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Groundwater & aquifers

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USGS2014

Stream seepage and groundwater levels, Wood River Valley, south-central Idaho, 2012-13

Stream discharge and water levels in wells were measured at multiple sites in the Wood River Valley, south-central Idaho, in August 2012, October 2012, and March 2013, as a component of data collection for a groundwater-flow model of the Wood River Valley aquifer system. This model is a cooperative and collaborative effort between the U.S. Geological Survey and the Idaho Department of Water Resources. Stream-discharge measurements for determination of seepage were made during several days on three occasions: August 27–28, 2012, October 22–24, 2012, and March 27–28, 2013. Discharge measurements were made at 49 sites in August and October, and 51 sites in March, on the Big Wood River, Silver Creek, their tributaries, and nearby canals. The Big Wood River generally gains flow between the Big Wood River near Ketchum streamgage (13135500) and the Big Wood River at Hailey streamgage (13139510), and loses flow between the Hailey streamgage and the Big Wood River at Stanton Crossing near Bellevue streamgage (13140800). Shorter reaches within these segments may differ in the direction or magnitude of seepage or may be indeterminate because of measurement uncertainty. Additional reaches were measured on Silver Creek, the North Fork Big Wood River, Warm Springs Creek, Trail Creek, and the East Fork Big Wood River. Discharge measurements also were made on the Hiawatha, Cove, District 45, Glendale, and Bypass Canals, and smaller tributaries to the Big Wood River and Silver Creek. Water levels in 93 wells completed in the Wood River Valley aquifer system were measured during October 22–24, 2012; these wells are part of a network established by the U.S. Geological Survey in 2006. Maps of the October 2012 water-table altitude in the unconfined aquifer and the potentiometric-surface altitude of the confined aquifer have similar topology to those on maps of October 2006 conditions. Between October 2006 and October 2012, water-table altitude in the unconfined aquifer rose by as much as 1.86 feet in 6 wells and declined by as much as 14.28 feet in 77 wells; average decline was 2.9 feet. A map of changes in the water‑table altitude of the unconfined aquifer shows that the largest declines were in tributary canyons and in an area roughly between Baseline and Glendale Roads. From October 2006 to October 2012, the potentiometric-surface altitude in 10 wells completed in the confined aquifer declined between 0.12 and 20.50 feet; average decline was 6.8 feet. A map of changes in the potentiometric-surface altitude of the confined aquifer shows that the largest declines were in the southwestern part of the Bellevue fan. Reduced precipitation prior to the October 2012 water-level measurements likely is partially responsible for 2006–12 water-table declines in the unconfined aquifer; the relative contribution of precipitation deficit and groundwater withdrawals to the declines is not known. Although the confined aquifer may not receive direct recharge from precipitation or streams, groundwater withdrawal from the confined aquifer induces flow from the unconfined aquifer. Declines in the confined aquifer are likely due to groundwater withdrawals and declines in the water table of the unconfined aquifer. A statistical analysis of five long-term monitoring wells (three completed in the unconfined aquifer, one in the confined aquifer, and one outside the aquifer system boundary) showed statistically significant declining trends in four wells.

Idaho↗

USGS2014

Stream-water and groundwater quality in and near the Citizen Potawatomi Nation Tribal Jurisdictional Area, Pottawatomie County, Oklahoma, 2012-13

The Citizen Potawatomi Nation needs to characterize their existing surface-water and groundwater resources in and near their tribal jurisdictional area to complete a water-resource management plan. Water resources in this area include surface water from the North Canadian and Little Rivers and groundwater from the terrace and alluvial aquifers and underlying bedrock aquifers. To assist in this effort, the U.S. Geological Survey (USGS), in cooperation with the Citizen Potawatomi Nation, collected water-quality samples at 4 sites on 3 streams and from 30 wells during 2012 and 2013 in and near the Citizen Potawatomi Nation Tribal Jurisdictional Area in central Oklahoma. Stream samples were collected eight times on the North Canadian River at the upstream USGS streamflow-gaging station North Canadian River near Harrah, Okla. (07241550); at the downstream USGS streamflow-gaging station North Canadian River at Shawnee, Okla. (07241800); and on the Little River at the USGS streamflow-gaging station Little River near Tecumseh, Okla., (07230500). Stream samples also were collected three times at an ungaged site, Deer Creek near McLoud, Okla. (07241590). Water properties were measured, and water samples were analyzed for concentrations of major ions, nutrients, trace elements, counts of fecal-indicator bacteria, and 69 organic compounds. The highest concentrations of dissolved solids and chlorides were measured in stream-water samples collected at the Little River near Tecumseh station. The Secondary Maximum Contaminant Level (SMCL) for dissolved solids in drinking water of 500 milligrams per liter (mg/L) was exceeded in 7 of 8 stream-water samples, with a median concentration of 844 mg/L at that station. The 250-mg/L SMCL for chloride was exceeded in 5 of the 8 stream-water samples collected at that station. Median concentrations of total dissolved nitrogen were about an order of magnitude higher in stream-water samples collected at the two stations on the North Canadian River than concentrations in stream-water samples collected at the Little River near Tecumseh station and the Deer Creek site. Median concentrations of total dissolved nitrogen were 4.36 and 2.89 mg/L in stream-water samples collected at the two North Canadian River stations, 0.35 mg/L in stream-water samples collected at the Little River near Tecumseh station, and 0.76 mg/L in stream-water samples collected at the Deer Creek site. Similar to nitrogen, median concentrations of total dissolved phosphorus were higher by about two orders of magnitude in stream-water samples collected at the two stations on the North Canadian River than concentrations in stream-water samples collected at the Little River near Tecumseh station and the Deer Creek site. Median concentrations of total dissolved phosphorus were 1.05 and 0.805 mg/L in stream-water samples collected at the two North Canadian River stations, 0.007 mg/L in stream-water samples collected at the Little River near Tecumseh station, and 0.032 mg/L from the Deer Creek site. Dissolved concentrations of total nitrogen, nitrate-nitrogen, orthophosphorus, and total phosphorus were highest in stream-water samples collected at the two North Canadian River stations at low streamflows, indicating that wastewater effluent may have been a notable source of these nutrients. Concentrations of most trace elements increased with increasing streamflow in stream-water samples collected at the two North Canadian River stations, indicating that most trace elements are washed into the river by runoff from the land surface or resuspended from streambed sediments. In general, most trace-element concentrations were below respective Maximum Contaminant Levels (MCLs) for public drinking-water supplies, except for one stream-water sample with an arsenic concentration of 10.1 micrograms per liter (µg/L) collected from the North Canadian River and one stream-water sample with a barium concentration of 2,690 µg/L collected from the Little River. At least one stream-water sample from each of the four stream sites sampled in this study contained a lead concentration exceeding the SMCL of 15 µg/L. All of these samples were collected during high streamflows. A greater number of organic compounds were detected in stream-water samples collected at the two stations on the North Canadian River than in stream-water samples collected at the Tecumseh station and Deer Creek site. In the 8 stream-water samples collected at the upstream Harrah station, 213 detections of organic compounds were measured, whereas in 8 samples collected at the downstream Shawnee station, 203 detections of organic compounds were measured. In contrast, 59 detections of organic compounds were measured in the 8 stream-water samples collected at the Tecumseh station, and 25 detections of organic compounds were measured in the 3 stream-water samples collected at the Deer Creek site; however, the 8 detections of 7 organic compounds in the 2 equipment-blank samples is problematic for evaluating these data, especially for the Deer Creek and Little River samples because of the comparatively low detection frequency and should be taken into consideration when evaluating these results. Groundwater samples also were collected once from 30 wells producing water from the Garber-Wellington aquifer; Admire, Chase, and Council Grove Groups; the Vanoss Formation; and the terrace and alluvial aquifers along the North Canadian River. Water properties were measured, and samples were analyzed for concentrations of major ions, nutrients, trace elements, and selected radionuclides in groundwater. Of 30 wells sampled for this study, 26 were completed in bedrock aquifers, and 4 were completed in terrace and alluvial aquifers. In general, groundwater in the study area is very hard, with a median concentration of 180 mg/L as calcium carbonate in water samples collected from the 30 wells. Concentrations of sulfate exceeded the 250-mg/L SMCL in two groundwater samples, and dissolved solids concentrations exceeded the 500-mg/L SMCL in nine groundwater samples. Trace-element concentrations did not exceed respective MCLs in the 30 groundwater samples collected for this study. Concentrations of the radionuclide uranium ranged from 0.03 to 79.5 µg/L, with a median concentration of 1.9 µg/L in the 30 groundwater samples collected. Two of the groundwater samples collected for this study had uranium concentrations exceeding the MCL of 30 µg/L, with concentrations of 79.5 and 31.1 µg/L. Generally, uranium concentrations were highest in water samples collected from wells completed in the Wellington Formation and the Chase, Council Grove, and Admire Groups in the southern and eastern parts of the study area.

