Geology topics
Publications and source records attributed to William A. Rouse.
Using a geology-based assessment methodology, the U.S. Geological Survey estimated undiscovered, technically recoverable mean conventional resources of 96 trillion cubic feet of gas in the Northern Alaska Province.
We document chemostratigraphy in an outcrop of late Albian to early Campanian (∼103–82 Ma) marine source rocks to better understand paleoenvironmental controls on trace element (TE) enrichment and organic matter accumulation in the distal Colville foreland basin of Arctic Alaska and how those drivers are linked to arc volcanism and successions of Cretaceous oceanographic and climatic biogeochemical events. This unique, 113-m-thick section of Cretaceous Hue Shale deposited during a series of previously undocumented Arctic Cretaceous oceanic anoxic events (Lease et al., 2024) is the only known exposure of thermally immature (0.48–0.52% R o , random vitrinite reflectance) Hue Shale in Arctic Alaska. Strata comprise mainly clay-rich mudstone with elevated total organic carbon (TOC) and hydrogen index values reaching 26.3 wt% (mean = 7.5 wt%) and 689 mg hydrocarbon (HC)/g TOC (mean = 385 mg HC/g TOC), respectively. Maceral composition consists predominantly of fluorescent amorphous organic matter, with abundant brightly fluorescent alginite, including Tasmanites , acritarchs, and Leiosphaeridia . Discrete layers of volcanic ash (preserved as bentonite) are present throughout the section and provide quantitative age control based on U–Pb dates. Chemostratigraphic trends are investigated to advance our understanding of local oceanographic conditions and controls on stratigraphic and temporal heterogeneity of Brookian source rocks. Concurrent sedimentary enrichment in Mo, U, V, Pb, and Cu across the Albian–Cenomanian boundary of the exposed basal gamma-ray zone, may reflect anoxic to euxinic benthic redox conditions favoring organic matter accumulation and preservation. Fluctuating degrees of anoxia-euxinia are inferred throughout the overlying Hue Shale succession, reflected by varying patterns of TE enrichment and TE–TOC covariation. Elevated C org /P molar ratios (>250) across most of the section, with several values exceeding 690, signify that enhanced biological productivity is sustained throughout deposition. Enhanced productivity, recorded by both C org /P and excess Ba, also parallels increases in source rock richness (elevated TOC and S 2 values) during the late Albian–early Cenomanian and late Cenomanian – Turonian. Enhanced productivity and variations in oceanic circulation/stratification likely both drove changes in benthic redox conditions that favored organic carbon accumulation and preservation. Increased continental arc volcanism (e.g., Okhotsk–Chukotka volcanic belt) and High Arctic Large Igneous Province magmatic eruptions throughout the Cretaceous, inferred to have influenced nutrient cycling and local aqueous nutrient availability, also have been invoked as potential drivers of organic carbon burial and source-rock development across the sedimentary sequence. Results presented here document the organic-rich and oil-prone source-rock quality of the Hue Shale in the distal part of the Colville foreland basin and bolster the potential for a Cretaceous petroleum system beneath the eastern North Slope.
