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T.L. Vallier

Publications and source records attributed to T.L. Vallier.

At least 19 recordsLinked to original sources

Subalkaline andesite from Valu Fa Ridge, a back-arc spreading center in southern Lau Basin: petrogenesis, comparative chemistry, and tectonic implications

Tholeiitic andesite was dredged from two sites on Valu Fa Ridge (VFR), a back-arc spreading center in Lau Basin. Valu Fa Ridge, at least 200 km long, is located 40-50 km west of the active Tofua Volcanic Arc (TVA) axis and lies about 150 km above the subducted oceanic plate. One or more magma chambers, traced discontinuously for about 100 km along the ridge axis, lie 3-4 km beneath the ridge. The mostly aphyric and glassy lavas had high volatile contents, as shown by the abundance and large sizes of vesicles. An extensive fractionation history is inferred from the high SiO2 contents and FeO* MgO ratios. Chemical data show that the VFR lavas have both volcanic arc and back-arc basin affinities. The volcanic arc characteristics are: (1) relatively high abundances of most alkali and alkaline earth elements; (2) low abundances of high field strength elements Nb and Ta; (3) high U/Th ratios; (4) similar radiogenic isotope ratios in VFR and TVA lavas, in particular the enrichment of 87Sr 86Sr relative to 206Pb 204Pb; (5) high 238U 230Th, 230Th 232Th, and 226Ra 230Th activity ratios; and (6) high ratios of Rb/Cs, Ba/Nb, and Ba/La. Other chemical characteristics suggest that the VFR lavas are related to MORB-type back-arc basin lavas. For example, VFR lavas have (1) lower 87Sr 86Sr ratios and higher 143Nd 144Nd ratios than most lavas from the TVA, except samples from Ata Island, and are similar to many Lau Basin lavas; (2) lower Sr/REE, Rb/Zr, and Ba/Zr ratios than in arc lavas; and (3) higher Ti, Fe, and V, and higher Ti/V ratios than arc lavas generally and TVA lavas specifically. Most characteristics of VFR lavas can be explained by mixing depleted mantle with either small amounts of sediment and fluids from the subducting slab and/or an older fragment of volcanic arc lithosphere. The eruption of subalkaline andesite with some arc affinities along a back-arc spreading ridge is not unique. Collision of the Louisville and Tonga ridges probably activated back-arc extension that ultimately led to the creation and growth of Valu Fa Ridge. Some ophiolitic fragments in circum-Pacific and circum-Tethyan allochthonous terranes, presently interpreted to have originated in volcanic arcs, may instead be fragments of lithosphere that formed during early stages of seafloor spreading in a back-arc basin. ?? 1991.

Chemical Geology↗

Petrology and age of volcanic-arc rocks from the continental margin of the Bering Sea: Implications for Early Eocene relocation of plate boundaries

Eocene volcanic flow and dike rocks from the Beringian margin have arc characteristics, implying a convergent history for this region during the early Tertiary. The extrusive rocks are basalt, basaltic andesite, andesite, and minor dacite and rhyolite. The intrusive sample is from a quartz diorite dike intruding serpentinized peridotite. Major-element oxide contents, particularly FeO*/MgO versus SiO 2 , identify both tholeiitic and calc-alkalic basalt; more silicic lavas have calc-alkalic affinities. Consistent with volcanic-arc compositions, spidergrams show pronounced Nb–Ta depletion and alkali enrichment relative to light-rare-earth-element ( LREE ) abundance. Chondrite-normalized REE plots show relatively flat patterns, with only slight LREE enrichment for tholeiitic compositions and greater LREE enrichment and lower heavy-rare-earth-element ( HREE ) abundance for calc-alkalic compositions. The samples, particularly those with calc-alkalic compositions, are rich in plagioclase that is strongly zoned; the more silicic samples contain orthopyroxene, clinopyroxene, and primary amphibole. The quartz diorite dike contains iron-rich almandine phenocrysts that appear to be magmatic, suggesting emplacement at great depth near the base of the crust or upper mantle.Chemical and mineralogical compositions are similar to those of modern Aleutian-arc lavas. They also resemble volcanic-arc compositions from western mainland Alaska, although greater chemical diversity and a stronger continental influence are observed in the Alaskan mainland rocks.Early Eocene ages of 54.4–50.2 Ma for the Beringian samples are well constrained by conventional K–Ar ages of nine plagioclase separates and by concordant 40 Ar/ 39 Ar incremental heating and total-fusion experiments. A concordant U–Pb zircon age of 53 Ma for the quartz-diorite dike is in good agreement with the K–Ar data.Plate motion studies of the North Pacific Ocean indicate more northerly directed subduction prior to the Tertiary and a continuous belt of arc-type volcanism extending from Siberia, along the Beringian margin, into mainland Alaska. Around 56 Ma (chron 25–24), subduction changed to a more westerly direction and subduction-related volcanism ceased for most of mainland Alaska. The increasingly oblique angle of convergence should have ended subduction along the Beringian margin as well. However, consistent ages of 54–50 Ma indicate a final pulse in arc-type magmatism during this period of plate adjustment, which may be explained by three different models: (1) The northern and central part of the Beringian margin maintained a higher angle of convergence, allowing a final pulse of arc-type magmatism. (2) The rocks erupted in an early, or proto, Aleutian arc and were rafted against the continental margin along transform faults. (3) The rocks erupted along a leaky transform fault, analogous to calc-alkalic volcanism in the southern California borderland.

