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Groundwater-quality data in the Cascade Range and Modoc Plateau study unit, 2010-Results from the California GAMA Program

Groundwater quality in the 39,000-square-kilometer Cascade Range and Modoc Plateau (CAMP) study unit was investigated by the U.S. Geological Survey (USGS) from July through October 2010, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program’s Priority Basin Project (PBP). The GAMA PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The CAMP study unit is the thirty-second study unit to be sampled as part of the GAMA PBP. The GAMA CAMP study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer system and to facilitate statistically consistent comparisons of untreated-groundwater quality throughout California. The primary aquifer system is defined as that part of the aquifer corresponding to the open or screened intervals of wells listed in the California Department of Public Health (CDPH) database for the CAMP study unit. The quality of groundwater in shallow or deep water-bearing zones may differ from the quality of groundwater in the primary aquifer system; shallow groundwater may be more vulnerable to surficial contamination. In the CAMP study unit, groundwater samples were collected from 90 wells and springs in 6 study areas (Sacramento Valley Eastside, Honey Lake Valley, Cascade Range and Modoc Plateau Low Use Basins, Shasta Valley and Mount Shasta Volcanic Area, Quaternary Volcanic Areas, and Tertiary Volcanic Areas) in Butte, Lassen, Modoc, Plumas, Shasta, Siskiyou, and Tehama Counties. Wells and springs were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells). Groundwater samples were analyzed for field water-quality indicators, organic constituents, perchlorate, inorganic constituents, radioactive constituents, and microbial indicators. Naturally occurring isotopes and dissolved noble gases also were measured to provide a dataset that will be used to help interpret the sources and ages of the sampled groundwater in subsequent reports. In total, 221 constituents were investigated for this study. Three types of quality-control samples (blanks, replicates, and matrix spikes) were collected at approximately 10 percent of the wells in the CAMP study unit, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Blanks rarely contained detectable concentrations of any constituent, suggesting that contamination from sample collection procedures was not a significant source of bias in the data for the groundwater samples. Replicate samples generally were within the limits of acceptable analytical reproducibility. Matrix-spike recoveries were within the acceptable range (70 to 130 percent) for approximately 90 percent of the compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is served to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH, and to non-regulatory benchmarks established for aesthetic concerns by CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. All organic constituents and most inorganic constituents that were detected in groundwater samples from the 90 grid wells in the CAMP study unit were detected at concentrations less than drinking-water benchmarks. Of the 148 organic constituents analyzed, 27 were detected in groundwater samples; concentrations of all detected constituents were less than regulatory and nonregulatory health-based benchmarks, and all were less than 1/10 of benchmark levels. One or more organic constituents were detected in 52 percent of the grid wells in the CAMP study unit: VOCs were detected in 30 percent, and pesticides and pesticide degradates were detected in 31 percent. Trace elements, major ions, nutrients, and radioactive constituents were sampled for at 90 grid wells in the CAMP study unit, and most detected concentrations were less than health-based benchmarks. Exceptions include three detections of arsenic greater than the USEPA maximum contaminant level (MCL-US) of 10 micrograms per liter (µg/L), two detections of boron greater than the CDPH notification level (NL-CA) of 1,000 µg/L, two detections of molybdenum greater than the USEPA lifetime health advisory level (HAL-US) of 40 µg/L, two detections of vanadium greater than the CDPH notification level (NL-CA) of 50 µg/L, one detection of nitrate, as nitrogen, greater than the MCL-US of 10 milligrams per liter (mg/L), two detections of uranium greater than the MCL-US of 30 µg/L and the MCL-CA of 20 picocuries per liter (pCi/L), one detection of radon-222 greater than the proposed MCL-US of 4,000 pCi/L, and two detections of gross alpha particle activity greater than the MCL-US of 15 pCi/L. Results for inorganic constituents with non-regulatory benchmarks set for aesthetic concerns showed that iron concentrations greater than the CDPH secondary maximum contaminant level (SMCL-CA) of 300 µg/L were detected in four grid wells. Manganese concentrations greater than the SMCL-CA of 50 µg/L were detected in nine grid wells. Chloride and TDS were detected at concentrations greater than the upper SMCL-CA benchmarks of 500 mg/L and 1,000 mg/L, respectively, in one grid well. Microbial indicators (total coliform and Escherichia coli [E. coli]) were detected in 11 percent of the 83 grid wells sampled for these analyses in the CAMP study unit. The presence of total coliform was detected in nine grid wells, and the presence of E. coli was detected in one of these same grid wells.

California↗

Flooded area and plant zonation in isolated wetlands in well fields in the Northern Tampa Bay Region, Florida, following reductions in groundwater-withdrawal rates

The extent and duration of the flooded area were compared in two reference wetlands and nine wetlands in well fields in the northern Tampa Bay region, Florida, to determine whether reductions in well-field groundwater-withdrawal rates resulted in increases in wetland flooded area. Flooded area, expressed as a percentage of the total wetland area, was used to provide a quantitative and comparable line of evidence for describing the hydrologic conditions in isolated wetlands of different sizes and locations. Flooded-area frequencies were quantified for periods with different groundwater-withdrawal rates that bracket reductions in well-field groundwater withdrawals. Four-year pre-reduction and post-reduction periods were applied to wetlands in Cypress Creek and Cross Bar Ranch well fields, whereas 3-year periods were applied to wetlands in Starkey well field. The reduced groundwater-withdrawal rates in Cypress Creek and Cross Bar Ranch well fields were 30 and 24 percent less than their pre-reduction rates, respectively. The reduced groundwater-withdrawal rate in the Starkey well field was 64 percent less. Total rainfall amounts were similar (differed by 1 percent or less) in the respective pre- and post-reduction periods, which minimized the effect that rainfall variability had on the analysis. Flooded-area patterns at the reference wetlands, which were unaffected by groundwater withdrawals, were similar during pre- and post-reduction periods, indicating that short-term rainfall variability within those periods did not affect the longer-term patterns of flooded-area extent and duration. One well-field wetland (W-33) experienced an extent and duration of flooded area similar to that observed at the reference wetlands. About 61–100 percent of W-33 was flooded 41 percent of the time during the pre-reduction period and 45 percent of the time in the post-reduction period. The amount of time the wetland was dry decreased from 40 percent in the pre-reduction period to 26 percent in the post-reduction period. The median elevation of the potentiometric surface of the Upper Floridan aquifer increased beneath this wetland by about 4 feet after reductions in groundwater-withdrawal rates. Four well-field wetlands (W-17, W-56, Starkey N, and Starkey 108) had substantial increases in the extent and duration of the flooded area after reductions in groundwater-withdrawal rates. These four wetlands were dry for 25–45 percent less time during the post-reduction period, when the pre- and post-reduction periods were compared. Up to 20 percent of W-56 was flooded more than three times as long after reductions in groundwater-withdrawal rates. All parts of W-17 were flooded for as much as 10 percent of the time in the post-reduction period. Parts of Starkey N and Starkey 108 were flooded for more than twice as much time after reductions in groundwater-withdrawal rates. The median elevation of the potentiometric surface of the Upper Floridan aquifer was about 4–8 feet higher beneath W-17 and W-56 after reductions in groundwater-withdrawal rates, whereas the median elevation increased beneath Starkey N and Starkey 108 by about 4 feet after reductions in groundwater-withdrawal rates. Four other well-field wetlands (W-41, Q-1, Starkey D, and Starkey E) were mostly dry before reductions in groundwater-withdrawal rates and remained mostly dry after the reductions. W-41 was dry 23 percent less time in the post-reduction period, but most of the increase in flooded area was confined to less than 20 percent of the total wetland area. Q-1 was dry for only 12 percent less time in the post-reduction period. The median elevation of the potentiometric surface of the Upper Floridan aquifer increased beneath W-41 by about 5 feet and beneath Q-1 by about 2 feet after reductions in groundwater-withdrawal rates. The extent and duration of the flooded area was unchanged at Starkey D when the post-reduction period was compared to the pre-reduction period. At Starkey E the extent of the flooded area decreased slightly during the post-reduction period. Even though groundwater-withdrawal rates at Starkey well field decreased in the post-reduction period, the median elevation of the potentiometric surface of the Upper Floridan aquifer did not increase beneath Starkey D and Starkey E after reductions in groundwater-withdrawal rates from this well field. Factors such as the high permeability of sediments beneath the wetlands, subsidence, or sinkholes could contribute to continued downward leakage from these four wetlands and the lack of recovery of wetland water levels. Plant zonation in the two reference wetlands and the nine well-field wetlands was described using data collected by the Southwest Florida Water Management District and Tampa Bay Water, a regional utility, in their Wetland Assessment Procedure (WAP). A scoring system was used to describe the distribution of trees, woody shrubs, and groundcover in zones at three depths along a transect line through each wetland. The locations of the three zones were identified on contoured wetland bathymetry maps and were discussed in relation to areas of the wetland bottom that flooded for different periods of time during the study. Higher scores are characteristic of a greater extent and duration of wetland flooded area. WAP scores and weighted average scores for wetland vegetation were generally consistent with the results of the flooded area analysis. The WAP scores and weighted average scores were higher overall and did not decline with time at four wetlands in well fields (W-33, W-56, Starkey N, and Starkey 108) during the years following reductions in groundwater-withdrawal rates. These four wetlands also had increases in the extent and duration of the flooded area during the post-reduction period. Scores for trees were more consistent than scores for shrubs and groundcover. WAP scores remained relatively low or generally declined at five well-field wetlands (Q-1, W-17, W-41, Starkey D, and Starkey E) during the years following reductions in groundwater-withdrawal rates, and weighted average scores either declined over time or remained low. These five wetlands either did not have an increase in the extent and duration of the flooded area, or if there was an increase, it was small.