Oklahoma↗

USGS2020

Hydrogeologic framework and simulation of predevelopment groundwater flow, eastern Abu Dhabi Emirate, United Arab Emirates

Groundwater in eastern Abu Dhabi in the United Arab Emirates is an important resource that is widely used for irrigation and domestic supplies in rural areas. The U.S. Geological Survey and the Environment Agency—Abu Dhabi cooperated on an investigation to integrate existing hydrogeologic information and to answer questions about regional groundwater resources in Abu Dhabi by developing a numerical groundwater flow model based on MODFLOW–2005 software. The groundwater flow model developed in this investigation provides an improved understanding of groundwater conditions in the eastern region of the Emirate of Abu Dhabi. The flow model simulates steady-state predevelopment conditions from before the rapid growth of modern pumping in the 1980s and was calibrated with 1,342 groundwater-level observations by use of automated and manual calibration techniques. The calibrated model provides good accuracy, with a mean error of 0.50 meters and a standard error of 5.92 meters for simulated groundwater levels. The results of the regional water budget simulation show that gap recharge, which is groundwater inflow through mountain-front gap alluvium, is the greatest source of water to the aquifer. In the base simulation scenario, gap recharge represents 80 percent of total inflow (119,470 of 149,403 cubic meters per day) and the greatest outflow from the aquifer is from evapotranspiration (93 percent of total outflow). Model scenario and sensitivity results reveal a need for data that more thoroughly and more accurately describe aquifer hydraulic conductivity, inflow to the aquifer from the Oman Mountains, and recharge from precipitation on the piedmont. Additional long-term aquifer pumping test observations would improve understanding of aquifer hydraulic conductivity, which would also improve model accuracy. Future studies can modify the model to understand the effect of land-use change and water use on groundwater supplies and simulate more complex groundwater flow conditions in a predictive mode.

Scientific Investigations Report↗

USGS2011

Effect of tidal fluctuations on transient dispersion of simulated contaminant concentrations in coastal aquifers

Variable-density groundwater models require extensive computational resources, particularly for simulations representing short-term hydrologic variability such as tidal fluctuations. Saltwater-intrusion models usually neglect tidal fluctuations and this may introduce errors in simulated concentrations. The effects of tides on simulated concentrations in a coastal aquifer were assessed. Three analyses are reported: in the first, simulations with and without tides were compared for three different dispersivity values. Tides do not significantly affect the transfer of a hypothetical contaminant into the ocean; however, the concentration difference between tidal and non-tidal simulations could be as much as 15%. In the second analysis, the dispersivity value for the model without tides was increased in a zone near the ocean boundary. By slightly increasing dispersivity in this zone, the maximum concentration difference between the simulations with and without tides was reduced to as low as 7%. In the last analysis, an apparent dispersivity value was calculated for each model cell using the simulated velocity variations from the model with tides. Use of apparent dispersivity values in models with a constant ocean boundary seems to provide a reasonable approach for approximating tidal effects in simulations where explicit representation of tidal fluctuations is not feasible.

