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Find USGS groundwater and aquifer publications. Search an aquifer name or place, compare source-supplied dates and open reports for hydrogeology, recharge and water-level studies.

At least 271 records · Page 15Linked to original sources

Vulnerability of recently recharged groundwater in principal aquifers of the United States to nitrate contamination

Recently recharged water (defined here as <60 years old) is generally the most vulnerable part of a groundwater resource to nonpoint-source nitrate contamination. Understanding at the appropriate scale the interactions of natural and anthropogenic controlling factors that influence nitrate occurrence in recently recharged groundwater is critical to support best management and policy decisions that are often made at the aquifer to subaquifer scale. New logistic regression models were developed using data from the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program and National Water Information System for 17 principal aquifers of the U.S. to identify important source, transport, and attenuation factors that control nonpoint source nitrate concentrations greater than relative background levels in recently recharged groundwater and were used to predict the probability of detecting elevated nitrate in areas beyond the sampling network. Results indicate that dissolved oxygen, crops and irrigated cropland, fertilizer application, seasonally high water table, and soil properties that affect infiltration and denitrification are among the most important factors in predicting elevated nitrate concentrations. Important differences in controlling factors and spatial predictions were identified in the principal aquifer and national-scale models and support the conclusion that similar spatial scales are needed between informed groundwater management and model development.

Environmental Science & Technology↗

Measuring and interpreting multilayer aquifer-system compactions for a sustainable groundwater-system development

Ever decreasing water resources and climate change have driven the increasing use of groundwater causing land subsidence in many countries. Geodetic sensors such as InSAR, GPS and leveling can detect surface deformation but cannot measure subsurface deformation. A single‐well, single‐depth extensometer can be used to measure subsurface deformation, but it cannot delineate the depths of major compaction and provide insight about the deformation mechanism throughout a complex aquifer system, unless man extensometers at different depths are used. We present a multilayer compaction well (MLCW), installed in a borehole, that uses magnetic rings to detect stratum compaction at 25 depths as deep as 300 m below land surface. Our laboratory and field assessments indicate 1 mm precision and accuracy for one single‐depth magnetic reading. We tested the performance of MLCW by measuring aquifer‐system compaction over the proximal, middle, and distal fans of the Choushui River Alluvial Fan (CRAF) that has long experienced severe land subsidence. The MLCW measurements were used to create time‐depth diagrams of compaction, showing different compaction rates at different layers of aquifers and aquitards to identify the depths of major compactions. The elastic (reversible) and inelastic (irreversible) compactions from MLCW were used in stress‐strain analyses to estimate skeletal specific storages and the safe groundwater levels, below which groundwater extractions have caused irreversible compactions. The hydrogeological parameters derived from MLCW measurements can help governmental agencies to determine effective land‐use and water‐use policies, and ascertain the best strategy for utilizing artificial recharge to prevent land subsidence and achieve sustainable groundwater management.

Water Resources Research↗

Nonlinear-regression groundwater flow modeling of a deep regional aquifer system

A nonlinear regression groundwater flow model, based on a Galerkin finite-element discretization, was used to analyze steady state two-dimensional groundwater flow in the areally extensive Madison aquifer in a 75,000 mi 2 area of the Northern Great Plains. Regression parameters estimated include intrinsic permeabilities of the main aquifer and separate lineament zones, discharges from eight major springs surrounding the Black Hills, and specified heads on the model boundaries. Aquifer thickness and temperature variations were included as specified functions. The regression model was applied using sequential F testing so that the fewest number and simplest zonation of intrinsic permeabilities, combined with the simplest overall model, were evaluated initially; additional complexities (such as subdivisions of zones and variations in temperature and thickness) were added in stages to evaluate the subsequent degree of improvement in the model results. It was found that only the eight major springs, a single main aquifer intrinsic permeability, two separate lineament intrinsic permeabilities of much smaller values, and temperature variations are warranted by the observed data (hydraulic heads and prior information on some parameters) for inclusion in a model that attempts to explain significant controls on groundwater flow. Addition of thickness variations did not significantly improve model results; however, thickness variations were included in the final model because they are fairly well defined. Effects on the observed head distribution from other features, such as vertical leakage and regional variations in intrinsic permeability, apparently were overshadowed by measurement errors in the observed heads. Estimates of the parameters correspond well to estimates obtained from other independent sources.

