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W. A. Duffield

Publications and source records attributed to W. A. Duffield.

At least 19 recordsLinked to original sources
USGS2012

Distribution of Quaternary rhyolite domes of the Coso Range, California: implications for extent of the geothermal anomaly.

38 separate domes and flows of phenocryst-poor, high-silica rhyolite of similar major element chemical composition were erupted over the past 1My from vents arranged in a crudely S-shaped array atop a granitic horst in the Coso Range, California. Most of the extrusions are probably less than about 0.3My old. The central part of the rhyolite field is characterized by high heat flow, low apparent resistivity, and substantial fumarolic activity indicative of an active geothermal system.

California↗
USGS2008

Effects of scoria-cone eruptions upon nearby human communities

Scoria-cone eruptions are typically low in volume and explosivity compared with eruptions from stratovolcanoes, but they can affect local populations profoundly. Scoria-cone eruption effects vary dramatically due to eruption style, tephra blanket extent, climate, types of land use, the culture and complexity of the affected group, and resulting governmental action. A comparison of a historic eruption (Parícutin, México) with prehistoric eruptions (herein we primarily focus on Sunset Crater in northern Arizona, USA) elucidates the controls on and effects of these variables. Long-term effects of lava flows extend little beyond the flow edges. These flows, however, can be used for defensive purposes, providing refuges from invasion for those who know them well. In arid lands, tephra blankets serve as mulches, decreasing runoff and evaporation, increasing infiltration, and regulating soil temperature. Management and retention of these scoria mulches, which can open new areas for agriculture, become a priority for farming communities. In humid areas, though, the tephra blanket may impede plant growth and increase erosion. Cultural responses to eruptions vary, from cultural collapse, through fragmentation of society, dramatic changes, and development of new technologies, to little apparent change. Eruptions may also be viewed as retribution for poor behavior, and attempts are made to mollify angry gods.

Geological Society of America Bulletin↗
USGS2002

Red Mountain volcano: A spectacular and unusual cinder cone in northern Arizona

Red Mountain, located in the Coconino National Forest of northern Arizona, 25 miles northwest of Flagstaff, is a volcanic cinder cone that rises 1,000 feet above the surrounding landscape. It is unusual in having the shape of a "U," open to the west, and in lacking the symmetrical shape of most cinder cones. In addition, a large natural amphitheater cuts into the cone's northeast flank. Erosional pillars called "hoodoos" decorate the amphitheater, and many dark mineral crystals erode out of its walls. Studies by U.S. Geological Survey (USGS) and Northern Arizona University scientists suggest that Red Mountain formed in eruptions about 740,000 years ago.

Arizona↗
USGS2001

The San Francisco volcanic field, Arizona

Northern Arizona's San Francisco Volcanic Field, much of which lies within Coconino and Kaibab National Forests, is an area of young volcanoes along the southern margin of the Colorado Plateau. During its 6-million-year history, this field has produced more than 600 volcanoes. Their activity has created a topographically varied landscape with forests that extend from the Pi?on-Juniper up to the Bristlecone Pine life zones. The most prominent landmark is San Francisco Mountain, a stratovolcano that rises to 12,633 feet and serves as a scenic backdrop to the city of Flagstaff.

Fact Sheet↗
USGS1999

A geochemical reconnaissance of the Alid volcanic center and geothermal system, Danakil depression, Eritrea