The Shublik Formation (Middle to Upper Triassic) is a heterogeneous unit that is a major hydrocarbon source rock in northern Alaska and the largest known Triassic phosphate accumulation in the world. This formation, which occurs in the subsurface and crops out within the Arctic Alaska basin, was deposited on a gently sloping ramp along the northwestern Laurentian margin. In this study, we document spatial and temporal facies variations within the Shublik and the overlying Karen Creek Sandstone (Upper Triassic) through 19 outcrop localities in the northeastern Brooks Range. New organic and inorganic geochemical data from these localities support and extend our sedimentologic and petrographic findings. The petrographic data come from an analysis of more than 900 thin sections, whereas age constraints come mainly from species of the pelecypod genera Daonella , Halobia , Eomonotis , and Monotis . Thirteen sites make up a main outcrop belt within which facies of the Shublik are spatially consistent but show marked vertical changes. Six additional outcrops located south of the main belt contain more distal facies of the Shublik that accumulated farther from land. Exposures of the Shublik Formation in its main outcrop belt are divisible into five informal lithologic units, each of which formed during a distinct transgressive to regressive sequence. The basal unit of the Shublik (Anisian? to Ladinian; Middle Triassic) is quartz siltstone to very fine grained sandstone that is locally phosphatic. The three middle units (Ladinian to middle Norian; Middle to Upper Triassic) contain various proportions of siliciclastic, carbonate, phosphatic, and organic material. The uppermost unit (middle to upper Norian; Upper Triassic) is mainly shale and mudstone. Highly phosphatic strata (10–34 percent phosphorus pentoxide) are chiefly Ladinian and lower to middle Norian. Highly phosphatic Ladinian strata have been transported, are granular, and formed during transgression and early regression. In contrast, highly phosphatic Norian strata include event beds and hardgrounds, contain displaced and in situ phosphate peloids and nodules, and cap regressive parasequences. The total organic content reaches 4.97 weight percent in the main belt and is highest in muddy beds, which are found mainly in the lower parts of the three middle units. Distal sections of the Shublik are typically finer grained, more organic-rich (total organic content as high as 6.33 weight percent), and less fossiliferous than those in the main belt. Both temporal and spatial factors shaped facies in the Shublik Formation. Shublik strata accumulated at a time of reduced tectonic activity in Arctic Alaska, resulting in diminished siliciclastic input. Marine upwelling along the northwestern Laurentian margin facilitated the development of heterozoan carbonates, as well as local concentrations of phosphatic and organic matter. Large- and small-scale eustatic cycles also affected this margin and provided further controls on Shublik facies distribution.
Using a geology-based assessment methodology, the U.S. Geological Survey estimated mean volumes of 1.8 billion barrels of oil and 119.9 trillion cubic feet of gas technically recoverable from undiscovered, conventional accumulations in Cretaceous and Cenozoic strata of the North Chukchi Basin.
The middle Cretaceous greenhouse period experienced profound environmental change including episodes of enhanced global burial of organic carbon marked by carbon isotopic excursions (CIEs). However, the role and response of polar regions like the newly formed, partially enclosed Arctic Ocean Basin during middle Cretaceous carbon burial remains enigmatic. We present the first Arctic deepwater CIE record that characterizes conditions offshore of the Alaska margin north of 75°N paleolatitude. Organic carbon isotopes (δ 13 C org ) and 103–82 Ma ash zircon U-Pb dates from the distal Hue Shale record multiple Albian–Campanian CIEs during slow ∼3–15 m/Myr sediment accumulation rates. Average total organic carbon (TOC) increased substantially during large 2–3 ‰ CIEs of the ∼101 Ma Albian-Cenomanian boundary event (from 7 to 18 % TOC) and ∼94 Ma Cenomanian-Turonian boundary event (5 to 10 % TOC). Turonian TOC remained elevated (8–13 %) during high global sea levels and temperatures of the Cretaceous Thermal Maximum, followed by an increase from 7 to 11 % TOC during the ∼90 Ma late Turonian event 1.5 ‰ CIE. Average TOC subsequently decreased in the Coniacian–Campanian, but relative maxima occurred during subtle 0.5–1 ‰ CIEs interpreted as the ∼87 Ma late Coniacian event (increase from 4 to 7 % TOC), ∼85 Ma Horseshoe Bay event (3.5 to 4.5 % TOC), and ∼84 Ma Santonian-Campanian boundary event (3.5 to 5 % TOC). Increases in hydrogen index and productivity proxies (P, Ba, Nd) that accompanied each CIE episode with enhanced TOC suggest a strong link between marine productivity and organic carbon burial at short-term CIE timescales. However, long-term (>5–8 Myr) changes in trace metal redox (Mo, Fe, V) and salinity (B/Ga) proxies suggest shifts in prevailing environmental conditions at timescales longer than the CIEs. Late Albian–middle Turonian marine salinity occurred during euxinic (103–98 Ma) and suboxic (98–90 Ma) conditions with deposition interpreted to have occurred within and beneath an oxygen minimum zone, respectively. In contrast, late Turonian–early Campanian (90–82 Ma) freshening and restricted euxinic basin conditions may signal the start of widespread restriction known to characterize the Paleogene Arctic. Overall, these results highlight that middle Cretaceous Arctic deepwater remained a productive marine carbon sink coupled to the global carbon cycle despite evolving Arctic greenhouse conditions.
