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Gaps in water quality modeling of hydrologic systems

This review assesses gaps in water quality modeling, emphasizing opportunities to improve next-generation models that are essential for managing water quality and are integral to meeting goals of scientific and management agencies. In particular, this paper identifies gaps in water quality modeling capabilities that, if addressed, could support assessments, projections, and evaluations of management alternatives to support ecosystem health and human beneficial use of water resources. It covers surface water and groundwater quality modeling, dealing with a broad suite of physical, biogeochemical, and anthropogenic drivers. Modeling capabilities for six constituents (or constituent categories) are explored: water temperature, salinity, nutrients, sediment, geogenic constituents, and contaminants of emerging concern. Each constituent was followed through the coupled atmospheric-hydrologic-human system, with prominent modeling gaps described for a diverse array of relevant inputs, processes, and human activities. Commonly identified modeling gaps primarily fall under three types: (1) model gaps, (2) data gaps, and (3) process understanding gaps. In addition to potential solutions for addressing specific individual modeling limitations, some broad approaches (e.g., enhanced data collection and compilation, machine learning, reduced-complexity modeling) are discussed as ways forward for tackling multiple gaps. This gap analysis establishes a framework of diverse approaches that may support improved process representation, scale, and accuracy of models for a wide range of water quality issues.

Water

Linking permafrost to the abundance, biomass, and energy density of fish in Arctic headwater streams

Permafrost thaw alters groundwater flow, river hydrology, stream-catchment interactions, and the availability of carbon and nutrients in headwater streams. The impact of permafrost on watershed hydrology and biogeochemistry of headwater streams has been demonstrated, but there is little understanding of how permafrost influences fish in these ecosystems. We examined relations among permafrost characteristics, the resulting changes in water temperature, stream hydrology (e.g., discharge flashiness), and macroinvertebrates, with the abundance, biomass, and energy density of juvenile Dolly Varden ( Salvelinus malma ) and Arctic Grayling ( Thymallus arcticus ) across 10 headwater streams in northwestern Alaska. Macroinvertebrate density was driven by concentrations of dissolved carbon and nutrients supporting stream food webs. Dolly Varden abundance was primarily related to water temperature with fewer fish in warmer streams, whereas Dolly Varden energy density decreased with the flashiness of the headwater streams. Dolly Varden biomass was related to both temperature and bottom-up food web effects. The energy density of Arctic Grayling decreased with warmer temperatures and discharge flashiness. These relations demonstrate the importance of terrestrial–aquatic connections in permafrost landscapes and indicate the complexity of landscape effects on fish. Because permafrost thaw is one of the most impactful changes occurring as the Arctic warms, an improved understanding of how stream temperature, hydrology, and bottom-up food web processes influence fish populations can aid forecasting of future conditions across the Arctic.

Alaska

Estimating domestic self-supplied water use in Rhode Island, 2014–21

Water withdrawal from private groundwater wells is often unaccounted for in water planning studies, and water from private wells can be a source of exposure to environmental contaminants. The sizes of populations that depend on private wells for domestic water use and the amounts of water that are withdrawn from these wells are generally poorly represented in data collection efforts because of the challenges of locating, metering, or gathering withdrawal information from individual property owners. To address this problem, the U.S. Geological Survey, in cooperation with the Rhode Island Water Resources Board, estimated the volume of water withdrawn from domestic self-supply wells and the populations who use them for the State of Rhode Island at a 30-meter pixel spatial resolution and one-month temporal resolution between July 2014 and June 2021. The number of people reliant on domestic self-supply wells has increased in Rhode Island over the study period; however, the statewide estimate of total water withdrawal has not statistically increased. Withdrawals from private wells are largest in the inland areas of the western part of the State, and the towns of Scituate and Charlestown have the highest estimated withdrawals. Statewide monthly withdrawals ranged from 3.987 million gallons per day in March 2018 to 7.767 million gallons per day in September 2016. The median per capita domestic water use rate was 46.0 gallons per capita per day.