Hydrogeology Journal↗

USGS2011

Groundwater-quality data in the northern Coast Ranges study unit, 2009: Results from the California GAMA Program

Groundwater quality in the 633-square-mile Northern Coast Ranges (NOCO) study unit was investigated by the U.S. Geological Survey (USGS) from June to November 2009, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program's Priority Basin Project (PBP) and the U.S. Geological Survey National Water-Quality Assessment Program (NAWQA). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The NOCO study unit was the thirtieth study unit to be sampled as part of the GAMA-PBP. The GAMA Northern Coast Ranges study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer systems, and to facilitate statistically consistent comparisons of untreated groundwater quality throughout California. The primary aquifer systems (hereinafter referred to as primary aquifers) are defined as that part of the aquifer corresponding to the perforation intervals of wells listed in the California Department of Public Health (CDPH) database for the NOCO study unit. The quality of groundwater in shallow or deep water-bearing zones may differ from the quality of groundwater in the primary aquifers; shallow groundwater may be more vulnerable to surficial contamination. In the NOCO study unit, groundwater samples were collected from 58 wells in 2 study areas (Interior Basins and Coastal Basins) in Napa, Lake, Mendocino, Glenn, Humboldt, and Del Norte Counties. The 58 wells were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the study areas. GAMA-PBP wells sampled as part of the spatially-distributed, randomized grid-cell network are referred to as "grid wells."The groundwater samples were analyzed for organic and special-interest constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, and perchlorate), naturally occurring inorganic constituents (trace elements, nutrients, dissolved organic carbon [DOC], major and minor ions, silica, total dissolved solids [TDS], and alkalinity), radioactive constituents (radon-222, radium isotopes, gross alpha and gross beta radioactivity, lead-210, and polonium-210), and microbial indicators (F-specific and somatic coliphage, Escherichia coli [E. coli] and total coliform). Naturally occurring isotopes (stable isotopes of hydrogen and oxygen in water, stable isotopes of carbon in dissolved inorganic carbon, activities of tritium, and carbon-14 abundance), and dissolved noble gases also were measured to identify the sources and ages of the sampled groundwater. In total, 239 constituents and 12 field water-quality indicators were measured. Three types of quality-control samples (blanks, replicates, and matrix-spikes) were collected at up to 12 percent of the wells in the NOCO study unit, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Blanks rarely contained detectable concentrations of any constituent, suggesting that contamination from sample collection procedures was not a significant source of bias in the data for the groundwater samples. Replicate samples generally were within the limits of acceptable analytical reproducibility. Matrix-spike recoveries were within the acceptable range (70 to 130 percent) for approximately 89 percent of the compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is served to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwa

Data Series↗

USGS2021

Groundwater hydrology and chemistry of Jamestown Island, Virginia—Potential effects of tides, storm surges, and sea-level rise on archaeological, cultural, and ecological resources

As the site of the first permanent English settlement in North America in 1607, Jamestown Island, Colonial National Historical Park (COLO), Virginia, contains a rich archaeological record that extends from the Paleoindian period (15,000 to 8,000 years ago) through the 20th century. The island is located on the lower James River near the mouth of Chesapeake Bay. Jamestown Island vegetation is dominated by upland forests surrounded by tidal, freshwater-to-oligohaline marshes. Along the Virginia coast, relative sea-level rise was more than 2.5 times the global average during the 20th century. Consequently, the National Park Service (NPS) has identified COLO as one of the 25 national parks most threatened by climate change. Surface waters across the island are hydraulically connected to the laterally continuous Surficial aquifer. The land-surface altitude of the island is low, with two-thirds of the island less than 5 feet (ft) above the North American Vertical Datum of 1988 (NAVD 88). Consequently, sea-level rise, combined with tides and storm surges, threatens the island and its resources as surface-water and groundwater levels rise, saltwater enters the Surficial aquifer, and groundwater chemistry changes. The impact of sea-level rise on the island’s surface-water resources has been well studied, but groundwater effects have been largely ignored. Quantifying the effects of tides, storm surges, and sea-level rise on groundwater levels and chemistry is essential to developing an effective strategy for managing climate-induced changes. The first step in developing a response strategy includes a parkwide general risk assessment for archaeological sites on the island, so that sites can be prioritized for management actions. The U.S. Geological Survey and the NPS began a study in 2015 to develop a long-term groundwater-monitoring program to evaluate this risk and to develop an updated management strategy. The groundwater-monitoring program consists of 45 wells and piezometers in two individual clusters and three transects across the island in different hydrologic and chemical settings. Samples for water quality were collected from the wells and piezometers from October 2015 through September 2018 at variable time intervals. Results of the monitoring identified disparate hydrologic and chemical responses to saltwater intrusion across the island. Specific conductance (an indicator of salinity) of groundwater beneath several marshes responded differently to changes in James River salinity. Groundwater response to changes in James River specific conductance appeared to be controlled by land-surface altitude and slope, differences in lateral and vertical sediment characteristics, distance from surface waters, and the degree of surface water/groundwater connectivity between channels and the aquifer. Groundwater chemistry data from monitoring wells at Black Point, a low-altitude, upland setting, are in contrast with conditions observed in Island House observation wells, a high-altitude, upland setting. Specific conductance (less than 200 microsiemens per centimeter [μS/cm]) and pH (greater than 5.0) of groundwater beneath much of the uplands that characterize the Island House observation wells are typical of groundwater in noncarbonate sedimentary aquifers recharged by precipitation. At Black Point, specific conductance ranged from 2,490 to 15,200 μS/cm, and pH ranged from 3.1 to 6.6 standard units. At the Black Point observation wells, the most saline and dense water was at the water table rather than deeper in the aquifer, causing a density inversion that persisted throughout the study. The density inversion likely resulted from differences in permeability between the shallow clay and fine-grained sands and the deeper coarse-grained sand and gravel. Groundwater with the lowest pH was at the water table. As saline groundwater flows through organic sediment beneath the marshes, bacterial biodegradation of organic matter creates anoxic conditions. Continued biodegradation concomitantly reduces iron-oxide minerals in the sediment and sulfate in saline water. When oxygen is reintroduced into groundwater, iron and sulfur can reoxidize to form sulfuric acid, locally lowering the pH of the water. This report describes the groundwater monitoring network design, rationale for site selection, monitoring approach, and results of monitoring from October 2015 through September 2018. Maps of inundation at selected water-level altitudes are included to identify the risk to archaeological, cultural, and ecological resources. The monitoring results of the hydrology and chemistry data are interpreted, and the different hydrologic and chemical settings are described. The implications of the study results for management decisions are presented, and suggestions for improving the monitoring network are included.