Florida↗

Simulated effects of increased groundwater withdrawals in the Cave Springs area, Hixson, Tennessee

Concern for future water supplies in Tennessee has grown in recent years as a result of increased awareness of competing needs, the impact of droughts, and the need for more water to support growing populations. The U.S. Geological Survey conducts investigations to improve the knowledge about interactions of geology, climate, humans, and ecosystems with the water cycle, which is critical to understanding and optimizing water availability. The Hixson Utility District in Hamilton County, Tennessee, uses groundwater resources in the Cave Springs area as a water supply, withdrawing water from two well fields located at Cave Springs and Walkers Corner. Historically, Hixson Utility District has withdrawn about 5 million gallons per day (Mgal/d) at the Cave Springs well field and between 2 and 3 Mgal/d at the Walkers Corner well field. To assess the capacity of the groundwater resources in the Cave Springs area to meet future demands, four different scenarios of increased groundwater withdrawals were analyzed using computer model simulations. In the study area, groundwater is present in both regolith and bedrock. Groundwater flow in the regolith occurs as diffuse flow as recharge from precipitation moves through the regolith to discharge to streams and springs or to the underlying bedrock. Most of the bedrock in the study area has low primary porosity and permeability; however, fracturing and dissolution have produced substantial secondary porosity and permeability. Groundwater flow through the bedrock occurs as both diffuse and conduit flow. Recharge to the aquifer is from two distinct sources: direct infiltration of precipitation and losing streams. A major source of recharge to the aquifer that supplies Cave Springs is surface water that is lost from North Chickamauga Creek as it flows from the Cumberland Plateau onto the Newman Limestone. Average annual streamflow loss (groundwater recharge) from this reach of North Chickamauga Creek for the period November 2000 through June 2006 is about 18 cubic feet per second (ft 3 /s). Groundwater leaves the aquifer as either discharge to North Chickamauga Creek, Poe Branch, and Lick Branch; discharge to Chickamauga Lake; spring flow to Cave Springs or Rogers Spring; or withdrawals at the Cave Springs or Walkers Corner well fields. Using computer model simulations, four scenarios of increased groundwater withdrawals were analyzed. Each of these four scenarios are compared to a base-case simulation that uses groundwater withdrawal rates from 2012 of 5.1 Mgal/d from the Cave Springs well field and 2.7 Mgal/d from the Walkers Corner well field. Under scenarios A and B, pumpage is increased at Cave Springs by 2 Mgal/d and 5 Mgal/d, respectively, while pumpage at Walkers Corner remains unchanged. Under scenarios C and D, pumpage is increased at Walkers Corner by 2.6 Mgal/d and 4.5 Mgal/d, respectively, while pumpage at Cave Springs remains unchanged. The effects of the increased withdrawals were analyzed by comparing water budget changes of the groundwater discharges to Chickamauga Lake, North Chickamauga Creek, Cave Springs, Poe Branch, and Lick Branch/Rogers Spring for each of the scenarios and evaluating changes in groundwater levels at the well fields. Under scenarios A and B, the largest change in the water budget occurs for flow to Cave Springs with decreases of 1.9 and 4.7 ft 3 /s, respectively. Similarly, groundwater discharge to North Chickamauga Creek decreases by 1.0 ft 3 /s and 2.6 ft 3 3/s, respectively. Under scenarios C and D, the largest change in the water budget occurs for flow to Chickamauga Lake with decreases of 1.3 ft 3 /s and 2.3 ft 3 /s, respectively. Similarly, groundwater discharge to North Chickamauga Creek decreases by 1.1 ft 3 /s and 2.1 ft 3 /s, respectively. Changes in groundwater levels at the well fields were also analyzed. At the Cave Springs well field, maximum declines in groundwater levels due to additional pumpage are less than 1 foot for all scenarios. Groundwater level changes at the Cave Springs well field are small due to the highly transmissive nature of the aquifer in this location. Maximum groundwater-level declines at Walkers Corner are less than 1 foot for scenarios A and B and about 52 feet and 82 feet for scenarios C and D, respectively. Under scenarios C and D, the regional potentiometric surface shows a large cone of depression centered on the Walkers Corner well field and elongated along geologic strike.