The Shublik Formation (Middle and Upper Triassic) is a mixed siliciclastic-carbonate-phosphatic unit in northern Alaska. It generated oil found in Prudhoe Bay and other accumulations and is a prospective self-sourced resource play on Alaska’s North Slope. Its distal, deeper-water equivalent—the Otuk Formation—consists largely of radiolarian chert, mudstone, and limestone and contains potential gas accumulations in the Brooks Range foothills to the south. New petrographic, fossil, geochemical, spectral gamma-ray, and zircon U-Pb data yield insights into facies changes in these units, which were deposited across a shallowly dipping shelf margin in a high-latitude setting. Samples come from four localities along a transect that extends ~410 km from present-day northeast (proximal) to southwest (distal) in northwest Alaska. Proximal Shublik facies (Brontosaurus 1 well) contain abundant siliciclastic detritus and local phosphate. Shublik-Otuk transitional facies occur in the probable onshore extension of the Hanna Trough (Surprise Creek); new zircon U-Pb data indicate an early Norian age for a bentonite bed in this section. Distal Otuk facies (Red Dog district, Cape Lisburne) are fine grained, biosiliceous, and organic rich. New detrital zircon U-Pb data from a distinctive sandstone member in the Otuk Formation at Cape Lisburne reinforce previous interpretations of a provenance to the present-day northwest and indicate a protracted history of Triassic magmatism for this source area. Triassic facies patterns in northwestern Alaska were shaped by sea-level change, climate, and regional tectonism. Organic-rich facies developed best at times (Ladinian–middle Norian) and/or in settings (distal shelf, Hanna Trough) with minimal dilution of organic matter by other detritus.
Using a geology-based assessment methodology, the U.S. Geological Survey estimated a mean of 1,407 billion (1.4 trillion) cubic feet of gas in conventional accumulations in Upper Devonian to Lower Cretaceous strata of the western North Slope, Alaska.
Using a geology-based assessment methodology, the U.S. Geological Survey estimated undiscovered, technically recoverable mean resources of 3.6 billion barrels of oil and 8.9 trillion cubic feet of natural gas (associated and nonassociated) in conventional accumulations in Mississippian through Paleogene strata in the central North Slope of Alaska.
Recent work on cores and outcrops of the Middle-Upper Triassic Shublik Formation has facilitated surface to subsurface correlation of depositional sequences across the Alaska North Slope. Five transgressive-regressive depositional sequences have been defined within three large-scale stratigraphic units. Outcrop spectral gamma-ray (GR) profiles were used to correlate observed stacking patterns with nearby exploration wells, and GR logs from 161 exploration wells were used to correlate the three large-scale stratigraphic units across the North Slope and nearby offshore. Interpretations of depositional facies and sequence stratigraphy in cores from 26 wells were used to corroborate regional correlations. Isochore maps constructed for each of the three stratigraphic units illustrate the influence of accommodation on depositional patterns and suggest reactivation of several older tectonic elements during Shublik deposition. An isochore map of the richest, oil-prone interval of the Shublik Formation reveals a thick pod south of Harrison Bay, the eastern part of which lies beneath a recent giant Shublik-sourced oil discovery in the Cretaceous Nanushuk Formation. In addition, when integrated with thermal maturity, this isochore map may provide leads for areas that are optimal for unconventional resource exploration.
Using a geology-based assessment methodology, the U.S. Geological Survey assessed mean undiscovered, technically recoverable continuous resources of 1.5 billion barrels of oil and 4.6 trillion cubic feet of gas in the Upper Cretaceous Tuscaloosa marine shale in onshore and State waters of Louisiana, Mississippi, Alabama, and Florida in the U.S. Gulf Coast region.