Virginia↗

USGS2016

Potentiometric surfaces, summer 2013 and winter 2015, and select hydrographs for the Southern High Plains aquifer, Cannon Air Force Base, Curry County, New Mexico

Cannon Air Force Base (Cannon AFB) is located in the High Plains physiographic region of east-central New Mexico, about 5 miles west of Clovis, New Mexico. The area surrounding Cannon AFB is primarily used for agriculture, including irrigated cropland and dairies. The Southern High Plains aquifer is the principal source of water for Cannon AFB, for the nearby town of Clovis, and for local agriculture and dairies. The Southern High Plains aquifer in the vicinity of Cannon AFB consists of three subsurface geological formations: the Chinle Formation of Triassic age, the Ogallala Formation of Tertiary age, and the Blackwater Draw Formation of Quaternary age. The Ogallala Formation is the main water-yielding formation of the Southern High Plains aquifer. Groundwater-supplied, center-pivot irrigation dominates pumping from the Southern High Plains aquifer in the area surrounding Cannon AFB, where the irrigation season typically extends from early March through October. The U.S. Geological Survey has been monitoring groundwater levels in the vicinity of Cannon AFB since 1954 and has developed general potentiometric-surface maps that show groundwater flow from northwest to southeast in the study area. While previous potentiometric-surface maps show the general direction of groundwater flow, a denser well network is needed to show details of groundwater flow at a local scale. Groundwater levels were measured in 93 wells during summer 2013 and 100 wells during winter 2015. The summer and winter potentiometric-surface maps display the presence of what is interpreted to be a groundwater trough trending from the northwest to the southeast through the study area. This groundwater trough may be the hydraulic expression of a Tertiary-age paleochannel. Groundwater north of the trough flows in a southerly direction into the trough, and groundwater south of the trough flows in an easterly direction into the trough. During the 18-month period between summer 2013 and winter 2015, changes in groundwater levels ranged from a rise of 10.0 to a decline of 3.8 feet. The regions to the north and south of the groundwater trough contained the majority of the rises in groundwater levels, whereas the regions within the trough contained the majority of the declines in groundwater levels. In contrast, the long-term groundwater-level trend in wells with 20 to 60 years of record is a steady decline in average annual water levels, with declines ranging from 0.41 to 2.81 feet per year. Overall, the northwestern part of the study area exhibits the smallest average annual declines, while the southeastern part of the study area exhibits the largest average annual declines.

New Mexico↗

USGS2012

Groundwater flow, quality (2007-10), and mixing in the Wind Cave National Park area, South Dakota

A study of groundwater flow, quality, and mixing in relation to Wind Cave National Park in western South Dakota was conducted during 2007-11 by the U.S. Geological Survey in cooperation with the National Park Service because of water-quality concerns and to determine possible sources of groundwater contamination in the Wind Cave National Park area. A large area surrounding Wind Cave National Park was included in this study because to understand groundwater in the park, a general understanding of groundwater in the surrounding southern Black Hills is necessary. Three aquifers are of particular importance for this purpose: the Minnelusa, Madison, and Precambrian aquifers. Multivariate methods applied to hydrochemical data, consisting of principal component analysis (PCA), cluster analysis, and an end-member mixing model, were applied to characterize groundwater flow and mixing. This provided a way to assess characteristics important for groundwater quality, including the differentiation of hydrogeologic domains within the study area, sources of groundwater to these domains, and groundwater mixing within these domains. Groundwater and surface-water samples collected for this study were analyzed for common ions (calcium, magnesium, sodium, bicarbonate, chloride, silica, and sulfate), arsenic, stable isotopes of oxygen and hydrogen, specific conductance, and pH. These 12 variables were used in all multivariate methods. A total of 100 samples were collected from 60 sites from 2007 to 2010 and included stream sinks, cave drip, cave water bodies, springs, and wells. In previous approaches that combined PCA with end-member mixing, extreme-value samples identified by PCA typically were assumed to represent end members. In this study, end members were not assumed to have been sampled but rather were estimated and constrained by prior hydrologic knowledge. Also, the end-member mixing model was quantified in relation to hydrogeologic domains, which focuses model results on major hydrologic processes. Finally, conservative tracers were weighted preferentially in model calibration, which distributed model errors of optimized values, or residuals, more appropriately than would otherwise be the case The latter item also provides an estimate of the relative effect of geochemical evolution along flow paths in comparison to mixing. The end-member mixing model estimated that Wind Cave sites received 38 percent of their groundwater inflow from local surface recharge, 34 percent from the upgradient Precambrian aquifer, 26 percent from surface recharge to the west, and 2 percent from regional flow. Artesian springs primarily received water from end members assumed to represent regional groundwater flow. Groundwater samples were collected and analyzed for chlorofluorocarbons, dissolved gasses (argon, carbon dioxide, methane, nitrogen, and oxygen), and tritium at selected sites and used to estimate groundwater age. Apparent ages, or model ages, for the Madison aquifer in the study area indicate that groundwater closest to surface recharge areas is youngest, with increasing age in a downgradient direction toward deeper parts of the aquifer. Arsenic concentrations in samples collected for this study ranged from 0.28 to 37.1 micrograms per liter (μg/L) with a median value of 6.4 μg/L, and 32 percent of these exceeded 10 μg/L. The highest arsenic concentrations in and near the study area are approximately coincident with the outcrop of the Minnelusa Formation and likely originated from arsenic in shale layers in this formation. Sample concentrations of nitrate plus nitrite were less than 2 milligrams per liter for 92 percent of samples collected, which is not a concern for drinking-water quality. Water samples were collected in the park and analyzed for five trace metals (chromium, copper, lithium, vanadium, and zinc), the concentrations of which did not correlate with arsenic. Dye tracing indicated hydraulic connection between three water bodies in Wind Cave.