Tennessee↗

Groundwater-quality data in the Santa Barbara study unit, 2011: Results from the California GAMA Program

Groundwater quality in the 48-square-mile Santa Barbara study unit was investigated by the U.S. Geological Survey (USGS) from January to February 2011, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program’s Priority Basin Project (PBP). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The Santa Barbara study unit was the thirty-fourth study unit to be sampled as part of the GAMA-PBP. The GAMA Santa Barbara study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer system, and to facilitate statistically consistent comparisons of untreated-groundwater quality throughout California. The primary aquifer system is defined as those parts of the aquifers corresponding to the perforation intervals of wells listed in the California Department of Public Health (CDPH) database for the Santa Barbara study unit. Groundwater quality in the primary aquifer system may differ from the quality in the shallower or deeper water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. In the Santa Barbara study unit located in Santa Barbara and Ventura Counties, groundwater samples were collected from 24 wells. Eighteen of the wells were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells), and six wells were selected to aid in evaluation of water-quality issues (understanding wells). The groundwater samples were analyzed for organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, and pharmaceutical compounds); constituents of special interest (perchlorate and N-nitrosodimethylamine [NDMA]); naturally occurring inorganic constituents (trace elements, nutrients, major and minor ions, silica, total dissolved solids [TDS], alkalinity, and arsenic, chromium, and iron species); and radioactive constituents (radon-222 and gross alpha and gross beta radioactivity). Naturally occurring isotopes (stable isotopes of hydrogen and oxygen in water, stables isotopes of inorganic carbon and boron dissolved in water, isotope ratios of dissolved strontium, tritium activities, and carbon-14 abundances) and dissolved noble gases also were measured to help identify the sources and ages of the sampled groundwater. In total, 281 constituents and water-quality indicators were measured. Three types of quality-control samples (blanks, replicates, and matrix spikes) were collected at up to 12 percent of the wells in the Santa Barbara study unit, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Blanks rarely contained detectable concentrations of any constituent, suggesting that contamination from sample collection procedures was not a significant source of bias in the data for the groundwater samples. Replicate samples generally were within the limits of acceptable analytical reproducibility. Matrix-spike recoveries were within the acceptable range (70 to 130 percent) for approximately 82 percent of the compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is served to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH and to non-regulatory benchmarks established for aesthetic concerns by CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. All organic constituents and most inorganic constituents that were detected in groundwater samples from the 18 grid wells in the Santa Barbara study unit were detected at concentrations less than drinking-water benchmarks. Of the 220 organic and special-interest constituents sampled for at the 18 grid wells, 13 were detected in groundwater samples; concentrations of all detected constituents were less than regulatory and non-regulatory health-based benchmarks. In total, VOCs were detected in 61 percent of the 18 grid wells sampled, pesticides and pesticide degradates were detected in 11 percent, and perchlorate was detected in 67 percent. Polar pesticides and their degradates, pharmaceutical compounds, and NDMA were not detected in any of the grid wells sampled in the Santa Barbara study unit. Eighteen grid wells were sampled for trace elements, major and minor ions, nutrients, and radioactive constituents; most detected concentrations were less than health-based benchmarks. Exceptions are one detection of boron greater than the CDPH notification level (NL-CA) of 1,000 micrograms per liter (μg/L) and one detection of fluoride greater than the CDPH maximum contaminant level (MCL-CA) of 2 milligrams per liter (mg/L). Results for constituents with non-regulatory benchmarks set for aesthetic concerns from the grid wells showed that iron concentrations greater than the CDPH secondary maximum contaminant level (SMCL-CA) of 300 μg/L were detected in three grid wells. Manganese concentrations greater than the SMCL-CA of 50 μg/L were detected in seven grid wells. Chloride was detected at a concentration greater than the SMCL-CA recommended benchmark of 250 mg/L in four grid wells. Sulfate concentrations greater than the SMCL-CA recommended benchmark of 250 mg/L were measured in eight grid wells, and the concentration in one of these wells was also greater than the SMCL-CA upper benchmark of 500 mg/L. TDS concentrations greater than the SMCL-CA recommended benchmark of 500 mg/L were measured in 17 grid wells, and concentrations in six of these wells were also greater than the SMCL-CA upper benchmark of 1,000 mg/L.

California↗

Groundwater-quality data in the Bear Valley and Selected Hard Rock Areas study unit, 2010: Results from the California GAMA Program

Groundwater quality in the 112-square-mile Bear Valley and Selected Hard Rock Areas (BEAR) study unit was investigated by the U.S. Geological Survey (USGS) from April to August 2010, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program’s Priority Basin Project (PBP). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The BEAR study unit was the thirty-first study unit to be sampled as part of the GAMA-PBP. The GAMA Bear Valley and Selected Hard Rock Areas study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer system and to facilitate statistically consistent comparisons of untreated groundwater quality throughout California. The primary aquifer system is defined as the zones corresponding to the perforation intervals of wells listed in the California Department of Public Health (CDPH) database for the BEAR study unit. Groundwater quality in the primary aquifer system may differ from the quality in the shallow or deep water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. In the BEAR study unit, groundwater samples were collected from two study areas (Bear Valley and Selected Hard Rock Areas) in San Bernardino County. Of the 38 sampling sites, 27 were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the primary aquifer system in the study unit (grid sites), and the remaining 11 sites were selected to aid in the understanding of the potential groundwater-quality issues associated with septic tank use and with ski areas in the study unit (understanding sites). The groundwater samples were analyzed for organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, pharmaceutical compounds, and wastewater indicator compounds [WICs]), constituents of special interest (perchlorate, N-nitrosodimethylamine [NDMA], and 1,2,3-trichloropropane [1,2,3-TCP]), and inorganic constituents (trace elements, nutrients, dissolved organic carbon [DOC], major and minor ions, silica, total dissolved solids [TDS], alkalinity, and arsenic and iron species), and uranium and other radioactive constituents (radon-222 and activities of tritium and carbon-14). Isotopic tracers (of hydrogen and oxygen in water, of nitrogen and oxygen in dissolved nitrate, of dissolved boron, isotopic ratios of strontium in water, and of carbon in dissolved inorganic carbon) and dissolved noble gases (argon, helium-4, krypton, neon, and xenon) were measured to help identify the sources and ages of sampled groundwater. In total, groundwater samples were analyzed for 289 unique constituents and 8 water-quality indicators in the BEAR study unit. Quality-control samples (blanks, replicate pairs, or matrix spikes) were collected at 13 percent of the sites in the BEAR study unit, and the results for these samples were used to evaluate the quality of the data from the groundwater samples. Blank samples rarely contained detectable concentrations of any constituent, indicating that contamination from sample collection or analysis was not a significant source of bias in the data for the groundwater samples. Replicate pair samples all were within acceptable limits of variability. Matrix-spike sample recoveries were within the acceptable range (70 to 130 percent) for approximately 84 percent of the compounds. This study did not evaluate the quality of water delivered to consumers. After withdrawal, groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is delivered to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH, and to non-health-based benchmarks established for aesthetic concerns by CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. All concentrations of organic and special-interest constituents from grid sites sampled in the BEAR study unit were less than health-based benchmarks. In total, VOCs were detected in 17 of the 27 grid sites sampled (approximately 63 percent), pesticides and pesticide degradates were detected in 4 grid sites (approximately 15 percent), and perchlorate was detected in 21 grid sites (approximately 78 percent). Inorganic constituents (trace elements, major and minor ions, nutrients, and uranium and other radioactive constituents) were sampled for at 27 grid sites; most concentrations were less than health-based benchmarks. Exceptions include one detection of arsenic greater than the USEPA maximum contaminant level (MCL-US) of 10 micrograms per liter (μg/L), three detections of uranium greater than the MCL-US of 30 μg/L, nine detections of radon-222 greater than the proposed MCL-US of 4,000 picocuries per liter (pCi/L), and one detection of fluoride greater than the CDPH maximum contaminant level (MCL-CA) of 2 milligrams per liter. Concentrations of inorganic constituents with non-health-based benchmarks (iron, manganese, chloride, and TDS) were less than the CDPH secondary maximum contaminant level (SMCL-CA) in most grid sites. Exceptions include two detections of iron greater than the SMCL-CA of 300 μg/L and one detection of manganese greater than the SMCL-CA of 50 μg/L.

