, ranged from 0.14 to 2.48 ft/d. Average annual precipitation in the model area was 19.6 inches per year (in/yr), and agriculture was the primary land use. Recharge to the Elm aquifer was by infiltration of precipitation through overlying outwash, lake sediments, and glacial till. The annual recharge for the model area, calculated by using a soil-water-balance method for water year (WY) 1975-2009, ranged from 0.028 inch in WY 1980 to 4.52 inches in WY 1986, with a mean of 1.56 inches. The annual potential evapotranspiration, calculated in soil-water-balance analysis, ranged from 21.8 inches in WY 1983 to 27.0 inches in WY 1985, with a mean of 24.6 inches. Water use from the glacial aquifer system primarily was from the Elm aquifer for irrigation, municipal, and suburban water supplies, and the annual rate ranged from 1.0 to 2.4 cubic feet per second (ft 3 /s). The MODFLOW-2005 numerical model represented the Elm aquifer, the Middle James aquifer, and the Deep James aquifer with model layers 1-3 respectively separated by confining layers 1-2 respectively. Groundwater flow was simulated with 75 stress periods beginning October 1, 1974, and ending September 30, 2009. Model grid spacing was 200 by 200 ft and boundaries were represented by specified-head boundaries and no-flow boundaries. The model used parameter estimation that focused on minimizing the difference between 954 observed and simulated hydraulic heads for 135 wells. Calibrated mean horizontal hydraulic conductivity values for model layers 1-3 were 94, 41, and 30 ft/d respectively. Vertical hydraulic conductivity values for confining layers 1 and 2 were 0.0002 and 0.0003 ft/d, respectively. Calibrated specific yield for model layer 1was 0.1 and specific storage ranged from 0.0003 to 0.0005 per foot. Calibrated mean recharge rates ranged from 2.5 in/yr where glacial till thickness was less than 10 ft to 0.8 in/yr where glacial till thickness was greater than 30 ft. Calibrated mean annual evapotranspiration rate was 8.8 in/yr. Simulated net streamflow gain from model layer 1 was 3.1 ft 3 /s.

South Dakota↗

USGS2012

Assessing potential effects of changes in water use with a numerical groundwater-flow model of Carson Valley, Douglas County, Nevada, and Alpine County, California

