Mineralogy and chemistry of samples from a drill hole in the southern extension of the land-pebble phosphate district, Florida
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Geology topics
Publications and source records attributed to Theodore Botinelly.
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Magnetic concentrates from 106 localities in three plutons of syenite and one pluton of shonkinite in the southern Asir were analyzed spectrographically for 31 elements to determine if anomaly-enhancement techniques would identify mineralization not disclosed by conventional geochemical sample media. Positive anomalies are lacking for all elements except vanadium. Vanadium contents as high as 0.7 percent were identified in magnetic concentrates from the syenite pluton to the southeast of Suq al Ithnayn, but magnetite is sparse. This observation indicates a need to reexamine magnetite-rich drill core for possible ore-grade tenors in vanadium from the zoned pluton at Lakathah. Experimental analyses for platinum-group metals in magnetic concentrates from layered mafic plutons at Jabal Sha'i', Jabal al Ashshar, and Hishshat al Hawi should be performed to determine whether micron-size particles of the platinum-group metals are present in mafic rocks of the Arabian Shield.
Samples of massive sulfide layers show an enrichment in many minor and trace elements in the central part of layers. Comparison of trace element contents of massive sulfides, magnetite, and disseminated sulfides suggests differences in origin. Trace element contents of samples from various mines suggest regional variations.
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Minerals of the alunite-jarosite, beudantlte, and plumbogummite groups can be divided on the basis of iron or aluminum content into two groups which are consistent in optical and X-ray characteristics. Both chemical and X-ray data are needed for identification.
Ocher occurs widely In the Montezuma district as small sinters and as bedded deposits of bog iron and ocher-cemented conglomerates. The iron of the ochers is derived from pyrite-rich veins and from pyritic hydrothermally altered rocks. Trace amounts of ore metals in the ocher and its admixed detritus are partly from the pyritic source rocks but also include contributions from other rocks and ores in the watershed, both during and after formation of the ocher deposit. Ocher is evidence for the presence and character of the generally ill exposed pyritic rocks, which are important, in evaluating the porphyry-metal system of ore deposits. The trace-element composition of the ocher is at best a qualitative guide to the ore metals present in the provenance of the ocher deposit but not to their abundance or necessarily to their mode of occurrence.
The Montezuma mining district, in the Colorado mineral belt, is defined by an assemblage of porphyry, ore, and altered rocks that originated in the venting of a Tertiary batholith through weak structures in Precambrian rocks. The ore consists of silver-lead-zinc veins clustered on the propylitic fringe of a geometrically complex system of altered rocks, which is centered on the intersection of the Oligocene Montezuma stock with the Montezuma shear zone of Precambrian ancestry. Alteration chemistry conforms to the standard porphyry-metal model but is developed around several small intrusives strung out along the shear zone and is expressed as a mottled pattern, rather than as the usual thick concentric zones centered on one large plug. The distribution of trace amounts of molybdenite is consistent with the postulate of molybdenite deposits in the district, but the mottled alteration pattern may signify small and scattered, possibly very deep, deposits. Disseminated molybdenite is essentially coextensive with altered rock and increases slightly in quantity toward the inner alteration zones. Two groups of molybdenite veins, associated with phyllic and potassic alteration, represent possible diffuse halos of molybdenite deposits. One group of veins resembles the Climax and Henderson deposits but was seen only in a small and isolated area of outcrops. The second group of molybdenite veins is in a bismuth-rich part of the Montezuma stock and underlies an area of bismuth veins; this group records the passage of contact metasomatic ore fluids. Another bismuth-rich area is in the southeast corner of the stock in a region of bismuth veins and may indicate a third group of molybdenite veins.
The first reported occurrence in the United States of galkhaite (Hg,Cu,Tl,Zn)(As,Sb)S 2 is at the Getchell mine, Humboldt County, Nev. The mineral occurs as brownish-black cubes associated with graphite, pyrite, and realgar. In polished section galkhaite is grayish white and isotropic with a deep-red internal reflection; reflectivity at 590 nm is 21.6 percent. Spectrographic analysis gave Hg 42 percent, Cu 5 percent, Zn 1.5 percent, Fe 0.7 percent, Tl 5 percent, As 24 percent, Sb 0.3 percent, and S (by difference) 21.3 percent. The mineral is cubic, a=10.36, and the strong lines of the X-ray powder pattern are 2.99 (100), 4.21 (90), 2.76 (80), 1.831 (70), 7.25 (60), 2.58 (40), 1.561 (40). The pattern is very similar to that of tetrahedrite except for the strong lines at 7.25, 4.21, and 2.76.
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