Alaska↗

Speculations on the petroleum geology of the accretionary body: an example from the central Aleutians

In the 300 km wide Adak-Amlia sector of the central Aleutian Trench ??? 36 000 km3 of offscraped trench fill makes up the wedge-shaped mass of the Aleutian accretionary body. Within this wedge, seismic reflection profiles reveal an abundance of potential hydrocarbon-trapping structures. These structures include antiforms, thrust and normal faults, and stratigraphic pinchouts. Maximum closure on these features is 2 km. In addition, the silt and possibly sand size sediment within the offscraped turbidite deposits, and the porous diatomaceous pelagic deposits interbedded with and at the base of the wedge, may define suitable reservoirs for the entrapment of hydrocarbons. Potential seals for these reservoirs include diagenetically-altered and -produced siliceous and carbonate sediment. The organic carbon input into the central Aleutian Trench, based on carbon analyses of DSDP Legs 18 and 19 core samples, suggests that the average organic carbon content within the accretionary body is approximately 0.3-0.6%. Heat flow across the Aleutian Terrace indicates that at present the oil generation window lies at a depth of 3-6.5 km. At depths of 8 km (which corresponds to the maximum depth the offscraped sediment has been seismically resolved beneath the lower trench slope), the probable high (170-180??C) temperatures prohibit all but gas generation. The dewatering of trench sediment and subducted oceanic crust should produce an abundance of fluids circulating within the accretionary body. These fluids and gases can conduct hydrocarbons to any of the abundant trapping geometries or be lost from the system through sea floor seepage. In the Aleutian accretionary body all the conditions necessary for the formation of oil and gas deposits exist. The size and ultimate preservation of these deposits, however, are dependent on the deformational history of the prism both during accretion and after the accretion process has been superceded by subsequent tectonic regimes. ?? 1984.

Marine and Petroleum Geology↗

Multiple microtektite horizons in upper Eocene marine sediments: No evidence for mass extinctions

Microtektites have been recovered from three horizons in eight middle Eocene to middle Oligocene marine sediment sequences. Five of these occurrences are coeval and of latest Eocene age (37.5 to 38.0 million years ago); three are coeval and of early late Eocene age (38.5 to 39.5 million years ago); and three are of middle Oligocene age (31 to 32 million years ago). In addition, rare probable microtektites have been found in sediments with ages of about 36.0 to 36.5 million years. The microtektite horizon at 37.5 to 38.0 million years can be correlated with the North American tektite-strewn field, which has a fission track age (minimum) of 34 to 35 million years and a paleomagnetic age of 37.5 to 38.0 million years. There is no evidence for mass faunal extinctions at any of the microtektite horizons. Many of the distinct faunal changes that occurred in the middle Eocene to middle Oligocene can be related to the formation of the Antarctic ice sheet and the associated cooling phenomena and intensification of bottom currents that led to large-scale dissolution of calcium carbonate and erosion, which created areally extensive hiatuses in the deep-sea sediment records. The occurrence of microtektite horizons of several ages and the lack of evidence for faunal extinctions suggest that the effects of extraterrestrial bolide impacts may be unimportant in the biologic realm during middle Eocene to middle Oligocene time.