Rhode Island

A conceptual framework to assess post-wildfire water quality: State of the science and knowledge gaps

Wildfire substantially alters aquatic ecosystems by inducing moderate to catastrophic physical and chemical changes. However, the relations of environmental and watershed variables that drive those effects are complex. We present a Driver-Factor-Stressor-Effect (DFSE) conceptual framework to assess the current state of the science related to post-wildfire water-quality. We reviewed 64 peer-reviewed papers using the DFSE framework to identify drivers, factors, stressors, and effects associated with each study. A total of five drivers were identified and ranked according to their frequency of occurrence in the literature: atmospheric processes > fire characteristics > ecologic processes and characteristics > land surface characteristics > soil characteristics. Commonly reported stressors include increased nutrients, runoff, and sediment transport. Furthermore, although several different factors have been used at least once to explain water-quality effects, relatively few factors outside of precipitation and fire characteristics are frequently studied. We identified several gaps indicating the need for long-term monitoring, multi-factor studies, consideration of organic contaminants, consideration of groundwater, and inclusion of soil characteristics. This assessment expands on other reviews and meta-analyses by exploring causal linkages between influential variables and overall effects in post-wildfire watersheds. Information gathered from our assessment and the framework itself can be used to inform future monitoring plans and as a guide for modeling efforts focused on better understanding specific processes or to mitigate potential risks of post-wildfire water quality.

Water Resources Research

U.S. Geological Survey Integrated Water Availability Assessment—2010–20

This professional paper is a multichapter report that assesses water availability in the United States for water years 2010–20. This work was conducted as part of the fulfillment of the mandates of Subtitle F of the Omnibus Public Land Management Act of 2009 (Public Law 111-11), also known as the SECURE Water Act. As such, this work examines the spatial and temporal distribution of water quantity and quality in surface water and groundwater, as related to human and ecosystem needs and as affected by human and natural influences. Chapter A introduces the National Integrated Water Availability Assessment and provides important background and definitions for how the report characterizes water availability and its components. Chapter A also presents the key findings of Chapters B–F and thus acts as a summary of the entire report. Chapter B is a national assessment of water supply, which is the quantity of water supplied through climatic inputs. Chapter C is a national assessment of water quality, which is the chemical and physical characteristics of water. Chapter D assesses water use including withdrawals and consumptive use in the conterminous United States. Chapter E presents an analysis of factors affecting future water availability under changing climate conditions. The National Integrated Water Availability Assessment culminates with Chapter F, which is an integrated assessment of water availability that considers the amount and quality of water coupled with the suitability of that water for specific uses. Together, these six chapters constitute the National Integrated Water Availability Assessment for water years 2010–20.

Professional Paper

Examining 22 years of ambient seismic wavefield at Mount St. Helens

An increase in seismic activity precedes most volcanic eruptions. Whereas event-based forecasting approaches have been successful, some eruptions remain unanticipated, resulting in casualties and damage. Our study leverages the recent advancements in ambient field seismology. We explore features extracted from continuous ambient fields using traditional methods, for example, peak ground velocity, peak ground acceleration, root mean square, root median square, real-time seismic amplitude measurement, and novel methods (displacement seismic amplitude ratio and spectral width). In addition, we explore unsupervised learning of higher order wavelet features using scattering networks. We find that combining all the methods was necessary to disentangle the effects of seismic sources from structural changes at Mount St. Helens. Although the ambient wavefield-based approach does not yield additional or more significant precursory signals than event-based methods at Mount St. Helens, our study demonstrates that the ambient wavefield provides supplementary information, mainly about structural changes and complements traditional methods. The ambient seismic wavefield offers additional insights into long-lasting processes. We find enhanced wave attenuation correlating with geochemical measurements. We interpret this as ongoing structural changes, such as dome growth or the evolution of the volcanic conduit system. On annual and decadal timescales, we interpret seasonal seismic attenuation in the shallow subsurface as groundwater fluctuations, corroborated by observations at the nearby Spirit Lake level. This multimethod approach at Mount St. Helens sheds light on a volcanic system’s underlying dynamics and structure.