Geological and geochemical studies indicate that a high-temperature geothermal system underlies the Alid volcanic center in the northern Danakil depression of Eritrea. Alid is a very late-Pleistocene structural dome formed by shallow intrusion of rhyolitic magma, some of which vented as lavas and pyroclastic flows. Fumaroles and boiling pools distributed widely over an area of ~10 km2 on the northern half of Alid suggest that an active hydrothermal system underlies much of that part of the mountain. Geothermometers indicate that the fumarolic gases are derived from a geothermal system with temperatures >225??C. The isotopic composition of condensed fumarolic steam is consistent with these temperatures and implies that the source water is derived primarily from either lowland meteoric waters or fossil Red Sea water, or both. Some gases vented from the system (CO2, H2S and He) are largely magmatic in origin. Permeability beneath the volcanic center may be high, given the amount of intrusion-related deformation and the active normal faulting within the Danakil depression.Geological and geochemical studies indicate that a high-temperature geothermal system underlies the Alid volcanic center in the northern Danakil depression of Eritrea. Alid is a very late-Pleistocene structural dome formed by shallow intrusion of rhyolitic magma, some of which vented as lavas and pyroclastic flows. Fumaroles and boiling pools distributed widely over an area of approx. 10 km2 on the northern half of Alid suggest that an active hydrothermal system underlies much of that part of the mountain. Geothermometers indicate that the fumarolic gases are derived from a geothermal system with temperatures >225??C. The isotopic composition of condensed fumarolic steam is consistent with these temperatures and implies that the source water is derived primarily from either lowland meteoric waters or fossil Red Sea water, or both. Some gases vented from the system (CO2, H2S and He) are largely magmatic in origin. Permeability beneath the volcanic center may be high, given the amount of intrusion-related deformation and the active normal faulting within the Danakil depression.

Geothermics↗
USGS1998

A model that helps explain Sr-isotope disequilibrium between feldspar phenocrysts and melt in large-volume silicic magma systems

Feldspar phenocrysts of silicic volcanic rocks are commonly in Sr-isotopic disequilibrium with groundmass. In some cases the feldspar is more radiogenic, and in others it is less radiogenic. Several explanations have been published previously, but none of these is able to accommodate both senses of disequilibrium. We present a model by which either more- or less-radiogenic feldspar (or even both within a single eruptive unit) can originate. The model requires a magma body open to interaction with biotite- and feldspar-bearing wall rock. Magma is incrementally contaminated as wall rock melts incongruently. Biotite preferentially melts first, followed by feldspar. Such melting behavior, which is supported by both field and experimental studies, first contaminates magma with a relatively radiogenic addition, followed by a less-radiogenic addition. Feldspar phenocrysts lag behind melt (groundmass of volcanic rock) in incorporating the influx of contaminant, thus resulting in Sr-isotopic disequilibrium between the crystals and melt. The sense of disequilibrium recorded in a volcanic rock depends on when eruption quenches the contamination process. This model is testable by isotopic fingerprinting of individual feldspar crystals. For a given set of geologic boundary conditions, specific core-to-rim Sr-isotopic profiles are expectable. Moreover, phenocrysts that nucleate at different times during the contamination process should record different and predictable parts of the history. Initial results of Sr-isotopic fingerprinting of sanidine phenocrysts from the Taylor Creek Rhyolite are consistent with the model. More tests of the model are desirable.Feldspar phenocrysts of silicic volcanic rocks are commonly in Sr-isotopic disequilibrium with groundmass. In some cases the feldspar is more radiogenic, and in others it is less radiogenic. Several explanations have been published previously, but none of these is able to accommodate both senses of disequilibrium. We present a model by which either more- or less-radiogenic feldspar (or even both within a single eruptive unit) can originate. The model requires a magma body open to interaction with biotite- and feldspar-bearing wall rock. Magma is incrementally contaminated as wall rock melts incongruently. Biotite preferentially melts first, followed by feldspar. Such melting behavior, which is supported by both field and experimental studies, first contaminates magma with a relatively radiogenic addition, followed by a less-radiogenic addition. Feldspar phenocrysts lag behind melt (groundmass of volcanic rock) in incorporating the influx of contaminant, thus resulting in Sr-isotopic disequilibrium between the crystals and melt. The sense of disequilibrium recorded in a volcanic rock depends on when eruption quenches the contamination process. This model is testable by isotopic fingerprinting of individual feldspar crystals. For a given set of geologic boundary conditions, specific core-to-rim Sr-isotopic profiles are expectable. Moreover, phenocrysts that nucleate at different times during the contamination process should record different and predictable parts of the history. Initial results of Sr-isotopic fingerprinting of sanidine phenocrysts from the Taylor Creek Rhyolite are consistent with the model. More tests of the model are desirable.

