Van E. Shaw | USGS Science

USGS1977

Mercury in oil shale from the mahogany zone of the Green River formation, eastern Utah and western Colorado

Mercury has been reported in concentrations as high as 4 parts per million from oil shale in the Green River Formation near the Federal oil-shale prototype lease-tracts U-a and U-b in eastern Utah. This high concentration of mercury if present throughout a minable zone, would be of concern in commercial oil-shale operations processing large volumes of shale. Using an improved analytical method, surface samples from eastern Utah previously reported to contain high concentrations of mercury were reanalyzed, and an additional 183 drill core samples from the Mahogany zone and adjacent beds were analyzed. The reanalyzed samples averaged slightly more than 0.35 ppm mercury and the drill-core samples averaged 0.37 ppm. The products from a Fischer assay of 100-gram sample of oil shale, found to yield 35 gallons pier ton of oil and 43 ppm of mercury, were analyzed for their mercury content. The spent shale contained only 2 percent of the total mercury in the assay products and the gas fraction contained about 58 percent.

Colorado, Utah↗

USGS1974

Distribution and occurrence of rare earths in the thorium veins on Hall Mountain, Idaho

Rare earths, although equal to or more abundant than thorium in many thorium veins, are much less abundant than thorium in the veins on Hall Mountain, Idaho. Total rare-earth content of these veins ranges from 0.00111 to 0.197 percent in 12 samples from 10 veins; the thoria (ThO 2 ) content, from 0.011 to 5.84 percent. The rare-earth oxide to thoria ratios range from 0.0019 to 3.22. Only two samples contained more rare earths than thorium, and these two samples came from veins related to a fault near the base of a thick sill; the others came from veins near the top of the same sill. The relative amounts of the individual lanthanides are remarkably similar in the Hall Mountain veins, although cerium, gadolinium, or dysprosium are the most abundant in different samples. These veins differ in lanthanide distribution both from the Earth's crust and from the thorium veins of the Lemhi Pass district, Idaho and Montana, in that they contain chiefly yttrium-group rare earths. Most of the rare earths occur in thorite, whose atomic structure will accommodate wide-ranging proportions of the rare earths. Cenosite, one of the few minerals with a high content of the yttrium group of rare earths, was found in one vein.

Idaho↗