California↗

Simulation of the Groundwater-Flow System in Pierce, Polk, and St. Croix Counties, Wisconsin

Groundwater is the sole source of residential water supply in Pierce, Polk, and St. Croix Counties, Wisconsin. A regional three-dimensional groundwater-flow model and three associated demonstration inset models were developed to simulate the groundwater-flow systems in the three-county area. The models were developed by the U.S. Geological Survey in cooperation with the three county governments. The objectives of the regional model of Pierce, Polk, and St. Croix Counties were to improve understanding of the groundwaterflow system and to develop a tool suitable for evaluating the effects of potential water-management programs. The regional groundwater-flow model described in this report simulates the major hydrogeologic features of the modeled area, including bedrock and surficial aquifers, groundwater/surface-water interactions, and groundwater withdrawals from high-capacity wells. Results from the regional model indicate that about 82 percent of groundwater in the three counties is from recharge within the counties; 15 percent is from surface-water sources, consisting primarily of recirculated groundwater seepage in areas with abrupt surface-water-level changes, such as near waterfalls, dams, and the downgradient side of reservoirs and lakes; and 4 percent is from inflow across the county boundaries. Groundwater flow out of the counties is to streams (85 percent), outflow across county boundaries (14 percent), and pumping wells (1 percent). These results demonstrate that the primary source of groundwater withdrawn by pumping wells is water that recharges within the counties and would otherwise discharge to local streams and lakes. Under current conditions, the St. Croix and Mississippi Rivers are groundwater discharge locations (gaining reaches) and appear to function as 'fully penetrating' hydraulic boundaries such that groundwater does not cross between Wisconsin and Minnesota beneath them. Being hydraulic boundaries, however, they can change in response to water withdrawals. Tributary rivers act as 'partially penetrating' hydraulic boundaries such that groundwater can flow underneath them through the deep sandstone aquifers. The model also demonstrates the effects of development on groundwater in the study area. Water-level declines since predevelopment (no withdrawal wells) are most pronounced where pumping is greatest and flow between layered aquifers is impeded by confining units or faults. The maximum simulated water-level decline is about 40 feet in the deep Mount Simon aquifer below the city of Hudson, Wisconsin. Three inset models were extracted from the regional model to demonstrate the process and additional capabilities of the U.S. Geological Survey MODFLOW code. Although the inset models were designed to provide information about the groundwater-flow system, results from the inset models are presented for demonstration purposes only and are not sufficiently detailed or calibrated to be used for decisionmaking purposes without refinement. Simulation of groundwater/lake-water interaction around Twin Lakes near Roberts, in St. Croix County, Wisconsin, showed that groundwater represents approximately 5 to 20 percent of the overall lake-water budget. Groundwater-contributing areas to streams in western Pierce County are generally similar in size to the surface-water-contributing areas but do not necessarily correspond to the same land area. Transient streamflow simulations of Osceola Creek in Polk County demonstrate how stream base flow can be influenced not only by seasonal precipitation and recharge variability but also by systematic changes to the system, such as groundwater withdrawal from wells.

Scientific Investigations Report↗

Hydrogeology, groundwater seepage, nitrate distribution, and flux at the Raleigh hydrologic research station, Wake County, North Carolina, 2005-2007

rom 2005 to 2007, the U.S. Geological Survey and the North Carolina Department of Environment and Natural Resources, Division of Water Quality, conducted a study to describe the geologic framework, measure groundwater quality, characterize the groundwater-flow system, and describe the groundwater/surface-water interaction at the 60-acre Raleigh hydrogeologic research station (RHRS) located at the Neuse River Waste Water Treatment Plant in eastern Wake County, North Carolina. Previous studies have shown that the local groundwater quality of the surficial and bedrock aquifers at the RHRS had been affected by high levels of nutrients. Geologic, hydrologic, and water-quality data were collected from 3 coreholes, 12 wells, and 4 piezometers at 3 well clusters, as well as from 2 surface-water sites, 2 multiport piezometers, and 80 discrete locations in the streambed of the Neuse River. Data collected were used to evaluate the three primary zones of the Piedmont aquifer (regolith, transition zone, and fractured bedrock) and characterize the interaction of groundwater and surface water as a mechanism of nutrient transport to the Neuse River. A conceptual hydrogeologic cross section across the RHRS was constructed using new and existing data. Two previously unmapped north striking, nearly vertical diabase dikes intrude the granite beneath the site. Groundwater within the diabase dike appeared to be hydraulically isolated from the surrounding granite bedrock and regolith. A correlation exists between foliation and fracture orientation, with most fractures striking parallel to foliation. Flowmeter logging in two of the bedrock wells indicated that not all of the water-bearing fractures labeled as water bearing were hydraulically active, even when stressed by pumping. Groundwater levels measured in wells at the RHRS displayed climatic and seasonal trends, with elevated groundwater levels occurring during the late spring and declining to a low in the late fall. Vertical gradients in the groundwater discharge area near the Neuse River were complex and were affected by fluctuations in river stage, with the exception of a well completed in a diabase dike. Water-quality data from the wells and surface-water sites at the RHRS were collected continuously as well as during periodic sampling events. Surface-water samples collected from a tributary were most similar in chemical composition to groundwater found in the regolith and transition zone. Nitrate (measured as nitrite plus nitrate, as nitrogen) concentrations in the sampled wells and tributary ranged from about 5 to more than 120 milligrams per liter as nitrogen. Waterborne continuous resistivity profiling conducted on the Neuse River in the area of the RHRS measured areas of low apparent resistivity that likely represent groundwater contaminated by high concentrations of nitrate. These areas were located on either side of a diabase dike and at the outfall of two unnamed tributaries. The diabase dike preferentially directed the discharge of groundwater to the Neuse River and may isolate groundwater movement laterally. Discrete temperature measurements made within the pore water beneath the Neuse River revealed seeps of colder groundwater discharging into warmer surface water near a diabase dike. Water-quality samples collected from the pore water beneath the Neuse River indicated that nitrate was present at concentrations as high as 80 milligrams per liter as nitrogen on the RHRS side of the river. The highest concentrations of nitrate were located within pore water collected from an area near a diabase dike that was identified as a suspected seepage area. Hydraulic head was measured and pore water samples were collected from two 140-centimeter-deep (55.1-inch-deep) multiport piezometers that were installed in bed sediments on opposite sides of a diabase dike. The concentration of nitrate in pore water at a suspected seepage area ranged from 42 to 82 milligrams per liter as nitrogen with a median concentration of 79 milligrams per liter as nitrogen. On the opposite side of the dike, concentrations of nitrate in pore water samples ranged from 3 to 91 milligrams per liter as nitrogen with a median concentration of 52 milligrams per liter. At one of the multiport piezometers the vertical gradient of hydraulic head between the Neuse River and the groundwater was too small to measure. At the multiport piezometer located in the suspected seepage area, an upward gradient of about 0.1 was present and explains the occurrence of higher concentrations of nitrate near the sediment/water interface. Horizontal seepage flux from the surficial aquifer to the edge of the Neuse River was estimated for 2006. Along a 130-foot flow path, the estimated seepage flux ranged from –0.52 to 0.2 foot per day with a median of 0.09 foot per day. The estimated advective horizontal mass flux of nitrate along a 300-foot reach of the Neuse River ranged from –10.9 to 5 pounds per day with a median of 2.2 pounds per day. The total horizontal mass flux of nitrate from the surficial aquifer to the Neuse River along the 130-foot flow path was estimated to be about 750 pounds for all of 2006. Seepage meters were deployed on the bed of the Neuse River in the areas of the multiport piezometers on either side of the diabase dike to estimate rates of vertical groundwater discharge and flux of nitrate. The average estimated daily seepage flux differed by two orders of magnitude between seepage areas. The potential vertical flux of nitrate from groundwater to the Neuse River was estimated at an average of 2.5 grams per day near one of the multiport piezometers and an average of 784 grams per day at the other. These approximations suggest that under some hydrologic conditions there is the potential for substantial quantities of nitrate to discharge from the groundwater to the Neuse River.

