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William W. Carothers

Publications and source records attributed to William W. Carothers.

2 recordsLinked to original sources

MINERALOGICAL STUDIES OF THE HYDROTHERMAL SYSTEM IN NEWBERRY VOLCANO DRILL HOLE 2, OREGON.

Studies of secondary mineral distribution, whole-rock chemical compositions, isotopes, and fluid inclusions are being conducted on the core from Newberry Volcano drill hole 2. Rocks from the drill core are divided into 3 major intervals on the basis of their alteration pattern, which is controlled by rock permeabilities, primary lithologies, and temperatures. Incomplete alteration of pumice-rich lithic tuff layers in the upper part of the altered section and lack of self-sealing in fractures of most lava flows suggest that the hydrothermal system is young. Most of the secondary minerals could have been formed at temperatures near those present today; maximum measured temperature was 265 degree C at the bottom of the hole. Fluid inclusions indicate that past temperatures in the deeper part of the drill hole may have been as much as 100 degree C hotter than presently measured temperatures.

Conference Paper↗

Methods for collection and analysis of geopressured geothermal and oil field waters

Present methods are described for the collection, preservation, and chemical analysis of waters produced from geopressured geothermal and petroleum wells. Detailed procedures for collection include precautions and equipment necessary to ensure that the sample is representative of the water produced. Procedures for sample preservation include filtration, acidification, dilution for silica, methyl isobutyl ketone (MIBK) extraction of aluminum, addition of potassium permanganate to preserve mercury, and precipitation of carbonate species as strontium carbonate for stable carbon isotopes and total dissolved carbonate analysis. Characteristics determined at the well site are sulfide, pH, ammonia, and conductivity. Laboratory procedures are given for the analysis of lithium, sodium, potassium, rubidium, cesium, magnesium, calcium, strontium, barium, iron, manganese, zinc, lead, aluminum, .and mercury by atomic absorption and flame emission spectroscopy. Chloride is determined by silver nitrate titration and fluoride by ion-specific electrode. Bromide and iodide concentrations are determined by the hypochlorite oxidation method. Sulfate is analyzed by titration using barium chloride with thorin indicator after pretreatment with alumina. Boron and silica are determined colorimetrically by the carmine and molybdate-blue methods, respectively. Aliphatic acid anions (C2 through C5) are determined by gas chromatography after separation and concentration in a chloroform-butanol mixture.

Water Supply Paper↗