Rapid growth and development within Carson Valley in Douglas County, Nevada, and Alpine County, California, has caused concern over the continued availability of groundwater, and whether the increased municipal demand could either impact the availability of water or result in decreased flow in the Carson River. Annual pumpage of groundwater has increased from less than 10,000 acre feet per year (acre-ft/yr) in the 1970s to about 31,000 acre-ft/yr in 2004, with most of the water used in agriculture. Municipal use of groundwater totaled about 10,000 acre-feet in 2000. In comparison, average streamflow entering the valley from 1940 to 2006 was 344,100 acre-ft/yr, while average flow exiting the valley was 297,400 acre-ft/yr. Carson Valley is underlain by semi-consolidated Tertiary sediments that are exposed on the eastern side and dip westward. Quaternary fluvial and alluvial deposits overlie the Tertiary sediments in the center and western side of the valley. The hydrology of Carson Valley is dominated by the Carson River, which supplies irrigation water for about 39,000 acres of farmland and maintains the water table less than 5 feet (ft) beneath much of the valley floor. Perennial and ephemeral watersheds drain the Carson Range and the Pine Nut Mountains, and mountain-front recharge to the groundwater system from these watersheds is estimated to average 36,000 acre-ft/yr. Groundwater in Carson Valley flows toward the Carson River and north toward the outlet of the Carson Valley. An upward hydraulic gradient exists over much of the valley, and artesian wells flow at land surface in some areas. Water levels declined as much as 15 ft since 1980 in some areas on the eastern side of the valley. Median estimated transmissivities of Quaternary alluvial-fan and fluvial sediments, and Tertiary sediments are 316; 3,120; and 110 feet squared per day (ft 2 /d), respectively, with larger transmissivity values in the central part of the valley and smaller values near the valley margins. A groundwater-flow model of Quaternary and Tertiary sediments in Carson Valley was developed using MODFLOW and calibrated to simulate historical conditions from water years 1971 through 2005. The 35-year transient simulation represented quarterly changes in precipitation, streamflow, pumping and irrigation. Inflows to the groundwater system simulated in the model include mountain-front recharge from watersheds in the Carson Range and Pine Nut Mountains, valley recharge from precipitation and land application of wastewater, agricultural recharge from irrigation, and septic-tank discharge. Outflows from the groundwater system simulated in the model include evapotranspiration from the water table and groundwater withdrawals for municipal, domestic, irrigation and other water supplies. The exchange of water between groundwater, the Carson River, and the irrigation system was represented with a version of the Streamflow Routing (SFR) package that was modified to apply diversions from the irrigation network to irrigated areas as recharge. The groundwater-flow model was calibrated through nonlinear regression with UCODE to measured water levels and streamflow to estimate values of hydraulic conductivity, recharge and streambed hydraulic-conductivity that were represented by 18 optimized parameters. The aquifer system was simulated as confined to facilitate numerical convergence, and the hydraulic conductivity of the top active model layers that intersect the water table was multiplied by a factor to account for partial saturation. Storage values representative of specific yield were specified in parts of model layers where unconfined conditions are assumed to occur. The median transmissivity ( T ) values (11,000 and 800 ft 2 /d for the fluvial and alluvial-fan sediments, respectively) are both within the third quartile of T values estimated from specific-capacity data, but T values for Tertiary sediments are larger than the third quartile estimated from specific-capacity data. The estimated vertical anisotropy for the Quaternary fluvial sediments (9,000) is comparable to the value estimated for a previous model of Carson Valley. The estimated total volume of mountain-front recharge is equivalent to a previous estimate from the Precipitation-Runoff Modeling System (PRMS) watershed models, but less recharge is estimated for the Carson Range and more recharge is estimated for the Pine Nut Mountains than the previous estimate. Simulated flow paths indicate that groundwater flows faster through the center of Carson Valley and slower through the lower hydraulic-conductivity Tertiary sediments to the east. Shallow flow in the center of the valley is towards drainage channels, but deeper flow is generally directed toward the basin outlet to the north. The aquifer system is in a dynamic equilibrium with large inflows from storage in dry years and large outflows to storage in wet years. Pumping has historically been less than 10 percent of outflows from the groundwater system, and agricultural recharge has been less than 10 percent of inflows to the groundwater system. Three principal sources of uncertainty that affect model results are: (1) the hydraulic characteristics of the Tertiary sediments on the eastern side of the basin, (2) the composition of sediments beneath the alluvial fans and (3) the extent of the confining unit represented within fluvial sediments in the center of the basin. The groundwater-flow model was used in five 55-year predictive simulations to evaluate the long-term effects of different water-use scenarios on water-budget components, groundwater levels, and streamflow in the Carson River. The predictive simulations represented water years 2006 through 2060 using quarterly stress periods with boundary conditions that varied cyclically to represent the transition from wet to dry conditions observed from water years 1995 through 2004. The five scenarios included a base scenario with 2005 pumping rates held constant throughout the simulation period and four other scenarios using: (1) pumping rates increased by 70 percent, including an additional 1,340 domestic wells, (2A) pumping rates more than doubled with municipal pumping increased by a factor of four over the base scenario, (2B) pumping rates of 2A with 2,040 fewer domestic wells, and (3) pumping rates of 2A with 3,700 acres removed from irrigation. The 55-year predictive simulations indicate that increasing groundwater withdrawals under the scenarios considered would result in as much as 40 ft and 60 ft of water-table decline on the west and east sides of Carson Valley, respectively. The water table in the central part of the valley would remain essentially unchanged, but water-level declines of as much as 30 ft are predicted for the deeper, confined aquifer. The increased withdrawals would reduce the volume of groundwater storage and decrease the mean downstream flow in the Carson River by as much as 16,500 acre-ft/yr. If, in addition, 3,700 acres were removed from irrigation, the reduction in mean downstream flow in the Carson River would be only 6,500 acre-ft/yr. The actual amount of flow reduction is uncertain because of potential changes in irrigation practices that may not be accounted for in the model. The projections of the predictive simulations are sensitive to rates of mountain-front recharge specified for the Carson Range and the Pine Nut Mountains. The model provides a tool that can be used to aid water managers and planners in making informed decisions. A prudent management approach would include continued monitoring of water levels on both the east and west sides of Carson Valley to either verify the predictions of the groundwater-flow model or to provide additional data for recalibration of the model if the predictions prove inaccurate.