North Carolina↗

Thirty years of regional groundwater-quality trend studies in the United States: Major findings and lessons learned

Changes in groundwater quality have been evaluated for more than 2,200 wells in 25 Principal Aquifers in the United States based on repeated decadal sampling (once every 10 years) from 1988 to 2021. The purpose of this study is to identify contaminants with changing concentrations, the locations and magnitude of those changes, the factors driving those changes, the obstacles to interpreting the changes, and approaches to ameliorate those obstacles. Sampling was conducted in 89 networks of 20–30 wells each that represent various geographic regions, aquifer types and land use types. Each network, and the wells that comprise them, are sampled on a rotating basis once every 10 years. Of the 28 constituents evaluated for trends, concentrations of Na, Cl, dissolved solids, SO 4 , and NO 3 exhibited statistically significant increases at the network level more frequently than other constituents. Factors affecting trends in Cl and NO 3 are emphasized in this study. Regional patterns show large increases of Cl in urban areas in the Northeast and Midcontinent, where road-deicing salt application rates are 10 to 100 times greater than in other regions of the country, and in semiarid and arid regions of the western United States, where evaporation concentrates solutes in recharge. The largest increases in NO 3 were in agricultural areas of the semiarid west, arid west and Pacific regions which are characterized by oxic groundwater, long-term increases in nitrogen fertilizer usage, and high rates of irrigation. However, finding a direct relation between increasing contaminant sources and corresponding groundwater quality response, particularly when sampling once every 10 years, can be complicated by factors such as uncertainty in the timing, mass, and location of contaminant sources, groundwater residence time (recharge date), geochemical conditions in the aquifer that affect contaminant transport, and variability in water quality due to climatic factors such as seasonality and hydrologic conditions. Understanding groundwater residence time allows the changes in groundwater quality to be evaluated in the context of recharge date rather than the sample date. Likewise, information on geochemical characteristics of the aquifer can be helpful for understanding relations between contaminant source inputs and groundwater concentrations. For example, oxic geochemical conditions in the aquifer may allow for conservative transport and accumulation of NO 3 in groundwater, whereas reducing environments could favor NO 3 degradation. Differences in hydrologic conditions (wetter or drier than average) on the date of sampling could impact the statistical results of sampling at decadal intervals and obscure long-term patterns. Samples collected under substantially different hydrologic conditions can be identified, and high-frequency sampling can improve interpretation of measured results in these cases. Although decadal sampling and associated water-quality interpretations have limitations, repeated, scheduled sampling of thousands of wells over multiple decades has great value for identifying and understanding long-term, regional groundwater-quality trends. Despite these limitations, the concepts presented herein provide options that could be used to interpret trends or changes when sampling over longer timespans, which is less common than trend networks with higher frequency sampling intervals.

Conterminous United States↗

The quality of our Nation's waters: Water quality in the Northern Atlantic Coastal Plain surficial aquifer system, Delaware, Maryland, New Jersey, New York, North Carolina, and Virginia, 1988-2009

The surficial aquifer system of the Northern Atlantic Coastal Plain is made up of unconfined aquifers that underlie most of the area. This aquifer system is a critical renewable source of drinking water and is the source of most flow to streams and of recharge to underlying confined aquifers. Millions of people rely on the surficial aquifer system for public and domestic water supply, in particular in the densely populated areas of Long Island, New York, and in southern New Jersey, but also in more rural areas. Because the aquifer sediments are permeable and the water table is shallow, the surficial aquifer system is vulnerable to contamination from chemicals that are applied to the land surface and carried into groundwater with infiltrating rainfall and snowfall. Major Findings The quality of most groundwater produced for public and domestic water supply is suitable for drinking, although contaminants at concentrations greater than human-health benchmarks have been detected in some places Nitrate is one of the most widespread contaminants in groundwater Radium occurs commonly in groundwater as a result of the degradation of uranium and thorium minerals naturally present in aquifer sediments Chemicals in groundwater move slowly and can be detected in the environment for several decades after they enter the surficial aquifer system

Delaware, Maryland, New Jersey, New York, North Ca↗

Nitrogen Loads in Groundwater Entering Back Bays and Ocean from Fire Island National Seashore, Long Island, New York