Using a geology-based assessment methodology, the U.S. Geological Survey estimated mean undiscovered, technically recoverable continuous resources of 10.7 trillion cubic feet of natural gas in Upper Devonian shales of the Appalachian Basin Province.
The Triassic Shublik Formation and the Triassic–Jurassic Otuk Formation are partially age-equivalent lithostratigraphic units that were deposited in the Arctic Alaska Basin (AAB). The Shublik Formation represents proximal deposition within the basin, with episodic siliciclastic input, whereas the Otuk Formation was deposited in the distal part of the basin, with significant intervals of mudstone and chert. Both the Shublik and Otuk Formations have significant intervals of organic-rich mudstone, and the Shublik is a major source rock for northern Alaska hydrocarbon accumulations such as Prudhoe Bay. The revised stratigraphic framework presented herein, based on the integration of lithostratigraphy and biostratigraphy, correlates intervals within these two formations, as well as the Ivishak Formation and the Karen Creek and Sag River Sandstones (which underlie and overlie the Shublik). This stratigraphic framework provides a basis for comparison of proximal and distal parts of the AAB through the Triassic, thus allowing for a more robust understanding of the spatial and temporal variability of lithology and organic richness within this basin. Five transgressive–regressive sequences are defined in the Shublik, based on lithostratigraphy and better age constraints provided by the revised stratigraphic framework. These sequences are age-correlative and recognized in other Arctic basins, implying that they have regional, and perhaps global, significance.
The U.S. Geological Survey (USGS) completed an assessment of undiscovered, technically recoverable unconventional petroleum resources in the Upper Cretaceous marine shale of the Tuscaloosa Group (Tuscaloosa marine shale; TMS) in 2018. As part of the geologic characterization in preparation for the assessment, a series of wireline log cross sections were constructed to illustrate TMS thickness trends and aid in the delineation of the assessment unit (AU). Lithostratigraphic units were correlated based on gamma ray, spontaneous potential, and resistivity log responses and generally follow the classic stratigraphic nomenclature first proposed in the 1960s. Correlated stratigraphic units include (from youngest to oldest) the Austin Group, Eagle Ford Shale, upper Tuscaloosa, Tuscaloosa marine shale, lower Tuscaloosa, and Lower Cretaceous. A high resistivity zone (HRZ) in the basal Tuscaloosa marine shale was delineated where resistivity was greater than 5 ohm-meters and high resistivity sections were separated by less than 20 feet of low resistivity shale. The HRZ was identified regionally and might indicate petroleum accumulations in the TMS. Third-party biostratigraphic data from wells in Mississippi and Louisiana were integrated into the well control, which aided wireline log correlation. Cross sections depict east-west thinning of the TMS onto the Sabine uplift and north-south thickening of the TMS off of the Lower Cretaceous shelf margin. The western boundary of the USGS-defined Tuscaloosa Marine Shale Continuous Oil AU was drawn in western Louisiana near the Texas-Louisiana state border based on stratigraphic thinning of the Upper Cretaceous section onto the structural high of the Sabine uplift as projected downdip.
As part of the U.S. Geological Survey’s 2018 hydrocarbon assessment of the Eagle Ford Group and associated Cenomanian-Turonian strata, a series of regional wireline-log cross sections were constructed to examine geologic characteristics of this stratigraphic interval across the Texas Gulf Coast from Mexico to Louisiana. The cross sections were used to help define six continuous assessment units based, in part, on stratigraphic thickness, lateral extent, and lithology. The locations of the strike and dip cross sections were selected to address questions pertinent to the hydrocarbon assessment. Stratigraphic correlation of the Eagle Ford Group and corresponding Cenomanian-Turonian mudstones has been debated for many years, and differences in interpretations remain. Formation tops published in the literature, from IHS Markit TM , as well as information from a commercial biostratigraphic database were used to define consistent criteria to construct these cross sections from interpreted wireline logs. Specific units of interest include the Austin Chalk, upper and lower Eagle Ford Group, mudstones of the Woodbine Group, and the Buda Limestone. Wireline gamma-ray (GR) logs through the Eagle Ford Group have values greater than 100 American Petroleum Institute (API) units in several areas of this study, including the Maverick Basin, the Karnes Trough, and the Brazos Basin. High GR values in mudstones may be interpreted to represent potential organic-rich intervals. These high GR zones provide a criterion to identify the lateral variability in potential Cenomanian-Turonian source rock intervals from South Texas to the Texas-Louisiana border.
