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Geology topics

William P. Dillon

Publications and source records attributed to William P. Dillon.

At least 37 records · Page 2Linked to original sources

Gas hydrate in seafloor sediments: Impact on future resources and drilling safety

Gas hydrate concentrates methane and sometimes other gases in its crystal lattice and this gas can be released intentionally creating a resource or escape accidentally forming a hazard. The densest accumulations of gas hydrate tend to occur at sites where the base of the gas hydrate stability zone (commonly the upper several hundred m of the sedimentary section) is configured to trap gas, often as a broad arch. The gas may rise from below or form by bacterial activity at shallow depth, but gas commonly is concentrated near the base of the gas hydrate stability zone by recycling. This gas accumulates in presumably leaky traps, then enriches the hydrate above as it migrates upward by diffusion, fluid movement through sedimentary pores, or flow along fracture channelways. Analysis of seismic reflection profiles is beginning to identify such concentrations and the circumstances that create them. The first attempt to explore for gas hydrate off Japan by the Japanese National Oil Corporation produced quite favorable results, showing high gas hydrate contents in permeable sediments. Gas hydrate dissociation can be a safety concern in drilling and production. The volume of water and gas released in dissociation is often greater than the volume of the hydrate, so overpressures can be created. Furthermore, the gas hydrate can provide shallow seals, so the possibility of high-pressure flows or generation of slides is apparent.

Conference Paper

Amplitude blanking related to the pore-filling of gas hydrate in sediments

Seismic indicators of gas-hydrate-bearing sediments include elevated interval velocities and amplitude reduction of seismic reflections owing to the presence of gas hydrate in the sediment's pore spaces. However, large amplitude blanking with relatively low interval velocities observed at the Blake Ridge has been enigmatic because realistic seismic models were absent to explain the observation. This study proposes models in which the gas hydrate concentrations vary in proportion to the porosity. Where gas hydrate concentrations are greater in more porous media, a significant amplitude blanking can be achieved with relatively low interval velocity. Depending on the amount of gas hydrate concentration in the pore space, reflection amplitudes from hydrate-bearing sediments can be much less, less or greater than those from corresponding non-hydrate-bearing sediments.

Marine Geophysical Research

Earthquakes and tsunamis in Puerto Rico and the U.S. Virgin Islands

Many earthquakes and tsunamis have occurred in the northeastern Caribbean, where the movements of the Earth's surface plates are rapid and complicated. Future such events pose serious hazards to the 3.7 million people who live in Puerto Rico and the U.S. Virgin Islands.

Puerto Rico, U.S. Virgin Islands

Trapping and migration of methane associated with the gas hydrate stability zone at the Blake Ridge Diapir: New insights from seismic data

The Blake Ridge Diapir is the southernmost of a line of salt diapirs along the Carolina trough. Diapirs cause faulting of the superjacent sediments, creating pathways for migration of fluids and gas to the seafloor. We analyzed reflection seismic data from the Blake Ridge Diapir, which is located in a region with known abundant gas hydrate occurrence. A striking feature in these data is a significant shallowing of the base of gas hydrate stability (BGHS) over the center of the diapir. The seafloor is warped up by about 100 m above the diapir, from about 2300 m to about 2200 m. The BGHS, as indicated by a bottom simulating reflection (BSR), is about 4.5 s off the flanks of the diapir, rising to about 4.15 s at the center. Above the diapir, a fault system appears to rise vertically from the BGHS to about 0.05 s below the seafloor (40-50 m); it then diverges into several steeply dipping faults that breach the seafloor and cover an area ~700 m in diameter. Other secondary faults diverge from the main fault or emerge directly from the BGHS near the crest of the diapir. Gas and other fluids may migrate upward through the faults. We performed complex trace analysis to compare the reflection strength and instantaneous frequency along individual reflections. A low-frequency anomaly over the center of the diapir indicates high seismic attenuation. This is interpreted to be caused by migration of fluids (probably methane) along fault pathways. The migration of gas (i.e. probably mainly methane) through the gas hydrate stability zone is not yet understood. We speculate that pore fluids in the faults may be too warm and too salty to form gas hydrate, even at depths where gas hydrate is stable away from the diapir. Alternatively, gas hydrates may seal the fault walls such that water supply is too low to transform all the gas into gas hydrates. The shallowing of the BSR may reflect increased heatflow above the diapir either caused by the high thermal conductivity of the underlying salt or by advective heat transport along with fluids. High pore water salinity shifts the gas hydrate stability to lower temperatures and may also play a significant role in BSR shallowing. We, therefore, investigated the possible effect of pore water salinity on shallowing of the BSR. We found that BSR shallowing may theoretically be entirely caused by increased salinity over the diapir, although geologically this would not be reasonable. This observation demonstrates the potential importance of pore water salinity for lateral variations of BSR depths, in particular, above salt structures: (C) 2000 Elsevier Science B.V.