South Dakota↗

USGS2014

Geochemistry of groundwater in the Beaver and Camas Creek drainage basins, eastern Idaho

The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, is studying the fate and transport of waste solutes in the eastern Snake River Plain (ESRP) aquifer at the Idaho National Laboratory (INL) in eastern Idaho. This effort requires an understanding of the natural and anthropogenic geochemistry of groundwater at the INL and of the important physical and chemical processes controlling the geochemistry. In this study, the USGS applied geochemical modeling to investigate the geochemistry of groundwater in the Beaver and Camas Creek drainage basins, which provide groundwater recharge to the ESRP aquifer underlying the northeastern part of the INL. Data used in this study include petrology and mineralogy from 2 sediment and 3 rock samples, and water-quality analyses from 4 surface-water and 18 groundwater samples. The mineralogy of the sediment and rock samples was analyzed with X-ray diffraction, and the mineralogy and petrology of the rock samples were examined in thin sections. The water samples were analyzed for field parameters, major ions, silica, nutrients, dissolved organic carbon, trace elements, tritium, and the stable isotope ratios of hydrogen, oxygen, carbon, sulfur, and nitrogen. Groundwater geochemistry was influenced by reactions with rocks of the geologic terranes—carbonate rocks, rhyolite, basalt, evaporite deposits, and sediment comprised of all of these rocks. Agricultural practices near and south of Dubois and application of road anti-icing liquids on U.S. Interstate Highway 15 were likely sources of nitrate, chloride, calcium, and magnesium to groundwater. Groundwater geochemistry was successfully modeled in the alluvial aquifer in Camas Meadows and the ESRP fractured basalt aquifer using the geochemical modeling code PHREEQC. The primary geochemical processes appear to be precipitation or dissolution of calcite and dissolution of silicate minerals. Dissolution of evaporite minerals, associated with Pleistocene Lake Terreton, is an important contributor of solutes in the Mud Lake-Dubois area. Oxidation-reduction reactions are important influences on the chemistry of groundwater at Camas Meadows and the Camas National Wildlife Refuge. In addition, mixing of different groundwaters or surface water with groundwater appears to be an important physical process influencing groundwater geochemistry in much of the study area, and evaporation may be an important physical process influencing the groundwater geochemistry of the Camas National Wildlife Refuge. The mass-balance modeling results from this study provide an explanation of the natural geochemistry of groundwater in the ESRP aquifer northeast of the INL, and thus provide a starting point for evaluating the natural and anthropogenic geochemistry of groundwater at the INL.

Idaho↗

USGS2016

Hydrogeologic framework and characterization of the Truxton Aquifer on the Hualapai Reservation, Mohave County, Arizona

The U.S. Geological Survey, in cooperation with the Bureau of Reclamation, developed this study to determine an estimate of groundwater in storage in the Truxton aquifer on the Hualapai Reservation in northwestern Arizona. For this study, the Truxton aquifer is defined as the unconfined, saturated groundwater in the unconsolidated to semiconsolidated older and younger basin-fill deposits of the Truxton basin overlying bedrock. The physical characteristics of the Truxton aquifer have not been well characterized in the past. In particular, the depth to impermeable granite bedrock and thickness of the basin are known in only a few locations where water wells have penetrated into the granite. Increasing water demands on the Truxton aquifer by both tribal and nontribal water users have led to concern about the long-term sustainability of this water resource. The Hualapai Tribe currently projects an increase of their water needs from about 300 acre-feet (acre-ft) per year to about 780 acre-ft per year by 2050 to support the community of Peach Springs, Arizona, and the southern part of the reservation. This study aimed to quantitatively develop better knowledge of aquifer characteristics, including aquifer storage and capacity, using (1) surface resistivity data collected along transects and (2) analysis of existing geologic, borehole, precipitation, water use, and water-level data. The surface resistivity surveys indicated that the depth to granite along the survey lines varied from less than 100 feet (ft) to more than 1,300 ft below land surface on the Hualapai Reservation. The top of the granite bedrock is consistent with the erosional character of the Truxton basin and exhibits deep paleochannels filled with basin-fill deposits consistent with the results of surface resistivity surveys and borehole logs from wells. The estimated average saturated thickness of the Truxton aquifer on the Hualapai Reservation is about 330 ft (with an estimated range of 260 to 390 ft), based on both resistivity results and the depth to water in wells. The saturated thickness might be greater in parts of the Truxton aquifer where paleochannels are incised into the granite underlying the basin-fill sediments. The estimated groundwater storage of the Truxton aquifer on the Hualapai Reservation ranges from 420,000 to 940,000 acre-ft and does not include groundwater storage in the aquifer outside the Hualapai Reservation boundary. In addition, the calculation of total storage in the Truxton aquifer does not determine nor indicate the availability and sustainability of that groundwater as a long-term resource. These results compared well with studies done on alluvial-basin aquifers in areas adjacent to this study. The part of the Truxton aquifer on the Hualapai Reservation represents about 20 percent of the entire aquifer.

Arizona↗

USGS2019

Geohydrology and water quality of the unconsolidated aquifers in the Enfield Creek Valley, town of Enfield, Tompkins County, New York