Washington

A review of post-wildfire adaptations of surface-water-quality models: Synthesis, gaps, and opportunities

As wildfires increasingly affect water-supply watersheds, the demand for models to predict water-quality responses is increasing. This work reviews and synthesizes existing post-wildfire applications of water-quality models in the context of geographic and ecohydrological distribution, hydrologic and water-quality response process representation, model parameterization, model and input data scales, model calibration data availability, as well as calibration and performance evaluation approaches. Emphasis is placed on models that simulate water-quality output, rather than sediment and erosional response as the primary focus. Here, identified gaps and opportunities to advance the post-wildfire application of water-quality models include: 1. applying models in under-represented geographic and ecohydrologic regions, 2. simulating multiple streamflow generation mechanisms, including groundwater, with an emphasis on shifting dominant flow pathways as the landscape recovers following wildfire, 3. adding studies that include the simulation of metals, 4. incorporating more biogeochemical and in-stream processes to model applications, 5. applying finer spatial and temporal resolution of precipitation data input as well as finer spatial resolution hydrologic response units, 6. implementing fully distributed grid or element models or finer resolution response units to capture burn severity heterogeneity, 7. collecting enhanced water-quality data for model calibration and validation, 8. conducting model-intercomparison studies, and 9. developing model parameter value guidance in post-wildfire applications. These identified gaps and opportunities may assist users in deciding on key processes and approaches to consider in modeling post-wildfire water-quality conditions.

Science of the Total Environment

Irrigated agriculture influences selenium levels in an endangered marsh bird

Selenium bioaccumulation in aquatic food webs poses risks to wildlife, particularly in wetlands receiving irrigation runoff. The Salton Sea, California’s largest lake, is primarily sustained by agricultural drainage. This drainage creates wetland habitat along the lakeshore that many bird species depend on, including the federally endangered Yuma Ridgway’s rail ( Rallus obsoletus yumanensis ). However, these marshes may pose an ecological trap – attracting rails despite high selenium exposure. We captured rails during the 2020–2023 breeding seasons and compared rail selenium levels within three types of marshes (fed with irrigation runoff, Colorado River water, or groundwater). We collected blood, breast feathers, and head feathers of rails in all three water sources for selenium comparisons. We tagged adult rails with GPS transmitters to locate nests and foraging locations where we collected eggshells, unhatched eggs, and prey. We assessed selenium exposure by collecting multiple prey species commonly eaten by rails in all three water sources. Selenium concentrations varied among sampling locations. Selenium concentrations in most sample types were predominately influenced by water source and marsh inflow velocity (sometimes in combination with marsh size). Distance to inflow, however, did not influence selenium concentrations in any sample type. Selenium concentrations were highest in agricultural-fed marshes compared to river-fed and spring-fed marshes. Increased marsh inflow velocities resulted in lower selenium concentrations. Given the risk of an ecological trap, our results suggest that supplementing wetlands with Colorado River water could mitigate selenium bioaccumulation in Yuma Ridgway’s rails.

California

Beyond the mangroves: A global synthesis of tidal forested wetland types, drivers and future information opportunities

There is increasing awareness of the global diversity of tidal forested wetlands (TFWs) and their significance in the provision of ecosystem services. These ecosystems, including mangrove forests, tidal freshwater forested wetlands, supratidal forests and transitional forests together span multiple climatic zones, geomorphic settings, and inundation and salinity regimes. We utilise case studies across five continents to demonstrate the state of knowledge among TFWs. Intertidal mangroves are the best-defined of the TFWs thanks to decades of research on their geomorphology, hydrology and ecology across their broad distribution. Non-mangrove forest settings, however, demonstrate more diverse hydrological, biochemical and vegetation conditions. In many cases, non-mangrove forests are situated at upper intertidal or supratidal elevations, where surface waters and groundwater are subject to interactions between tides freshwater inputs. Salinity datasets show variations ranging from tidal freshwater forested wetlands and ‘low-salinity mangroves’ to mesohaline or marine salinities, often with high temporal variability. While the floristic composition of non-mangrove forests vary among biogeographic regions, locally dominant TFW species are commonly distributed beyond the tidal niche into non-tidal wetland and upland forests. This presents challenges for traditional remote sensing approaches to ecosystem mapping, which are mostly lacking for non-mangrove forests. Geomorphic approaches and developments in machine learning offer opportunities to address this.