Blake Ridge Diapir

Seismic reflection results from the GYRE 1997 cruise of the Bryant Canyon on the Louisiana Gulf Coast

The Texas-Louisiana continental slope is one of the few remaining frontiers for hydrocarbon exploration within the US Exclusive Economic Zone. This area has a complex seafloor morphology and highly discontinuous shallow stratigraphy that are the result of deformation by the highly mobile Louann salt that underlies much of this margin shoreward of the Sigsbee Escarpment.Gas hydrates exist both on the sea floor and at depth throughout the gas hydrate stability zone which extends to several hundred meters beneath the sea floor at greater water depths. Multibeam bathymetry, GLORIA sidescan sonar imagery, and site-specific studies have identified the presence of faults, mass-wasting deposits, variable sediment types, and gas hydrates exposed on the seafloor. The expression of these features on the seafloor suggests a tectonically active area. The distribution of these different processes and their relation to the subsurface stratigraphy and tectonic setting are not well understood, yet an understanding of these issues is essential as exploration extends into this deep-water area. To address the questions of surficial processes and their connection with deeper structures underlying this continental margin, a three-week cruise was conducted by the USGS in April, 1997 aboard the RV GYRE. The study area focussed on Bryant Canyon, a former submarine canyon, through which turbidity currents transported sands from a shelf-edge delta upslope of the study area to the Bryant Fan on the rise seaward of the base of the slope. The cruise was divided into two parts. The first part was devoted to collecting seismic-reflection profiles across parts of the canyon system to define the shallow stratigraphy and to determine the presence and distribution of gas hydrates in this area. Approximately 555 km of single-channel seismic-reflection data were collected during this first part of the cruise. A track map showing the locations of the profiles, low-resolution images of the profiles, and the SEG-Y format of these data are all presented on this CD-ROM. During the second part of the cruise, 38 piston cores were collected to describe the shallow subsurface facies of the study area. The coring data will be availible in an open file report to be published by Hans Nelson.

Lousiana

Natural gas hydrate: A frozen asset?

Vast stores of methane are locked away below the ocean floor and under the polar permafrost. Could they represent an important future energy resource?

Chemistry and Industry (London)

Sea-floor methane blow-out and global firestorm at the K-T boundary

A previously unsuspected source of fuel for the global firestorm recorded by soot in the Cretaceous-Tertiary impact layer may have resided in methane gas associated with gas hydrate in the end-Cretaceous seafloor. End-Cretaceous impact-generated shock and megawaves would have had the potential to initiate worldwide oceanic methane gas blow-outs from these deposits. The methane would likely have ignited and incompletely combusted. This large burst of methane would have been followed by longer-term methane release as a part of a positive thermal feedback in the disturbed ocean-atmosphere system.

Geo-Marine Letters

Seismic-reflection surveys of the Blake Ridge, R/V Cape Hatteras 1992 and 1995: Data acquisition, navigation, and processing

As part of an ongoing study, seismic-reflection profiles were collected over the Blake Ridge in 1992 and 1995, in order to map the volume and distribution of methane hydrate. Faulting and seafloor instabilities appear to be related to methane hydrate processes at the Blake Ridge. Seismic profiles display a prominent collapse structure at the crest, which is inferred to have resulted from the mobilization of sediment that was associated with methane hydrate dissociation.

Open-File Report

Seismic reflections identify finite differences in gas hydrate resources

Gas hydrate is a gas-bearing, ice-like crystalline solid. The substance's build ing blocks consist of a gas molecule (generally methane) sur-rounded by a cage of water molecules. The total amount of methane in hydrate in the world is immense - the most recent speculative estimate centers on values of 21x1015 cu meters. Thus, it may represent a future energy resource. This estimate was presented by Keith Kvenvolden at the International Symposium on Methane Hydrates, Resources in the Near Future, sponsor ed by Japanese National Oil Company (Tokyo, October, 1998). But, as with any natural resource, there is a need to find naturally occurring concentrations in order to effectively extract gas. We need to answer four basic questions: Do methane hydrate concentrations suitable for methane extraction exist? How can we recognize these concentrations? Where are concentrations located? What processes control methane hydrate concentrations? Gas hydrate occurs naturally at the pressure/ temperature/chemical conditions that are present within ocean floor sediments at water depths greater than about 500 meters. The gas hydrate stability zone (GHSZ) extends from the sea bottom downward to a depth where the natural increase in temperature causes the hydrate to melt (dissociate), even though the downward pressure increase is working to increase gas hydrate stability. Thus, the base of the GHSZ tends to parallel the seafloor at any given water depth (pressure), because the sub-seafloor isotherms (depths of constant temperature) generally parallel the seafloor. The layer at which gas hydrate is stable commonly extends from the sea floor to several hundred meters below it. The gas in most gas hydrates is methane, generated by bacteria in the sediments. In some cases, it can be higher carbon-number, thermogenic hydrocarbon gases that rise from greater depths.