Fire Island is a barrier island that lies south of central Long Island, N.Y. It is about 60 km (37 mi) long and 0.5 km (1/4 mi) wide and is bounded by the Great South Bay, Narrow Bay, and Moriches Bay estuaries to the north; by the Atlantic Ocean to the south; by Fire Island Inlet to the west; and by Moriches Inlet to the east (fig. 1). Fire Island National Seashore (FIIS) encompasses a 42-km (26-mi) length of Fire Island that is bordered by Robert Moses State Park to the west and Smith Point County Park to the east (fig. 2). Interspersed throughout FIIS are 17 residential beach communities that together contain about 4,100 homes. The barrier island's summer population increases 50-fold through the arrival of summer residents and vacationers. The National Park Service (NPS) has established several facilities on the island to accommodate visitors to FIIS. About 2.2 million people visit at least one of the 17 communities and (or) Smith Point County Park, the waterways surrounding Fire Island, or a FIIS facility annually (National Park Service, 2007). Combined visitation on a peak-season weekend day can be as high as 100,000 (National Park Service, 2002). Most homes and businesses in the 17 barrier-island communities discharge untreated wastewater directly to the shallow (water-table) aquifer through private septic systems and cesspools; the NPS facilities discharge wastewater to this aquifer through leach fields and cesspools. (The community of Ocean Beach (fig. 2) has a treatment plant that discharges to tidewater.) Contaminants in sewage entering the shallow groundwater move through the flow system and are ultimately discharged to adjacent marine surface waters, where they can pose a threat to coastal habitats. A contaminant of major concern is nitrogen, which is derived from fertilizers and human waste. The continuous inflow of nitrogen to surface-water bodies can lead to increased production of phytoplankton and macroalgae, which in turn can cause oxygen depletion, decreases in size of estuarine fish and shellfish communities, and loss of submerged seagrass habitat through light limitation (Valiela and others, 1992). The FIIS boundary extends roughly 1.2 km (0.8 mi) into the back-barrier estuaries of Great South Bay, Narrow Bay, and Moriches Bay (fig. 1). Within this estuarine zone are extensive areas of seagrass, shellfish, and finfish habitat, as well as intense recreational activity (Bokuniewicz and others, 1993). Management strategies for protection of these habitats require data on (1) concentrations and movement of nutrients and other human-derived contaminants that enter the groundwater system from on-site septic systems, and (2) aquifer characteristics and groundwater flow patterns. These data can then be used in three-dimensional flow models of the shallow aquifer system to predict the rates of groundwater discharge to the marine surface waters that bound Fire Island and the concentrations of nitrogen entering these water bodies from the aquifer's discharge zones. In 2004, the U.S. Geological Survey (USGS), in cooperation with the NPS, began a 3-year investigation to (1) measure groundwater levels within four local study areas at FIIS, (2) collect groundwater samples from these areas for nutrient (nitrogen) analysis, (3) develop a three-dimensional model of the hydrologic system and adjacent saltwater bodies for groundwater-flow delineation and particle tracking, and (4) apply the results of groundwater-discharge simulations to calculate the annual nitrogen loads in these discharges, particularly those entering Great South Bay, which together with the other back bays receives an estimated 80 percent of the total groundwater discharge from Fire Island. The four areas on which the investigation focused were the communities of Kismet and Robbins Rest, the NPS Visitor Center at Watch Hill, and the undeveloped Otis Pike Fire Island High Dune Wilderness (shown in panels A, B, C, and D in fig. 2); these were

Open-File Report↗

Plan of study for the Ohio-Indiana carbonate-bedrock and glacial- aquifer system

The major aquifers of 35,000 sq mi area in western Ohio and eastern Indiana consist of Silurian and Devonian carbonate bedrock and Quaternary glacial deposits. These bedrock units and glacial deposits have been designated for study as part of the U.S. Geological Survey 's Regional Aquifer System Analysis program, a nationwide program to assess the regional hydrology, geology and water quality of the Nation 's most important aquifers. The purpose of the study is to define the hydrology, geochemistry, and geologic framework of the aquifer system within the Silurian and Devonian rocks and glacial deposits, with emphasis on describing the groundwater flow patterns and characterizing the water quality. The study, which began in 1988 , is expected to be completed in 1993. In 1980, the aquifers in the study area supplied more than 280 million gallons of water/day to industry, agriculture, and a population of more than 6.3 million people. With a projected future population growth to 7.1 million in 1990, and with intensified agricultural and industrial uses, water withdrawals from these bedrock and glacial aquifers are expected to be increased. The most significant groundwater problems in the study area result from the pronounced areal differences in availability and quality of the groundwater. These differences are related to the lateral discontinuity of many of the glacial deposits and to variations in secondary permeability of the bedrock aquifers associated with patterns of fracturing. Planned activities of the study include compilation of available geohydrologic and water quality data, such as groundwater levels, geohydrologic properties of aquifers, chemical analyses, land use and water use data, and ancillary data such as digital satellite images. Additional geohydrologic and water quality data may be collected from existing wells or wells that may be drilled for this study. A computerized, geographic information system will be used as a data base management tool and for spatial analysis and presentation of the data. A digital computer model will be developed to study the regional groundwater flow system and to investigate the effects of development on the aquifer system. (USGS)

Open-File Report↗

Hydrogeologic framework and conceptual model of the Red River alluvial aquifer east of Lake Texoma, southeastern Oklahoma, 1980–2022

The 1973 Oklahoma Groundwater Law (Oklahoma Statutes §82-1020.5) requires that the Oklahoma Water Resources Board conduct hydrologic investigations of the State’s groundwater basins to support a determination of the maximum annual yield for each groundwater basin. At present (2025), the Oklahoma Water Resources Board has not established a maximum annual yield for the Red River alluvial aquifer east of Lake Texoma. To support the evaluation and determination of a maximum annual yield, a hydrogeologic framework and conceptual groundwater-flow model were developed to assess groundwater availability in the Red River alluvial aquifer east of Lake Texoma. The scope of this hydrologic investigation is the alluvium and terrace containing the Red River alluvial aquifer in Oklahoma between Lake Texoma, the Texas State line, and the Arkansas State line, an extent referred to in this report as “the eastern part of the Red River alluvial aquifer.” Parts of the alluvium and terrace extent in Arkansas and Texas are included in some analyses to address hydrologic influences from outside the aquifer’s boundaries in Oklahoma. The eastern part of the Red River alluvial aquifer in southeastern Oklahoma consists of approximately 401,280 acres of Quaternary alluvium and terrace deposits associated with the Red River and its major tributaries. Mean annual recharge to the aquifer for the 1980–2022 study period was estimated to be 8.62 inches per year, or 17.98 percent of the mean annual precipitation over the same period (47.94 inches). This mean annual recharge rate is equivalent to an inflow of approximately 288,250 acre-feet per year for the eastern part of the Red River alluvial aquifer. Recharge estimated using the Soil-Water-Balance code accounts for 98.7 percent of the conceptual-model inflows to the eastern part of the Red River alluvial aquifer. Saturated-zone evapotranspiration accounts for 11.9 percent and net streambed seepage accounts for 87.4 percent of the outflows in the conceptual model.

Arkansas, Oklahoma, Texas↗

Geohydrologic framework of the coastal plain aquifers of South Carolina

The U.S. Geological Survey is conducting a series of investigations of aquifers throughout the United States as a part of the RASA (Regional Aquifer System Analysis) program. These investigations provide a comprehensive regional understanding of groundwater resources throughout the Nation. The Coastal Plain aquifers in South Carolina are being studied as a part of this program. An important part of a description of the groundwater resources is the development of a geohydrologic framework. Such a framework delineates the aquifers through which groundwater flows and the confining units which retard the flow of groundwater between aquifers. The Coastal Plain of South Carolina is underlain by a wedge of sediments that thickens from its inner margin, the Fall Line, to the coast and consists of sand, silt, clay, and limestone of Late Cretaceous to Holocene age. These sediments are underlain by pre-Cretaceous rocks consisting of consolidated sedimentary rocks of Triassic age and a complex of metamorphic and igneous rocks similar to those found near the surface in the Piedmont province of the State. The geohydrologic framework that divides the sediments of the South Carolina Coastal Plain into the Coastal Plain aquifer system is delineated by eleven geohydrologic sections and four maps showing the configuration of the top or base of individual aquifers. Although flow within the Coastal Plain aquifer system is three dimensional, simplifying the system by dividing it into a framework of discrete hydrologic units can aid significantly in understanding the hydrology of the system. This framework is the basis for the aquifers used in potentiometric mapping, transmissivity mapping, geochemical analysis, and groundwater flow modeling for the South Carolina RASA program. (Lantz-PTT)