Preprint

Investigating the influence of climate and volcanic surface aging on fluvial erosion: A case study of Réunion Island, Indian Ocean

Precipitation is one of the dominant drivers of landscape erosion and evolution; however, the effects of typical rainfall compared with less frequent, high-magnitude precipitation events on erosion remain unclear. Volcanic islands are ideal locations to study such phenomena due to their simple geometries, nontectonic construction, and strong spatiotemporal rainfall gradients. However, spatial variation in surface age, created during their construction, often complicates their degradation histories by introducing temporal changes in erosion rates as drainage networks develop. Réunion Island (western Indian Ocean) presents a clear example of this, with an east–west gradient in both surface age and mean annual precipitation, as well as infrequent cyclones that alter the background rainfall pattern. In this study, we analyze the effects of surface age, average rainfall, and rainfall variability on basin development and fluvial erosion across the island. We calculate basin-averaged values of basin morphology, age, precipitation, river discharge, eroded volumes, and erosion rates, and use these to analyze the dominant drivers of landscape evolution through a series of correlation analyses. Our results indicate a temporal dependence on the influence of precipitation, with young surfaces being dominantly eroded by high-rainfall events and older surfaces eroded by mean annual rainfall patterns. Furthermore, we show that drainage development of shield volcanoes follows similar trends to other volcano types, and suggest that surface permeability and groundwater structure are important controls on runoff-driven erosion on shield volcanoes. These results add new components to the question of how precipitation impacts erosion.

Réunion Island

Surficial geology and Quaternary fault map of the Las Vegas Valley, Clark County, Nevada

The Surficial Geology and Quaternary Fault Map of the Las Vegas Valley, Clark County, Nevada is a 1:50,000-scale compilation of published 1:24,000-scale geologic maps integrated with new field and desktop mapping. This geologic map compilation and GIS database are part of a broader study on the Quaternary faults in the Las Vegas Valley, the results of which are summarized in this report. The map compilation utilized a variety of digital base maps to evaluate the characteristics of surficial deposits and Quaternary fault scarps including lidar data in undeveloped parts of the valley and orthorectified historical aerial photos in the urbanized center of the valley. The map distinguishes twenty surficial map units including alluvial-fan and ephemeral-wash deposits, groundwater discharge deposits of the Las Vegas Formation, and alluvium deposits of Las Vegas Wash. Quaternary faults include the Quaternary Las Vegas Valley fault system in the center of the valley and the Frenchman Mountain fault system along the eastern margin. All Quaternary fault traces in the valley were evaluated, and the previously published fault mapping was modified as needed. The new mapping and uniform correlation of surficial deposits displaced by Quaternary faults yields a consistent valley-wide characterization of the recency of fault activity. The map and GIS database include a Quaternary geochronology compilation of 119 previously published surficial deposit ages of various types, 35 new luminescence ages, and 3 new radiocarbon ages. The new age data further bracket the ages of the Las Vegas basin Quaternary stratigraphy and provide new constraints on the timing of Quaternary fault activity.

Nevada

Toward a new framework to evaluate process-based model configurations and quantify data worth prior to calibration

Model criticism, discrimination, and selection methods often rely on calibrated model outputs. Because calibration can be computationally expensive, model criticism can first be undertaken by assessing model outputs obtained from limited prior parameter ensembles. However, such prior-based methods are often heuristic and do not formalize the notion of balancing model consistency with data and model complexity (i.e., model adequacy). We present a new framework to discriminate among candidate models prior to calibration that formalizes prior-to-calibration model adequacy into a metric to implicitly balance prior model output data coverage with model complexity represented by prior output (co)variance. The prior model adequacy metric “Mahalanobis distance deviation” quantifies the deviation of (a) the set of squared Mahalanobis distances of data from a prior model output distribution from (b) the set of squared Mahalanobis distances of data from their own distribution. A new data worth metric “discernment value” is also presented which quantifies the value of data for screening less-adequate models prior to calibration. Discernment value is calculated from the change in variance of a weighted average of prior model outputs from all candidate models due to less-adequate model outputs receiving lower weight. The framework is demonstrated using a one-dimensional groundwater flow model with eight possible configurations. A synthetic data network is used to test the framework. Results show the framework identifies the candidate models most similar to the true model used to create the synthetic data. Discernment values show variation in the value of different data types and locations for screening less-adequate models.