Journal of Volcanology and Geothermal Research↗
USGS1996

Roof-rock contamination of Taylor Creek Rhyolite, New Mexico, as recorded in hornblende phenocrysts and biotite xenocrysts

The Taylor Creek Rhyolite, a group of coeval, mid-Tertiary, silica-rich rhyolite lava domes in southwestern New Mexico, is notable for recording bulk-rock evidence of minor, yet easily measurable, contamination of its source magma reservoir resulting from assimilation of Proterozoic roof rock. Most of the evidence is recorded in trace element concentrations and 87Sr/86Sri ratios, which are far different in unconlaminated magma and roof rocks. Hornblende phenocrysts and biotite xenocrysts also record the effects of contamination. Electron microprobe analyses show that all hornblende grains are zoned to Mg-rich and Fe- and Mn-poor rims. Rim MgO content is typically about 10 wt% greater than core MgO content. Other hornblende constituents are not measurably variable. Biotite xenocrysts, trace mineral constituents, are present only in the domes that are most contaminated, as judged by bulk-rock variations in trace element concentrations and 87Sr/ 86Sri. Biotite grains are invariably partly to almost completely altered. Microprobe analyses of the cores of the least-altered grains show that large variations in Fe and Mg and that biotite contains 2-20 times as much Mg as fresh biotite phenocrysts in other silica-rich rhyolite lavas. Fe and Mg are negatively correlated in hornblende and biotite, consistent with mixing two end-member compositions. The mass ratio of contaminant to magma was probably less than 1:100, and major constituents, including Al, were not measurably affected in hornblende. Al-in-hornblende barometry yields essentially a constant calculated pressure of about 1.5 kbar, which is consistent with the interpretation that all contamination occurred in a boundary zone about 300 m thick at the top of the magma reservoir.

American Mineralogist↗
USGS1995

Roof-rock contamination of magma along the top of the reservoir for the Bishop Tuff

The Bishop Tuff, a Quaternary high-silica rhyolite in east-central California, is widely considered the type example of a vertically and monotonically zoned pyroclastic deposit that represents zoning in the source magma reservoir, inverted during the process of pyroclastic emplacement. However, the deposit of plinian pumice, which forms the base of the Bishop Tuff and represents the initial 10% or so of all magma erupted during the event that produced the Bishop Tuff, contains features at odds with monotonic zoning for the reservoir. Relative to overlying ignimbrite, the plinian deposit contains a reversal in trace-element zoning. The data have been previously interpreted as due to processes of chemical fractionation and evolution operating within a magma system closed to chemical interactions with its roof rocks. However, it is suggested here that the reversed zoning and other above-noted features can be explained equally well as consequences of minor assimilation of roof rocks into a magma reservoir that was erupted from the top down. -from Authors

Journal of Volcanology and Geothermal Research↗
USGS1992

Compositional gradients in large reservoirs of silicic magma as evidenced by ignimbrites versus Taylor Creek Rhyolite lava domes