South Carolina↗

The 2016 groundwater flow model for Dane County, Wisconsin

A new groundwater flow model for Dane County, Wisconsin, replaces an earlier model developed in the 1990s by the Wisconsin Geological and Natural History Survey (WGNHS) and the U.S. Geological Survey (USGS). This modeling study was conducted cooperatively by the WGNHS and the USGS with funding from the Capital Area Regional Planning Commission (CARPC). Although the overall conceptual model of the groundwater system remains largely unchanged, the incorporation of newly acquired high-quality datasets, recent research findings, and improved modeling and calibration techniques have led to the development of a more detailed and sophisticated model representation of the groundwater system. The new model is three-dimensional and transient, and conceptualizes the county’s hydrogeology as a 12-layer system including all major unlithified and bedrock hydrostratigraphic units and two high-conductivity horizontal fracture zones. Beginning from the surface down, the model represents the unlithified deposits as two distinct model layers (1 and 2). A single layer (3) simulates the Ordovician sandstone and dolomite of the Sinnipee, Ancell, and Prairie du Chien Groups. Sandstone of the Jordan Formation (layer 4) and silty dolostone of the St. Lawrence Formation (layer 5) each comprise separate model layers. The underlying glauconitic sandstone of the Tunnel City Group makes up three distinct layers: an upper aquifer (layer 6), a fracture feature (layer 7), and a lower aquifer (layer 8). The fracture layer represents a network of horizontal bedding-plane fractures that serve as a preferential pathway for groundwater flow. The model simulates the sandstone of the Wonewoc Formation as an upper aquifer (layer 9) with a bedding-plane fracture feature (layer 10) at its base. The Eau Claire aquitard (layer 11) includes shale beds within the upper portion of the Eau Claire Formation. This layer, along with overlying bedrock units, is mostly absent in the preglacially eroded valleys along the Yahara River valley and in northeastern Dane County. Layer 12 represents the Mount Simon sandstone as the lowermost model layer. It directly overlies the Precambrian crystalline basement rock, whose top surface forms the lower boundary of the model. The model uses the USGS MODFLOW-NWT finite-difference code, a standalone version of MODFLOW-2005 that incorporates the Newton (NWT) solver. MODFLOW-NWT improves the handling of unconfined conditions by smoothing the transition from wet to dry cells. The model explicitly simulates groundwater–surface-water interaction with streamflow routing and lake-level fluctuation. Model input included published and unpublished hydrogeologic data from recent estimates of aquifer hydraulic conductivities. A spatial groundwater recharge distribution was obtained from a recent GIS-based, soil-water-balance model for Dane County. Groundwater withdrawals from pumping were simulated for 572 wells across the entire model domain, which includes Dane County and portions of seven neighboring counties—Columbia, Dodge, Green, Iowa, Jefferson, Lafayette, and Rock. These wells withdrew an average of 60 million gallons per day (mgd) over the 5-year period from 2006 through 2010. Within Dane County, 385 wells were simulated with an average withdrawal rate of 52 mgd. Model calibration used the parameter estimation code PEST, and calibration targets included heads, stream and spring flows, lake levels, and borehole flows. Steady-state calibration focused on the period 2006 through 2010; the transient calibration focused on the 7-week drought period from late May through July 2012. This model represents a significant step forward from previous work because of its finer grid resolution, improved hydrostratigraphic discretization, transient capabilities, and more sophisticated representation of surface-water features and multi-aquifer wells. Potential applications of the model include evaluation of potential sites for and impacts of new high-capacity wells, development of wellhead protection plans, evaluating the effects of changing land use and climate on groundwater, and quantifying the relationships between groundwater and surface water.

Wisconsin↗

Potential effects of groundwater pumping on water levels, phreatophytes, and spring discharges in Spring and Snake Valleys, White Pine County, Nevada, and adjacent areas in Nevada and Utah

Assessing hydrologic effects of developing groundwater supplies in Snake Valley required numerical, groundwater-flow models to estimate the timing and magnitude of capture from streams, springs, wetlands, and phreatophytes. Estimating general water-table decline also required groundwater simulation. The hydraulic conductivity of basin fill and transmissivity of basement-rock distributions in Spring and Snake Valleys were refined by calibrating a steady state, three-dimensional, MODFLOW model of the carbonate-rock province to predevelopment conditions. Hydraulic properties and boundary conditions were defined primarily from the Regional Aquifer-System Analysis (RASA) model except in Spring and Snake Valleys. This locally refined model was referred to as the Great Basin National Park calibration (GBNP-C) model. Groundwater discharges from phreatophyte areas and springs in Spring and Snake Valleys were simulated as specified discharges in the GBNP-C model. These discharges equaled mapped rates and measured discharges, respectively. Recharge, hydraulic conductivity, and transmissivity were distributed throughout Spring and Snake Valleys with pilot points and interpolated to model cells with kriging in geologically similar areas. Transmissivity of the basement rocks was estimated because thickness is correlated poorly with transmissivity. Transmissivity estimates were constrained by aquifer-test results in basin-fill and carbonate-rock aquifers. Recharge, hydraulic conductivity, and transmissivity distributions of the GBNP-C model were estimated by minimizing a weighted composite, sum-of-squares objective function that included measurement and Tikhonov regularization observations. Tikhonov regularization observations were equations that defined preferred relations between the pilot points. Measured water levels, water levels that were simulated with RASA, depth-to-water beneath distributed groundwater and spring discharges, land-surface altitudes, spring discharge at Fish Springs, and changes in discharge on selected creek reaches were measurement observations. The effects of uncertain distributed groundwater-discharge estimates in Spring and Snake Valleys on transmissivity estimates were bounded with alternative models. Annual distributed groundwater discharges from Spring and Snake Valleys in the alternative models totaled 151,000 and 227,000 acre-feet, respectively and represented 20 percent differences from the 187,000 acre-feet per year that discharges from the GBNP-C model. Transmissivity estimates in the basin fill between Baker and Big Springs changed less than 50 percent between the two alternative models. Potential effects of pumping from Snake Valley were estimated with the Great Basin National Park predictive (GBNP-P) model, which is a transient groundwater-flow model. The hydraulic conductivity of basin fill and transmissivity of basement rock were the GBNP-C model distributions. Specific yields were defined from aquifer tests. Captures of distributed groundwater and spring discharges were simulated in the GBNP-P model using a combination of well and drain packages in MODFLOW. Simulated groundwater captures could not exceed measured groundwater-discharge rates. Four groundwater-development scenarios were investigated where total annual withdrawals ranged from 10,000 to 50,000 acre-feet during a 200-year pumping period. Four additional scenarios also were simulated that added the effects of existing pumping in Snake Valley. Potential groundwater pumping locations were limited to nine proposed points of diversion. Results are presented as maps of groundwater capture and drawdown, time series of drawdowns and discharges from selected wells, and time series of discharge reductions from selected springs and control volumes. Simulated drawdown propagation was attenuated where groundwater discharge could be captured. General patterns of groundwater capture and water-table declines were similar for all scenarios. Simulated drawdowns greater than 1 ft propagated outside of Spring and Snake Valleys after 200 years of pumping in all scenarios.