Great Plains, Madison aquifer↗

Design and Installation of a Groundwater Monitoring-Well Network in the High Plains Aquifer, Colorado

The High Plains aquifer is an important water source for irrigated agriculture and domestic supplies in northeastern Colorado. To address the needs of Colorado's Groundwater Protection Program, the U.S. Geological Survey designed and installed a groundwater monitoring-well network in cooperation with the Colorado Department of Agriculture in 2008 to characterize water quality in the High Plains aquifer underlying areas of irrigated agriculture in eastern Colorado. A 30-well network was designed to provide for statistical representation of water-quality conditions by using a computerized technique to generate randomly distributed potential groundwater sampling sites based on aquifer extent, extent of irrigated agricultural land, depth to water from land surface, and saturated thickness. Twenty of the 30 sites were selected for well installation, and wells were drilled and installed during the period June-September 2008. Lithologic logs and well-construction reports were prepared for each well, and wells were developed after drilling to remove mud and foreign material to provide for good hydraulic connection between the well and aquifer. Documentation of the well-network design, site selection, lithologic logs, well-construction diagrams, and well-development records is presented in this report.

Data Series↗

Groundwater environmental tracer data collected from the Chicot, Evangeline, and Jasper aquifers in Montgomery County and adjacent counties, Texas, 2008

The Gulf Coast aquifer system is the primary water supply for Montgomery County in southeastern Texas, including part of the Houston metropolitan area and the cities of Magnolia, Conroe, and The Woodlands Township, Texas. The U.S. Geological Survey, in cooperation with the Lone Star Groundwater Conservation District, collected environmental tracer data in the Gulf Coast aquifer system, primarily in Montgomery County. Forty existing groundwater wells screened in the Gulf Coast aquifer system were selected for sampling in Montgomery County (38 wells), Waller County (1 well), and Walker County (1 well). Groundwater-quality samples, physicochemical properties, and water-level data were collected once from each of the 40 wells during March-September 2008. Groundwater-quality samples were analyzed for dissolved gases and the environmental tracers sulfur hexafluoride, chlorofluorocarbons, tritium, helium-4, and helium-3/tritium. Water samples were collected and processed onsite using methods designed to minimize changes to the water-sample chemistry or contamination from the atmosphere. Replicate samples for quality assurance and quality control were collected with each environmental sample. Well-construction information and environmental tracer data for March-September 2008 are presented.

Montgomery, Texas↗

Groundwater availability of the Denver Basin aquifer system, Colorado

The Denver Basin aquifer system is a critical water resource for growing municipal, industrial, and domestic uses along the semiarid Front Range urban corridor of Colorado. The confined bedrock aquifer system is located along the eastern edge of the Rocky Mountain Front Range where the mountains meet the Great Plains physiographic province. Continued population growth and the resulting need for additional water supplies in the Denver Basin and throughout the western United States emphasize the need to continually monitor and reassess the availability of groundwater resources. In 2004, the U.S. Geological Survey initiated large-scale regional studies to provide updated groundwater-availability assessments of important principal aquifers across the United States, including the Denver Basin. This study of the Denver Basin aquifer system evaluates the hydrologic effects of continued pumping and documents an updated groundwater flow model useful for appraisal of hydrologic conditions.

Colorado↗

Chloride in Groundwater and Surface Water in Areas Underlain by the Glacial Aquifer System, Northern United States