From 2013 to 2018, the U.S. Geological Survey, in cooperation with the Town of Enfield and the Tompkins County Planning Department, studied the unconsolidated aquifer in the Enfield Creek Valley in the town of Enfield, Tompkins County, New York. The valley will likely undergo future development as the population of Tompkins County increases and spreads out from the metropolitan areas. The Town of Enfield, Tompkins County, and the New York State Departments of Health and Environmental Conservation need geohydrologic information to help planners develop a more comprehensive approach to water-resource management in Tompkins County. The Enfield Creek Valley is underlain by an unconfined aquifer that consists of saturated alluvium, alluvial-fan deposits, and ice-contact (kame) sand and gravel. A confined aquifer of discontinuous ice-contact sand and gravel overlies bedrock. Depth to bedrock in the valley ranges from about 50 feet below land surface from just north of the Enfield Creek divide in the northern part of the aquifer to the confluence of Fivemile Creek to at least 140 feet below land surface from Fivemile Creek to where the valley orientation changes from north-south to northwest-southeast. Depth to bedrock is much shallower from the valley orientation change to the southeastern part of the aquifer because Enfield Creek has carved through overlying sediments into bedrock as the creek drops 450 feet into the Cayuga Inlet Valley. A small buried valley running south to north was identified within the Fivemile Creek drainage along the western edge of the town. However, the valley fill consists of glacial till, and no sand-and-gravel aquifer is present. The unconfined aquifers are recharged by direct infiltration of precipitation, surface runoff, and shallow subsurface flow from hillsides, and by seepage loss from streams overlying the aquifer. The confined aquifers are recharged mostly by precipitation that enters the adjacent valley walls, by groundwater flowing from bordering till or bedrock, and by flow from the bottom of the valley. Also, some recharge may be occurring where confining units are absent or from confining units with sediments of moderate permeability. Groundwater discharges to Enfield Creek, its tributaries, and wetlands and is lost through evapotranspiration from the water table or is withdrawn from domestic, commercial, and agricultural wells. About 700 individual well owners depend on the unconsolidated aquifers for their water supply. An estimated 28,300,000 gallons per year are withdrawn. Groundwater samples were collected from eight test wells drilled for this study, and six surface-water samples were collected from five locations on Enfield Creek. Of the eight wells sampled, two were finished in unconfined sand-and-gravel aquifers, two were finished in confined sand-and-gravel aquifers, and four were finished at or near the shale bedrock surface. Water quality in the study area generally met State and Federal drinking-water standards. However, some samples exceeded maximum contaminant levels for barium (25 percent of samples) and secondary maximum containment levels for chloride (25 percent), dissolved solids (25 percent of samples), iron (70 percent of samples), and manganese (75 percent of samples). Groundwater from 75 percent of the wells sampled for methane had concentrations greater than the Office of Surface Mining Reclamation and Enforcement recommended action level of 10 to 28 milligrams per liter. The two deepest wells sampled, TM1075 and TM1077, had the highest specific conductance, chloride, and sodium concentrations of all wells sampled. The chloride/bromide ratios of these samples suggest the source may represent a mixture of saline formation waters with shallow dilute groundwater and may receive recharge contribution from two tributaries overlying bedrock to the west and southwest of the aquifer. In general, the highest yields are from wells completed within about 50 feet below land surface, which may tap either type of aquifer.

New York↗

USGS2000

Fate and origin of 1,2-dichloropropane in an unconfined shallow aquifer

A shallow aquifer with different redox zones overlain by intensive agricultural activity was monitored for the occurrence of 1,2-dichloropropane (DCP) to assess the fate and origin of this pollutant. DCP was detected more frequently in groundwater samples collected in aerobic and nitrate-reducing zones than those collected from iron-reducing zones. Simulated DCP concentrations for groundwater entering an iron-reducing zone were calculated from a fate and transport model that included dispersion, sorption, and hydrolysis but not degradation. Simulated concentrations were well in excess of measured values, suggesting that microbial degradation occurred in the iron-reducing zone. Microcosm experiments were conducted using aquifer samples collected from iron-reducing and aerobic zones to evaluate the potential for microbial degradation of DCP and to explain field observations. Hydrogenolysis of DCP and production of monochlorinated propanes in microcosm experiments occurred only with aquifer materials collected from the iron-reducing zone, and no dechlorination was observed in microcosms established with aquifer materials collected from the aerobic zones. Careful analyses of the DCP/1,2,2-trichloropropane ratios in groundwater indicated that older fumigant formulations were responsible for the high levels of DCP present in this aquifer.A shallow aquifer with different redox zones overlain by intensive agricultural activity was monitored for the occurrence of 1,2-dichloropropane (DCP) to assess the fate and origin of this pollutant. DCP was detected more frequently in groundwater samples collected in aerobic and nitrate-reducing zones than those collected from iron-reducing zones. Simulated DCP concentrations for groundwater entering an iron-reducing zone were calculated from a fate and transport model that included dispersion, sorption, and hydrolysis but not degradation. Simulated concentrations were well in excess of measured values, suggesting that microbial degradation occurred in the iron-reducing zone. Microcosm experiments were conducted using aquifer samples collected from iron-reducing and aerobic zones to evaluate the potential for microbial degradation of DCP and to explain field observations. Hydrogenolysis of DCP and production of monochlorinated propanes in microcosm experiments occurred only with aquifer materials collected from the iron-reducing zone, and no dechlorination was observed in microcosms established with aquifer materials collected from the aerobic zones. Careful analyses of the DCP/1,2,2-trichloropropane ratios in groundwater indicated that older fumigant formulations were responsible for the high levels of DCP present in this aquifer.

Washington↗

USGS2010

Decadal-scale changes in dissolved-solids concentrations in groundwater used for public supply, Salt Lake Valley, Utah

Basin-fill aquifers are a major source of good-quality water for public supply in many areas of the southwestern United States and have undergone increasing development as populations have grown over time. During 2005, the basin-fill aquifer in Salt Lake Valley, Utah, provided approximately 75,000 acre-feet, or about 29 percent of the total amount of water used by a population of 967,000. Groundwater in the unconsolidated basin-fill deposits that make up the aquifer occurs under unconfined and confined conditions. Water in the shallow unconfined part of the groundwater system is susceptible to near-surface contamination and generally is not used as a source of drinking water. Groundwater for public supply is withdrawn from the deeper unconfined and confined parts of the system, termed the principal aquifer, because yields generally are greater and water quality is better (including lower dissolved-solids concentrations) than in the shallower parts of the system. Much of the water in the principal aquifer is derived from recharge in the adjacent Wasatch Range (mountain-block recharge). In many areas, the principal aquifer is separated from the overlying shallow aquifer by confining layers of less permeable, fine-grained sediment that inhibit the downward movement of water and any potential contaminants from the surface. Nonetheless, under certain hydrologic conditions, human-related activities can increase dissolved-solids concentrations in the principal aquifer and result in groundwater becoming unsuitable for consumption without treatment or mixing with water having lower dissolved-solids concentrations. Dissolved-solids concentrations in areas of the principal aquifer used for public supply typically are less than 500 milligrams per liter (mg/L), the U.S. Environmental Protection Agency (EPA) secondary (nonenforceable) drinking-water standard. However, substantial increases in dissolved-solids concentrations in the principal aquifer have been documented in some areas used for public supply, raising concerns as to the source(s) and cause(s) of the higher concentrations and the potential long-term effects on groundwater quality.