Offshore

Evidence for faulting related to dissociation of gas hydrate and release of methane off the southeastern United States

This paper is part of the special publication Gas hydrates: relevance to world margin stability and climatic change (eds J.P. Henriet and J. Mienert). An irregular, faulted, collapse depression about 38 x 18 km in extent is located on the crest of the Blake Ridge offshore from the south- eastern United States. Faults disrupt the sea floor and terminate or sole out about 40-500 m below the sea floor at the base of the gas hydrate stable zone, which is identified from the location of the bottom simulating reflection (BSR). Normal faults are common but reverse faults and folds also are widespread. Folds commonly convert upward into faults. Sediment diapirs and deposits of sediments that were erupted onto the sea floor are also present. Sea-floor depressions at faults may represent locations of liquid/gas vents. The collapse was probably caused by overpressures and by the decoupling of the overlying sediments by gassy muds that existed just beneath the zone of gas hydrate stability.

Blake Ridge

Faulting of gas-hydrate-bearing marine sediments - contribution to permeability

Extensive faulting is observed in sediments containing high concentrations of methane hydrate off the southeastern coast of the United States. Faults that break the sea floor show evidence of both extension and shortening; mud diapirs are also present. The zone of recent faulting apparently extends from the ocean floor down to the base of gas-hydrate stability. We infer that the faulting resulted from excess pore pressure in gas trapped beneath the gas hydrate-beating layer and/or weakening and mobilization of sediments in the region just below the gas-hydrate stability zone. In addition to the zone of surface faults, we identified two buried zones of faulting, that may have similar origins. Subsurface faulted zones appear to act as gas traps.

Conference Paper

Seismic velocities for hydrate-bearing sediments using weighted equation

A weighted equation based on the three-phase time-average and Wood equations is applied to derive a relationship between the compressional wave (P wave) velocity and the amount of hydrates filling the pore space. The proposed theory predicts accurate P wave velocities of marine sediments in the porosity range of 40-80% and provides a practical means of estimating the amount of in situ hydrate using seismic velocity. The shear (S) wave velocity is derived under the assumption that the P to S wave velocity ratio of the hydrated sediments is proportional to the weighted average of the P to S wave velocity ratios of the constituent components of the sediment. In the case that all constituent components are known, a weighted equation using multiphase time-average and Wood equations is possible. However, this study showed that a three-phase equation with modified matrix velocity, compensated for the clay content, is sufficient to accurately predict the compressional wave velocities for the marine sediments. This theory was applied to the laboratory measurements of the P and S wave velocities in permafrost samples to infer the amount of ice in the unconsolidated sediment. The results are comparable to the results obtained by repeatedly applying the two-phase wave scattering theory. The theory predicts that the Poisson's ratio of the hydrated sediments decreases as the hydrate concentration increases and the porosity decreases. In consequence, the amplitude versus offset (AVO) data for the bottom-simulating reflections may reveal positive, negative, or no AVO anomalies depending on the concentration of hydrates in the sediments.

Journal of Geophysical Research B: Solid Earth

Seismic reflection profile of the Blake Ridge near sites 994, 995, and 997

Seismic reflection profiles near Sites 994, 995, and 997 were collected with seismic sources that provide maximum resolution with adequate power to image the zone of gas hydrate stability and the region direction beneath it. The overall structure of the sediment drift deposit that constitutes the Blake Ridge consists of southwestward-dipping strata. These strata are approximately conformal to the seafloor on the southwest side of the ridge and are truncated by erosion on the northeast side. A bottom-simulating reflection (BSR) marks the velocity contrast between gas hydrate-bearing sediment and regions containing free gas beneath the zone of gas hydrate stability. The BSR is strong and continuous near the ridge crest but becomes discontinuous on the flanks, where concentration of gas is reduced and dipping strata pass through the level of the base o fgas hydrate stability or the strata are disrupted by faults. Seismic reflection amplitudes appear to be reduced in the region of gas hydrate formation compared to normal amplitudes. A faulted zone ~0.5-0.6 s thick parallels reflections from strata. We infer that this may represent a formerly gas hydrate-bearing zone that was faulted because of a breakdown of hydrate near its phase limit (at the base of the zone). Strong reflections at the top of the faulted zone are caused by free-gas acccumulation at Site 994. Similar strong reflections probably are caused by free-gas accumulations where the top of the faulted zone rises above the BSR, although this would require local free gas within the hydrate-stable zone.

Blake Plateau