A study of chloride in groundwater and surface water was conducted for the glacial aquifer system of the northern United States in forested, agricultural, and urban areas by analyzing data collected for the National Water-Quality Assessment Program from 1991 to 2004. Groundwater-quality data from a sampling of 1,329 wells in 19 states were analyzed. Chloride concentrations were greater than the secondary maximum contaminant level established by the U.S. Environmental Protection Agency of 250 milligrams per liter in 2.5 percent of samples from 797 shallow monitoring wells and in 1.7 percent of samples from 532 drinking-water supply wells. Water samples from shallow monitoring wells in urban areas had the largest concentration of chloride, followed by water samples from agricultural and forested areas (medians of 46, 12, and 2.9 milligrams per liter, respectively). An analysis of chloride:bromide ratios, by mass, and chloride concentrations compared to binary mixing curves for dilute groundwater, halite, sewage and animal waste, potassium chloride fertilizer, basin brines, seawater, and landfill leachate in samples from monitoring wells indicated multiple sources of chloride in samples from wells in urban areas and agricultural areas. Water from shallow monitoring wells in urban areas had the largest chloride:bromide ratio, and samples with chloride:bromide ratios greater than 1,000 and chloride concentrations greater than 100 milligrams per liter were dominated by halite; however, the samples commonly contained mixtures that indicated input from sewage or animal waste. Chloride:bromide ratios were significantly larger in samples from public-supply drinking-water wells than from private drinking-water wells, and ratios were significantly larger in all drinking-water wells in eastern and central regions of the glacial aquifer system than in west-central and western regions of the glacial aquifer system. Surface-water-quality data collected regularly during varying time periods from 1991-2004 from 100 basins dominated by forested, agricultural, or urban land in 15 states were analyzed to determine maximum measured chloride concentrations. Samples from 15 sites in east, central, and west-central areas, collected primarily in winter, had chloride concentrations higher than the U.S. Environmental Protection Agency recommended chronic criterion concentration for aquatic life of 230 milligrams per liter. Concentrations of chloride in base-flow samples were predictive of maximum measured chloride concentrations, indicating that inputs of chloride from groundwater and (or) point-source wastewater discharges increase the likelihood of samples exceeding the recommended chronic aquatic criterion. Multiple linear regression analyses showed that the density of major roads, potential evapotranspiration, and the percentage of annual runoff from saturated overland flow were significant factors in describing the range of maximum measured chloride concentrations in the basins studied. Chloride loads and yields were determined at 95 surface-water-monitoring stations in basins dominated by forested, agricultural, or urban land. Annual chloride yield was largest in the urban basins (median of 88 tons per square mile) and smallest in the forested basins (median of 6.4 tons per square mile). The median chloride yield in the agricultural basins was 15.4 tons per square mile. Multiple linear regression analyses showed that the density of highways (roads in U.S. highway system), the number of major wastewater discharges in the basin, potential evapotranspiration, and urban minus agricultural land area were significant factors in describing the range of average annual chloride yields. Upward trends in chloride loads were apparent in several urban basins for which additional long-term data were available. Increases in chloride loads over time may be related to a variety of factors, including increases in road area and consequent deicing, incr

Scientific Investigations Report↗

Multilevel groundwater monitoring of hydraulic head and temperature in the eastern Snake River Plain aquifer, Idaho National Laboratory, Idaho, 2009–10

During 2009 and 2010, the U.S. Geological Survey’s Idaho National Laboratory Project Office, in cooperation with the U.S. Department of Energy, collected quarterly, depth-discrete measurements of fluid pressure and temperature in nine boreholes located in the eastern Snake River Plain aquifer. Each borehole was instrumented with a multilevel monitoring system consisting of a series of valved measurement ports, packer bladders, casing segments, and couplers. Multilevel monitoring at the Idaho National Laboratory has been ongoing since 2006. This report summarizes data collected from three multilevel monitoring wells installed during 2009 and 2010 and presents updates to six multilevel monitoring wells. Hydraulic heads (heads) and groundwater temperatures were monitored from 9 multilevel monitoring wells, including 120 hydraulically isolated depth intervals from 448.0 to 1,377.6 feet below land surface. Quarterly head and temperature profiles reveal unique patterns for vertical examination of the aquifer’s complex basalt and sediment stratigraphy, proximity to aquifer recharge and discharge, and groundwater flow. These features contribute to some of the localized variability even though the general profile shape remained consistent over the period of record. Major inflections in the head profiles almost always coincided with low-permeability sediment layers and occasionally thick sequences of dense basalt. However, the presence of a sediment layer or dense basalt layer was insufficient for identifying the location of a major head change within a borehole without knowing the true areal extent and relative transmissivity of the lithologic unit. Temperature profiles for boreholes completed within the Big Lost Trough indicate linear conductive trends; whereas, temperature profiles for boreholes completed within the axial volcanic high indicate mostly convective heat transfer resulting from the vertical movement of groundwater. Additionally, temperature profiles provide evidence for stratification and mixing of water types along the southern boundary of the Idaho National Laboratory. Vertical head and temperature change were quantified for each of the nine multilevel monitoring systems. The vertical head gradients were defined for the major inflections in the head profiles and were as high as 2.1 feet per foot. Low vertical head gradients indicated potential vertical connectivity and flow, and large gradient inflections indicated zones of relatively low vertical connectivity. Generally, zones that primarily are composed of fractured basalt displayed relatively small vertical head differences. Large head differences were attributed to poor vertical connectivity between fracture units because of sediment layering and/or dense basalt. Groundwater temperatures in all boreholes ranged from 10.2 to 16.3˚C. Normalized mean hydraulic head values were analyzed for all nine multilevel monitoring wells for the period of record (2007-10). The mean head values suggest a moderately positive correlation among all boreholes, which reflects regional fluctuations in water levels in response to seasonality. However, the temporal trend is slightly different when the location is considered; wells located along the southern boundary, within the axial volcanic high, show a strongly positive correlation.