Utah↗

USGS2020

Altitude of the potentiometric surface in the Mississippi River Valley alluvial aquifer, spring 2018

A potentiometric-surface map for spring 2018 was created for the Mississippi River Valley alluvial (MRVA) aquifer using available groundwater-altitude data from 1,126 wells completed in the MRVA aquifer and from the altitude of the top of the water surface in area rivers from 66 streamgages. Personnel from Arkansas Natural Resources Commission, Arkansas Department of Health, Arkansas Geological Survey, Illinois Department of Agriculture, Illinois State Water Survey, Louisiana Department of Natural Resources, Louisiana Department of Transportation and Development, Mississippi Department of Environmental Quality, Missouri Department of Natural Resources, Yazoo Mississippi Delta Joint Water Management District, U.S. Department of Agriculture-Natural Resources Conservation Service, and U.S. Geological Survey (USGS) routinely collect groundwater-level data from wells screened in the MRVA aquifer. The USGS and the U.S. Army Corps of Engineers routinely collect data on river stage and streamflow for the rivers overlying the MRVA aquifer area. The potentiometric-surface map for 2018 was created utilizing existing groundwater and surface-water altitudes to support investigations to characterize the MRVA aquifer as part of the USGS Water Availability and Use Science Program. Sufficient data were available to map the potentiometric surface of the MRVA aquifer for spring 2018 for about 87 percent of the aquifer area. The potentiometric contours ranged from 10 to 340 feet above North American Vertical Datum of 1988. The regional direction of groundwater flow was generally to the south-southwest, except in areas of groundwater-altitude depressions, where groundwater flowed into the depression, and near rivers, where flow can be from aquifer to the river or from the river into the aquifer. There are large depressions in the potentiometric-surface map in the lower one-half of the Cache region and in most of the Grand Prairie and Delta regions.

Mississippi River Valley alluvial aquifer↗

USGS2010

Model Refinement and Simulation of Groundwater Flow in Clinton, Eaton, and Ingham Counties, Michigan

A groundwater-flow model that was constructed in 1996 of the Saginaw aquifer was refined to better represent the regional hydrologic system in the Tri-County region, which consists of Clinton, Eaton, and Ingham Counties, Michigan. With increasing demand for groundwater, the need to manage withdrawals from the Saginaw aquifer has become more important, and the 1996 model could not adequately address issues of water quality and quantity. An updated model was needed to better address potential effects of drought, locally high water demands, reduction of recharge by impervious surfaces, and issues affecting water quality, such as contaminant sources, on water resources and the selection of pumping rates and locations. The refinement of the groundwater-flow model allows simulations to address these issues of water quantity and quality and provides communities with a tool that will enable them to better plan for expansion and protection of their groundwater-supply systems. Model refinement included representation of the system under steady-state and transient conditions, adjustments to the estimated regional groundwater-recharge rates to account for both temporal and spatial differences, adjustments to the representation and hydraulic characteristics of the glacial deposits and Saginaw Formation, and updates to groundwater-withdrawal rates to reflect changes from the early 1900s to 2005. Simulations included steady-state conditions (in which stresses remained constant and changes in storage were not included) and transient conditions (in which stresses changed in annual and monthly time scales and changes in storage within the system were included). These simulations included investigation of the potential effects of reduced recharge due to impervious areas or to low-rainfall/drought conditions, delineation of contributing areas with recent pumping rates, and optimization of pumping subject to various quantity and quality constraints. Simulation results indicate potential declines in water levels in both the upper glacial aquifer and the upper sandstone bedrock aquifer under steady-state and transient conditions when recharge was reduced by 20 and 50 percent in urban areas. Transient simulations were done to investigate reduced recharge due to low rainfall and increased pumping to meet anticipated future demand with 24 months (2 years) of modified recharge or modified recharge and pumping rates. During these two simulation years, monthly recharge rates were reduced by about 30 percent, and monthly withdrawal rates for Lansing area production wells were increased by 15 percent. The reduction in the amount of water available to recharge the groundwater system affects the upper model layers representing the glacial aquifers more than the deeper bedrock layers. However, with a reduction in recharge and an increase in withdrawals from the bedrock aquifer, water levels in the bedrock layers are affected more than those in the glacial layers. Differences in water levels between simulations with reduced recharge and reduced recharge with increased pumping are greatest in the Lansing area and least away from pumping centers, as expected. Additionally, the increases in pumping rates had minimal effect on most simulated streamflows. Additional simulations included updating the estimated 10-year wellhead-contributing areas for selected Lansing-area wells under 2006-7 pumping conditions. Optimization of groundwater withdrawals with a water-resource management model was done to determine withdrawal rates while minimizing operational costs and to determine withdrawal locations to achieve additional capacity while meeting specified head constraints. In these optimization scenarios, the desired groundwater withdrawals are achieved by simulating managed wells (where pumping rates can be optimized) and unmanaged wells (where pumping rates are not optimized) and by using various combinations of existing and proposed well locations.

Scientific Investigations Report↗

USGS2013

Relation between organic-wastewater compounds, groundwater geochemistry, and well characteristics for selected wells in Lansing, Michigan