Science↗

Sedimentation and deformation in the Amlia Fracture Zone sector of the Aleutian Trench

A wedge-shaped, landward thickening mass of sedimentary deposits composed chiefly of terrigenous turbidite beds underlies the west-south west-trending Amlia sector (172°20′–173°30′W) of the Aleutian Trench. Pacific oceanic crust dips northward beneath the sector's sedimentary wedge and obliquely underthrusts (30° off normal) the adjacent Aleutian Ridge. The trench floor and subsurface strata dip gently northward toward the base of the inner trench slope. The dip of the trench deposits increases downsection from about 0.2° at the trench floor to as much as 6–7° just above basement. The wedge is typically 2–2.5 km thick, but it is thickest (3.7–4.0 km) near the base of the inner slope overlying the north-trending Amlia Fracture Zone and also east of this structure. Slight undulations and relatively abrupt offsets of the trench floor reflect subsurface and generally west-trending structures within the wedge that are superimposed above ridges and swales in the underlying oceanic basement. The southern or seaward side of some of these structures are bordered by high-angle faults or abrupt flexures. Across these offsets the northern side of the trench floor and underlying wedge is typically upthrown. West-flowing turbidity currents originating along the Alaskan segment of the trench (1200 km to the east) probably formed the greater part of the Amlia wedge during the past 0.5 m.y. The gentle northward or cross-trench inclination of the trench floor and underlying wedge probably reflects regional downbending of the oceanic lithosphere and trench-floor basement faulting and rotation. Much of the undulatory flexuring of the trench wedge can be attributed to differential compaction over buried basement relief. However, abrupt structural offsets attest to basement faulting. Faulting is associated with extensional earthquakes in the upper crust. The west-trending basement offsets are probably normal faults that dip steeply south or antithetic to the north dip of the subducting oceanic crust. Up-to-arc extensional faulting can be attributed to the downbending of the Pacific plate into the Aleutian subduction zone. The rupturing direction and dip is controlled by zones of crustal weakness that parallel north Pacific magnetic anomalies, which were formed south of a late Cretaceous—early Tertiary spreading center (Kula—Pacific Ridge). The strike of these anomalies is fortuitously nearly parallel to the Amlia sector. The up-to-arc fracturing style may locally assist in elevating blocks of trench deposits to form the toe of the trench's landward slope, which is in part underlain by a compressionally thickened accretionary mass of older trench deposits. Compressional structures that can be related to underthrusting are only indistinctly recorded in the turbidite wedge that underlies the trench floor.

Alaska↗

The geologic history of the Mid-Pacific Mountains in the central North Pacific Ocean; A synthesis of deep-sea drilling studies

The Mid-Pacific Mountains constitute one of the largest aseismic rises in the central North Pacific Ocean. They have been generated by mid-plate volcanic events prior to Barremian time, but their volcanic activity continued through the remainder of the Cretaceous. Evidence of the latest stages of this volcanism are the trachytic ashes included in mid- and Late Cretaceous sediments and the presence of guyots atop the main volcanic pedestal. The thermal and volcanic history of the oldest part of the Pacific Plate and its plate tectonic movements since Cretaceous time have led to considerable horizontal and vertical movements of the Mid-Pacific Mountains. Reconstruction of their subsidence and evidence from the sediments from Site 463 suggest that they once, in Cretaceous time, constituted large, tropical volcanic islands which were covered by vegetation and which shed their erosional debris over the adjacent island slopes. Neritic fossils in Maastrichtian sediments document the presence of shoal areas until the end of the Mesozoic. Since then they have subsided to their present water depth. The horizontal movements of the Pacific Plate have carried the Mid-Pacific Mountains from a position well south of the Cretaceous equator to their present position under the unproductive surface waters of the subtropical central North Pacific Ocean. Site 463, on the western Mid-Pacific Mountains, probably crossed the equator in Maastrichtian time. Shallow-water-derived calcareous fossils are incorporated into the pelagic sediments covering the Mid-Pacific Mountains. They have been displaced from their source areas along the flanks of seamounts over the adjacent regions during times of low sea-level stands. Debris of land plants in Aptian sediments documents the presence of emergent volcanoes during that time. The pelagic sediments penetrated at Site 463 consist largely of a sequence of Cretaceous chalks, limestones, and cherts which accumulated fast and which document the presence of highly productive surface water masses around the former volcanic islands and above the shoals. The development of oxygen-deficient depositional environments and the lack of evidence for intensive reworking suggest at the same time very sluggish water movements in the meso- and bathypelagic environment during Early and mid-Cretaceous times. The Cenozoic calcareous oozes, on the other hand, are very condensed. They are interrupted in several places by hiatuses, and despite their position well above the CCD they show effects of dissolution and poor preservation of the calcareous faunas and floras. The frequency of reworked pelagic material together with the hiatuses indicate episodes of intensive renewal of the meso- and bathypelagic water masses which generated intensive sea-floor erosion and which were probably triggered by the climatic deterioration in the polar regions

Initial Reports of the D.S.D.P.↗