The Taylor Creek Rhyolite of southwest New Mexico consists of 20 lava domes and flows that were emplaced during a period of a few thousand years or less in late Oligocene time. Including genetically associated pyroclastic deposits, which are about as voluminous as the lava domes and flows, the Taylor Creek Rhyolite represents roughly 100 km3 of magma erupted from vents distributed throughout an area of several hundred square kilometers. Major-element composition is metaluminous to weakly peraluminous high-silica rhyolite and is nearly constant throughout the lava field. The magma reservoir for the Taylor Creek Rhyolite was vertically zoned in trace elements, 87Sr/86Sr, and phenocryst abundance and size. Mean trace-element concentrations, ranges in concentrations, and element-pair correlations are similar to many subalkaline silicic ignimbrites. However, the polarity of the zonation was opposite that in reservoirs for ignimbrites, for most constituents. For example, compared to the Bishop Tuff, only 87Sr/86Sr and Sc increased upward in both reservoirs. Quite likely, a dominant but nonerupted volume of the magma reservoir for the Taylor Creek Rhyolite was zoned like that for the Bishop Tuff, whereas an erupted, few-hundred-meter-thick cap on the magma body was variably contaminated by roof rocks whose contribution to this part of the magma system moderated relatively extreme trace-element concentrations of uncontaminated Taylor Creek Rhyolite but did not change the sense of correlation for most element pairs. The contaminant probably was a Precambrian rock of broadly granitic composition and with very high 87Sr/86Sr. Although examples apparently are not yet reported in the literature, evidence for a similar thin contaminated cap on reservoirs for large-volume silicic ignimbrites may exist in the bottom few meters of ignimbrites or perhaps only in the pumice fallout that normally immediately precedes ignimbrite emplacement. 87Sr/86Sr in sanidine phenocrysts of the Taylor Creek Rhyolite is higher than that of their host whole rocks. Covariation of this isotope ratio with sanidine abundance and size indicates positive correlations for all three features with decreasing distance to the roof of the magma reservoir. The sanidine probably is more radiogenic than host whole rock because growing phenocrysts partly incorporated Sr from the first partial melt of roof rocks, which contained the highly radiogenic Sr of Precambrian biotite ?? hornblende, whereas diffusion was too slow for sanidine to incorporate much of the Sr from subsequently produced less radiogenic partial melt of roof rocks, before eruption quenched the magma system. Disequilibrium between feldspar phenocrysts and host groundmass is fairly common for ignimbrites, and a process of contamination similar to that for the Taylor Creek Rhyolite may help explain some of these situations. ?? 1992 Springer-Verlag.

Contributions to Mineralogy and Petrology↗
USGS1992

Geology and geothermal potential of the Tecuamburro Volcano area, Guatemala

Tecuamburro, an andesitic stratovolcano in southeastern Guatemala, is within the chain of active volcanoes of Central America. Though Tecuamburro has no record of historic eruptions, radiocarbon ages indicate that eruption of this and three other adjacent volcanoes occurred within the past 38,300 years. The youngest eruption produced a dacite dome. Moreover, powerful steam explosions formed a 250 m wide crater about 2900 years ago near the base of this dome. The phreatic crater contains a pH-3 thermal lake. Fumaroles are common along the lake shore, and several other fumaroles are located nearby. Neutral-chloride hot springs are at lower elevations a few kilometers away. All thermal manifestations are within an area of about 400 km 2 roughly centered on Tecuamburro Volcano. Thermal implications of the volume, age, and composition of the post-38.3 ka volcanic rocks suggest that magma, or recently solidified hot plutons, or both are in the crust beneath these lavas. Chemical geothermometry carried out by other workers suggests that a hydrothermal-convection system is centered over this crustal heat source. Maximum temperatures of about 300°C are calculated for samples collected in the area of youngest volcanism, whereas samples from outlying thermal manifestations yield calculated temperatures ≤ <- 165° C "> 165°C . An 808 m deep drill hole completed in 1990 to partly test the geothermal model developed from surface studies attained a maximum temperature of almost 240°C. Thus, the possibility of a commercial-grade hydrothermal resource in the area seems high.

Tecuamburro Volcano↗
USGS1992

Evidence for the reversal of gradients in the uppermost parts of silicic magma reservoirs

Evidence from large-volume ignimbrites indicates that the source-magma reservoirs for most of these voluminous silicic pyroclastic deposits contained monotonic vertical chemical gradients at the time of eruption. However, gradients from a large-volume magma reservoir that produced a group of penecontemporaneous silicic lava domes, but no ignimbrite, show a reversal of the usual ignimbrite pattern. This reversal originated by modification of the usual pattern through minor assimilation of partially melted roof rocks. Eruptions that produced these domes apparently just tapped the uppermost part of their source reservoir. They thereby provide a high-resolution instantaneous view of this variably contaminated part of the magma system. Although not yet reported in the literature, similar reversals should be recorded in other groups of penecontemporaneous silicic domes and perhaps also in the lowermost parts of ignimbrites or in their underlying coeruptive Plinian deposits. The long-standing paradigm for monotonic zoning in large-volume reservoirs of silicic magma may require modification.

Geology↗