The U.S. Geological Survey estimated mean undiscovered, technically recoverable resources of 8.7 billion barrels of oil and 25 trillion cubic feet of natural gas (associated and nonassociated) in conventional accumulations in the Cretaceous Nanushuk and Torok Formations in the National Petroleum Reserve in Alaska, adjacent State and Native lands, and State waters. The estimated undiscovered oil resources in the Nanushuk and Torok Formations are significantly higher than previous estimates, owing primarily to recent, larger than anticipated oil discoveries.
Recent oil production from the Upper Cretaceous Tuscaloosa marine shale (TMS) has elevated the formation, previously assessed by the USGS in 2011 as part of the Eagle Ford Group, to its own distinct assessment unit for an upcoming assessment. Geologic characterization in preparation for the 2017 assessment has included the analysis of rock samples and produced oils, and the interpretation of well logs and biostratigraphic data. Results include new mapped extents of the reservoir, which reaches a maximum thickness of almost 500 feet in southern Mississippi and central Louisiana, and geochemical interpretations which support a self-sourced origin for high gravity (36-48 API) low sulfur oil. Programmed pyrolysis and petrography indicate the TMS contains dominantly Type III gas-prone kerogen with some Type II oil-prone kerogen present in the most organic-rich samples. TMS samples contain an average of 47 weight percent total clays, had organic carbon content which ranged from 0.14 to 4.0 weight percent, and had a thermal maturity of 0.57 to 0.99 percent vitrinite reflectance in the productive area. These characteristics were the same for the TMS within an area defined as a “high resistivity zone” and outside of it. These results will be integral to the planned USGS assessment of the TMS.
Using a geology-based assessment methodology, the U.S. Geological Survey estimated mean undiscovered, technically recoverable continuous resources that total 464 million barrels of oil and 4.08 trillion cubic feet of gas in the Lower Mississippian Sunbury Shale and Middle Devonian–Lower Mississippian Chattanooga Shale of the Appalachian Basin Province.
Technically recoverable undiscovered hydrocarbon resources in continuous accumulations are present in Upper Devonian and Lower Mississippian strata in the Appalachian Basin Petroleum Province. The province includes parts of New York, Pennsylvania, Ohio, Maryland, West Virginia, Virginia, Kentucky, Tennessee, Georgia, and Alabama. The Upper Devonian and Lower Mississippian strata are part of the previously defined Devonian Shale-Middle and Upper Paleozoic Total Petroleum System (TPS) that extends from New York to Tennessee. This publication presents a revision to the extent of the Devonian Shale-Middle and Upper Paleozoic TPS. The most significant modification to the maximum extent of the Devonian Shale-Middle and Upper Paleozoic TPS is to the south and southwest, adding areas in Tennessee, Georgia, Alabama, and Mississippi where Devonian strata, including potential petroleum source rocks, are present in the subsurface up to the outcrop. The Middle to Upper Devonian Chattanooga Shale extends from southeastern Kentucky to Alabama and eastern Mississippi. Production from Devonian shale has been established in the Appalachian fold and thrust belt of northeastern Alabama. Exploratory drilling has encountered Middle to Upper Devonian strata containing organic-rich shale in west-central Alabama. The areas added to the TPS are located in the Valley and Ridge, Interior Low Plateaus, and Appalachian Plateaus physiographic provinces, including the portion of the Appalachian fold and thrust belt buried beneath Cretaceous and younger sediments that were deposited on the U.S. Gulf Coastal Plain.