Idaho↗

Preliminary groundwater flow model of the basin-fill aquifers in Detrital, Hualapai, and Sacramento Valleys, Mohave County, northwestern Arizona

Preliminary numerical models were developed to simulate groundwater flow in the basin-fill alluvium in Detrital, Hualapai, and Sacramento Valleys in northwestern Arizona. The purpose of this exercise was to gather and evaluate available information and data, to test natural‑recharge concepts, and to indicate directions for improving future regional groundwater models of the study area. Both steady-state and transient models were developed with a single layer incorporating vertically averaged hydraulic properties over the model layer. Boundary conditions for the models were constant-head cells along the northern and western edges of the study area, corresponding to the location of the Colorado River, and no-flow boundaries along the bedrock ridges that bound the rest of the study area, except for specified flow where Truxton Wash enters the southern end of Hualapai Valley. Steady-state conditions were simulated for the pre-1935 period, before the construction of Hoover Dam in the northwestern part of the model area. Two recharge scenarios were investigated using the steady-state model—one in which natural aquifer recharge occurs directly in places where water is available from precipitation, and another in which natural aquifer recharge from precipitation occurs in the basin-fill alluvium that drains areas of available water. A transient model with 31 stress periods was constructed to simulate groundwater flow for the period 1935–2010. The transient model incorporates changing Colorado River, Lake Mead, and Lake Mohave water levels and includes time-varying groundwater withdrawals and aquifer recharge. Both the steady-state and transient models were calibrated to available water-level observations in basin-f ill alluvium, and simulations approximate observed water-level trends throughout most of the study area.

Arizona↗

Kinetic and mineralogic controls on the evolution of groundwater chemistry and 87Sr/86Sr in a sandy silicate aquifer, northern Wisconsin, USA

Substantial flowpath-related variability of 87Sr/86Sr is observed in groundwaters collected from the Trout Lake watershed of northern Wisconsin. In the extensive shallow aquifer composed of sandy glacial outwash, groundwater is recharged either by seepage from lakes or by precipitation that infiltrates the inter-lake uplands. 87Sr/86Sr of groundwater derived mainly as seepage from a precipitation-dominated lake near the head of the watershed decreases with progressive water chemical evolution along its flowpath due primarily to enhanced dissolution of relatively unradiogenic plagioclase. In contrast, 87Sr/86Sr of groundwater derived mainly from precipitation that infiltrates upland areas is substantially greater than that of precipitation collected from the watershed, due to suppression of plagioclase dissolution together with preferential leaching of Sr from radiogenic phases such as K-feldspar and biotite. The results of a column experiment that simulated the effects of changing residence time of water in the aquifer sand indicate that mobile waters obtain relatively unradiogenic Sr, whereas stagnant waters obtain relatively radiogenic Sr. Nearly the entire range of strontium-isotope composition observed in groundwaters from the watershed was measured in the experimental product waters. The constant mobility of water along groundwater recharge flowpaths emanating from the lakes promotes the dissolution of relatively unradiogenic plagioclase, perhaps due to effective dispersal of clay mineral nuclei resulting from dissolution reactions. In contrast, episodic stagnation in the unsaturated zone along the upland recharge flowpaths suppresses plagioclase dissolution, perhaps due to accumulation of clay mineral nuclei on its reactive surfaces. Differences in redox conditions along these contrasting flowpaths probably enhance the observed differences in strontium isotope behavior. This study demonstrates that factors other than the calculated state of mineral saturation must be considered when attempting to simulate chemical evolution along flowpaths, and that reaction models must be able to incorporate changing contributions from reacting minerals in the calculations.