Water Resources Research

Anaerobic biodegradation of perfluorooctane sulfonate (PFOS) and microbial community composition in soil amended with a dechlorinating culture and chlorinated solvents

Perfluorooctane sulfonate (PFOS), one of the most frequently detected per - and polyfluoroalkyl substances (PFAS) occurring in soil, surface water, and groundwater near sites contaminated with aqueous film-forming foam (AFFF), has proven to be recalcitrant to many destructive remedies, including chemical oxidation. We investigated the potential to utilize microbially mediated reduction (bioreduction) to degrade PFOS and other PFAS through addition of a known dehalogenating culture, WBC-2, to soil obtained from an AFFF-contaminated site. A substantial decrease in total mass of PFOS (soil and water) was observed in microcosms amended with WBC-2 and chlorinated volatile organic compound (cVOC) co-contaminants — 46.4 ± 11.0 % removal of PFOS over the 45-day experiment. In contrast, perfluorooctanoate (PFOA) and 6:2 fluorotelomer sulfonate (6:2 FTS) concentrations did not decrease in the same microcosms. The low or non-detectable concentrations of potential metabolites in full PFAS analyses, including after application of the total oxidizable precursor assay, indicated that defluorination occurred to non-fluorinated compounds or ultrashort-chain PFAS. Nevertheless, additional research on the metabolites and degradation pathways is needed. Population abundances of known dehalorespirers did not change with PFOS removal during the experiment, making their association with PFOS removal unclear. An increased abundance of sulfate reducers in the genus Desulfosporosinus (Firmicutes) and Sulfurospirillum (Campilobacterota) was observed with PFOS removal, most likely linked to initiation of biodegradation by desulfonation. These results have important implications for development of in situ bioremediation methods for PFAS and advancing knowledge of natural attenuation processes.

Science of the Total Environment

A 10-year continuous daily simulation of chloride flux from a suburban watershed in Fairfax County, Virginia, USA

Increasing levels of chloride in surface water are associated with detrimental effects on water quality, aquatic ecosystems, infrastructure, and human health. Numerous mass-balance studies have inferred watershed transport processes by interpreting chloride inputs and outputs, but few represent internal dynamics explicitly. We constructed a coupled water/chloride mass balance model to gain insights into storage, residence time, and transport processes in a 10-km 2 urban watershed. The model, which operates over a 10-year period at a daily time scale, represents storage in a dynamic soil-moisture reservoir, quick-flow runoff from storm events, and slow-flow runoff that sustains streamflow in dry weather. The calibrated model accurately represented (a)the observed transition from a streamflow enrichment regime in cold months to a dilution regime in warmer months, (b) the observed tendency for late-summer concentrations to be higher after winters with heavy snowfall, and (c) a period-of-record downward trend in chloride concentration likely associated with a downward trend in annual snowfall. Estimated chloride inputs averaged 195 metric tons per year, while the average output was 270 metric tons per year. In contrast, estimated storage was only 107 metric tons. The estimated mean residence time in groundwater was 1.27 years. This short residence time indicates that efforts to reduce inputs will manifest as decreased concentrations in streamflow on a management-relevant time scale of several years. The coupled mass balance model yielded insights into internal watershed dynamics that would not be possible from simple input/output analysis; such models can be useful tools for gaining insight into small watershed hydrology and pollutant transport.

Virginia

Searching for seismic precursors - The Barry Landslide hazard clean up

The Barry Landslide, located in Barry Arm of Prince William Sound, Alaska, poses a major hazard due to its steep, unstable slopes and the potential for a massive landslide-generated tsunami. With an estimated volume of 500–700 million cubic meters, the Barry Landslide could trigger highly destructive waves. In this study, we focus on seismic signals from the Barry Landslide, which are critical for providing timely tsunami warnings. Since the summer of 2020, the region has been instrumented to monitor the landslide, but the seismic record is complicated by the presence of nearby glaciers and frequent regional earthquakes. Among these signals, we analyze a specific class of short-duration, high-frequency seismic events that exhibit strong seasonal variability, increasing in rate from late summer to mid-winter before ceasing abruptly in late winter or early spring. Our analysis suggests that the source of these signals is likely near or beneath Cascade Glacier, adjacent to the landslide, rather than within the landslide mass itself. We apply detection algorithms to construct a time history for this signal type, which we then compare with environmental factors like precipitation, temperature, and slope displacement data from ground-based radar and remote sensing. Correlations indicate that these seismic events may be driven by seasonal hydrological changes, particularly the freeze-up of subglacial water pathways. While these events are not directly linked to landslide motion, they serve as indirect markers of subsurface hydrological conditions that influence slope stability. Our findings highlight the complex interplay between glaciers, groundwater, and landslide dynamics, emphasizing the need for multi-parameter monitoring to assess evolving geohazards in the region.