California;Nevada↗

USGS1996

Geohydrologic units and water-level conditions in the Terrace alluvial aquifer and Paluxy Aquifer, May 1993 and February 1994, near Air Force Plant 4, Fort Worth area, Texas

The terrace alluvial aquifer underlying Air Force Plant 4 and the adjacent Naval Air Station (formerly Carswell Air Force Base) in the Fort Worth area, Texas, is contaminated locally with organic and metal compounds. Residents south and west of Air Force Plant 4 and the Naval Air Station are concerned that contaminants might enter the underlying Paluxy aquifer, which provides water to the city of White Settlement, south of Air Force Plant 4, and to residents west of Air Force Plant 4. The U.S. Environmental Protection Agency has qualified Air Force Plant 4 for Superfund cleanup. The pertinent geologic units include -A~rom oldest to youngest the Glen Rose, Paluxy, and Walnut Formations, Goodland Limestone, and terrace alluvial deposits. Except for the Glen Rose Formation, all units crop out at or near Air Force Plant 4 and the Naval Air Station. The terrace alluvial deposits, which nearly everywhere form the land surface, range from 0 to about 60 feet thick. These deposits comprise a mostly unconsolidated mixture of gravel, sand, silt, and clay. Mudstone and sandstone of the Paluxy Formation crop out north, west, and southwest of Lake Worth and total between about 130 and about 175 feet thick. The terrace alluvial deposits and the Paluxy Formation comprise the terrace alluvial aquifer and the Paluxy aquifer, respectively. These aquifers are separated by the Goodland-Walnut confining unit, composed of the Goodland Limestone and (or) Walnut Formation. Below the Paluxy aquifer, the Glen Rose Formation forms the Glen Rose confining unit. Water-level measurements during May 1993 and February 1994 from wells in the terrace alluvial aquifer indicate that, regionally, ground water flows toward the east-southeast beneath Air Force Plant 4 and the Naval Air Station. Locally, water appears to flow outward from ground-water mounds maintained by the localized infiltration of precipitation and reportedly by leaking water pipes and sanitary and (or) storm sewer lines beneath the assembly building at Air Force Plant 4. North of Farmers Branch, the terrace alluvial aquifer discharges into Lake Worth, Meandering Road Creek, Farmers Branch, and the West Fork Trinity River. South of Farmers Branch, ground water appears to flow mostly north-northeastward. Greater precipitation prior to the May 1993 measurements caused water levels to average approximately 5 ft higher in May 1993 than in February 1994. Regional ground-water gradients indicate west to east-southeastward flow in the Paluxy aquifer, with a dominant southeastward component beneath Air Force Plant 4. Water-level maps for the Paluxy "upper sand" reveal an elongated groundwater mound beneath southeastern parts of Air Force Plant 4, which indicates a localized, vertical conduit through which contaminated water from the terrace alluvial aquifer might enter upper parts of the Paluxy aquifer. The Paluxy "upper sand" apparently is mostly unsaturated and hydraulically separated from the deeper, regionally extensive parts of the Paluxy aquifer, most of which are fully saturated. While water levels in the "upper sand" were as much as 10 ft higher in May 1993 than in February 1994, water levels in most deeper parts of the Paluxy aquifer were slightly higher in February 1994 than they were in May 1993.

Texas↗

USGS2017

Methane in aquifers used for public supply in the United States

In 2013 to 2015, 833 public supply wells in 15 Principal aquifers in the U.S. were sampled to identify which aquifers contained high methane concentrations (>1 mg/L) and determine the geologic, hydrologic, and geochemical conditions associated with high concentrations. This study represents the first national assessment of methane in aquifers used for public supply in the U.S. and, as such, advances the understanding of the occurrence and distribution of methane in groundwater nationally. Methane concentrations >1 and > 10 mg/L occurred in 6.7 and 1.1% of the samples, respectively. Most high concentrations occurred in aquifers in the Atlantic and Gulf Coastal Plain regions and upper Midwest. High methane concentrations were most commonly associated with Tertiary and younger aquifer sediments, old groundwater (>60 years), and concentrations of oxygen, nitrate-N, and sulfate <0.5 mg/L. Concentrations of methane were also positively correlated (p < 0.05) with dissolved organic carbon and ammonium. Case studies in Florida, Texas, and Iowa were used to explore how regional context from this data set could aid our understanding of local occurrences of methane in groundwater. Regional data for methane, Br/Cl ratios, sulfate, and other parameters helped identify mixing processes involving end members such as wastewater effluent-impacted groundwater, saline formation water, and pore water in glacial till that contributed methane to groundwater in some cases and supported methane oxidation in others.

Applied Geochemistry↗