Geochimica et Cosmochimica Acta↗

Elevated manganese concentrations in United States groundwater, role of land surface–soil–aquifer connections

Chemical data from 43 334 wells were used to examine the role of land surface–soil–aquifer connections in producing elevated manganese concentrations (>300 μg/L) in United States (U.S.) groundwater. Elevated concentrations of manganese and dissolved organic carbon (DOC) in groundwater are associated with shallow, anoxic water tables and soils enriched in organic carbon, suggesting soil-derived DOC supports manganese reduction and mobilization in shallow groundwater. Manganese and DOC concentrations are higher near rivers than farther from rivers, suggesting river-derived DOC also supports manganese mobilization. Anthropogenic nitrogen may also affect manganese concentrations in groundwater. In parts of the northeastern U.S. containing poorly buffered soils, ∼40% of the samples with elevated manganese concentrations have pH values < 6 and elevated concentrations of nitrate relative to samples with pH ≥ 6, suggesting acidic recharge produced by the oxidation of ammonium in fertilizer helps mobilize manganese. An estimated 2.6 million people potentially consume groundwater with elevated manganese concentrations, the highest densities of which occur near rivers and in areas with organic carbon rich soil. Results from this study indicate land surface–soil–aquifer connections play an important role in producing elevated manganese concentrations in groundwater used for human consumption.

Environmental Science & Technology↗

Emerging contaminants in groundwater, karst, and the Edwards Aquifer

Karst aquifers have hydrogeologic characteristics that render them uniquely vulnerable to contamination from emerging contaminants (ECs). ECs comprise numerous chemical groups, including pharmaceuticals, personal-care products, flame retardants, perfluorinated and polyfluorinated compounds, nanoparticles and microplastics. Many ECs have sources, transport pathways, and chemical characteristics that facilitate their infiltration into groundwater, either indirectly from surface water or directly from sources such as landfill leachate and septic systems. What little is known about the occurrence, fate, and transport of ECs in the Edwards aquifer indicates that the aquifer might be increasingly vulnerable to this type of contamination. The natural physical characteristics of this karst aquifer and anthropogenic sources of ECs associated with increased urbanization in central Texas contribute to this vulnerability. In this chapter, we review groups of ECs and their sources, occurrence of ECs in groundwater and karst, and what is known about occurrence of ECs in the Edwards aquifer. We conclude by discussing specific factors, such as rapid flow and contaminant sources, that contribute to the vulnerability of the Edwards aquifer to contamination by ECs.

Texas↗

Assessing legacy nitrogen in groundwater using numerical models of the Long Island aquifer system, New York

Nitrogen transported along groundwater flow paths in coastal aquifers can contribute substantially to nitrogen loading into surface water receptors, particularly in hydrologic systems dominated by groundwater discharge. Nitrogen entrained in the aquifer is a function of land use and associated nitrogen sources at the time of groundwater recharge, which may differ considerably from present-day sources. Legacy nitrogen can result in substantial discrepancies between observed present-day nitrogen loading to surface water receptors and loading estimated from present-day sources. Additionally, legacy nitrogen can continue to discharge into surface waters after nitrogen mitigation actions have been undertaken. Here, we use a numerical modeling framework to compare three methods of estimating time-varying historical nitrogen loads to four water bodies (receptors) on eastern Long Island, New York. The methods span a range of data requirements and process complexity, from instantaneous receptor loads calculated from steady-state groundwater contributing areas, to transient loads estimated by explicitly simulating legacy groundwater nitrogen transport over a century with large changes in nitrogen sources and hydrologic conditions. The effects of legacy nitrogen on estimated receptor loads varied temporally and spatially within the study area. Depending on antecedent nitrogen inputs and hydrologic conditions, historical annual nitrogen loads estimated from transient simulations accounting for legacy nitrogen can be quite similar (<10% difference) or substantially different (±100%) from those estimated from simpler instantaneous methods. Continued input of present-day nitrogen sources using methods that account for legacy nitrogen results in asymptotic increases in receptor nitrogen loads over time, indicating that simulated present-day receptor nitrogen loads are not in equilibrium with present-day inputs. For these receptors in disequilibrium, models simulating transient groundwater nitrogen transport could be used to account for legacy nitrogen lag times to help resource managers evaluate the potential effectiveness of proposed nitrogen mitigation actions.