In 2010, groundwater from 20 Lansing Board of Water and Light (BWL) production wells was tested for 69 organic-wastewater compounds (OWCs). The OWCs detected in one-half of the sampled wells are widely used in industrial and environmental applications and commonly occur in many wastes and stormwater. To identify factors that contribute to the occurrence of these constituents in BWL wells, the U.S. Geological Survey (USGS) interpreted the results of these analyses and related detections of OWCs to local characteristics and groundwater geochemistry. Analysis of groundwater-chemistry data collected by the BWL during routine monitoring from 1969 to 2011 indicates that the geochemistry of the BWL wells has changed over time, with the major difference being an increase in sodium and chloride. The concentrations of sodium and chloride were positively correlated to frequency of OWC detections. The BWL wells studied are all completed in the Saginaw aquifer, which consists of water-bearing sandstones of Pennsylvanian age. The Saginaw aquifer is underlain by the Parma-Bayport aquifer, and overlain by the Glacial aquifer. Two possible sources of sodium and chloride were evaluated: basin brines by way of the Parma-Bayport aquifer, and surficial sources by way of the Glacial aquifer. To determine if water from the underlying aquifer had influenced well-water geochemistry over time, the total dissolved solids concentration and changes in major ion concentrations were examined with respect to well depth, age, and pumping rate. To address a possible surficial source of sodium and chloride, 25 well, aquifer, or hydrologic characteristics, and 2 groundwater geochemistry variables that might influence whether, or the rate at which, water from the land surface could reach each well were compared to OWC detections and well chemistry. The statistical tests performed during this study, using available variables, indicated that reduced time of travel of water from the land surface to the well opening was significantly correlated with detections of OWCs. No specific well or aquifer characteristic was correlated with OWC detections; however, wells with detections tended to have less modeled confining material thickness (as simulated in the regional groundwater flow model), which is an estimate of the amount of clay or shale between the Glacial and Saginaw aquifers. Additional analyses and collection of other data would be required to more conclusively identify the source and to determine the potential vulnerability of other wells because each BWL well may have a somewhat unique set of characteristics that governs its response to pumping. Therefore, it is possible that a relevant explanatory variable was not included in this analysis. The current patterns of geochemistry, and the relation between these patterns and volume of pumpage for the BWL wells, indicates other wells may be susceptible to OWCs in the future.

Michigan↗

USGS2023

Occurrence of pharmaceutical compounds in the San Antonio segment of the Edwards (Balcones fault zone) aquifer, south-central Texas, June 2018–August 2020

The occurrence of pharmaceutical compounds (hereinafter referred to as “pharmaceuticals”) in surface water that recharges the San Antonio segment of the Edwards aquifer in south-central Texas is of concern with respect to potential effects on groundwater quality. This study, conducted during June 2018–August 2020 by the U.S. Geological Survey in cooperation with the San Antonio Water System, used a source-to-sink approach (that is, from aquifer recharge to aquifer discharge) to compare the occurrences and concentrations of pharmaceuticals in recharging (losing) streams to those in relatively shallow and relatively deep groundwater. Individual pharmaceutical concentrations in surface water were all less than 200 nanograms per liter, and most were less than 50 nanograms per liter. The two most common pharmaceuticals in surface water were metformin (50-percent detection frequency) and caffeine (25-percent detection frequency). In contrast to surface-water sites, few detections of pharmaceuticals above the detection limit were quantified at groundwater sites. On the basis of studied sample sites that are considered to be representative of the Edwards aquifer recharge zone, groundwater results collectively indicate that pharmaceuticals currently (2020) do not substantially impair water quality in the shallow unconfined part of the Edwards aquifer. Although groundwater pharmaceutical detections were not common, two detections of acetaminophen occurred in samples collected from a relatively deep confined part of the aquifer, indicating that this part of the aquifer is potentially vulnerable to pharmaceutical contamination. The near absence of wastewater treatment plant discharges and Texas Land Application Permit facilities within the drainage areas of streams in this study could explain reduced inputs of pharmaceuticals relative to pesticides on the Edwards aquifer recharge zone and their reduced occurrence in unconfined groundwater. In the western part of the study area, numerous pharmaceutical detections in the Frio River indicate that pharmaceutical sources in rural areas also exist with potential water-quality effects. Although reported pharmaceutical concentrations for the San Antonio segment of the Edwards aquifer are currently (2020) low, ongoing development in the region has the potential to increase contaminant loads, including for pharmaceuticals.

Texas↗

USGS2012

Water-level altitudes and continuous and discrete water quality at and near an aquifer storage and recovery site, Bexar, Atascosa, and Wilson Counties, Texas, June 2004-September 2011

The U.S. Geological Survey (USGS), in cooperation with the San Antonio Water System (SAWS), collected data during 2004–11 to characterize the quality of native groundwater from the San Antonio segment of the Edwards aquifer (hereinafter, Edwards aquifer) and preinjection and postinjection water from the Carrizo aquifer (informal name commonly applied to the upper part of the Carrizo-Wilcox aquifer in the area) at and near an aquifer storage and recovery (ASR) site in Bexar, Atascosa, and Wilson Counties, Texas. Daily mean water-level altitude, water temperature, and specific conductance were measured continuously in a monitoring well on the ASR site to determine how injection and withdrawal at the ASR site might affect local groundwater. Groundwater samples were collected and analyzed for selected physical properties and constituents to characterize the quality of native groundwater from the Edwards aquifer and preinjection and postinjection water from the Carrizo aquifer near the ASR site to provide a better understanding of possible changes in the quality of groundwater near an active ASR site that might result from the mixing of water from different aquifers. During injection periods, the water-level altitude in the monitoring well generally increased as the amount of water being injected into all wells at the ASR site increased and decreased as the amount of water being injected into all wells at the ASR site decreased. During withdrawal periods, the water-level altitude in the monitoring well generally increased as the total volume of water being withdrawn from all wells at the ASR site decreased and generally decreased as the total volume of water being withdrawn from all wells increased. Daily mean water temperature fluctuated by less than 1 degree Celsius and was determined to be independent of injection or withdrawal conditions at the ASR site. Changes in daily mean specific-conductance values measured at four depths in the monitoring well at the ASR site occurred without regard to total ASR site injection or withdrawal volumes. No substantial differences were measured over time in major-ion, trace-element, or isotope chemistry of water samples collected from the wells that supplied water from the Edwards aquifer. Little variation in water chemistry was detected in the samples collected from four wells designed to inject and withdraw water at the ASR site, regardless of whether the ASR site was injecting or withdrawing water. The similarity of major-ion and isotope chemistry between the Edwards aquifer source wells and the four ASR wells indicates that little, if any, migration of injected water away from the ASR wells has occurred. In a well located closest to the ASR site in the direction of regional flow for the Carrizo aquifer, a greater alkalinity value and a smaller concentration of chloride were measured in the most recent sample than in all other samples collected at this well. Substantial increases in dissolved iron and manganese concentrations also were observed in this well. The increased alkalinity value and dissolved iron and manganese concentrations and the decreased chloride concentration in the well could indicate that the injected water from the Edwards aquifer had begun to move into at least a part of the strata supplying these wells and might be causing iron and manganese mobilization in the Carrizo aquifer.

Texas↗