USGS ScienceSearch

Geology topics

V.D. Cvetkovic

Publications and source records attributed to V.D. Cvetkovic.

4 recordsLinked to original sources

A solute flux approach to transport in heterogeneous formations: 2. Uncertainty analysis

Uncertainty in the mass flux for advection dominated solute movement in heterogeneous porous media is investigated using the Lagrangian framework developed in paper 1 by Dagan et al. (this issue). Expressions for the covariance of the mass flux and cumulative mass flux are derived as functions of the injection volume and sampling area size relative to the scale of heterogeneity. The result is illustrated for solute advection in three types of heterogeneous porous media: stratified formations, two‐ and three‐dimensional porous media; small perturbation approximation is used for the two‐ and three‐dimensional cases. Variances of the mass flux and cumulative mass flux are evaluated as functions of the injection volume (area) scale versus log‐hydraulic conductivity integral scale. The greatest decrease in coefficient of variation (CV) of the mass flux is for the source scale 1–5 times the hydraulic conductivity integral scale; further increase in the source size decreases CV comparatively less. The variance of the cumulative mass flux (or total discharge) indicates that for the source size of 20 hydraulic conductivity integral scales, the transport conditions are almost ergodic. The present results also indicate that the cumulative mass flux is a relatively robust quantity for describing field‐scale solute transport.

Water Resources Research

A solute flux approach to transport in heterogeneous formations: 1. The general framework

It is common to represent solute tranport in heterogeneous formations in terms of the resident concentration C (x, t), regarded as a random space function. The present study investigates the alternative representation by q , the solute mass flux at a point of a control plane normal to the mean flow. This representation is appropriate for many field applications in which the variable of interest is the mass of solute discharged through a control surface. A general framework to compute the statistical moments of q and of the associated total solute discharge Q and mass M is established. With x the direction of the mean flow, a solute particle is crossing the control plane at y = η, z = ζ and at the travel (arrival) time τ. The associated expected solute flux value is proportional to the joint probability density function (pdf) g 1 of η, ζ and τ, whereas the variance of q is shown to depend on the joint pdf g 2 of the same variables for two particles. In turn, the statistical moments of η, ζ and τ depend on those of the velocity components through a system of stochastic ordinary differential equations. For a steady velocity field and neglecting the effect of pore‐scale dispersion, a major simplification of the problem results in the independence of the random variables η, ζ and τ. As a consequence, the pdf of η and ζ can be derived independently of τ. A few approximate approaches to derive the statistical moments of η, ζ and τ are outlined. These methods will be explored in paper 2 in order to effectively derive the variances of the total solute discharge and mass, while paper 3 will deal with the nonlinear effect of the velocity variance upon the moments of η, ζ and τ

Water Resources Research

Stochastic analysis of solute arrival time in heterogeneous porous media

Longitudinal advective solute movement in heterogeneous porous media is investigated by considering the solute arrival time at a plane perpendicular to the mean fluid velocity. The moments of the solute arrival time are defined in terms of the stochastic properties of a statistically anisotropic hydraulic conductivity field. The flux‐averaged concentration is specified by introducing the moments of the arrival time into a probability density function for the arrival time. The quadratic dependence of the arrival time variance on position in the vicinity of an injection point is indicative of a nondiffusive process. For the assumed spatial correlation of the hydraulic conductivity, the variance of the arrival time asymptotically approaches a linear dependence on the position from the injection point similar to a diffusion process. The impact of assuming solute movement to be a diffusive process from the onset of the solute injection causes erroneous estimates of flux‐averaged concentrations at distances from the injection point that are of the order of the correlation length of the hydraulic conductivity. The arrival time analysis and the particle position analysis given in Dagan (1982, 1984) are complementary interpretations of advective solute movement that yield different definitions of the solute concentration; the position analysis intrinsically defines the resident or volume‐averaged concentration, while the flux‐averaged concentration is defined from the arrival time analysis. The temporal variation of the resident and flux‐averaged concentration are similar at a given position for small values of the variance of the hydraulic conductivity, or at distances from the solute injection point that are large relative to correlation length of the hydraulic conductivity.

Water Resources Research

Solute advection in stratified formations

Advection‐dominated solute movement in stratified formations is investigated using a Lagrangian interpretation of particle motion. A probability density function (pdf) for particle position quantifies the expected depth‐integrated resident concentration. A pdf for particle arrival time quantifies the expected depth‐integrated rate of mass arrival, from which the flux‐averaged concentration can be defined. The difference between the flux‐averaged and resident concentrations is shown to be significant for the variability in the hydraulic conductivity that is commonly encountered in field applications. The influence of porosity variations on the advection‐dominated solute movement in stratified porous media is shown to be notable only for large variability in the effective porosity.

Water Resources Research