EarthArXiv↗

Estimated groundwater withdrawals from principal aquifers in the United States, 2015

In 2015, about 84,600 million gallons per day (Mgal/d) of groundwater were withdrawn in the United States for various uses including public supply, self-supplied domestic, industrial, mining, thermoelectric power, aquaculture, livestock, and irrigation. Of this total, about 94 percent (79,200 Mgal/d) was withdrawn from principal aquifers, which are defined as regionally extensive aquifers or aquifer systems that have the potential to be used as sources of water of suitable quality and quantity to meet various needs. The remaining 6 percent (5,400 Mgal/d) was withdrawn from other, nonprincipal aquifers in the United States. Sixty-six principal aquifers belonging to 5 major lithologic groups have been identified and delineated in the United States, including Puerto Rico and the U.S. Virgin Islands. Of the water withdrawn from principal aquifers in 2015, 81 percent (63,900 Mgal/d) was from the unconsolidated and semiconsolidated sand and gravel lithologic group, 7.1 percent (5,630 Mgal/d) was from the igneous and metamorphic-rock lithologic group, 6.8 percent (5,360 Mgal/d) was from the carbonate-rock lithologic group, 3.4 percent (2,680 Mgal/d) was from the sandstone lithologic group, and 2.2 percent (1,710 Mgal/d) was from the sandstone and carbonate-rock lithologic group. The most heavily pumped of the 24 principal aquifers and aquifer systems within the unconsolidated and semiconsolidated sand and gravel lithologic group were the High Plains aquifer (12,300 Mgal/d), Mississippi River Valley alluvial aquifer (12,100 Mgal/d), Central Valley aquifer system (11,100 Mgal/d), and Basin and Range basin-fill aquifers (7,390 Mgal/d). Withdrawals for irrigation were 48,100 Mgal/d and accounted for 75 percent of the total withdrawals from this lithologic group. Although unconsolidated sand and gravel aquifers are widely distributed and were used as sources of water in all States except Hawaii and the U.S. Virgin Islands, 56 percent of the total withdrawn from unconsolidated and semiconsolidated sand and gravel aquifers was in just four States: California (15,600 Mgal/d), Arkansas (9,560 Mgal/d), Nebraska (5,570 Mgal/d), and Texas (4,830 Mgal/d). The most heavily pumped of the seven principal aquifers within the igneous and metamorphic-rock lithologic group were the Snake River Plain (2,930 Mgal/d) and Columbia Plateau basaltic-rock aquifers (1,080 Mgal/d), which are located in the northwestern United States and together accounted for 71 percent of the water withdrawn from this lithologic group. Withdrawals for irrigation were 4,190 Mgal/d and accounted for more than 74 percent of the total withdrawals from this lithologic group. Seventy-eight percent of the withdrawals from igneous and metamorphic-rock aquifers were in three States: Idaho (3,230 Mgal/d), Washington (614 Mgal/d), and Oregon (528 Mgal/d). The most heavily pumped of the 15 principal aquifers and aquifer systems within the carbonate-rock lithologic group were the Floridan aquifer system (3,180 Mgal/d) and the Biscayne aquifer (679 Mgal/d), which are in the southeastern United States and together accounted for almost 72 percent of the withdrawals from this lithologic group. Withdrawals for public supply (2,440 Mgal/d) and irrigation (1,610 Mgal/d) together accounted for almost 76 percent of the total withdrawals from this lithologic group. Although water was withdrawn from carbonate-rock aquifers in 35 States, 71 percent of the total withdrawn was in Florida (3,020 Mgal/d) and Georgia (785 Mgal/d). The most heavily pumped of the 15 principal aquifers within the sandstone lithologic group was the Cambrian-Ordovician aquifer system (921 Mgal/d), which is in the north-central United States and accounted for 34 percent of the water withdrawn from this lithologic group. Withdrawals for public supply were 1,030 Mgal/d and accounted for 38 percent of the total withdrawals from this lithologic group. Although sandstone aquifers were used as sources of water in 32 States, 45 percent of the total withdrawn from sandstone aquifers was in five States: Minnesota (321 Mgal/d), Wisconsin (319 Mgal/d), Kansas (193 Mgal/d), Illinois (187 Mgal/d), and Pennsylvania (179 Mgal/d). The most heavily pumped of the five principal aquifers and aquifer systems within the sandstone and carbonate-rock lithologic group were the Edwards-Trinity aquifer system (661 Mgal/d) in the south-central United States and the Valley and Ridge aquifers (551 Mgal/d) of the eastern United States, which together accounted for 71 percent of total withdrawals from this lithologic group. Withdrawals from sandstone and carbonate-rock aquifers for public-supply (713 Mgal/d), irrigation (469 Mgal/d), and self-supplied domestic (253 Mgal/d) uses accounted for about 84 percent of the total withdrawals from this lithologic group. Although water was withdrawn from sandstone and carbonate-rock aquifers in 25 States, 65 percent of the total withdrawn was in Texas (651 Mgal/d), Pennsylvania (238 Mgal/d), and Florida (223 Mgal/d).