Scientific Investigations Report↗

Groundwater conditions in Georgia, 2010–2011

The U.S. Geological Survey collects groundwater data and conducts studies to monitor hydrologic conditions, better define groundwater resources, and address problems related to water supply, water use, and water quality. In Georgia, water levels were monitored continuously at 186 wells during calendar year 2010 and at 181 wells during calendar year 2011. Because of missing data or short periods of record (less than 3 years) for several of these wells, a total of 168 wells are discussed in this report. These wells include 17 in the surficial aquifer system, 19 in the Brunswick aquifer system and equivalent sediments, 70 in the Upper Floridan aquifer, 16 in the Lower Floridan aquifer and underlying units, 10 in the Claiborne aquifer, 1 in the Gordon aquifer, 11 in the Clayton aquifer, 14 in the Cretaceous aquifer system, 2 in Paleozoic-rock aquifers, and 8 in crystalline-rock aquifers. Data from the well network indicate that water levels generally declined during the 2010 through 2011 calendar-year period, with water levels declining in 158 wells and rising in 10. Water levels declined over the period of record at 106 wells, increased at 56 wells, and remained relatively constant at 6 wells. In addition to continuous water-level data, periodic water-level measurements were collected and used to construct potentiometric-surface maps for the Upper Floridan aquifer in Camden, Charlton, and Ware Counties, Georgia, and adjacent counties in Florida during May–June 2010, and in the following areas in Georgia: the Brunswick area during August 2010 and August 2011, in the Albany–Dougherty County area during November 2010 and November 2011, and in the Augusta–Richmond County area during October 2010 and August 2011. In general, water levels in these areas were lower during 2011 than during 2010; however, the configuration of the potentiometric surfaces in each of the areas showed little change. Groundwater quality in the Floridan aquifer system is monitored in the Albany, Savannah, and Brunswick areas of Georgia. In the Albany area, nitrate as nitrogen concentrations in the Upper Floridan aquifer during 2011 generally decreased from 2010; however, concentrations in two wells remained above the U.S. Environmental Protection Agency (USEPA) 10-milligrams-per-liter (mg/L) drinking-water standard. In the Savannah area, specific conductance and chloride concentrations were measured in water samples from discrete depths in two wells completed in the Upper Floridan aquifer. Data from the two wells indicate that chloride concentrations in the Upper Floridan aquifer showed little change during calendar years 2010 through 2011 and remained below the 250 mg/L USEPA secondary drinking-water standard. During calendar years 2010 through 2011, chloride concentrations in the Lower Floridan aquifer increased slightly at Tybee Island and Skidaway Island, remaining above the drinking-water standard. In the Brunswick area, maps showing the chloride concentration of water in the Upper Floridan aquifer constructed using data collected from 32 wells during August 2010 and from 30 wells during August 2011 indicate that chloride concentrations remained above the USEPA secondary drinking-water standard in an approximately 2-square-mile area. During calendar years 2010 through 2011, chloride concentrations generally decreased in over 70 percent of the wells sampled during 2011, with a maximum decrease of 200 mg/L in a well located in the north-central part of the Brunswick area.

Georgia↗

Evaluation of water quality in the Langford Valley–Irwin Groundwater Subbasin, Fort Irwin National Training Center, California, 1993–2019

The U.S. Army Fort Irwin National Training Center (NTC), 120 miles northeast of Los Angeles in the Mojave Desert of California, obtains its potable water supply from the Bicycle Valley and Langford Valley groundwater basins; Langford Valley groundwater basin is further subdivided into the Langford Well Lake and Irwin groundwater subbasins. The Irwin groundwater subbasin contains younger, unconsolidated deposits that have a saturated thickness of as much as 200 feet (ft) and a lower aquifer within older unconsolidated deposits as thick as 650 ft. Groundwater recharge under predevelopment conditions (before 1941) occurred primarily from infiltration of intermittent streamflow in small washes that cross the Irwin groundwater subbasin. Since that time, groundwater recharge has increased because of growth of the NTC in recent years and as a result of other processes, including (1) infiltration of treated wastewater into the aquifer through ponds near the NTC wastewater treatment facility (WWTF) and (2) infiltration of imported water and treated wastewater used for landscape irrigation at base housing and athletic fields. Water samples were collected from 17 wells and analyzed for field parameters, chemical constituents, and isotope composition in the Irwin groundwater subbasin between 2014 and 2019. These data were supplemented with water-chemistry data collected during 1993–95 and at other times if available. Between 1993–95 and 2015–19, median dissolved solids and nitrate concentrations in water from wells in the Irwin groundwater subbasin increased from 620 to 1,030 milligrams per liter (mg/L) and from 2.8 to 4.5 mg/L as nitrogen, respectively. After 2014, dissolved solids and nitrate concentrations in water from wells near the NTC WWTF decreased as a result of changes in source water quality attributable to reverse osmosis of treated drinking water delivered within the Irwin groundwater subbasin and to increased levels of treatment at the NTC WWTF. Based on delta oxygen-18 and delta deuterium isotope data, increases in dissolved solids concentrations in water from most wells were consistent with evaporation prior to recharge and mobilization of soluble salts from the unsaturated zone. Arsenic and fluoride concentrations in water from wells decreased between 1993–95 and 2015–19 as the basin filled with treated wastewater, but 2015–19 concentrations generally exceeded the California State Water Resources Control Board maximum contaminant levels of 10 micrograms per liter for arsenic and 2 mg/L for fluoride. Most groundwater in the Irwin groundwater subbasin has unadjusted carbon-14 ages ranging from 18,400 to 12,350 years before present. However, water from well 10E3, located along the wash near the subbasin outflow in the southeastern part of the Irwin groundwater subbasin, contained measurable tritium, which is consistent with infiltration of intermittent streamflow and groundwater recharge from the wash after 1952. Chemical and isotopic data indicate that treated wastewater is present in water from most wells in the upper aquifer that underlies the Irwin groundwater subbasin. Wells were not sampled to adequately determine the extent of treated wastewater and changes in water quality within the lower aquifer that underlies the Irwin groundwater subbasin.

California↗

The Effect of modeled recharge distribution on simulated groundwater availability and capture

Simulating groundwater flow in basin-fill aquifers of the semiarid southwestern United States commonly requires decisions about how to distribute aquifer recharge. Precipitation can recharge basin-fill aquifers by direct infiltration and transport through faults and fractures in the high-elevation areas, by flowing overland through high-elevation areas to infiltrate at basin-fill margins along mountain fronts, by flowing overland to infiltrate along ephemeral channels that often traverse basins in the area, or by some combination of these processes. The importance of accurately simulating recharge distributions is a current topic of discussion among hydrologists and water managers in the region, but no comparative study has been performed to analyze the effects of different recharge distributions on groundwater simulations. This study investigates the importance of the distribution of aquifer recharge in simulating regional groundwater flow in basin-fill aquifers by calibrating a groundwater-flow model to four different recharge distributions, all with the same total amount of recharge. Similarities are seen in results from steady-state models for optimized hydraulic conductivity values, fit of simulated to observed hydraulic heads, and composite scaled sensitivities of conductivity parameter zones. Transient simulations with hypothetical storage properties and pumping rates produce similar capture rates and storage change results, but differences are noted in the rate of drawdown at some well locations owing to the differences in optimized hydraulic conductivity. Depending on whether the purpose of the groundwater model is to simulate changes in groundwater levels or changes in storage and capture, the distribution of aquifer recharge may or may not be of primary importance.

Arizona↗