Alaska

Surface variable‐based machine learning for scalable arsenic prediction in undersampled areas

In the United States, private wells are not federally regulated, and many households do not test for Arsenic (As). Chronic exposure is linked with multiple health outcomes, and risk can change sharply over short distances and with well depth. Coarse maps or sparse sampling often miss exceedances. Most existing models operate at ∼1 km resolution and use groundwater chemistry or detailed geologic logs, which limits their use in undersampled areas where improved guidance is most needed. We overcome these limitations by developing a machine learning model for Minnesota, USA, that predicts As exposure risk using only surficial variables from remote sensing and global data sets. Variables related to surface water hydrology and geomorphology are selected based on mechanistic links that control redox conditions and As mobilization. Local training was essential, and surficial geology variables that are more sensitive to local conditions were needed to maximize model accuracy. The resulting complete model was sufficiently sensitive to generate accurate and detailed risk maps and depth profiles of As concentrations above the 10 μg/L maximum contaminant level. Accuracy depended on local training data density. We identified a training data density of 0.07 wells/km 2 as a practical target for stable county-level performance. Maps of exceedance probabilities highlight priority areas for testing that are particularly important in rural communities that have received less sampling. These results support public health action by guiding where to install wells and where to test them, how much new sampling is needed, and where treatment outreach is most urgent.

Minnesota

Season and antecedent conditions impact concentration-discharge relationships for dissolved organic carbon and alkalinity in southeast Alaskan watershed

Fluvial export of dissolved carbon plays an important role in watershed-scale biogeochemistry. Predicted changes in climate are expected to impact watershed hydrologic regimes, and in turn, the sources and export of dissolved carbon from watersheds. Here, we utilize high resolution measurements of discharge and dissolved carbon concentration to examine how concentration-discharge (CQ) relationships vary seasonally and during high flow events over the main runoff season (May–October) in a temperate forested watershed in Southeast Alaska. Concentration-discharge relationships for dissolved organic carbon (DOC) and alkalinity demonstrated strong seasonal patterns, with more linear relationships in May and June versus other months. Changing power law model slopes ( b values; the exponent in a power law regression between runoff and carbon yields) indicated potentially shifting watershed sources (biogenic vs. geologic) and contrasting dominant flowpaths (shallow vs. deeper groundwater) for DOC and alkalinity over the sampling period. During the largest storm event of the study, DOC and alkalinity b values shifted from an overall pattern of transport (mean b = 1.58 values >1.0 indicate transport limitation) and source limitation (mean b = 0.48, values <1.0 indicate source limitation) to chemostatic (DOC, b = 0.99; alkalinity, b = 1.019). In June through August, patterns in hysteresis index suggest that CQ relationships were altered when storms followed in close succession to each other. Together, these findings indicate that seasonal and antecedent flow conditions play a role in dissolved carbon export from forested watersheds. Understanding these dynamics, particularly during winter months, will become increasingly important as changes to hydroclimate impact riverine carbon export.

Alaska

Land application of drill waste: A scope analysis

Drilling fluid waste land application, a process where drilling wastes are spread and tilled into the land surface, has become common in some petroleum-producing states, however, the potential benefits and risks of this practice are not well studied. Drilling fluids can be water- or oil-based and can have high concentrations of total soluble salts and total petroleum hydrocarbons. Comprehensive chemical characterization of these fluids is not well documented in the literature, and the extent of land application is largely unknown. We hypothesized that the land application of drill waste would fluctuate over time due to economic factors. To begin to understand the extent of historical and potential future land application, we analyzed data from over 5,800 drilling fluid land application permits collected by the Oklahoma Corporation Commission for years 2000, 2005, 2010, and 2015–2020. During the years studied, drilling fluid wastes were applied to more than 250,000 acres in Oklahoma, with over 54,000 thousand barrels (Mbbl) of liquids and nearly 21,000 Mbbl of solids applied. Land application is widespread (occurring in 59/77 counties), however recent drilling activity, land availability, and the economics of transportation have created conditions favorable for land application specifically in the Anadarko Basin. Land application can co-occur with sensitive areas, such as important groundwater and surface-water drinking sources and agricultural fields used for subsistence or feed crop production. Our approach for quantifying the extent of land application, along with further chemical characterization studies, can aid operators and land managers who are considering this practice in assessing the associated benefits and risks.

Oklahoma