Circular↗

Rebuttal to “The case of the Biscayne Bay and aquifer near Miami, Florida: density-driven flow of seawater or gravitationally driven discharge of deep saline groundwater?” by Weyer (Environ Earth Sci 2018, 77:1–16)

A recent paper by Weyer (Environ Earth Sci 2018, 77:1–16) challenges the widely accepted interpretation of groundwater heads and salinities in the coastal Biscayne aquifer near Miami, Florida, USA. Weyer (2018) suggests that the body of saltwater that underlies fresh groundwater just inland of the coast is not a recirculating wedge of seawater, but results instead from upward migration of deep saline groundwater driven by regional flow. Perhaps more significantly, Weyer (2018) also asserts that established hydrologic theory is fundamentally incorrect with respect to buoyancy. Instead of acting along the direction of gravity (that is, vertically), Weyer (2018) claims, buoyancy acts instead along the direction of the pressure gradient. As a result, Weyer (2018) considers currently available density-dependent groundwater flow and transport modeling codes, and the analyses based on them, to be in error. In this rebuttal, we clarify the inaccuracies in the main points of Weyer’s (2018) paper. First, we explain that Weyer (2018) has misinterpreted observed equivalent freshwater heads in the Biscayne aquifer and that his alternative hypothesis concerning the source of the saltwater does not explain the observed salinities. Then, we review the established theory of buoyancy to identify the problem with Weyer’s (2018) alternative theory. Finally, we present theory and cite successful benchmark simulations to affirm the suitability of currently available codes for modeling density-dependent groundwater flow and transport.

Environmental Earth Sciences↗

Groundwater quality in the Sacramento Metropolitan shallow aquifer, California

The Sacramento metropolitan (SacMetro) study unit covers approximately 3,250 square kilometers of the Central Valley along the eastern edge of the northern and southern ends of the San Joaquin and Sacramento Valleys, respectively. Groundwater withdrawals supply a significant portion of the water-resource needs of the region. In the southern portion of the study unit, groundwater accounts for nearly 90 percent of water demand in the area (South Area Water Council, 2011). Groundwater sampled in the SacMetro study unit comes from alluvial aquifers primarily composed of sediments derived from the Sierra Nevada Mountains to the east. Recharge to the groundwater system is primarily from the streams draining the Sierra Nevada, and from precipitation and infiltration of applied irrigation water (California Department of Water Resources, 2003). The public-supply aquifer system assessments of this area in 2005 found elevated concentrations of inorganic constituents including arsenic, iron, and manganese as well as of solvents in some wells (Bennett and others, 2010; 2011). This study was designed to provide a statistically representative assessment of the quality of groundwater resources used for domestic drinking water in the SacMetro study unit. A complete listing of what was measured, including the sampling results, are presented in Bennett and others, 2019. A total of 49 wells were sampled between July 2017 and November 2017 (Bennett and others, 2019). The wells in the study were 32–160 meters deep, and water levels were 1–62 meters below land surface.

California↗

Chemical Constituents in Groundwater from Multiple Zones in the Eastern Snake River Plain Aquifer at the Idaho National Laboratory, Idaho, 2005-08

From 2005 to 2008, the U.S. Geological Survey's Idaho National Laboratory (INL) Project office, in cooperation with the U.S. Department of Energy, collected water-quality samples from multiple water-bearing zones in the eastern Snake River Plain aquifer. Water samples were collected from six monitoring wells completed in about 350-700 feet of the upper part of the aquifer, and the samples were analyzed for major ions, selected trace elements, nutrients, selected radiochemical constituents, and selected stable isotopes. Each well was equipped with a multilevel monitoring system containing four to seven sampling ports that were each isolated by permanent packer systems. The sampling ports were installed in aquifer zones that were highly transmissive and that represented the water chemistry of the top four to five model layers of a steady-state and transient groundwater-flow model. The model's water chemistry and particle-tracking simulations are being used to better define movement of wastewater constituents in the aquifer. The results of the water chemistry analyses indicated that, in each of four separate wells, one zone of water differed markedly from the other zones in the well. In four wells, one zone to as many as five zones contained radiochemical constituents that originated from wastewater disposal at selected laboratory facilities. The multilevel sampling systems are defining the vertical distribution of wastewater constituents in the eastern Snake River Plain aquifer and the concentrations of wastewater constituents in deeper zones in wells Middle 2051, USGS 132, and USGS 103 support the concept of groundwater flow deepening in the southwestern part of the INL.

Scientific Investigations Report↗

Factors affecting groundwater quality in the Valley and Ridge aquifers, eastern United States, 1993-2002

Chemical and microbiological analyses of water from 230 wells and 35 springs in the Valley and Ridge Physiographic Province, sampled between 1993 and 2002, indicated that bedrock type (carbonate or siliciclastic rock) and land use were dominant factors influencing groundwater quality across a region extending from northwestern Georgia to New Jersey. The analyses included naturally occurring compounds (major mineral ions and radon) and anthropogenic contaminants [pesticides and volatile organic compounds (VOCs)], and contaminants, such as nitrate and bacteria, which commonly increase as a result of human activities. Natural factors, such as topographic position and the mineral composition of underlying geology, act to produce basic physical and geochemical conditions in groundwater that are reflected in physical properties, such as pH, temperature, specific conductance, and alkalinity, and in chemical concentrations of dissolved oxygen, radon, and major mineral ions. Anthropogenic contaminants were most commonly found in water from wells and springs in carbonate-rock aquifers. Nitrate concentrations exceeded U.S. Environmental Protection Agency maximum contaminant levels in 12 percent of samples, most of which were from carbonate-rock aquifers. Escherichia coli (E. coli), pesticide, and VOC detection frequencies were significantly higher in samples from sites in carbonate-rock aquifers. Naturally occurring elements, such as radon, iron, and manganese, were found in higher concentrations in siliciclastic-rock aquifers. Radon levels exceeded the proposed maximum contaminant level of 300 picocuries per liter in 74 percent of the samples, which were evenly distributed between carbonate- and siliciclastic-rock aquifers. The land use in areas surrounding wells and springs was another significant explanatory variable for the occurrence of anthropogenic compounds. Nitrate and pesticide concentrations were highest in samples collected from sites in agricultural areas and lowest in samples collected from sites in undeveloped areas. Volatile organic compounds were detected most frequently and in highest concentrations in samples from sites in urban areas, and least frequently in agricultural and undeveloped areas. No volatile organic compound concentrations and concentrations from only one pesticide, dieldrin, exceeded human-health benchmarks.

Alabama;Georgia;Tennessee;North Carolina;Virginia;↗